02-Stoichiometric Calculations (1).ppt

1
Stoichiometric Calculations
朱信
Hsin Chu
Professor
Dept. of Environmental Engineering
National Cheng Kung University

2
1. Applications of the Combustion
Equation
• (1) Stoichiometric proportions for finding
the correct air supply rate for a fuel
(2) Composition of the combustion products
is useful during the design, commissioning
and routine maintenance of a boiler
installation
• On-site measurements of flue gas composition
and temperature are used as a basis for
calculating the efficiency of the boiler at
routine maintenance intervals.

3
2. Combustion Air Requirements: Gaseous
Fuels
• Calculating the air required for gaseous fuels
combustion is most convenient to work on a
volumetric basis.
• The stoichiometric combustion reaction of
methane is :
CH4 + 2O2 → CO2 + 2H2O
which shows that each volume (normally 1 m3)
of methane requires 2 volumes of oxygen to
complete its combustion.

4
• If we ignore the components which are
present in the parts per million range, air
consists of about 0.9% by volume argon,
78.1% nitrogen and 20.9% oxygen (ignoring
water vapor). Carbon dioxide is present at
0.038%.
• For the purposes of combustion calculations
the composition of air is approximated as a
simple mixture of oxygen and nitrogen:
oxygen 21%
nitrogen 79%

5
• The complete relationship for stoichiometric
combustion:
CH4 + 2O2 + 7.52N2 → CO2 + 2H2O +7.52N2
as the volume of nitrogen will be 2×79÷21=7.52.
• A very small amount of nitrogen is oxidized but the
resulting oxides of nitrogen (NOX) are not formed in
sufficient quantities to concern us here.
However, they are highly significant in terms of air
pollution.

6
• It can be seen that the complete combustion
of one volume of methane will require
(2+7.52=9.52) volumes of air, so the
stoichiometric air-to-fuel (A/F) ratio for
methane is 9.52.
• In practice it is impossible to obtain complete
combustion under stoichiometric conditions.
Incomplete combustion is a waste of energy
and it leads to the formation of carbon
monoxide, an extremely toxic gas, in the
products.

7
• Excess air is expressed as a percentage
increase over the stoichiometric
requirement and is defined by:
• Excess air will always reduce the efficiency
of a combustion system.
/ /
100%
/
actual A F ratio stoichiometric A F ratio
stoichiometric A F ratio



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• It is sometimes convenient to use term
excess air ratio, defined as:
• Where sub-stoichiometric (fuel-rich) air-
to-fuel ratios may be encountered, for
instance, in the primary combustion zone of
a low-NOX burner, the equivalence ratio is
often quoted. This is given by:
/
/
actual A F ratio
/
/
actual A F ratio

9
3. Flue Gas Composition-Gaseous
Fuels
• The composition of the stoichiometric
combustion products of methane is:
1 volume CO2
7.52 volumes N2
2 volumes H2O
• Given a total product volume, per volume of
fuel burned, of 10.52 if water is in the vapor
phase, or 8.52 if the water is condensed to a
liquid.
The two cases are usually abbreviated to “wet”
and “dry”.

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• The proportion of carbon dioxide in this mixture is
therefore
• The instruments used to measure the composition
of flue gases remove water vapor from the mixture
and hence give a dry reading, so the dry flue gas
composition is usually of greater usefulness.
1
100% 9.51% and
10.52
1
100% 11.74%
8.52
wet
dry
 
 

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• Considering the combustion of methane with 20%
excess air, the excess air (0.2×9.52) of 1.9 volumes
will appear in the flue gases as (0.21×1.9)=0.4 volumes
of oxygen and (1.9-0.4)=1.5 volumes of nitrogen.
• The complete composition will be:
constituent vol/vol methane
CO2 1
O2 0.4
N2 9.02
H2O 2
giving a total product volume of 12.42 (wet) or 10.42
(dry).

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• The resulting composition of the flue
gases, expressed as percentage by
volume, is:
Constituent % vol (dry) % vol (wet)
CO2 9.6 8.1
O2 3.8 3.2
N2 86.6 72.6
H2O – 16.1

13
• Example 1:
A gas consists of 70% propane (C3H8) and 30%
butane (C4H10) by volume. Find:
(a) The stoichiometric air-to-fuel ratio and
(b) The percentage excess air present if a dry
analysis of the combustion products shows 9%
CO2 (assume complete combustion).
• Solution:
The combustion reactions for propane and butane are:
3 8 2 2 2 2 2
5 18.8 3 4 18.8
C H O N CO H O N
    
4 10 2 2 2 2 2
6.5 24.5 4 5 24.5
C H O N CO H O N
    

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• (a) Stoichiometric Air Requirement
On the basis of 1 volume of the fuel gas,
the propane content requires
0.7 × (5 + 18.8) = 16.7 vols air
and the butane requires
0.3 × (6.5 + 24.5) = 6.3 vols air
Hence the stoichiometric air-to-fuel
ratio is 23:1.

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• (b) Excess Air
The combustion products (dry) will contain
(0.7 × 3) + (0.3 × 4) = 3.3 vols CO2
(0.7 × 18.8) + (0.3 × 24.5) = 20.5 vols N2
plus υ volumes excess air, giving a total volume of products of
(23.8 + υ ).
• Given that the measured CO2 in the products is 9%, we can write:
hence υ = 12.87 vols
• The stoichiometric air requirement is 23 vols so the percentage excess
air is:
9 3.3
100 (23.8 )



12.87
100% 55.9%
23
 

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4. Combustion Air Requirements-Solid
and Liquid Fuels
• The way in which the combustion equation is used
reflects the available information on the analysis of
the solid or liquid fuels.
This takes the form of an element-by-element
analysis (referred to as an ultimate analysis) which
gives the percentage by mass of each element
present in the fuel.
• An example of an ultimate analysis of a liquid fuel (oil)
might be :
Component % by mass
Carbon (C) 86
Hydrogen(H2) 14

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• Each constituent is considered separately via its own
combustion equation.
For the carbon:
C + O2 → CO2
12kg 32kg 44kg
or for 1 kg of fuel
• So each kg of oil requires 2.29 kg oxygen for
combustion of its carbon and produces 3.15 kg CO2 as
product.
32 44
0.86 0.86 0.86 (kg)
12 12
   

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• Similarly
H2 + ½ O2 → H2O
2kg 16kg 18kg
or per kg of fuel
• In order to burn the hydrogen content of the
oil 1.12 kg oxygen are needed and 1.26 kg
water is formed.
16 18
0.14 0.14 0.14 (kg)
2 2
   

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• The total oxygen requirement is thus (2.29 + 1.12) or
3.41 kg.
A given quantity of air consists of 21% by volume of
oxygen.
• We can simply transform to a mass basis thus:
Component vol fraction(vf) vf × MW Mass fraction
Oxygen 0.21 6.72
Nitrogen 0.79
6.72
0.233
28.84

22.12
28.84
22.12
0.767
28.84


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• We can now establish that 3.41 kg oxygen,
which is the stoichiometric requirement, will
be associated with:
• The stoichiometric air-to-fuel ratio is thus
3.41 + 11.23 = 14.6 : 1
0.767
3.41 11.23 kg nitrogen
0.233
 

21
5. Combustion Products-Solid and Liquid
Fuels
• The stoichiometric combustion products from
combustion of the oil are:
CO2 3.15 kg
H2O 1.26 kg
N2 11.23 kg
• The combustion products would normally be
needed as a volume percentage, so the
reverse operation to that which was
performed for air above is required.

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• Hence if we require a dry volume percentage
of the above products the following tabular
procedure is convenient:
Component Mass/kg fuel kmoles/kg fuel mole fraction
CO2 3.15 0.151
N2 11.23 0.849
• The stoichiometric combustion products are
thus 15.1% CO2 and 84.9% N2.
3.15
0.0716
44

11.23
0.4011
28
0.4727


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• Solid fuels, and many liquid fuels, contain
compounds of sulfur. For the purposes of
stoichiometric calculations this is assumed to
burn to sulfur dioxide:
S + O2 → SO2
• In reality a mixture of sulfur dioxide and
sulfur trioxide (SO3) is produced, but it is
conventional to assume combustion to SO2
when calculating air requirements.

24
• Solid fuels and some oils produce ash when they burn.
The percentage of ash in the fuel is part of the
ultimate analysis and, as far as we are concerned at
the moment, ash is simply treated as a totally inert
substance.
• Many solid fuels contain small amounts of oxygen and
nitrogen. The oxygen present in the fuel is
considered to be available for burning the carbon,
hydrogen and sulfur present.
The nitrogen in the fuel is taken to appear as gaseous
nitrogen in the combustion products.

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• Example 2: Combustion Calculation for a Coal
A coal has the following ultimate analysis:
% by mass
Carbon 90
Hydrogen 3
Oxygen 2.5
Nitrogen 1
Sulfur 0.5
Ash 3
Calculate:
(a) the volumetric air supply rate required if 500 kg/h of coal
is to be burned at 20% excess air and
(b) the resulting %CO2 (dry) by volume in the combustion
products.

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• Solution:
Lay out the calculation on a tabular basis using 1 kg coal:
Mass (per kg) O2 Required Products
Carbon 0.9
Hydrogen 0.03
Sulfur 0.005
Oxygen 0.025 -0.025 -
Nitrogen 0.01 - 0.01
Ash 0.03 - -
32
0.9 2.4
12
 
16
0.03 0.24
2
 
32
0.005 0.005
32
  64
0.005 0.01
32
 
18
0.03 0.27
2
 
44
0.9 3.3
12
 

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• (a) Oxygen required to burn 1 kg coal = 2.4 +
0.24 + 0.005 - 0.025 = 2.62 kg.
Air required =
Actual air supplied = 11.25 × 1.2 = 13.5 kg
Assuming a density for air of 1.2 kg/m3,
the flow rate will be:
2.62
11.25 kg
0.233

3
500
13.5 1.56 m /s
1.2 3600
 


28
• (b) To get the %CO2 in the combustion products we
need to know the amounts of oxygen and nitrogen
in the flue gases.
Air supplied = 13.5 kg per kg coal, of which
oxygen is
13.5 × 0.233 = 3.14 kg, and nitrogen
13.5 – 3.14 = 10.36 kg.
• The combustion products will thus contain:
3.14 – 2.62 = 0.52 kg O2 and
10.36 + 0.01 = 10.37 kg N2.

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• A second tabular procedure can now be used for the volumetric
composition of the flue gases:
Product Mass/kg coal Mol. Wt. kmoles/kg coal %volume
CO2 3.3 44 0.075=(3.3/44) 16.25=(0.075/0.4614)
SO2 0.01 64 0.000156 0.03
O2 0.52 32 0.0162 3.51
N2 10.37 28 80.20
0.37
0.4614

30
6. Practical Significance of the Flue Gas
Composition
• It is comparatively easy to make on-site
measurements of the dry volumetric concentration of
either carbon dioxide or oxygen in the flue gases.
• Either of these measurements can be used to
calculate the air-to-fuel ratio (or excess air) if the
composition of the fuel is known and the combustion
of the fuel is complete.
• The volume percentage of oxygen or carbon dioxide in
the flue gas will be influenced by the level of excess
air and also by the carbon:hydrogen ratio present in
the fuel.

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• If pure carbon is burnt, the only combustion product is
carbon dioxide, so each molecule of oxygen in the
combustion air becomes a molecule of carbon dioxide in
the flue gas.
This means that the stoichiometric combustion of carbon
will produce 21% by volume CO2.
• If we consider for the moment that hydrocarbon fuels
consist only of carbon and hydrogen, as the
carbon:hydrogen ratio of the fuel decreases the
stoichiometric air-to-fuel ratio will increase.
This is because 1 kg carbon requires 32/12=2.67 kg of
oxygen for complete combustion but 1 kg hydrogen
requires 8 kg oxygen.

32
• The percentage CO2 in the flue gases will fall as the
carbon:hydrogen ratio in the fuel decreases as
(1) less carbon dioxide will be produced per kilogram
of fuel and
(2) the increased air requirement means that the
carbon dioxide produced will be diluted by the
extra nitrogen in the flue gas.
• This effect is illustrated in Table 2.1 (next slide).
The carbon:hydrogen ratio in fuels lie between the
limits of 75:25 (methane) to around 95:5 (high carbon
coals).

33
Table 2.1 Carbon dioxide concentraton in flue
gases
C : H (by mass) Satoichiometric %CO2
100 0
95 5
90 10
85 15
80 20
75 25
70 30
65 35
21.00
18.67
16.62
14.81
13.19
11.73
10.42
9.23

34
• Next slide (Fig. 2.1)
There is a unique relationship between
the composition of the flue gas and the
excess air for any given fuel.

36
• Next Slide (Fig. 2.2)
A plot of the percentage CO2 in the flue
gases over a range of values of excess
air for C:H ratios ranging from 75:25 to
95:5.
The curves for fuels with higher C:H
ratios lie above those for fuels with a
lower value of this ratio.

02-Stoichiometric Calculations (1).ppt

38
• Next Slide (Fig. 2.3)
The relationship between the
percentage oxygen in the flue gas and
the excess air is very similar for a wide
range of fuels.
This is different from the CO2 curves.

40
• Take the combustion of two “extreme” cases: one kmole of carbon
and one kmole of methane. In each case we will consider 100%
excess air.
• The combustion of carbon under these conditions is described by:
C+ 2 O2 + 7.52 N2 → CO2 + O2 + 7.52 N2
The percentage of oxygen in the flue gas is thus:
[1/(1+1+7.52)]×100%=10.5%
• The corresponding equation for methane is
CH4 + 4 O2 + 15.05 N2 → CO2 +2 H2O +2 O2 +15.05 N2
giving a percentage oxygen of
[2/(1+2+15.05)]×100%=11%

41
7. Sub-stoichiometric Combustion
• There are circumstances in which localized fuel-rich combustion
can take place, such as where combustion of the fuel is a two-
stage process with secondary air added downstream of the
primary combustion zone.
• The mechanism of combustion of a fuel with less than the
stoichiometric air requirement consists of the following
sequence of events:
(1) The available oxygen firstly burns all the hydrogen in the
fuel to water vapor.
(2)All the carbon in the fuel is then burned to carbon
monoxide.
(3)The remaining oxygen is consumed by burning carbon
monoxide to carbon dioxide.

42
• Next slide (Fig. 2.4)
It can be seen that as the air supply
falls below the stoichiometric
requirement the percentage of carbon
monoxide in the flue gas increases very
quickly.

Air fuel ratio
Figure 2.4 Sub-stiochiometric combustion of natural gas

44
• Example 3: Combustion of a Fuel under Sub-
Stoichiometric Conditions
Estimate the wet and dry flue gas composition if
propane is burned with 95% of the stiochiometric air
requirement.
• Solution:
the stoichiometric reaction for this fuel is
C3H8 + 5 O2 → 3 CO2 + 4H2O
On a volumetric basis we have (5 × 0.95)=4.75
volumes of O2 available. This means that the
accompanying nitrogen is 17.87 volumes.

45
• Firstly all the hydrogen in the fuel is burned
to water.
This will produce 4 volumes of water vapor
and consume 2 volumes of oxygen, leaving
2.75 volumes for further combustion of the
carbon in the fuel.
• We assume that all the carbon initially burns
to carbon monoxide and then the remaining
oxygen is used in burning the carbon
monoxide to carbon dioxide.

46
• Burning the carbon to CO will produce 3 volumes of
CO and use up 1.5 volumes of oxygen, leaving (2.75-
1.5)=1.25 volumes of oxygen for further combustion.
• Next reaction is
CO + ½ O2 → CO2
So 1.25 volumes oxygen can burn 2.5 volumes of
carbon monoxide, producing 2.5 volumes of carbon
dioxide.
• The remaining carbon monoxide is therefore
(3-2.5)=0.5 volume.

47
• The products of combustion are thus:
N2 17.87 volumes
CO 0.5
CO2 2.5
H2O 4.0
Total 24.87
• Giving the percentage compositions:
Wet(%) Dry(%)
N2 71.9 85.6
CO 2.0 2.4
CO2 10.0 12.0
H2O 16.1 -

02-Stoichiometric Calculations (1).ppt

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