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Getting Data From Spectra
First Lets Make Sure:
We Are All On The Same Page
Bruce Phebus
What you should have:
If you don’t you are way Behind!
• Wavelengths calculated for all the peaks
on your spectrum
• Peaks assigned to R and P branches
J” & J’ values assigned to each peak.
• All your data organized, labeled, and given
to your lab partners.
Ahh now to Linest!
What are we doing to today?
• We will calculate all of our constants!
ωe ωexe Be α
• We will have reduced mass, μ, for each of
our isotopes H79Br & H81Br
• Isotopic abundance Br 79 is 50.7%
• Isotopic abundance Br 81 is 49.3%
Label 79 and 81 peaks
• Uncertainties as well
What are we doing to today
continued…
• We will calculate all of our constants!
k = The spring constant
De
o = Dissociation Energy
Re = Bond length
• Shaowei’s slides have the equations!
“Data Analysis and Lab Report”
• Note k and k the Boltzmann constant are
not the same even though they look it on
his slides!
Questions Ask Them!
• Make sure you keep up with
the pace of the class as we
don’t meet often falling behind
one day means falling behind a
week!
• Do Differential Error Prop Now!
On the Subject of Reff’s:
• You need to look up references for
your reports
–They are a graded portion of your
report
• A hint for the HBr report “T.A. Ford”
– Very handy but you can’t use the reference.
– “A third year chemistry project” doesn’t count
as citation worthy science. You figure it out.
Next Week:
• You should not be doing data
analysis you should be writing
and making certain your data
is correct.

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3) Getting Numbers from that Data

  • 1. Getting Data From Spectra First Lets Make Sure: We Are All On The Same Page Bruce Phebus
  • 2. What you should have: If you don’t you are way Behind! • Wavelengths calculated for all the peaks on your spectrum • Peaks assigned to R and P branches J” & J’ values assigned to each peak. • All your data organized, labeled, and given to your lab partners.
  • 3. Ahh now to Linest!
  • 4. What are we doing to today? • We will calculate all of our constants! ωe ωexe Be α • We will have reduced mass, μ, for each of our isotopes H79Br & H81Br • Isotopic abundance Br 79 is 50.7% • Isotopic abundance Br 81 is 49.3% Label 79 and 81 peaks • Uncertainties as well
  • 5. What are we doing to today continued… • We will calculate all of our constants! k = The spring constant De o = Dissociation Energy Re = Bond length • Shaowei’s slides have the equations! “Data Analysis and Lab Report” • Note k and k the Boltzmann constant are not the same even though they look it on his slides!
  • 6. Questions Ask Them! • Make sure you keep up with the pace of the class as we don’t meet often falling behind one day means falling behind a week! • Do Differential Error Prop Now!
  • 7. On the Subject of Reff’s: • You need to look up references for your reports –They are a graded portion of your report • A hint for the HBr report “T.A. Ford” – Very handy but you can’t use the reference. – “A third year chemistry project” doesn’t count as citation worthy science. You figure it out.
  • 8. Next Week: • You should not be doing data analysis you should be writing and making certain your data is correct.