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Fuel crisis in the world
 Conventional sources of energy -
  facing extinction

 Pollution from the fossil fuel
  products burnt everyday.

 Rise in the prices of diesel and
  petrol
ARTIFICIAL PETROL



                         -Anshul Gupta
                       Lokesh Pathrabe
               Institute of Technology,
         Nirma University, Ahmedabad.
Hydrogen: The present scenario

 Abundant in nature.


 Batteries powered by hydrogen can deliver higher
 power and longer lifetime.

 If used as a fuel, would reduce the carbon emissions
 to a great extent.
Properties that make it an
 efficient fuel
 Wide range of flammability


 Low ignition energy


 High auto ignition temperature


 High diffusivity
Problems with hydrogen
 Storage of hydrogen in high pressure low temperature
  condition could cause premature ignition.

 Hydrogen + air mixture is highly inflammable.


 Due to low ignition energy, the hot gases and the hot
  spots on the cylinder can serve as sources of ignition.

 lean operation can reduce the power output due to a
  reduction in the volumetric heating value of the air/fuel
  mixture.
The new technique
 Ammonium hydride is used as a source of hydrogen.


 Hydride is trapped in micro-beads that are manufactured by
  electrospinning.

 Hydrogen is released from hydride compound by
  Thermolysis.

 The consumed hydride can be sent for rehydrogenation for
  further use.
Role of Ammonia Borane
 H3NBH3 is more hydrogen dense than liquid hydrogen.


 Hydrogen can be easily disassociated from the remaining
  material.

 Exists in normal temperatures and pressures.


 As a solid it is easily transportable.


Therefore, it has attracted attention as a source of
 hydrogen fuel.
Micro – beads
 Micro-beads are uniform
  polymer particles of size
  0.5 micron to 500 micron in
  diameter.

 Micro-beads are used for
  isolation and handling of
  specific material or molecules.

 Here polystyrene is used as
  polymer to manufacture micro-
  beads.
Why micro-beads ?
 Nano-porous polymer speeds up the kinetics of hydrogen
 desorption.
•Reduces the temperature of desorption.

•Filters out many of the damaging chemicals
( Borazine and Ammonia).

• It protects the hydrides from oxygen and water,
making it possible to handle it in air.



These micro-beads can be manufactured by
co-axial electrospinning.
Coaxial electrospinning
Design for use in the vehicles
Regeneration of Ammonia Borane
Artificial petrol hydrogen ppt
Changes in the gasoline engine
design
   Engine material

   Avoiding Pre-ignition of hydrogen

    Improving the fuel injection system
    Thermal dilution system

   A disk-shaped combustion chamber
   Properly ventilation
Efficiency of H2 engines
Case of Emissions




 Emissions of hydrogen engine       Emissions of a gasoline engine
H + N2 + O2         ->        H2O + N2 + Nox
2H2 + O2 ->             2H2O
Phi=(Stoichiometric A/F ratio)/( actual A/F ratio)
Coal based Thermal power
plant
Hydrogen based power plant
Artificial petrol hydrogen ppt
Other Applications and Scope
 Batteries powered by hydrogen can deliver higher power and
  longer lifetime.

 For use as a fuel additive to reduce the carbon emissions from
  a hydrocarbon fuel such as gasoline, diesel, JP-8, jet-fuel or
  kerosene.

 Thousands of high pressure hydrogen fueling stations will not
  need to be built to accommodate hydrogen cars. Slight
  modifications of current fueling stations will be needed only.


This solution could accelerate the introduction and acceptance
  of hydrogen cars on a wide scale very quickly.
References
 Adsorption of Methane and Hydrogen on Mesocarbon
  Microbeads by Experiment and Molecular Simulation
Xiaohong Shao and Wenchuan Wang.

 Core-Shell Nanofibers: Nano Channel and Capsule by Coaxial
  Electro spinning
Fengyu Li1, 2, Yong Zhao1 and Yanlin Song1
1Institute of Chemistry Chinese Academy of Sciences, Beijing.

 Thermally induced hydrogen release from ammonia-borane
  studied by coupled Calorimetric, volumetric, spectrometric
  and thermo kinetics analysis techniques
R. André, E. Wirth, P. Leparlouër
 Fabrication of structured micro and nanofibers by coaxial
  Electro spinning.
Juan Esteban Díaz1, Alberto Fernández-Nieves2, Antonio
  Barrero1, 3, ManuelMárquez4 and Ignacio G.
  Loscertales1.
 Ammonia-Borane and Related N-B-H Compounds and
  Materials: Safety Aspects, Properties and Applications
Clinton F. Lane Department of Chemistry and Biochemistry
  Northern Arizona University.
       Separation of Polystyrene Microbeads Using
  Dielectrophoretic/Gravitational Field-Flow-Fractionation
Xiao-Bo Wang, Jody Vykoukal, Frederick F. Becker, and
  Peter R. C. Gascoyne.
 cella energy limited website.
Thank you

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Artificial petrol hydrogen ppt

  • 1. Fuel crisis in the world  Conventional sources of energy - facing extinction  Pollution from the fossil fuel products burnt everyday.  Rise in the prices of diesel and petrol
  • 2. ARTIFICIAL PETROL -Anshul Gupta Lokesh Pathrabe Institute of Technology, Nirma University, Ahmedabad.
  • 3. Hydrogen: The present scenario  Abundant in nature.  Batteries powered by hydrogen can deliver higher power and longer lifetime.  If used as a fuel, would reduce the carbon emissions to a great extent.
  • 4. Properties that make it an efficient fuel  Wide range of flammability  Low ignition energy  High auto ignition temperature  High diffusivity
  • 5. Problems with hydrogen  Storage of hydrogen in high pressure low temperature condition could cause premature ignition.  Hydrogen + air mixture is highly inflammable.  Due to low ignition energy, the hot gases and the hot spots on the cylinder can serve as sources of ignition.  lean operation can reduce the power output due to a reduction in the volumetric heating value of the air/fuel mixture.
  • 6. The new technique  Ammonium hydride is used as a source of hydrogen.  Hydride is trapped in micro-beads that are manufactured by electrospinning.  Hydrogen is released from hydride compound by Thermolysis.  The consumed hydride can be sent for rehydrogenation for further use.
  • 7. Role of Ammonia Borane  H3NBH3 is more hydrogen dense than liquid hydrogen.  Hydrogen can be easily disassociated from the remaining material.  Exists in normal temperatures and pressures.  As a solid it is easily transportable. Therefore, it has attracted attention as a source of hydrogen fuel.
  • 8. Micro – beads  Micro-beads are uniform polymer particles of size 0.5 micron to 500 micron in diameter.  Micro-beads are used for isolation and handling of specific material or molecules.  Here polystyrene is used as polymer to manufacture micro- beads.
  • 9. Why micro-beads ?  Nano-porous polymer speeds up the kinetics of hydrogen desorption.
  • 10. •Reduces the temperature of desorption. •Filters out many of the damaging chemicals ( Borazine and Ammonia). • It protects the hydrides from oxygen and water, making it possible to handle it in air. These micro-beads can be manufactured by co-axial electrospinning.
  • 12. Design for use in the vehicles
  • 15. Changes in the gasoline engine design  Engine material  Avoiding Pre-ignition of hydrogen  Improving the fuel injection system  Thermal dilution system  A disk-shaped combustion chamber  Properly ventilation
  • 16. Efficiency of H2 engines
  • 17. Case of Emissions Emissions of hydrogen engine Emissions of a gasoline engine H + N2 + O2 -> H2O + N2 + Nox 2H2 + O2 -> 2H2O Phi=(Stoichiometric A/F ratio)/( actual A/F ratio)
  • 18. Coal based Thermal power plant
  • 21. Other Applications and Scope  Batteries powered by hydrogen can deliver higher power and longer lifetime.  For use as a fuel additive to reduce the carbon emissions from a hydrocarbon fuel such as gasoline, diesel, JP-8, jet-fuel or kerosene.  Thousands of high pressure hydrogen fueling stations will not need to be built to accommodate hydrogen cars. Slight modifications of current fueling stations will be needed only. This solution could accelerate the introduction and acceptance of hydrogen cars on a wide scale very quickly.
  • 22. References  Adsorption of Methane and Hydrogen on Mesocarbon Microbeads by Experiment and Molecular Simulation Xiaohong Shao and Wenchuan Wang.  Core-Shell Nanofibers: Nano Channel and Capsule by Coaxial Electro spinning Fengyu Li1, 2, Yong Zhao1 and Yanlin Song1 1Institute of Chemistry Chinese Academy of Sciences, Beijing.  Thermally induced hydrogen release from ammonia-borane studied by coupled Calorimetric, volumetric, spectrometric and thermo kinetics analysis techniques R. André, E. Wirth, P. Leparlouër
  • 23.  Fabrication of structured micro and nanofibers by coaxial Electro spinning. Juan Esteban Díaz1, Alberto Fernández-Nieves2, Antonio Barrero1, 3, ManuelMárquez4 and Ignacio G. Loscertales1.  Ammonia-Borane and Related N-B-H Compounds and Materials: Safety Aspects, Properties and Applications Clinton F. Lane Department of Chemistry and Biochemistry Northern Arizona University.  Separation of Polystyrene Microbeads Using Dielectrophoretic/Gravitational Field-Flow-Fractionation Xiao-Bo Wang, Jody Vykoukal, Frederick F. Becker, and Peter R. C. Gascoyne.  cella energy limited website.