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03/13/25
seminar
on
Atomic and Ionic Radii,
Bond length and Measurement of Radius
presented by
SOORAJ.B
1st sem Applied Geology
Mysore University…..
Submitted to
Dr.G.S.Gopalakrishna, Professor
DOS.Earth Science
Mysore university
03/13/25
CONTENTS
INTRODUCTION
ATOMIC RADII
ATOMIC RADII TREND
IONS
IONIC RADII
BOND LENGTH AND MEASUREMENTS
CONCLUSION
REFERENCE
03/13/25
INTRODUCTION
Crystallography is the branch of science which deals with all the
aspects of crystals, that is, their formation from the melts, internal
structure and external shape or morphology. An elementary
knowledge of crystallography is essential for all those who have to
deal with minerals in one way or another such as mining engineers,
civil engineers and engineering geologist
ATOM
●
Atom is a basic unit of matter that consists of a dense central
nucleus surrounded by a cloud of negatively charged electrons.
The atomic nucleus contains a mix of positively charged protons
and electrically neutral neutrons .
●
The electrons of an atom are bound to the nucleus by the
electromagnetic force.
●
An atom containing an equal number of protons and electrons is
electrically neutral, otherwise it has a positive charge if there are
fewer electrons or negative charge if there are more electrons
Atomic and Ionic Radii, Bond length and Measurement of Radius.ppt
Rutherford model of an Atom
Dalton’s Atomic Theory
●
All matter is composed of extremely small particles called atoms.
●
All atoms of a given element are identical in size, mass, and other
properties. Atoms of different elements differ in size, mass, and
other properties.
●
Atoms cannot be subdivided, created, or destroyed.
●
Atoms of different elements can combine in simple, whole-number
ratios to form compounds.
●
In chemical reactions, atoms are combined, separated, or
rearranged.
03/13/25
ATOMIC RADII
The atomic radius of an element is basically the size
of the atom.
We can determine the atomic radius by finding half
the length between the nucleus’ of two atoms of the
same elements.
Atomic and Ionic Radii, Bond length and Measurement of Radius.ppt
03/13/25
ATOMIC RADII TREND
03/13/25
GRAPH…
03/13/25
The size of atoms (and therefore the atomic radii) increase as we go
down groups on the periodic table (since more energy levels are
added), but as we go to the right, the size decreases because…
Electrons are being added to the same shell, which does not change
the size of the atom, but protons are also being added to the nucleus,
which pulls the electrons inwards towards the center, decreasing the
radius.
Ion
●
An ion is an atom or molecule in which the total number of
electrons is not equal to the total number of protons, giving it a
net positive or negative electrical charge.
●
The name was given by physicist Michael Faraday for the
substances that allow a current to pass ("go") between electrodes
in a solution, when an electric field is applied.
●
An ion consisting of a single atom is an atomic or monatomic ion;
if it consists of two or more atoms, it is a molecular or polyatomic
ion.
03/13/25
IONS
● When an atom gains an electron, it becomes
negatively charged (more electrons than protons )
and is called an anion.
● In the same way that nonmetal atoms can gain
electrons, metal atoms can lose electrons.
● They become positively charged cations.
03/13/25
IONIC RADII
The ionic radius is the radius of an ion.
Starting from the left, we can see that sodium’s ion has a
smaller radius than it’s uncharged atom, because it has
one less electron, and therefore the nucleus is able to pull
them closer. This same pattern continues until Si 4+ (the
atoms lose more and more electrons, making the pull from
the nucleus stronger each time).
03/13/25
Cont.…….
Then at Si4-, the atomic radius increases because it has 4 extra
electrons that repel, forcing the ion out (and therefore getting
bigger). Then the ionic radii continues on it’s decreasing
pattern, because the ions after silicon each have one less extra
electron then the previous element, and therefore push out
(repel) less.
Sodium Ion
03/13/25
GOLDSCHMIDT’S RULES
Ions similar radii & the same charge will enter into a crystal in
amounts proportional to their concentration in liquid.
When two ions with same charge complete for a lattice site, the ion
of smaller radius will be preferentially incorporated into the growing
crystal
When two ions of same radius complete for lattice site, the ions with
higher charge will be preferentially incorporated into growing crystal.
03/13/25
BOND LENGTH
Bond length is the distance between the nuclei in a bond.
These are determined by X-ray diffraction. This is always an
average distance, because atoms are always vibrating with
respect to each other, so there is really no fixed distance
between any two nuclei.
Bond length decreases from single to double to triple bonds.
C-C (154 pm) C=C (133 pm) Triple bonded carbon atoms (120
pm).
Bond Length
03/13/25
MEASUREMENT OF BOND LENGTH
● The best is infrared spectroscopy.
Measurement in this domain allow to measure the
vibration between 2 atoms in a bond and to
measure the length and angle between two bonds
stretching vibrations measures the length and
bending vibrations the angles.
03/13/25
MEASUREMENT OF RADII
If two identical atoms are bonded together as in the crystal
of a pure metal their bond length equal twice the radius of
an individual atom
Thus if bond length can be determined in crystals of pure
elements ,the radii for the individual atoms know
03/13/25
Crystals of pure metals very often adopt a face
centered cubic (FCC) or body centered cubic(BCC)
structure, this is to say that if the target atom are
replaced by point at their centers, the underlying
space lattice will be either face centered cubic or
body centered cubic.
03/13/25
CONCLUSION
●
An atom is the smallest unit of a substance that retains the
properties of that substance.
●
An atom gets larger as the number of electronic shells
increase; therefore the radius of atoms increases as you
go down a certain group in the periodic table of elements.
In general, the size of an atom will decrease as you move
from left to the right of a certain period.
●
The radius of each atom in an ionic bond will be different
than that in a covalent bond
Cont.....
●
Bond length is related to bond order, when more electrons
participate in bond formation the bond will get shorter.
●
Bond length is also inversely related to bond strength and the
bond dissociation energy, as a stronger bond will be shorter. In
a bond between two identical atoms half the bond distance is
equal to the covalent radius.
03/13/25
REFERENCE
●
Crystallography and Crystal Chemistry1994 by F.D.Bloss
p:19-24
●
Rutley’s Elements of Mineralogy 27th
Edition Revised by
C.D.Gribble p:11-15
●
Pauling, Linus. Atomic Radii and Interatomic Distances in
Metal, Journal of the American Chemical Society 194769
(3), p:542-553
●
www.wikipedia.com
Atomic and Ionic Radii, Bond length and Measurement of Radius.ppt

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Atomic and Ionic Radii, Bond length and Measurement of Radius.ppt

  • 1. 03/13/25 seminar on Atomic and Ionic Radii, Bond length and Measurement of Radius presented by SOORAJ.B 1st sem Applied Geology Mysore University….. Submitted to Dr.G.S.Gopalakrishna, Professor DOS.Earth Science Mysore university
  • 2. 03/13/25 CONTENTS INTRODUCTION ATOMIC RADII ATOMIC RADII TREND IONS IONIC RADII BOND LENGTH AND MEASUREMENTS CONCLUSION REFERENCE
  • 3. 03/13/25 INTRODUCTION Crystallography is the branch of science which deals with all the aspects of crystals, that is, their formation from the melts, internal structure and external shape or morphology. An elementary knowledge of crystallography is essential for all those who have to deal with minerals in one way or another such as mining engineers, civil engineers and engineering geologist
  • 4. ATOM ● Atom is a basic unit of matter that consists of a dense central nucleus surrounded by a cloud of negatively charged electrons. The atomic nucleus contains a mix of positively charged protons and electrically neutral neutrons . ● The electrons of an atom are bound to the nucleus by the electromagnetic force. ● An atom containing an equal number of protons and electrons is electrically neutral, otherwise it has a positive charge if there are fewer electrons or negative charge if there are more electrons
  • 7. Dalton’s Atomic Theory ● All matter is composed of extremely small particles called atoms. ● All atoms of a given element are identical in size, mass, and other properties. Atoms of different elements differ in size, mass, and other properties. ● Atoms cannot be subdivided, created, or destroyed. ● Atoms of different elements can combine in simple, whole-number ratios to form compounds. ● In chemical reactions, atoms are combined, separated, or rearranged.
  • 8. 03/13/25 ATOMIC RADII The atomic radius of an element is basically the size of the atom. We can determine the atomic radius by finding half the length between the nucleus’ of two atoms of the same elements.
  • 12. 03/13/25 The size of atoms (and therefore the atomic radii) increase as we go down groups on the periodic table (since more energy levels are added), but as we go to the right, the size decreases because… Electrons are being added to the same shell, which does not change the size of the atom, but protons are also being added to the nucleus, which pulls the electrons inwards towards the center, decreasing the radius.
  • 13. Ion ● An ion is an atom or molecule in which the total number of electrons is not equal to the total number of protons, giving it a net positive or negative electrical charge. ● The name was given by physicist Michael Faraday for the substances that allow a current to pass ("go") between electrodes in a solution, when an electric field is applied. ● An ion consisting of a single atom is an atomic or monatomic ion; if it consists of two or more atoms, it is a molecular or polyatomic ion.
  • 14. 03/13/25 IONS ● When an atom gains an electron, it becomes negatively charged (more electrons than protons ) and is called an anion. ● In the same way that nonmetal atoms can gain electrons, metal atoms can lose electrons. ● They become positively charged cations.
  • 15. 03/13/25 IONIC RADII The ionic radius is the radius of an ion. Starting from the left, we can see that sodium’s ion has a smaller radius than it’s uncharged atom, because it has one less electron, and therefore the nucleus is able to pull them closer. This same pattern continues until Si 4+ (the atoms lose more and more electrons, making the pull from the nucleus stronger each time).
  • 16. 03/13/25 Cont.……. Then at Si4-, the atomic radius increases because it has 4 extra electrons that repel, forcing the ion out (and therefore getting bigger). Then the ionic radii continues on it’s decreasing pattern, because the ions after silicon each have one less extra electron then the previous element, and therefore push out (repel) less.
  • 18. 03/13/25 GOLDSCHMIDT’S RULES Ions similar radii & the same charge will enter into a crystal in amounts proportional to their concentration in liquid. When two ions with same charge complete for a lattice site, the ion of smaller radius will be preferentially incorporated into the growing crystal When two ions of same radius complete for lattice site, the ions with higher charge will be preferentially incorporated into growing crystal.
  • 19. 03/13/25 BOND LENGTH Bond length is the distance between the nuclei in a bond. These are determined by X-ray diffraction. This is always an average distance, because atoms are always vibrating with respect to each other, so there is really no fixed distance between any two nuclei. Bond length decreases from single to double to triple bonds. C-C (154 pm) C=C (133 pm) Triple bonded carbon atoms (120 pm).
  • 21. 03/13/25 MEASUREMENT OF BOND LENGTH ● The best is infrared spectroscopy. Measurement in this domain allow to measure the vibration between 2 atoms in a bond and to measure the length and angle between two bonds stretching vibrations measures the length and bending vibrations the angles.
  • 22. 03/13/25 MEASUREMENT OF RADII If two identical atoms are bonded together as in the crystal of a pure metal their bond length equal twice the radius of an individual atom Thus if bond length can be determined in crystals of pure elements ,the radii for the individual atoms know
  • 23. 03/13/25 Crystals of pure metals very often adopt a face centered cubic (FCC) or body centered cubic(BCC) structure, this is to say that if the target atom are replaced by point at their centers, the underlying space lattice will be either face centered cubic or body centered cubic.
  • 24. 03/13/25 CONCLUSION ● An atom is the smallest unit of a substance that retains the properties of that substance. ● An atom gets larger as the number of electronic shells increase; therefore the radius of atoms increases as you go down a certain group in the periodic table of elements. In general, the size of an atom will decrease as you move from left to the right of a certain period. ● The radius of each atom in an ionic bond will be different than that in a covalent bond
  • 25. Cont..... ● Bond length is related to bond order, when more electrons participate in bond formation the bond will get shorter. ● Bond length is also inversely related to bond strength and the bond dissociation energy, as a stronger bond will be shorter. In a bond between two identical atoms half the bond distance is equal to the covalent radius.
  • 26. 03/13/25 REFERENCE ● Crystallography and Crystal Chemistry1994 by F.D.Bloss p:19-24 ● Rutley’s Elements of Mineralogy 27th Edition Revised by C.D.Gribble p:11-15 ● Pauling, Linus. Atomic Radii and Interatomic Distances in Metal, Journal of the American Chemical Society 194769 (3), p:542-553 ● www.wikipedia.com