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Department of Fisheries and Marine Science
Noakhali Science and Technology University
Biogeochemical
cycles
What are biogeochemical cycles?
• Earth system has four parts
– Atmosphere
– Hydrosphere
– Lithosphere
– Biosphere
• Biogeochemical cycles: The chemical
interactions (cycles) that exist between
the atmosphere, hydrosphere,
lithosphere, and biosphere.
• Abiotic (physio-chemical) and biotic
processes drive these cycles
• Focus on carbon and water cycles (but
could include all necessary elements for
life). N - cycle weakly touched on!
The biogeochemical cycle
involves the movement of
elements and compounds
among the land (lithosphere),
organisms, air (atmosphere)
and the oceans (hydrosphere).
Human activities can affect
these cycles
Lithosphere
Atmosphere
Biosphere
Hydrosphere
3
 The biogeochemical cycle is the continuous flow of elements
and compounds between organisms and the earth
 The ocean plays a role in the biogeochemical cycle for
elements including carbon and nitrogen
 As part of the carbon cycle, carbon dissolves into the surface
ocean from the atmosphere and is used for photosynthesis
How do elements move through the
biogeochemical cycle?
Organisms use
elements as
nutrients
and put
nutrients back
into the
environment
Elements travel
among air, land and sea
through
physical processes
4
Various biogeochemical cycles
• Water cycle
• The Nitrogen Cycle
• The Carbon Cycle
• The Sulfur Cycle
• The Phosphorus Cycle
• The Hydrogen Cycle
• The Oxygen Cycle
What is common amongst them?
• Each compound (water, carbon, nitrogen)
typically exists in all four parts of the Earth
System
• Transformations
– are important
– can lead to positive & negative consequences
The Water
Cycle
Water
• 3 states
– Solid
– Liquid
– Gas
• The 3 states of water are determined
mostly by temperature.
• Even though water is constantly changing
states, the total amount of water on Earth
remains constant.
• Over 70% of the Earth’s surface is covered
by oceans
• Water is constantly being cycled between
the atmosphere (air), hydrosphere (water),
and lithosphere (land).
•The repeating change of water on
the Earth creates a cycle
• As water goes through its cycle, it
can be a solid (ice), a liquid (water),
or a gas (water vapor)
•Ice can change to become water or
water vapor
•Water can change to become ice
or water vapor
•Water vapor can change to
become ice or water.
Evaporation
• The sun (temperature) is the energy
force that powers the water cycle
• It heats oceans, lakes, rivers and causes
water to change from the liquid state to
the gaseous state
• The oceans contribute to about 80-90%
of the water vapor in the atmosphere.
• During evaporation, the impurities (for
example, Salt) are left behind.
– This is important because about 97%
of the water on Earth is salt water
(oceans) and only 3% is freshwater
(rivers, streams, lakes, ponds, and in
the ground).
Condensation
• When atmospheric
temperature decreases, the
water vapor (gas) changes
back into a liquid.
• Condensation is the opposite
of evaporation.
• Small water droplets are
formed in the atmosphere.
• Collections of water droplets
form clouds in the sky or fog at
ground level.
• You can see condensation on
drinks in the summertime or
leaves in the morning.
Water vapor
condensing on a
cold window.
Water vapor
condensing on a
cold mirror.
More condensation
Water vapor condensing on the cold car windshield.
More
condensation
Water vapor condensing on grass or a spider web--dew.
More condensation
Precipitation
• Tiny water droplets bounce around in a
cloud and as they hit each other, they
stick together and become larger.
• The clouds get heavy and eventually
water falls back to the Earth.
• Precipitation can occur in the form of
rain, freezing rain, sleet, snow, or hail.
• Most precipitation falls back into the
oceans or onto land. If precipitation
falls in the form of snow it can
accumulate in the form of ice caps or
glaciers.
• Most of the condensed water in clouds
does not actually fall as precipitation.
•Rain: Sleet:
•Snow: Hail:
Surface Runoff
• About 1/3 of the water that
returns to the Earth as
precipitation runs off the
surface of the land, down hill,
into streams, rivers, lakes, and
oceans.
• The other 2/3 of precipitation is
evaporated, transpired, or is
infiltrated into ground water.
• Surface Runoff is a very
important part of the water
cycle because it returns water
once again to the bodies of
water, where evaporation
occurs.
• For example, when snow melts
Biogeochemical cycle
Surface run-off from a farm field
During a heavy rain, water flows over the soil filling
creeks which then flow into streams and finally into
rivers. The surface runoff that flows into a creek is
beginning its journey back to the ocean.
Infiltration
• Not all surface runoff water flows back into streams, rivers,
lakes, and oceans. Some of it soaks into the ground.
• Infiltration is the downward movement of water from the land
surface into soil or underlying rock layers.
• This water can replenish aquifers, which store large amounts of
freshwater that can be removed from the ground using a water
well.
• Some infiltration stays close to the land surface and can seep
back into surface-water bodies (and the ocean) as
groundwater discharge.
• Some groundwater finds
openings in the land surface
and comes out as
freshwater springs.
Transpiration
• Water is returned to the
atmosphere by plants.
• Water is absorbed by
plants (usually through
the roots) from water
that is in the soil.
• The water travels up
through the plant and
then is evaporated back
into the atmosphere
from the plant surface
(usually the leaves).
Sublimation
• Sublimation is the
conversion between the
solid and gaseous form of
water, with no
intermediate liquid stage.
• This occurs when there is
low atmospheric pressure.
• An example of this is when
snow and ice change into
water vapor in the air
without first melting into
water.
Phase Diagram for Water
Biogeochemical cycle
Biogeochemical cycle
• Humans use water for drinking, respiration, perspiration, and
elimination of wastes are all part of this cycle
• Large amounts of water are needed for most economic
activities: agriculture and mining, food processing,
manufacturing
• Lakes and rivers provide towns and cities with a means of
discharging wastes
• Generation of electricity from thermal power plants
• Waterways provide transportation
• Recreational activities
• Some people view the rivers and large lakes of this country as a
part of their own identity
Biogeochemical cycle
The Carbon Cycle
Most of you is water.
But a surprising part of
the rest of you is carbon!
This is you, without water - a
lump of Carbon
What’s so Special About Carbon?
• Carbon is one of the most
important elements in the
earth system.
• The carbon atom has four
valence electrons and has
the ability to form bonds
with as many as four other
atoms including other
carbon atoms.
C
e-
e-
e- e-
e-
e-
What’s so Special About Carbon?
• Carbon can readily bond
with almost any element on
the periodic table.
• Carbon is unparalleled
among elements in its
ability to bond with itself
almost indefinitely, forming
carbon chains, loops and
braches.
• What's more, the bonds
forged between carbon
atoms are very, very strong.
Why is Carbon so Important?
All life, from a whale to a redwood tree, down to a
lady bug, to an amoeba, down to our cells,
even to the components inside our cells — all
of it contains carbon. Carbon is the “duct tape
of life,” It holds us together.
Carbon is the main source of food energy. When
you eat carbon molecules (plants and animals),
the digestive juices in your stomach break the
carbon bonds inside and release the energy in
the form of calories.
Why is Carbon so Important?
Hydrocarbon Molecules
(coal oil, natural gas)
are the primary
sources of energy in
our modern society.
Carbon Molecules (CO2
and CH4) in the
atmosphere are
greenhouse gasses
and are play a key
role in climate
change.
The Carbon Cycle
• Carbon atoms continually move through living
organisms, the oceans, the atmosphere, and the rocks
that make up the earth system. This movement is
known as the carbon cycle.
• The paths taken by carbon atoms through this cycle are
extremely complex, and may take years to millions of
years to come full circle.
• In the cycle there are various sinks, or stores, of carbon
and fluxes, or processes, by which the various sinks
exchange carbon on various time scales.
Dissolution
Plants
Phytoplankton
“Biomass”
Fossil
Fuels
The Carbon Cycle
Decomposition
Respiration
Combustion
Carbon In
Atmosphere
Carbon In
Rocks
Carbon
In Ocean Water
Weathering
Tectonics
Evaporation
Lithification
Soil
Marine Sediment
“Organic Matter”
Photosynthesis
Boxes are carbon sinks Arrows are carbon fluxes
Consumption
Atmospheric
Carbon Dioxide
Plants use carbon
dioxide to make their
food (photosynthesis
green plants are
eaten by animals
respiration
dead remains of plants and
animals
decay by fungi and
bacteria
Biogeochemical cycle
Step 1: PHOTOSYNTHESIS
• During photosynthesis, plants, algae, and
cyanobacteria remove Carbon dioxide from
the air and fix, or incorporate it into
complex organic compounds such as glucose.
• Photosynthesis incorporates carbon from the
abiotic into the biological compounds of
producers.
Step 2: DECOMPOSITION, ANIMAL & PLANT RESPIRATION, SOIL
MICROORGANISM RESPIRATION.
• Many of the compounds are used as fuel for cellular
respiration by the producer that made them, by a
consumer that eats producer, or by a decomposer that
breaks down the remains of the producer or consumer.
• The process of a cellular respiration returns Carbon
dioxide to the atmosphere. A similar carbon cycle
occurs in aquatic ecosystems between aquatic
organisms and dissolved Carbon dioxide in water.
Step 3: PARTLY DECOMPOSED PLANT REMAINS (COAL)
Millions of years ago vast
coal beds formed from the
bodies of ancient trees that
were buried and subjected to
anaerobic conditions before
they had fully decayed.
Step 4: MARINE PLANKTON REMAINS
• The oils of unicellular marine organisms probably
gave rise to the underground deposits of oil and
natural gas that accumulated in the geologic past.
• Coal, oil, and natural gas, called fossil fuels
because they formed from the remains of
ancient organisms. Fossil fuels are non-
renewable resources. The Earth has a finite or
limited supply of these resources.
Step 5: COMBUSTION (HUMAN & NATURAL)
The process of burning or combustion,
may return the carbon in oil, coal,
natural gas, and wood to the
atmosphere. In combustion, organic
molecules are rapidly oxidized
(combined with oxygen) and converted
carbon dioxide and water with an
accompanying release of light and heat.
Step 6: BURIAL AND COMPACTION TO FORM ROCK
(LIMESTONE)
An even greater amount of carbon that is
stored for millions of years is
incorporated into the shells of marine
organisms. When these organisms die,
their shells sink to the ocean floor and
sediments cover them forming cemented
together to form limestone, a meter
thick.
Step 7: EROSION OF LIMESTONE TO FORM
DISSOLVED CO2
When the process of geologic uplift
expose limestone, chemical and
physical weathering processes slowly
erode it away. This returns carbon to
the water and atmosphere where it is
available to participate in the carbon
cycle once again.
Changes in Atmospheric C02
Dr. Pieter Tans, NOAA/ESRL (www.esrl.noaa.gov/gmd/cgg/trends)
Nitrogen Cycle
Forms of Nitrogen
• Urea  CO(NH2)2
• Ammonia  NH3 (gaseous)
• Ammonium  NH4
• Nitrate  NO3
• Nitrite  NO2
• Atmospheric nitrogen  N2
• Organic N
Nitrogen Cycle: Key Points
• Nitrogen is in the atmosphere as N2 (78%)
• N2 is an inert gas and cannot be used by plants
or animals
• N2 can be converted to a usable form via
– Lightening
– N-fixing plants and cyanobacteria
– Industrial process (energy intensive)
• Nitrogen limits plant growth
• Nitrogen is easily lost from biological systems
Roles of Nitrogen
• Plants and bacteria use nitrogen in the
form of NH4
+ or NO3
-
• It serves as an electron acceptor in
anaerobic environment
• Nitrogen is often the most limiting nutrient
in soil and water.
There are 4 phases in the cycle:
• Nitrogen fixation = NH3/NH4
+
• Decay = decomposing organic nitrogen into
NH4
+
• Nitrification = converting NH4
+ to NO2 to NO3
• Denitrification = converting NO3 into N2
Micro-organisms play an important part in this cycle!
Nitrogen Fixation
• The enormous energy of lightning breaks nitrogen molecules
apart and enables the nitrogen atoms to combine with oxygen
forming nitrogen oxides (N2O)
• Nitrogen oxides dissolve in rain, forming nitrates (NO3)
• Nitrates (NO3) are carried to the ground with the rain.
N
N O
(NO3)
(N2O)
Decay
• Animals acquire their amino acids when they eat plants.
• When animals and plants die their remains are used as
food by micro-organisms such as bacteria and fungi.
• Decomposers convert the nitrogen back into ammonia
(NH3)
Ammonia (NH3) is
stored in soil.
Decomposers convert organic
nitrogen to ammonia (NH3) Ammonia (NH3) is used by
some plants
Nitrifying bacteria in soil combine
ammonia with oxygen
Ammonia changes to nitrites
Nitrifying bacteria in soil convert
nitrites to nitrates
Plants absorb nitrates and
grow!
Ammonia Nitrites Nitrates
(NH3) (NO3)(NO2)
Nitrification
• Living in the soil are nitrifying bacteria.
• First, Nitrosomonas bacteria combine ammonia with oxygen to
form nitrites.
• Then another group of nitrifying bacteria, Nitrobacter, convert
nitrites to nitrates which green plants can absorb and use!
Dinitrification
• Removes a limiting nutrient from the
environment
• 4NO3
-
+ C6H12O6 2N2 + 6 H20
• Inhibited by O2
• Not inhibited by ammonia
• Microbial reaction
• Nitrate is the terminal electron acceptor
Denitrifying
bacteria
Nitrates
(NO3
–)
Detritivores
Ammonium (NH4
+)
Amino acids
and proteins in
plants and animals
Detritus
Assimilation
by plants
Nitrogen-fixing
bacteria in soil
Nitrogen
fixation
Decomposition
Nitrogen-fixing
bacteria in root
nodules of legumes
Nitrogen
fixation
Nitrogen (N2) in atmosphere
Oxygen Cycle
Oxygen
• Oxygen – a colorless, odorless, tasteless gas
• Denser than air
• Poor conductor of heat and electricity
• Oxygen, one of the main components of the Earth’s
atmosphere, can always be found with other
elements.
• Two oxygen atoms make up one oxygen molecule,
and three oxygen atoms together make up the
molecule called ozone.
Biological Importance of Oxygen
• Humans need it to breathe
• Needed for decomposition of organic waste
• Water can dissolve oxygen and it is this dissolved
oxygen that supports aquatic life.
Ecological Importance of Oxygen
• Without oxygen at the bottom of the water body,
anaerobic bacteria (those that live without oxygen)
produce acids. These acids not only increase acidity, but
also cause a massive release of phosphorus and
nitrogen, two major fertilizers, from the organic
sediment and into the water column.
• These same anaerobic bacteria put toxic gases in the
water including hydrogen sulfide (that rotten egg
smell), ammonia, carbon dioxide and methane. These
gases are all toxic to fish, beneficial bacteria and
insects.
• Lack of bottom oxygen is the cause of odors produced
by anaerobic bacteria.
The Main Reservoirs
• Biosphere (living things)
• Lithosphere (Earth’s crust)
• Atmosphere (air)
• Hydrosphere(water)
The reservoirs are the locations in which
oxygen is found.
Biogeochemical cycle
What is the Oxygen Cycle?
• In the oxygen cycle, oxygen atoms present in
the earth circulate through a series of intricate
processes.
• Like the nitrogen, carbon, and water cycles, the
oxygen cycle is a biogeochemical cycle.
• A biogeochemical cycle is the movement of
matter through the biotic and the abiotic
spheres of the ecosystem.
Step One of Oxygen Cycle
Plant release oxygen into the
atmosphere as a by-product
of photosynthesis.
oxygen
Photosynthesis
• Plants take in carbon dioxide and water and
use them to make food. Their food is simple
sugar — glucose.
Photosynthesis
•Definition- process in which green plants use the energy from
the sun to make carbohydrates from carbon dioxide and water in
the presence of chlorophyll.
Photosynthesis (continued)
• Plants pull the carbon off CO2 and use the carbon in
glucose. (They do not need the oxygen for this. They get that from water, H2O.)
• Plants release the oxygen (O2) back into the
atmosphere.
• Other organisms use the free oxygen for respiration.
Biogeochemical cycle
Step Two of Oxygen Cycle
• Animals take in oxygen through the process of
respiration.
• Animals then break down sugars and food.
Respiration
• Process by which an organism exchanges gases with its
environment
• Process → oxygen is abstracted from air, transported to cells
for the oxidation of organic molecules while CO2 and H2O, the
products of oxidation, are returned to the environment
Step Three in Oxygen Cycle
• Carbon dioxide is released by animals and used in plants in
photosynthesis.
• Oxygen is balanced between the atmosphere and the ocean.
How do plants contribute?
• The oxygen cycle begins with plants and
photosynthesis.
• Through photosynthesis, plants convert the
energy from the sun and water into
carbohydrates and oxygen.
• During the day: plants convert carbon dioxide
into oxygen.
• During the night: plants convert oxygen into
carbon dioxide to maintain their metabolism.
How do animals contribute?
• Humans and animals breathe in oxygen
and breathe out carbon dioxide through
their processes of metabolism, sparking
the process of photosynthesis, once
again linking back to the plants’
contribution to the oxygen cycle.
Biogeochemical cycle
Biogeochemical cycle

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Biogeochemical cycle

  • 1. Department of Fisheries and Marine Science Noakhali Science and Technology University Biogeochemical cycles
  • 2. What are biogeochemical cycles? • Earth system has four parts – Atmosphere – Hydrosphere – Lithosphere – Biosphere • Biogeochemical cycles: The chemical interactions (cycles) that exist between the atmosphere, hydrosphere, lithosphere, and biosphere. • Abiotic (physio-chemical) and biotic processes drive these cycles • Focus on carbon and water cycles (but could include all necessary elements for life). N - cycle weakly touched on!
  • 3. The biogeochemical cycle involves the movement of elements and compounds among the land (lithosphere), organisms, air (atmosphere) and the oceans (hydrosphere). Human activities can affect these cycles Lithosphere Atmosphere Biosphere Hydrosphere 3  The biogeochemical cycle is the continuous flow of elements and compounds between organisms and the earth  The ocean plays a role in the biogeochemical cycle for elements including carbon and nitrogen  As part of the carbon cycle, carbon dissolves into the surface ocean from the atmosphere and is used for photosynthesis
  • 4. How do elements move through the biogeochemical cycle? Organisms use elements as nutrients and put nutrients back into the environment Elements travel among air, land and sea through physical processes 4
  • 5. Various biogeochemical cycles • Water cycle • The Nitrogen Cycle • The Carbon Cycle • The Sulfur Cycle • The Phosphorus Cycle • The Hydrogen Cycle • The Oxygen Cycle
  • 6. What is common amongst them? • Each compound (water, carbon, nitrogen) typically exists in all four parts of the Earth System • Transformations – are important – can lead to positive & negative consequences
  • 8. Water • 3 states – Solid – Liquid – Gas • The 3 states of water are determined mostly by temperature. • Even though water is constantly changing states, the total amount of water on Earth remains constant. • Over 70% of the Earth’s surface is covered by oceans • Water is constantly being cycled between the atmosphere (air), hydrosphere (water), and lithosphere (land).
  • 9. •The repeating change of water on the Earth creates a cycle • As water goes through its cycle, it can be a solid (ice), a liquid (water), or a gas (water vapor) •Ice can change to become water or water vapor •Water can change to become ice or water vapor •Water vapor can change to become ice or water.
  • 10. Evaporation • The sun (temperature) is the energy force that powers the water cycle • It heats oceans, lakes, rivers and causes water to change from the liquid state to the gaseous state • The oceans contribute to about 80-90% of the water vapor in the atmosphere. • During evaporation, the impurities (for example, Salt) are left behind. – This is important because about 97% of the water on Earth is salt water (oceans) and only 3% is freshwater (rivers, streams, lakes, ponds, and in the ground).
  • 11. Condensation • When atmospheric temperature decreases, the water vapor (gas) changes back into a liquid. • Condensation is the opposite of evaporation. • Small water droplets are formed in the atmosphere. • Collections of water droplets form clouds in the sky or fog at ground level. • You can see condensation on drinks in the summertime or leaves in the morning.
  • 12. Water vapor condensing on a cold window.
  • 13. Water vapor condensing on a cold mirror. More condensation
  • 14. Water vapor condensing on the cold car windshield. More condensation
  • 15. Water vapor condensing on grass or a spider web--dew. More condensation
  • 16. Precipitation • Tiny water droplets bounce around in a cloud and as they hit each other, they stick together and become larger. • The clouds get heavy and eventually water falls back to the Earth. • Precipitation can occur in the form of rain, freezing rain, sleet, snow, or hail. • Most precipitation falls back into the oceans or onto land. If precipitation falls in the form of snow it can accumulate in the form of ice caps or glaciers. • Most of the condensed water in clouds does not actually fall as precipitation.
  • 18. Surface Runoff • About 1/3 of the water that returns to the Earth as precipitation runs off the surface of the land, down hill, into streams, rivers, lakes, and oceans. • The other 2/3 of precipitation is evaporated, transpired, or is infiltrated into ground water. • Surface Runoff is a very important part of the water cycle because it returns water once again to the bodies of water, where evaporation occurs. • For example, when snow melts
  • 20. Surface run-off from a farm field During a heavy rain, water flows over the soil filling creeks which then flow into streams and finally into rivers. The surface runoff that flows into a creek is beginning its journey back to the ocean.
  • 21. Infiltration • Not all surface runoff water flows back into streams, rivers, lakes, and oceans. Some of it soaks into the ground. • Infiltration is the downward movement of water from the land surface into soil or underlying rock layers. • This water can replenish aquifers, which store large amounts of freshwater that can be removed from the ground using a water well. • Some infiltration stays close to the land surface and can seep back into surface-water bodies (and the ocean) as groundwater discharge. • Some groundwater finds openings in the land surface and comes out as freshwater springs.
  • 22. Transpiration • Water is returned to the atmosphere by plants. • Water is absorbed by plants (usually through the roots) from water that is in the soil. • The water travels up through the plant and then is evaporated back into the atmosphere from the plant surface (usually the leaves).
  • 23. Sublimation • Sublimation is the conversion between the solid and gaseous form of water, with no intermediate liquid stage. • This occurs when there is low atmospheric pressure. • An example of this is when snow and ice change into water vapor in the air without first melting into water. Phase Diagram for Water
  • 26. • Humans use water for drinking, respiration, perspiration, and elimination of wastes are all part of this cycle • Large amounts of water are needed for most economic activities: agriculture and mining, food processing, manufacturing • Lakes and rivers provide towns and cities with a means of discharging wastes • Generation of electricity from thermal power plants • Waterways provide transportation • Recreational activities • Some people view the rivers and large lakes of this country as a part of their own identity
  • 28. The Carbon Cycle Most of you is water. But a surprising part of the rest of you is carbon! This is you, without water - a lump of Carbon
  • 29. What’s so Special About Carbon? • Carbon is one of the most important elements in the earth system. • The carbon atom has four valence electrons and has the ability to form bonds with as many as four other atoms including other carbon atoms. C e- e- e- e- e- e-
  • 30. What’s so Special About Carbon? • Carbon can readily bond with almost any element on the periodic table. • Carbon is unparalleled among elements in its ability to bond with itself almost indefinitely, forming carbon chains, loops and braches. • What's more, the bonds forged between carbon atoms are very, very strong.
  • 31. Why is Carbon so Important? All life, from a whale to a redwood tree, down to a lady bug, to an amoeba, down to our cells, even to the components inside our cells — all of it contains carbon. Carbon is the “duct tape of life,” It holds us together. Carbon is the main source of food energy. When you eat carbon molecules (plants and animals), the digestive juices in your stomach break the carbon bonds inside and release the energy in the form of calories.
  • 32. Why is Carbon so Important? Hydrocarbon Molecules (coal oil, natural gas) are the primary sources of energy in our modern society. Carbon Molecules (CO2 and CH4) in the atmosphere are greenhouse gasses and are play a key role in climate change.
  • 33. The Carbon Cycle • Carbon atoms continually move through living organisms, the oceans, the atmosphere, and the rocks that make up the earth system. This movement is known as the carbon cycle. • The paths taken by carbon atoms through this cycle are extremely complex, and may take years to millions of years to come full circle. • In the cycle there are various sinks, or stores, of carbon and fluxes, or processes, by which the various sinks exchange carbon on various time scales.
  • 34. Dissolution Plants Phytoplankton “Biomass” Fossil Fuels The Carbon Cycle Decomposition Respiration Combustion Carbon In Atmosphere Carbon In Rocks Carbon In Ocean Water Weathering Tectonics Evaporation Lithification Soil Marine Sediment “Organic Matter” Photosynthesis Boxes are carbon sinks Arrows are carbon fluxes Consumption
  • 35. Atmospheric Carbon Dioxide Plants use carbon dioxide to make their food (photosynthesis green plants are eaten by animals respiration dead remains of plants and animals decay by fungi and bacteria
  • 37. Step 1: PHOTOSYNTHESIS • During photosynthesis, plants, algae, and cyanobacteria remove Carbon dioxide from the air and fix, or incorporate it into complex organic compounds such as glucose. • Photosynthesis incorporates carbon from the abiotic into the biological compounds of producers.
  • 38. Step 2: DECOMPOSITION, ANIMAL & PLANT RESPIRATION, SOIL MICROORGANISM RESPIRATION. • Many of the compounds are used as fuel for cellular respiration by the producer that made them, by a consumer that eats producer, or by a decomposer that breaks down the remains of the producer or consumer. • The process of a cellular respiration returns Carbon dioxide to the atmosphere. A similar carbon cycle occurs in aquatic ecosystems between aquatic organisms and dissolved Carbon dioxide in water.
  • 39. Step 3: PARTLY DECOMPOSED PLANT REMAINS (COAL) Millions of years ago vast coal beds formed from the bodies of ancient trees that were buried and subjected to anaerobic conditions before they had fully decayed.
  • 40. Step 4: MARINE PLANKTON REMAINS • The oils of unicellular marine organisms probably gave rise to the underground deposits of oil and natural gas that accumulated in the geologic past. • Coal, oil, and natural gas, called fossil fuels because they formed from the remains of ancient organisms. Fossil fuels are non- renewable resources. The Earth has a finite or limited supply of these resources.
  • 41. Step 5: COMBUSTION (HUMAN & NATURAL) The process of burning or combustion, may return the carbon in oil, coal, natural gas, and wood to the atmosphere. In combustion, organic molecules are rapidly oxidized (combined with oxygen) and converted carbon dioxide and water with an accompanying release of light and heat.
  • 42. Step 6: BURIAL AND COMPACTION TO FORM ROCK (LIMESTONE) An even greater amount of carbon that is stored for millions of years is incorporated into the shells of marine organisms. When these organisms die, their shells sink to the ocean floor and sediments cover them forming cemented together to form limestone, a meter thick.
  • 43. Step 7: EROSION OF LIMESTONE TO FORM DISSOLVED CO2 When the process of geologic uplift expose limestone, chemical and physical weathering processes slowly erode it away. This returns carbon to the water and atmosphere where it is available to participate in the carbon cycle once again.
  • 44. Changes in Atmospheric C02 Dr. Pieter Tans, NOAA/ESRL (www.esrl.noaa.gov/gmd/cgg/trends)
  • 46. Forms of Nitrogen • Urea  CO(NH2)2 • Ammonia  NH3 (gaseous) • Ammonium  NH4 • Nitrate  NO3 • Nitrite  NO2 • Atmospheric nitrogen  N2 • Organic N
  • 47. Nitrogen Cycle: Key Points • Nitrogen is in the atmosphere as N2 (78%) • N2 is an inert gas and cannot be used by plants or animals • N2 can be converted to a usable form via – Lightening – N-fixing plants and cyanobacteria – Industrial process (energy intensive) • Nitrogen limits plant growth • Nitrogen is easily lost from biological systems
  • 48. Roles of Nitrogen • Plants and bacteria use nitrogen in the form of NH4 + or NO3 - • It serves as an electron acceptor in anaerobic environment • Nitrogen is often the most limiting nutrient in soil and water.
  • 49. There are 4 phases in the cycle: • Nitrogen fixation = NH3/NH4 + • Decay = decomposing organic nitrogen into NH4 + • Nitrification = converting NH4 + to NO2 to NO3 • Denitrification = converting NO3 into N2 Micro-organisms play an important part in this cycle!
  • 50. Nitrogen Fixation • The enormous energy of lightning breaks nitrogen molecules apart and enables the nitrogen atoms to combine with oxygen forming nitrogen oxides (N2O) • Nitrogen oxides dissolve in rain, forming nitrates (NO3) • Nitrates (NO3) are carried to the ground with the rain. N N O (NO3) (N2O)
  • 51. Decay • Animals acquire their amino acids when they eat plants. • When animals and plants die their remains are used as food by micro-organisms such as bacteria and fungi. • Decomposers convert the nitrogen back into ammonia (NH3) Ammonia (NH3) is stored in soil. Decomposers convert organic nitrogen to ammonia (NH3) Ammonia (NH3) is used by some plants
  • 52. Nitrifying bacteria in soil combine ammonia with oxygen Ammonia changes to nitrites Nitrifying bacteria in soil convert nitrites to nitrates Plants absorb nitrates and grow! Ammonia Nitrites Nitrates (NH3) (NO3)(NO2) Nitrification • Living in the soil are nitrifying bacteria. • First, Nitrosomonas bacteria combine ammonia with oxygen to form nitrites. • Then another group of nitrifying bacteria, Nitrobacter, convert nitrites to nitrates which green plants can absorb and use!
  • 53. Dinitrification • Removes a limiting nutrient from the environment • 4NO3 - + C6H12O6 2N2 + 6 H20 • Inhibited by O2 • Not inhibited by ammonia • Microbial reaction • Nitrate is the terminal electron acceptor
  • 54. Denitrifying bacteria Nitrates (NO3 –) Detritivores Ammonium (NH4 +) Amino acids and proteins in plants and animals Detritus Assimilation by plants Nitrogen-fixing bacteria in soil Nitrogen fixation Decomposition Nitrogen-fixing bacteria in root nodules of legumes Nitrogen fixation Nitrogen (N2) in atmosphere
  • 56. Oxygen • Oxygen – a colorless, odorless, tasteless gas • Denser than air • Poor conductor of heat and electricity • Oxygen, one of the main components of the Earth’s atmosphere, can always be found with other elements. • Two oxygen atoms make up one oxygen molecule, and three oxygen atoms together make up the molecule called ozone.
  • 57. Biological Importance of Oxygen • Humans need it to breathe • Needed for decomposition of organic waste • Water can dissolve oxygen and it is this dissolved oxygen that supports aquatic life.
  • 58. Ecological Importance of Oxygen • Without oxygen at the bottom of the water body, anaerobic bacteria (those that live without oxygen) produce acids. These acids not only increase acidity, but also cause a massive release of phosphorus and nitrogen, two major fertilizers, from the organic sediment and into the water column. • These same anaerobic bacteria put toxic gases in the water including hydrogen sulfide (that rotten egg smell), ammonia, carbon dioxide and methane. These gases are all toxic to fish, beneficial bacteria and insects. • Lack of bottom oxygen is the cause of odors produced by anaerobic bacteria.
  • 59. The Main Reservoirs • Biosphere (living things) • Lithosphere (Earth’s crust) • Atmosphere (air) • Hydrosphere(water) The reservoirs are the locations in which oxygen is found.
  • 61. What is the Oxygen Cycle? • In the oxygen cycle, oxygen atoms present in the earth circulate through a series of intricate processes. • Like the nitrogen, carbon, and water cycles, the oxygen cycle is a biogeochemical cycle. • A biogeochemical cycle is the movement of matter through the biotic and the abiotic spheres of the ecosystem.
  • 62. Step One of Oxygen Cycle Plant release oxygen into the atmosphere as a by-product of photosynthesis. oxygen
  • 63. Photosynthesis • Plants take in carbon dioxide and water and use them to make food. Their food is simple sugar — glucose.
  • 64. Photosynthesis •Definition- process in which green plants use the energy from the sun to make carbohydrates from carbon dioxide and water in the presence of chlorophyll.
  • 65. Photosynthesis (continued) • Plants pull the carbon off CO2 and use the carbon in glucose. (They do not need the oxygen for this. They get that from water, H2O.) • Plants release the oxygen (O2) back into the atmosphere. • Other organisms use the free oxygen for respiration.
  • 67. Step Two of Oxygen Cycle • Animals take in oxygen through the process of respiration. • Animals then break down sugars and food.
  • 68. Respiration • Process by which an organism exchanges gases with its environment • Process → oxygen is abstracted from air, transported to cells for the oxidation of organic molecules while CO2 and H2O, the products of oxidation, are returned to the environment
  • 69. Step Three in Oxygen Cycle • Carbon dioxide is released by animals and used in plants in photosynthesis. • Oxygen is balanced between the atmosphere and the ocean.
  • 70. How do plants contribute? • The oxygen cycle begins with plants and photosynthesis. • Through photosynthesis, plants convert the energy from the sun and water into carbohydrates and oxygen. • During the day: plants convert carbon dioxide into oxygen. • During the night: plants convert oxygen into carbon dioxide to maintain their metabolism.
  • 71. How do animals contribute? • Humans and animals breathe in oxygen and breathe out carbon dioxide through their processes of metabolism, sparking the process of photosynthesis, once again linking back to the plants’ contribution to the oxygen cycle.