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CHEMICAL NAMES AND
FORMULAS
Naming Binary Molecular Compounds
MOLECULAR COMPOUNDS
 Molecular compounds are inorganic compounds that take the
form of discrete molecules. Examples include such familiar
substances as water (H2O) and carbon dioxide (CO2). These
compounds are very different from ionic compounds like sodium
chloride (NaCl). Ionic compounds are formed when metal atoms lose
one or more of their electrons to nonmetal atoms. The resulting
cations and anions are electrostatically attracted to each other.
MOLECULAR COMPOUNDS
 So what holds the atoms of a molecule together? Rather
than forming ions, the atoms of a molecule share
their electrons in such a way that a bond forms between a
pair of atoms. In a carbon dioxide molecule, there are two of
these bonds, each occurring between the carbon atom and one
of the two oxygen atoms
CARBON DIOXIDE
Carbon dioxide molecules
consist of a central carbon
atom bonded to 2 oxygen
atoms.
NAMING BINARY
MOLECULAR COMPOUNDS
 Recall that a molecular formula shows the number of atoms of
each element that a molecule contains. A molecule of water contains
two hydrogen atoms and one oxygen atom, so its formula is H2O. A
molecule of octane, which is a component of gasoline, contains 8
atoms of carbon and 18 atoms of hydrogen. The molecular formula
of octane is C8H18C8H18
NAMING BINARY
MOLECULAR COMPOUNDS
 Naming binary (two-element) molecular compounds is
similar to naming simple ionic compounds. The first element
in the formula is simply listed using the name of the element.
The second element is named by taking the stem of the
element name and adding the suffix -ide. A system of
numerical prefixes is used to specify the number of atoms in a
molecule.
Numerical Prefixes for Naming Binary Covalent Compounds
Number of Atoms in Compound Prefix on the Name of the Element
1 mono-*
2 di-
3 tri-
4 tetra-
5 penta-
6 hexa-
7 hepta-
8 octa-
9 nona-
10 deca-
*This prefix is not used for the first element’s name
CHEMICAL NAMES AND FORMULAS naming and presentation
 Generally, the less electronegative element is
written first in the formula, though there are a
few exceptions. Carbon is always first in a
formula and hydrogen is after nitrogen in a
formula such as NH3. The order of common
nonmetals in binary compound formulas
is CC, PP, NN, HH, SS, II, BrBr, ClCl, OO, FF
 The a or o at the end of a prefix is usually
dropped from the name when the name of
the element begins with a vowel. As an
example, four oxygen atoms, is tetroxide
instead of tetraoxide
 The prefix is "mono" is not added to the
first element’s name if there is only one
atom of the first element in a molecule.
SOME EXAMPLES OF MOLECULAR
COMPOUNDS
Formula Name
NO nitrogen monoxide
N2O dinitrogen monoxide
S2Cl2 disulfur dichloride
Cl2O7 dichlorine heptoxide
 Notice that the mono- prefix is not used with
the nitrogen in the first compound, but is
used with the oxygen in both of the first two
examples. The S2Cl2 emphasizes that the
formulas for molecular compounds are not
reduced to their lowest ratios. The o of
the mono- and the a of hepta-are dropped
from the name when paired with oxide.
SIMPLE MOLECULA R COMPOUNDS
W IT H COMMON NA MES
 For some simple covalent compounds, we use common names
rather than systematic names. We have already encountered these
compounds, but we list them here explicitly:
 H2O: water
 NH3: ammonia
 CH4: methane
 H2O2: hydrogen peroxide
 Methane is the simplest organic
compound. Organic compounds are
compounds with carbon atoms and are
named by a separate nomenclature
system.
 Some Compounds Have Both Covalent
and Ionic Bonds
1. CO2
2. SO2
3. CS2
4. CF4
5. SeCl2
6. SO3
7. SF6
8. Cl2O
9. ClF
10.ClF5

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CHEMICAL NAMES AND FORMULAS naming and presentation

  • 1. CHEMICAL NAMES AND FORMULAS Naming Binary Molecular Compounds
  • 2. MOLECULAR COMPOUNDS  Molecular compounds are inorganic compounds that take the form of discrete molecules. Examples include such familiar substances as water (H2O) and carbon dioxide (CO2). These compounds are very different from ionic compounds like sodium chloride (NaCl). Ionic compounds are formed when metal atoms lose one or more of their electrons to nonmetal atoms. The resulting cations and anions are electrostatically attracted to each other.
  • 3. MOLECULAR COMPOUNDS  So what holds the atoms of a molecule together? Rather than forming ions, the atoms of a molecule share their electrons in such a way that a bond forms between a pair of atoms. In a carbon dioxide molecule, there are two of these bonds, each occurring between the carbon atom and one of the two oxygen atoms
  • 4. CARBON DIOXIDE Carbon dioxide molecules consist of a central carbon atom bonded to 2 oxygen atoms.
  • 5. NAMING BINARY MOLECULAR COMPOUNDS  Recall that a molecular formula shows the number of atoms of each element that a molecule contains. A molecule of water contains two hydrogen atoms and one oxygen atom, so its formula is H2O. A molecule of octane, which is a component of gasoline, contains 8 atoms of carbon and 18 atoms of hydrogen. The molecular formula of octane is C8H18C8H18
  • 6. NAMING BINARY MOLECULAR COMPOUNDS  Naming binary (two-element) molecular compounds is similar to naming simple ionic compounds. The first element in the formula is simply listed using the name of the element. The second element is named by taking the stem of the element name and adding the suffix -ide. A system of numerical prefixes is used to specify the number of atoms in a molecule.
  • 7. Numerical Prefixes for Naming Binary Covalent Compounds Number of Atoms in Compound Prefix on the Name of the Element 1 mono-* 2 di- 3 tri- 4 tetra- 5 penta- 6 hexa- 7 hepta- 8 octa- 9 nona- 10 deca- *This prefix is not used for the first element’s name
  • 9.  Generally, the less electronegative element is written first in the formula, though there are a few exceptions. Carbon is always first in a formula and hydrogen is after nitrogen in a formula such as NH3. The order of common nonmetals in binary compound formulas is CC, PP, NN, HH, SS, II, BrBr, ClCl, OO, FF
  • 10.  The a or o at the end of a prefix is usually dropped from the name when the name of the element begins with a vowel. As an example, four oxygen atoms, is tetroxide instead of tetraoxide
  • 11.  The prefix is "mono" is not added to the first element’s name if there is only one atom of the first element in a molecule.
  • 12. SOME EXAMPLES OF MOLECULAR COMPOUNDS Formula Name NO nitrogen monoxide N2O dinitrogen monoxide S2Cl2 disulfur dichloride Cl2O7 dichlorine heptoxide
  • 13.  Notice that the mono- prefix is not used with the nitrogen in the first compound, but is used with the oxygen in both of the first two examples. The S2Cl2 emphasizes that the formulas for molecular compounds are not reduced to their lowest ratios. The o of the mono- and the a of hepta-are dropped from the name when paired with oxide.
  • 14. SIMPLE MOLECULA R COMPOUNDS W IT H COMMON NA MES  For some simple covalent compounds, we use common names rather than systematic names. We have already encountered these compounds, but we list them here explicitly:  H2O: water  NH3: ammonia  CH4: methane  H2O2: hydrogen peroxide
  • 15.  Methane is the simplest organic compound. Organic compounds are compounds with carbon atoms and are named by a separate nomenclature system.  Some Compounds Have Both Covalent and Ionic Bonds
  • 16. 1. CO2 2. SO2 3. CS2 4. CF4 5. SeCl2 6. SO3 7. SF6 8. Cl2O 9. ClF 10.ClF5