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COLLOIDS

 Definition and Properties of Colloids
              Classification of Colloids
  Importance of ColloidsTo Daily Life
Classify Them!
   brine solution      ice cream soda
   muddy water         starch solution
   marshmallow         marbles in water
   butter              gelatin
   air                 brass
   paint               ruby
   sand and water      pebbles and water
   soda
Solution          Colloid        Suspension

air               butter           marbles in
brass             gelatin          water
brine solution    ice cream soda   muddy water
soda              marshmallow      pebbles and
starch solution   paint            water
                  ruby             sand and water
Comparison of the Properties of
           Solutions, Colloids, And Suspensions
    Property         Solution            Colloid            Suspension
Particle Size    Less than 1 nm      1 to 100 nm          More than 100 nm


Appearance       Clear               Cloudy               Cloudy

Homogeneity      Homogeneous         Homogeneous or       Heterogeneous
                                     Heterogeneous
Transparency     Transparent but     Often translucent    Often opaque but
                 often colored       and opaque but       can be translucent
                                     can be transparent
Separation       Does not separate   Does not separate    Separates or settles


Filterability    Passes through      Passes through       Particles do not
                 filter paper        filter paper         pass through filter
                                                          paper
Unique Properties of Colloids

                       Tyndall Effect
                          A beam of light
                           passing through
                           a transparent
                           pure colorless
                           solid, liquid or
                           gas cannot be
                           seen except at
                           the point where
                           it enters and
                           leaves the object.
                          scattering of light
   Brownian Movement
      If a colloid is viewed
       under a special
       microscope, the
       dispersed particles will
       be seen moving in a
       rapid, random, zigzag
       motion through the
       dispersion medium.
      This motion in a
       colloid is one of the
       reasons why particles
       remain suspended
       indefinitely.
     Electric Charge
             A dispersed colloidal particle can
              adsorb electrically charged particles
              on its surface.
             opposite attracts; same repel
             prevents coagulation and
  OMG!        precipitation of dispersed colloidal
You’re my     particles
  exact
opposite!
                           I think I am
                           attracted to
                                you!
activated carbon




   Adsoptive Property
       Adsoption is the process of collecting a thin layer of
        molecules or ions of a substance with which it is in
        contact.
       Surfaces of solids and liquids can adsorb molecules from
        fluid phases (liquids and gases) onto their surface.
          • Chemisorption – fairly strong, resembling chemical
             bonds, and difficult to break
             ex: activated charcoal
          • Physisorption – weak, involves only Van der Waals
             forces and the adsorbed material can usually
             removed again.
             ex: silica gel
                                                silica gel
Animation References

                Animation of Tyndall Effect:
                 http://www.yteach.com/page.php/r
 I want to       esources/view_all?id=mixture_coll
see those…       oid_solubility_molarity_solution_c
                 oncentration_dilution_ion_titration
                 _mass_percent_t_page_3&from=
                 search
                Animation of Brownian Movement:
                 www.edumedia-
                 sciences.com/en/a247-brownian-
                 motion
Classification of Colloids
 components : dispersed particles (solute)
  and dispersing medium (solvent)
 can be classified according to:
     Phase
     Affinity Between Phases


                       Fabulous!
Types of Colloids
Dispersed    Dispersion         Name                  Examples
Particles     Medium

Gas         Liquid        Foam              Beaten egg white, shaving
                                            cream, whipped cream, ice
                                            cream soda

Gas         Solid         Solid foam        Marshmallow, rubber foam

Liquid      Gas           Liquid aerosols   Clouds, fog, mist, hair spray,
                                            deodorant spray

Liquid      Liquid        Emulsion          Milk, mayonnaise, blood

Liquid      Solid         Gel               Cheese, butter, margarine
Dispersed    Dispersion         Name               Examples
Particles     Medium

Solid       Gas           Soild aerosol   Smoke, dust in air

Solid       Liquid        Sol             Paint, starch mixture, hot
                                          chocolate, gelatin
Solid       Solid         Solid sol       Colored glass, gem glass like
                                          ruby and garnet
Classification According To
Phase
   AEROSOLS
       suspension of
        liquid or solid
        particles in
        gas
solid foam



                  FOAMS
                      colloidal
liquid foam            dispersions
                       of gas
                       bubbles in
                       liquids
                       (liquid
                       foams) or
                       solid (solid
                       foams)
   EMULSIONS
      colloidal dispersion of liquid
       either a liquid or a solid.
      The 2 components of an
       emulsion are usually
       immiscible and require an
       addition of emulsifying
       agent or peptizing
       agent to form stable
       emulsion.
      If the dispersed particles in
       an emulsion are relatively
       large, they still tend to
       separate from the dispersion
       medium. This could be
       prevented by the a process
       called homogenization.
   SOLS
       a solid
        dispersed in
        either a
        solid or a
        liquid
   GELS
       a colloidal system in
        which the dispersed
        phase consists of
        fibrous, interwoven
        particles called
        fibrils which exert a
        marked effect on
        the physical
        properties of the
        dispersing medium
Classification According to
Affinity Between Phases
 Lyophilic  solvent – loving; have a
  strong attraction for the molecules of the
  dispersing medium.
 Lyophobic  solvent –fearing; dispersed
  phase are actually immiscible with the
  solvent under normal conditions.

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Colloids

  • 1. COLLOIDS Definition and Properties of Colloids Classification of Colloids Importance of ColloidsTo Daily Life
  • 2. Classify Them!  brine solution  ice cream soda  muddy water  starch solution  marshmallow  marbles in water  butter  gelatin  air  brass  paint  ruby  sand and water  pebbles and water  soda
  • 3. Solution Colloid Suspension air butter marbles in brass gelatin water brine solution ice cream soda muddy water soda marshmallow pebbles and starch solution paint water ruby sand and water
  • 4. Comparison of the Properties of Solutions, Colloids, And Suspensions Property Solution Colloid Suspension Particle Size Less than 1 nm 1 to 100 nm More than 100 nm Appearance Clear Cloudy Cloudy Homogeneity Homogeneous Homogeneous or Heterogeneous Heterogeneous Transparency Transparent but Often translucent Often opaque but often colored and opaque but can be translucent can be transparent Separation Does not separate Does not separate Separates or settles Filterability Passes through Passes through Particles do not filter paper filter paper pass through filter paper
  • 5. Unique Properties of Colloids  Tyndall Effect  A beam of light passing through a transparent pure colorless solid, liquid or gas cannot be seen except at the point where it enters and leaves the object.  scattering of light
  • 6. Brownian Movement  If a colloid is viewed under a special microscope, the dispersed particles will be seen moving in a rapid, random, zigzag motion through the dispersion medium.  This motion in a colloid is one of the reasons why particles remain suspended indefinitely.
  • 7. Electric Charge  A dispersed colloidal particle can adsorb electrically charged particles on its surface.  opposite attracts; same repel  prevents coagulation and OMG! precipitation of dispersed colloidal You’re my particles exact opposite! I think I am attracted to you!
  • 8. activated carbon  Adsoptive Property  Adsoption is the process of collecting a thin layer of molecules or ions of a substance with which it is in contact.  Surfaces of solids and liquids can adsorb molecules from fluid phases (liquids and gases) onto their surface. • Chemisorption – fairly strong, resembling chemical bonds, and difficult to break ex: activated charcoal • Physisorption – weak, involves only Van der Waals forces and the adsorbed material can usually removed again. ex: silica gel silica gel
  • 9. Animation References  Animation of Tyndall Effect: http://www.yteach.com/page.php/r I want to esources/view_all?id=mixture_coll see those… oid_solubility_molarity_solution_c oncentration_dilution_ion_titration _mass_percent_t_page_3&from= search  Animation of Brownian Movement: www.edumedia- sciences.com/en/a247-brownian- motion
  • 10. Classification of Colloids  components : dispersed particles (solute) and dispersing medium (solvent)  can be classified according to:  Phase  Affinity Between Phases Fabulous!
  • 11. Types of Colloids Dispersed Dispersion Name Examples Particles Medium Gas Liquid Foam Beaten egg white, shaving cream, whipped cream, ice cream soda Gas Solid Solid foam Marshmallow, rubber foam Liquid Gas Liquid aerosols Clouds, fog, mist, hair spray, deodorant spray Liquid Liquid Emulsion Milk, mayonnaise, blood Liquid Solid Gel Cheese, butter, margarine
  • 12. Dispersed Dispersion Name Examples Particles Medium Solid Gas Soild aerosol Smoke, dust in air Solid Liquid Sol Paint, starch mixture, hot chocolate, gelatin Solid Solid Solid sol Colored glass, gem glass like ruby and garnet
  • 13. Classification According To Phase  AEROSOLS  suspension of liquid or solid particles in gas
  • 14. solid foam  FOAMS  colloidal liquid foam dispersions of gas bubbles in liquids (liquid foams) or solid (solid foams)
  • 15. EMULSIONS  colloidal dispersion of liquid either a liquid or a solid.  The 2 components of an emulsion are usually immiscible and require an addition of emulsifying agent or peptizing agent to form stable emulsion.  If the dispersed particles in an emulsion are relatively large, they still tend to separate from the dispersion medium. This could be prevented by the a process called homogenization.
  • 16. SOLS  a solid dispersed in either a solid or a liquid
  • 17. GELS  a colloidal system in which the dispersed phase consists of fibrous, interwoven particles called fibrils which exert a marked effect on the physical properties of the dispersing medium
  • 18. Classification According to Affinity Between Phases  Lyophilic  solvent – loving; have a strong attraction for the molecules of the dispersing medium.  Lyophobic  solvent –fearing; dispersed phase are actually immiscible with the solvent under normal conditions.