TRP 2
Storage of Hazardous Materials
IAMC Toolkit
Innovative Approaches for the Sound
Management of Chemicals and Chemical Waste
2
The presence of hazardous substances in a
company involves special rules for handling,
processing, disposal and storage of such
substances. This presentation explains the rules
to be applied when establishing storage systems.
The reader will learn about the use of the
systems providing illustrations of technical
solutions, general storage rules and specific
rules for each storage category (including
incompatibilities).
Introduction
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1. Risk identification
and safety
2. Transport and
storage
3. Fire and explosion
protection
4. Emergency
response
11. Chemical classification
and labelling
21. Internal transport of
chemicals
31. Fire protection
41. Emergency response
plan
12. Risk assessment
22. Internal pedestrian
routes
32. Fire protection in
welding and cutting
operations
13. Safety rules 23. Storage 33. Explosion protection
14. Personal protective
equipment
34. Container cleaning
15. Skin protection
16. Emergency escape
routes
17. Handling of solvents,
acids and bases
18. Safety in gas tank
handling
Hazard Management
Checklists
4
1. Introduction
2. Storage Concept
3. Technical Solutions
• General storage rules
• Specific rules for each storage category
• Specific storage incompatibilities
4. Examples
Contents
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Introduction – Storage Locations
Storage
Production line
Mechanical
workshop
Storage
Storage
Storage
Storage may be necessary at many places in a
production unit. Different (possibly incompatible)
chemicals might be stored in proximity. Measures should
be taken to avoid potentially dangerous situations.
Storage
Source: CSD
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Introduction
Appropriate storage may prevent hazardous chemical reactions.
POTENTIAL DANGER CONSEQUENCES
Fire/Explosion
Toxic vapours and gases
Secondary reactions
Water and soil pollution, due to
contaminated fire-fighting water
Flooding
Environmental contamination due to
polluted water
Leakages
Dispersion of toxic substances, harmful
to the environment
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Introduction
Appropriate storage may prevent hazardous chemical reactions.
POTENTIAL DANGER CONSEQUENCES
Acids + non precious metals
Spontaneous combustion (gaseous
hydrogen)
Oxidants + organic materials (wood,
paper, etc.)
Fire, explosion
Acids + bases
Exothermic reaction (heat emission +
corrosive projections)
Nitric acid + organic substances or
metals
Toxic nitrous gas
Chlorine bleach + acids Toxic gaseous chlorine
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Storage Concept
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9
Storage Concept
The rules that guarantee the appropriate storage of
hazardous materials are summarized in the
storage concept, drawn up by the safety officer
of a factory.
These rules are the same for large and small companies.
Their application needs to be adapted to each situation,
in a case-by-case approach.
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Storage Concept
General objectives
1. Matching local conditions and measures to the hazards
of stored products
2. Identification of conflicts and adjustment of storage
3. Compliance with legal requirements
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Storage Concept
Contents of the storage concept
Description of the
local environment
- Storage conditions
- Physical properties
of storage room(s)
- Definitions of the
stored substances
Hazardous
substances
- Quantities
- Nature, hazards
- Identification on a
map (storage and
handling)
Measures
- Structural
- Technical
- Organizational
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Table of contents (example)
 Hazardous substances: overview of the
dangers
 Identification of the storage place(s): map
 Receipt and storage
‒ Storage rules
‒ Illustrations
 Safety data sheets (SDSs)
 Inventory of hazardous substances
 Accidents
‒ Spillage
‒ Inhalation or contact with the skin or eyes
 Waste storage and disposal
 Organization: responsibilities and tasks
‒ Training
12
Storage Concept
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Storage Concept
Organization: Tasks and responsibilities
Training, information, documentation
Hazard experts
Chemical products
coordinator
Safety manager
External support
communication
Production supervisor
For each sector
Information, monitoring
communication
Communication, monitoring
Users
Employees, workers, temporary workers, etc.
Information and
documentation of chemical
products and associated
hazards
Information about
conditions of use and
requirements
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Source : CSD / ISSPPRO
Technical Solutions
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15
General Storage Rules: Containers
Original containers
 Hazardous substances must always be stored in their
original containers.
 If they have to be poured into another container, the new
receptacle must have the same mechanical, chemical
and physical properties and must be properly labelled.
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General Storage Rules: Identification of Hazardous Materials
Hazardous materials must be clearly identified.
Inventory and safety data sheets (SDSs)
The following data must be accessible:
1. A register listing the maximum quantities for each
category of hazardous material and the currently stored
quantities
2. The storage position(s) on a map
3. A file containing the SDSs for every substance stored
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General Storage Rules: Identification of Hazardous Materials
Inventory and safety data sheets (SDSs)
Source: CSD Source: CSD
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General Storage Rules: Identification of Hazardous Materials
Identification of storage places (main and secondary)
Source: CSD
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General Storage Rules: Identification of Hazardous Materials
The containers must be labelled and the places where
hazardous substances are stored must be marked.
Minimum information required on the labels:
Source: United Nations, Globally Harmonized System of Classification and
Labelling of Chemicals (GHS)
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General Storage Rules: Identification of Hazardous Materials
Label example
Methanol (solvent) (N° CE: 603-001-00-X)
Highly flammable liquid and vapour H225
Toxic if swallowed
Toxic in contact with skin
Toxic if inhaled
Causes damage to organs (especially to eyes)
H301
H311
H331
H370
Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
Store in a well-ventilated place. Keep container tightly closed.
Wear protective gloves/clothing, eye/face protection.
If on skin: wash with water and soap.
If swallowed: Rinse mouth. Do NOT induce vomiting. Immediately call a poison centre or a
doctor.
Store locked up.
P210
P403/233
P280
P302/352
P301/310
P405
Chemistry Example Sàrl 200 litres
St. Example 10, 1111 Town
Telephone 032 600 60 60
2
1
3
4
5
Source: Based on Sicherheitsinstitut
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General Storage Rules: Excluding Storage Incompatibilities
What are storage incompatibilities?
 Certain chemical substances when mixed together can trigger violent
and potentially hazardous reactions. Such substances are
incompatible and must not be stored together.
 The compatibility matrices on the following slides show a classification
of substances that, according to their hazardous properties, must not
be stored together (red), can be stored together under certain
conditions that have to be verified in the SDS (orange) or can usually
be stored together without disadvantages (green).
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General Storage Rules: Excluding Storage Incompatibilities
General incompatibilities
Legend:
+
-
o
Can be stored together
Cannot be stored together
Can be stored together under
certain conditions (check the
SDSs)
Objective:
Avoid hazardous reactions
Source: Based on Neosys
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Formicacid
Solutionofammonia
Solutionofiron
chloride(III)
Solutionofiron
chloride(III)sulfate
Aceticacid
Hydrofluoricacid
Solutionofpotas-
siumhydroxide
Solutionofsodium
hydroxide
Solutionofsodium
hydrogensulfite
Solutionofsodium
hypochlorite
Peraceticacid
Phosphoricacid
Nitricacid
Hydrochloricacid
Sulphuricacid
Hydrogenperoxide
Storage
category
8 8 8 8 3 6.1 8 8 10/12 5 5 8 5 8 8 5
Formic acid 8
Solution of ammonia 8
Solution of iron chloride (III) 8
Solution of iron chloride (III)
sulfate
8
Acetic acid 3
Hydrofluoric acid 6.1
Solution of potassium
hydroxide
8
Solution of sodium
hydroxide
8
Solution of sodium
hydrogensulfite
10/12
Solution of sodium
hypochlorite
5
Peracetic acid 5
Phosphoric acid 8
Nitric acid 5
Hydrochloric acid 8
Sulphuric acid 8
Hydrogen peroxide 5
23Source: Based on Sicherheitsinstitut
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Objectives:
 Prevent human exposure and environmental contamination
 Prevent the mixing of substances and hazardous reactions
Hazardous liquid substances must be stored on a
catch basin.
24
General Storage Rules: Leakages Must Be Confined
Overflows, leakages, accidental spillage, etc. may occur.
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General Storage Rules: Leakages Must Be Confined
Catch basins: Examples
From the smallest quantities to the largest
Bulk storage
Source: ECA
Post-storage
Source: CSD
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Container storage
Source: UNIDO
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General Storage Rules: Leakages Must Be Confined
Catch basins: Design
 The retention capacity must provide for at least 100% of
the highest volume stored.
 The material must be adapted to the substances stored
(e.g. concrete is not suitable for solvent retention).
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General Storage Rules
Other general rules
1. The flooring of the storage area must be impermeable. A special
coating (sealing) will often be necessary, as concrete is permeable to
many substances. This coating must be incombustible. Structural
2. The separation of the storage areas (or compartments) according to
the storage categories must be clearly identified and labelled
(flammable, toxic, corrosive, etc.). Good practice
3. Other non-hazardous materials should not be stored in the same
place (wrapping, paper, cardboard, spare parts, etc.). Good practice
4. The containers must be protected from any mechanical or thermal
influence (heat sources, object falls, pressure through weight, etc.).
Good practice
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General Storage Rules
5. There must be one responsible person (and one substitute)
appointed for the storage area(s). Organizational
6. Appropriate personal protective equipment (PPE) must be easily
available and properly maintained. Organizational
7. At least one eye shower must be installed. An emergency shower can
be necessary. Organizational
8. Store minimum quantities. Good practice
9. Control stock, i.e. first-in/first-out, move redundant stock. Good practice
10. Segregate “empties” (cylinders, sacks, drums, bottles). Good practice
11. Ensure adequate access for both normal and emergency purposes
with alternative routes. Structural/Good practice
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General Storage Rules
12. Monitor stock, (temperature, pressure, degradation of substances,
deterioration of packaging or containers/corrosion, leakages,
condition of labels, expiry date, etc.) Good practice
13. Decontamination and first-aid provisions (neutralize/destroy, fire-
fighting). Technical
14. Appropriate gas/vapour/fume/pressure venting must be available
(e.g. flame arrestors, scrubbers, absorbers, stacks). Technical
15. Provide adequate, safe lighting. Technical
16. Limit stack heights. Generally chemicals should be stored off the
ground (e.g. to facilitate cleaning, to keep above any ingress of
water in the event of flooding).
Source: Hazardous Chemicals Handbook
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General Storage Rules – Exercise
Cite the four main storage rules
and give examples of measures.
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General Storage Rules – Exercise
Four main storage rules
Methyl-
Flammaline
Source: United Nations
Source: Based on Neosys
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Source: UNIDO
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General Storage Rules – Exercise
Four main storage rules
1. Original container
 Hazardous substances must always be stored in their original
containers.
 If they have to be poured into another container, the new
receptacle must have the same mechanical, chemical and
physical properties and must be properly labelled.
2. Hazardous material must be clearly identified
 The following information should be available:
 A register including the maximum quantities for each
category of hazardous material and the currently stored
quantities
 The storage position(s) on a map
 A file containing the SDSs for every substance stored
Methyl-
Flammaline
Source: United Nations
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General Storage Rules – Exercise
Four main storage rules
3. Exclude storage incompatibilities
 Hazardous substances must be stored separately from any other
non-hazardous material, and especially from food or drugs.
 Acids and bases must not be stored together.
4. Leakages must be confined
Hazardous liquids must be stored on a catch basin in order to manage
overflow, leakage or accidental spillage. The objective of containing the
liquid and avoiding its dispersion is to prevent:
 Environmental contamination and human exposure
 One of the hazardous reactions previously mentioned
Source: Based on Neosys
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Source: UNIDO
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Specific Storage Rules – Categories
Storage class Substances property ADR/UN labeling GHS labelling
SC 2 Liquefied or under pressure gas
SC 3 Flammable liquid
SC 4.1 Flammable solid
SC 4.2 Auto flammable
SC 4.3 Contact with water produces
flammable gas emissions
SC 5 Oxidizing substances / organic
peroxides
SC 6.1 Toxic
SC 8 Corrosive or caustic
SC 9 Other hazardous substances, incl.
environmentally hazardous
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Source: United Nations
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Specific Storage Rules – Categories
N° Storage category
2 Gases: compressed liquefied or dissolved under pressure
3 Flammable liquids
4.1 Flammable solids
4.2 Pyrophoric substances
4.3 Water reactive substances (substances which in contact with
water emit flammable gases)
5 Oxidizing substances and organic peroxides
6 Toxic substances
8 Corrosive and caustic substances
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Specific Storage Rules – Category 2
Storage Category 2: Liquefied gases or gases under
pressure
 Gas bottles must be protected by a fence.
 Use natural or forced ventilation:
 Extraction near the ceiling if the gas is lighter than the air
 Extraction near the floor if the gas is denser than the air
 Air renewal 3 to 5 times per hour
 Ammoniac and gaseous chlorine require specific storage
conditions, designed by a specialist (service provider).
SPECIFIC DANGERS
- Gas leakage
- In case of accidental destruction or fire, the pressurized
container can turn into a dangerous projectile.
Source: Suva
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Specific Storage Rules – Category 3
Storage Category 3: Flammable liquids
 Keep away from ignition sources.
 Electrical devices in storage rooms must be grounded and used
so as to avoid ignition.
 Empty containers must be carefully cleaned as explosive air/gas
mixes might develop.
 Smoking is forbidden and appropriate prohibitive signs are
displayed.
 Containers must always be closed to avoid evaporation.
SPECIFIC DANGERS
- Flammability of the substance
- Potentially explosive vapours
Source: Suva
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Specific Storage Rules – Category 3
Danger classes Description Examples
F1 Liquids with a maximum flash
point of 21°C
Gasoline, acetone,
cellulose thinner
F2
Liquids with a flashpoint higher
than 21°C and lower than 55°C
Petroleum, mineral oil
F3
Liquids with a flashpoint higher
than 55°C and lower than 100°C
Extra-light heating oil,
diesel
F4 Liquids with a flashpoint higher
than 100°C
Lubricating oils,
vegetable oils
F5
Liquids with low flammability
Halogenated
hydrocarbons
F6 Incombustible liquids Water
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Source: Based on VKF/AEAI
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Specific Storage Rules – Category 3
Flammable liquids: Categories and quantities
Maximum authorized quantity [l]
Storage place (small
container/tank)
Categories F1 and F2 Categories F3, F4 and F5
Any type of room max. 5 max. 30
Cupboard made of hardly
flammable materials
max. 100 max. 450
Premises with specific structural
properties designed to resist fire
> 100 > 450
Source: Based on VKF/AEAI
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Specific Storage Rules – Category 3
Flammable liquids: Large quantities
Quantity Structural requirements
>100 litres (F1, F2)
>450 litres (F3, F4, F5)
Flammable liquids can be stored together in a
specific room built from material with a fire
resistance period of 30 minutes and fire
compartments.
>1,000 litres
Each substance must be isolated in a specific
fire compartment.
>2,000 litres Protection against lightning is mandatory.
Source: Based on VKF/AEAI
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Specific Storage Rules – Category 3
 For compatible substances (A and B), storage compartments should be
divided into storage subareas separated by at least 3 metres.
 For incompatible substances (A and C), storage compartments should be
separated by at least 10 metres or by a firewall.
A B
Min. 3 m
A C
Min. 10 m
A C
Source: CSD
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Specific Storage Rules – Category 3
 Natural ventilation is sufficient if:
 The room has two openings directly connected to
the ambient air.
 One opening is placed at a maximum height of
10 cm above the ground.
 Each opening requires at least 20 cm2 per square
metre of floor area.
 Forced ventilation: Air extractors might be
needed to renew the air 3 to 5 times per
hour.
 Extraction from the upper or lower part of the
premises is chosen according to the gas property.
 The opening must be placed at a maximum height
of 10 cm above the ground.
Storage rooms must be properly ventilated
Source: Suva
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Specific Storage Rules – Category 3
 Forced ventilation is mandatory in
large warehouses where liquids
are stored in stacks on pallets.
 The air replacement frequency (3
to 5 air exchanges per hour) is
calculated based on 3 metres
elevation.
Storage rooms must be properly ventilated
Source: ECA
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Specific Storage Rules – Category 3
Outdoor storage
 Drums containing flammable liquids are preferably stored outdoors, so
that any flammable vapour can readily disperse. Similar considerations
may apply to the dispersion of vapours and fumes from drums
containing toxic liquids or solids. In some cases, weather protection is
provided by a roof.
 The next slide provides recommendations on outdoor storage from the
Hazardous Chemicals Handbook, including safety distances to
neighbouring buildings.
 As a comparison, the Swiss procedure for the evaluation of safety
distances is presented on the next slide but one.
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Outdoor storage: International recommendations
 Label each drum and affix appropriate warnings (e.g. “Highly
Flammable”).
 Limit stack heights, e.g. 4.5 m for 200 litre drums, 5 m for drums
stored on end and 4 m on pallets.
 Segregate highly flammable liquids and mark the stacks. Classify
the area as Zone 2. Place material >15 m away from any working
building, facility building or plant and 7.5 m from plant boundaries and
boundary fences.
 Place stacks of combustible material >7.5 m away from buildings
and 4 m from plant boundary fences.
 Restrict the number of 180 litre drums to 1,500.
 Provide >5 m clearance between adjacent stacks with access on
three sides for fire fighting.
45
Specific Storage Rules – Category 3
Source: Hazardous Chemicals Handbook UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated
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Specific Storage Rules – Category 3
(Swiss Procedure)
 Access must be limited to authorized persons (a fence is mandatory,
surveillance might be needed).
 A safety distance to neighbouring buildings must be observed,
depending on the category, the volume of liquids and the risks for the
neighbourhood.
Outdoor storage
Buried or unburied tanks, stored outside a building or installation
Neighbouring building
(risk evaluation)
Safety distance
Outdoor storage
(volume and danger class)
Source: Based on ECA
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Specific Storage Rules – Category 3
(Swiss Procedure)
Outdoor storage: Evaluation of the neighbourhood risk
Neighbouring building – Activity
Neighbouring
building – Type
Low danger
(Production, treatment and
storage of non-flammable
material)
Medium danger
(Engineering workshops,
car repair, offices,
apartments)
High danger
(Storage/Treatment of
hazardous materials, wood
processing, printing, buildings
with many occupants)
Specifically
resistant to fire
Low Low Low
Non-flammable
(concrete)
Low Medium High
Flammable
(wood)
Medium High High
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Specific Storage Rules – Category 3
(Swiss Procedure)
Outdoor storage: Safety distance for storage in containers
[Metres] Categories F1 and F2 Categories F3, F4 and F5
Risk
evaluation:
Neighbouring
building
<5,000 l
5,000-
50,000 l
>50,000 l <5,000 l
5,000-
50,000 l
>50,000 l
Low 5 10 15 - 5 8
Medium 10 15 20 5 8 12
High 15 20 25 8 12 15
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Specific Storage Rules – Category 3
(Swiss Procedure)
Outdoor storage: Safety distance for storage in tanks
[Metres] Categories F1 and F2 Categories F3, F4 and F5
Risk
evaluation:
Neighbouring
building
Overpressure
resistant tank
<500 m3 >500 m3
Overpressure
resistant tank
<500 m3 >500 m3
Low 12 20 30 6 10 15
Medium 16 25 35 8 12 18
High 20 30 40 10 15 20
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Specific Storage Rules: Flammable Liquids –
Exercise
What are the main dangers related to
flammable substances?
Provide four storage measures.
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Specific Storage Rules: Flammable Liquids –
Exercise
 Main dangers:
 Flammability of the substance
 Potentially explosive vapours
 Storage measures:
Min. 10 m
Source: SUVA
Neighbouring
building
(risk evaluation)
Safety distance
Outdoor storage
(volume and danger
class)
Source: Suva
Source: Based on ECA
Source: CSD
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Specific Storage Rules – Category 4.1
Storage Category 4.1: Flammable solids
 Dust deposits must be avoided and regularly cleaned.
 Proximity to ignition sources must be avoided.
 For quantities over 1,000 kg, the substances must be isolated in
a fire compartment.
SPECIFIC DANGERS
- Fire can smoulder for days or weeks, unnoticed,
before actual flames are visible.
- Consider that even non-flammable solids can be
explosive (dust or flour).
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Source: Shutterstock
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Specific Storage Rules – Category 4.2
Storage Category 4.2: Pyrophoric (auto-flammable)
substances
 Must never be stored outdoors
 Must be protected from any heat source, the ambient
temperature should be controlled
 Must not be stored with combustible, explosive or
flammable substances
 For quantities over 1,000 kg, the substances must be isolated in
a fire compartment.
SPECIFIC DANGERS
- Can ignite very fast when in contact with the air, even in very low quantities
- Examples: phosphor, freshly prepared metallic powders
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Specific Storage Rules – Category 4.3
Storage Category 4.3: Water reactive substances
 Must be stored in a dry place in hermetically closed containers
 Must not be stored with halogens (fluorine, chlorine,
bromine)
 For quantities over 100 kg, the substances must be isolated in a
fire compartment.
 Specific extinguishers must be available and the sign “Do not
extinguish with water” must be visible.
SPECIFIC DANGERS
- Substances which in contact with water emit flammable gases that can ignite
spontaneously
- Examples: calcium, zinc powder
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Specific Storage Rules – Category 5
Storage Category 5: Oxidizing substances/organic
peroxides
 Must not be stored with combustibles (even non-hazardous
substances, wood or paper) or caustic substances
 Small quantities (less than 100 kg), can be stored in the same
room as other substances, but in a separate specific metal box
or cupboard. Some organic peroxides must be refrigerated.
 For quantities over 100 kg, the substances must be isolated in a
fire compartment.
SPECIFIC DANGERS
- Create highly flammable or explosive mixes with any combustible material,
flammable substance or just paper, sugar or wood
- Examples: ferric nitrate, hydrogen peroxide, lead perchlorate
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Specific Storage Rules – Category 6.1
Storage Category 6.1: Toxic substances
 The storage premises must be secured and only
accessible to authorized persons (key or code).
 For quantities over 1,000 kg, the substances must be
isolated in a fire compartment.
SPECIFIC DANGERS
- Can be very harmful, even fatal, in very small quantities
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Specific Storage Rules – Category 8
Storage Category 8: Corrosive and caustic substances
 Must not be stored with substances that create toxic gases
with acids or with combustive and oxidizing substances
 Containers and catch basins must be resistant to corrosion
(special plastics or resin).
 Acids and bases must be physically separated and stored on
distinct catch basins.
 For quantities over 1,000 kg, the substance must be isolated in
a fire compartment.
SPECIFIC DANGERS
- Can be very harmful, even fatal, in case of contact with the skin, the eyes or
in case of ingestion or inhalation of vapours
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Storage of Hazardous Waste
The same rules apply!
Store hazardous waste in the same way you would
store the substance.
 Adequate labelling
 Suitable storage premises
 Proper storage conditions
 …
UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated
59
In Case of an Accident
Accident Reaction Required material
Spillage and
leakage
Cover the liquid with absorbent
material. The absorbent material
used must be treated as
hazardous waste.
Confine the liquid.
Evacuate the area.
Absorbent material (e.g.
sand)
Physical barriers
Contact with eye
or skin
Rinse abundantly.
Contact medical assistance.
Eye wash facility, shower
(at least direct access to
water)
Phone
Inhalation Breath fresh air and contact
medical assistance.
Phone
Onset of fire Extinguish if possible.
Contact rescue services.
Fire blanket, extinguisher
(specific to the chemicals
stored)UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated
Examples
UNIDO│IAMC Toolkit│Images may not be copied,
transmitted or manipulated
60
61
What Is Correct, What Is Not?
 Acid storage and transfer to
operation area
 Correct:
 Appropriate tank in terms of material and
stability
 Wrong:
 No label, no hazard warning
 No catch basin
Source: CSD
UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated
62
What Is Correct, What Is Not?
 Hydrochloric acid
stored in five 200-
litre containers
 Correct:
 Appropriate containers
in terms of material and
stability
 Wrong:
 Direct sun
 No catch basin
 Danger is not clearly
indicated
Source: CSD
UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated
63
What Is Correct, What Is Not?
 Paint and flammable substances
stored in a metal cupboard in an
operation area
 Correct:
 The place of each substance is labelled.
 The cupboard is made of non-flammable
material (metal).
 Wrong:
 The labels are not standard labels
(some information is missing).
 Some containers do not have any label.
 To be checked:
 Retention capacity might not be
sufficient.
Source: CSD
UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated
64
Additional Information
 Hazardous substances are stored in different ways, usually on racks or
in stacks. As long as the storage premises are small, the type of
storage has no critical impact in case of a fire or a major accident.
 However, the larger the quantities stored, the greater influence the
type of storage premises will have on the fire (accident) event.
 The type of storage has a direct influence on the safety measures to
implement.
UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated
65
Additional Information - Storage Rooms
Type of storage Main dangers Measures
High-rack storage
- Very high influence of the packaging
(wooden pallets, cardboard, plastic films)
- Storage location not always easily accessible
- Stack effect which can lead to the rapid
propagation of a fire
- When the storage height exceeds 7.5 m, the
rules should be stricter (extinguishing
installations might be required).
Stacked storage
- Origin of the fire often inaccessible
- Collapse
- Limit the partial storage areas to 100 m2.
- Impose minimum distances of 2.5 m
between stacks.
- Limit the width per stack to a maximum of
four pallets.
- Limit the height per stack to 5 or 6 m.
Bottle storage
- Bursting of pressure vessels (especially in
case of an increase in temperature)
- Propagation of the fire by bottle or aerosol
bombs projected in the air
- Propagation of gases
- Store outdoors or in a fire compartment.
- Implement ventilation measures.
- If necessary, install a gas detector.
- If necessary, provide extinguishing
installations
- Protect against explosions.
Storage at very low
temperatures
- Frostbites
- Asphyxiation
- Gas propagation
- Explosion
- Hypothermia
- Temperature monitoring
- Storage in a fire compartment
- Ventilation measures
- Protection against explosions
- If necessary, install a gas alarm unitSource: Based on FOEN
UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated
66
Key messages
A Storage Concept aims at :
 Matching local conditions and measures to the
hazards of stored products
 Identifying conflicts and adjustment of storage
 Complying with legal requirements
Technical Solutions should be applied to adequately
manage storage rules. Specific rules for each
storage category should be established.
UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated
Sources
UNIDO│IAMC Toolkit│Images may not be copied,
transmitted or manipulated
67
Fusce posuere, magna sed pulvinar ultricies,
purus lectus malesuada libero, sit amet magna
eros quis (ARIAL 32).
Sources
 CSD Engineers, Switzerland/ISSPPRO, Germany, 2015
 Vereinigung Kantonaler Feuerversicherungen: Directive de
protection incendie, liquides inflammables, 2003
(http://www.vkf.ch) (Switzerland)
 United Nations: Globally Harmonized System of Classification
and Labelling of Chemicals (GHS), 2003, last revision 2013
 Carson, P., Mumford, C.: Hazardous Chemicals Handbook
(Second Edition), 2002
 United Nations: UN Recommendations on the Transport of
Dangerous Goods, last revision 2013
68UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated
Fusce posuere, magna sed pulvinar ultricies,
purus lectus malesuada libero, sit amet magna
eros quis (ARIAL 32).
Sources
 FOEN: Guide «Entreposage des matières dangereuses»,
Switzerland, 2011
 VKF/AEAI: Directive protection incendie, liquides inflammables,
Switzerland, 2003
 VKF/AEAI: Distances de sécurité, compartiments coupe-feu,
Switzerland, 2003
 Suva: Liste de contrôle – Stockage de liquides facilement
inflammables, Switzerland, 2011
 Sicherheitsinstitut: Lagerung gefährlicher Stoffe, Leitfaden für
die Praxis, Überarbeitete Auflage 2011, Switzerland, 2011
 Neosys: Formation matières dangereuses, Switzerland, 2011
69UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated
Fusce posuere, magna sed pulvinar ultricies,
purus lectus malesuada libero, sit amet magna
eros quis (ARIAL 32).
Images
 CSD Engineers, Switzerland, 2015
 United Nations Industrial Development Organization (UNIDO),
2015
 United Nations: Globally Harmonized System of Classification
and Labelling of Chemicals (GHS), 2003, last revision 2013
 FOEN: Guide «Entreposage des matières dangereuses»,
Switzerland, 2011
 Suva: Liste de contrôle – Stockage de liquides facilement
inflammables, Switzerland, 2011
70UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated
Fusce posuere, magna sed pulvinar ultricies,
purus lectus malesuada libero, sit amet magna
eros quis (ARIAL 32).
Images
 ECA: Incendie et éléments naturels: Distances de sécurité.
Cours spécialiste en protection incendie AEAI, Switzerland,
2011
 ECA Incendie et éléments naturels: Installations sprinklers,
Switzerland, 2008
 Suva: Santé et sécurité au travail lors de l’emploi de solvants,
Switzerland, 2012
 Suva: Bouteilles à gaz – Entrepôts, rampes, systèmes de
distribution de gaz, Switzerland, 2007
 Shutterstock, USA, 2015
71UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated
72
This presentation was prepared with the requested diligence
and with the generally accepted principles of the relevant
field.
If a third party uses the contents of the presentation in order
to take decisions, the authors disclaim any liability for any
kind of direct or indirect (consequential) damage.
Disclaimer
UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated

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D23 1 storage_of_hazardous_materials_final-web

  • 1. TRP 2 Storage of Hazardous Materials IAMC Toolkit Innovative Approaches for the Sound Management of Chemicals and Chemical Waste
  • 2. 2 The presence of hazardous substances in a company involves special rules for handling, processing, disposal and storage of such substances. This presentation explains the rules to be applied when establishing storage systems. The reader will learn about the use of the systems providing illustrations of technical solutions, general storage rules and specific rules for each storage category (including incompatibilities). Introduction UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated
  • 3. 1. Risk identification and safety 2. Transport and storage 3. Fire and explosion protection 4. Emergency response 11. Chemical classification and labelling 21. Internal transport of chemicals 31. Fire protection 41. Emergency response plan 12. Risk assessment 22. Internal pedestrian routes 32. Fire protection in welding and cutting operations 13. Safety rules 23. Storage 33. Explosion protection 14. Personal protective equipment 34. Container cleaning 15. Skin protection 16. Emergency escape routes 17. Handling of solvents, acids and bases 18. Safety in gas tank handling Hazard Management Checklists
  • 4. 4 1. Introduction 2. Storage Concept 3. Technical Solutions • General storage rules • Specific rules for each storage category • Specific storage incompatibilities 4. Examples Contents UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated
  • 5. 5 Introduction – Storage Locations Storage Production line Mechanical workshop Storage Storage Storage Storage may be necessary at many places in a production unit. Different (possibly incompatible) chemicals might be stored in proximity. Measures should be taken to avoid potentially dangerous situations. Storage Source: CSD UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated
  • 6. 6 Introduction Appropriate storage may prevent hazardous chemical reactions. POTENTIAL DANGER CONSEQUENCES Fire/Explosion Toxic vapours and gases Secondary reactions Water and soil pollution, due to contaminated fire-fighting water Flooding Environmental contamination due to polluted water Leakages Dispersion of toxic substances, harmful to the environment UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated
  • 7. 7 Introduction Appropriate storage may prevent hazardous chemical reactions. POTENTIAL DANGER CONSEQUENCES Acids + non precious metals Spontaneous combustion (gaseous hydrogen) Oxidants + organic materials (wood, paper, etc.) Fire, explosion Acids + bases Exothermic reaction (heat emission + corrosive projections) Nitric acid + organic substances or metals Toxic nitrous gas Chlorine bleach + acids Toxic gaseous chlorine UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated
  • 8. Storage Concept UNIDO│IAMC Toolkit│Images may not be copied, transmitted or manipulated 8
  • 9. 9 Storage Concept The rules that guarantee the appropriate storage of hazardous materials are summarized in the storage concept, drawn up by the safety officer of a factory. These rules are the same for large and small companies. Their application needs to be adapted to each situation, in a case-by-case approach. UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated
  • 10. 10 Storage Concept General objectives 1. Matching local conditions and measures to the hazards of stored products 2. Identification of conflicts and adjustment of storage 3. Compliance with legal requirements UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated
  • 11. 11 Storage Concept Contents of the storage concept Description of the local environment - Storage conditions - Physical properties of storage room(s) - Definitions of the stored substances Hazardous substances - Quantities - Nature, hazards - Identification on a map (storage and handling) Measures - Structural - Technical - Organizational UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated
  • 12. Table of contents (example)  Hazardous substances: overview of the dangers  Identification of the storage place(s): map  Receipt and storage ‒ Storage rules ‒ Illustrations  Safety data sheets (SDSs)  Inventory of hazardous substances  Accidents ‒ Spillage ‒ Inhalation or contact with the skin or eyes  Waste storage and disposal  Organization: responsibilities and tasks ‒ Training 12 Storage Concept UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated
  • 13. 13 Storage Concept Organization: Tasks and responsibilities Training, information, documentation Hazard experts Chemical products coordinator Safety manager External support communication Production supervisor For each sector Information, monitoring communication Communication, monitoring Users Employees, workers, temporary workers, etc. Information and documentation of chemical products and associated hazards Information about conditions of use and requirements UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated Source : CSD / ISSPPRO
  • 14. Technical Solutions UNIDO│IAMC Toolkit│Images may not be copied, transmitted or manipulated 14
  • 15. 15 General Storage Rules: Containers Original containers  Hazardous substances must always be stored in their original containers.  If they have to be poured into another container, the new receptacle must have the same mechanical, chemical and physical properties and must be properly labelled. UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated
  • 16. 16 General Storage Rules: Identification of Hazardous Materials Hazardous materials must be clearly identified. Inventory and safety data sheets (SDSs) The following data must be accessible: 1. A register listing the maximum quantities for each category of hazardous material and the currently stored quantities 2. The storage position(s) on a map 3. A file containing the SDSs for every substance stored UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated
  • 17. 17 General Storage Rules: Identification of Hazardous Materials Inventory and safety data sheets (SDSs) Source: CSD Source: CSD UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated
  • 18. 18 General Storage Rules: Identification of Hazardous Materials Identification of storage places (main and secondary) Source: CSD UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated
  • 19. 19 General Storage Rules: Identification of Hazardous Materials The containers must be labelled and the places where hazardous substances are stored must be marked. Minimum information required on the labels: Source: United Nations, Globally Harmonized System of Classification and Labelling of Chemicals (GHS) UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated
  • 20. 20 General Storage Rules: Identification of Hazardous Materials Label example Methanol (solvent) (N° CE: 603-001-00-X) Highly flammable liquid and vapour H225 Toxic if swallowed Toxic in contact with skin Toxic if inhaled Causes damage to organs (especially to eyes) H301 H311 H331 H370 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Store in a well-ventilated place. Keep container tightly closed. Wear protective gloves/clothing, eye/face protection. If on skin: wash with water and soap. If swallowed: Rinse mouth. Do NOT induce vomiting. Immediately call a poison centre or a doctor. Store locked up. P210 P403/233 P280 P302/352 P301/310 P405 Chemistry Example Sàrl 200 litres St. Example 10, 1111 Town Telephone 032 600 60 60 2 1 3 4 5 Source: Based on Sicherheitsinstitut UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated
  • 21. 21 General Storage Rules: Excluding Storage Incompatibilities What are storage incompatibilities?  Certain chemical substances when mixed together can trigger violent and potentially hazardous reactions. Such substances are incompatible and must not be stored together.  The compatibility matrices on the following slides show a classification of substances that, according to their hazardous properties, must not be stored together (red), can be stored together under certain conditions that have to be verified in the SDS (orange) or can usually be stored together without disadvantages (green). UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated
  • 22. 22 General Storage Rules: Excluding Storage Incompatibilities General incompatibilities Legend: + - o Can be stored together Cannot be stored together Can be stored together under certain conditions (check the SDSs) Objective: Avoid hazardous reactions Source: Based on Neosys UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated
  • 23. Formicacid Solutionofammonia Solutionofiron chloride(III) Solutionofiron chloride(III)sulfate Aceticacid Hydrofluoricacid Solutionofpotas- siumhydroxide Solutionofsodium hydroxide Solutionofsodium hydrogensulfite Solutionofsodium hypochlorite Peraceticacid Phosphoricacid Nitricacid Hydrochloricacid Sulphuricacid Hydrogenperoxide Storage category 8 8 8 8 3 6.1 8 8 10/12 5 5 8 5 8 8 5 Formic acid 8 Solution of ammonia 8 Solution of iron chloride (III) 8 Solution of iron chloride (III) sulfate 8 Acetic acid 3 Hydrofluoric acid 6.1 Solution of potassium hydroxide 8 Solution of sodium hydroxide 8 Solution of sodium hydrogensulfite 10/12 Solution of sodium hypochlorite 5 Peracetic acid 5 Phosphoric acid 8 Nitric acid 5 Hydrochloric acid 8 Sulphuric acid 8 Hydrogen peroxide 5 23Source: Based on Sicherheitsinstitut UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated
  • 24. Objectives:  Prevent human exposure and environmental contamination  Prevent the mixing of substances and hazardous reactions Hazardous liquid substances must be stored on a catch basin. 24 General Storage Rules: Leakages Must Be Confined Overflows, leakages, accidental spillage, etc. may occur. UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated
  • 25. 25 General Storage Rules: Leakages Must Be Confined Catch basins: Examples From the smallest quantities to the largest Bulk storage Source: ECA Post-storage Source: CSD UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated Container storage Source: UNIDO
  • 26. 26 General Storage Rules: Leakages Must Be Confined Catch basins: Design  The retention capacity must provide for at least 100% of the highest volume stored.  The material must be adapted to the substances stored (e.g. concrete is not suitable for solvent retention). UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated
  • 27. 27 General Storage Rules Other general rules 1. The flooring of the storage area must be impermeable. A special coating (sealing) will often be necessary, as concrete is permeable to many substances. This coating must be incombustible. Structural 2. The separation of the storage areas (or compartments) according to the storage categories must be clearly identified and labelled (flammable, toxic, corrosive, etc.). Good practice 3. Other non-hazardous materials should not be stored in the same place (wrapping, paper, cardboard, spare parts, etc.). Good practice 4. The containers must be protected from any mechanical or thermal influence (heat sources, object falls, pressure through weight, etc.). Good practice UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated
  • 28. 28 General Storage Rules 5. There must be one responsible person (and one substitute) appointed for the storage area(s). Organizational 6. Appropriate personal protective equipment (PPE) must be easily available and properly maintained. Organizational 7. At least one eye shower must be installed. An emergency shower can be necessary. Organizational 8. Store minimum quantities. Good practice 9. Control stock, i.e. first-in/first-out, move redundant stock. Good practice 10. Segregate “empties” (cylinders, sacks, drums, bottles). Good practice 11. Ensure adequate access for both normal and emergency purposes with alternative routes. Structural/Good practice UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated
  • 29. 29 General Storage Rules 12. Monitor stock, (temperature, pressure, degradation of substances, deterioration of packaging or containers/corrosion, leakages, condition of labels, expiry date, etc.) Good practice 13. Decontamination and first-aid provisions (neutralize/destroy, fire- fighting). Technical 14. Appropriate gas/vapour/fume/pressure venting must be available (e.g. flame arrestors, scrubbers, absorbers, stacks). Technical 15. Provide adequate, safe lighting. Technical 16. Limit stack heights. Generally chemicals should be stored off the ground (e.g. to facilitate cleaning, to keep above any ingress of water in the event of flooding). Source: Hazardous Chemicals Handbook UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated
  • 30. 30 General Storage Rules – Exercise Cite the four main storage rules and give examples of measures. UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated
  • 31. 31 General Storage Rules – Exercise Four main storage rules Methyl- Flammaline Source: United Nations Source: Based on Neosys UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated Source: UNIDO
  • 32. 32 General Storage Rules – Exercise Four main storage rules 1. Original container  Hazardous substances must always be stored in their original containers.  If they have to be poured into another container, the new receptacle must have the same mechanical, chemical and physical properties and must be properly labelled. 2. Hazardous material must be clearly identified  The following information should be available:  A register including the maximum quantities for each category of hazardous material and the currently stored quantities  The storage position(s) on a map  A file containing the SDSs for every substance stored Methyl- Flammaline Source: United Nations UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated
  • 33. 33 General Storage Rules – Exercise Four main storage rules 3. Exclude storage incompatibilities  Hazardous substances must be stored separately from any other non-hazardous material, and especially from food or drugs.  Acids and bases must not be stored together. 4. Leakages must be confined Hazardous liquids must be stored on a catch basin in order to manage overflow, leakage or accidental spillage. The objective of containing the liquid and avoiding its dispersion is to prevent:  Environmental contamination and human exposure  One of the hazardous reactions previously mentioned Source: Based on Neosys UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated Source: UNIDO
  • 34. 34 Specific Storage Rules – Categories Storage class Substances property ADR/UN labeling GHS labelling SC 2 Liquefied or under pressure gas SC 3 Flammable liquid SC 4.1 Flammable solid SC 4.2 Auto flammable SC 4.3 Contact with water produces flammable gas emissions SC 5 Oxidizing substances / organic peroxides SC 6.1 Toxic SC 8 Corrosive or caustic SC 9 Other hazardous substances, incl. environmentally hazardous UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated Source: United Nations
  • 35. 35 Specific Storage Rules – Categories N° Storage category 2 Gases: compressed liquefied or dissolved under pressure 3 Flammable liquids 4.1 Flammable solids 4.2 Pyrophoric substances 4.3 Water reactive substances (substances which in contact with water emit flammable gases) 5 Oxidizing substances and organic peroxides 6 Toxic substances 8 Corrosive and caustic substances UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated
  • 36. 36 Specific Storage Rules – Category 2 Storage Category 2: Liquefied gases or gases under pressure  Gas bottles must be protected by a fence.  Use natural or forced ventilation:  Extraction near the ceiling if the gas is lighter than the air  Extraction near the floor if the gas is denser than the air  Air renewal 3 to 5 times per hour  Ammoniac and gaseous chlorine require specific storage conditions, designed by a specialist (service provider). SPECIFIC DANGERS - Gas leakage - In case of accidental destruction or fire, the pressurized container can turn into a dangerous projectile. Source: Suva UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated
  • 37. 37 Specific Storage Rules – Category 3 Storage Category 3: Flammable liquids  Keep away from ignition sources.  Electrical devices in storage rooms must be grounded and used so as to avoid ignition.  Empty containers must be carefully cleaned as explosive air/gas mixes might develop.  Smoking is forbidden and appropriate prohibitive signs are displayed.  Containers must always be closed to avoid evaporation. SPECIFIC DANGERS - Flammability of the substance - Potentially explosive vapours Source: Suva UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated
  • 38. 38 Specific Storage Rules – Category 3 Danger classes Description Examples F1 Liquids with a maximum flash point of 21°C Gasoline, acetone, cellulose thinner F2 Liquids with a flashpoint higher than 21°C and lower than 55°C Petroleum, mineral oil F3 Liquids with a flashpoint higher than 55°C and lower than 100°C Extra-light heating oil, diesel F4 Liquids with a flashpoint higher than 100°C Lubricating oils, vegetable oils F5 Liquids with low flammability Halogenated hydrocarbons F6 Incombustible liquids Water UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated Source: Based on VKF/AEAI
  • 39. 39 Specific Storage Rules – Category 3 Flammable liquids: Categories and quantities Maximum authorized quantity [l] Storage place (small container/tank) Categories F1 and F2 Categories F3, F4 and F5 Any type of room max. 5 max. 30 Cupboard made of hardly flammable materials max. 100 max. 450 Premises with specific structural properties designed to resist fire > 100 > 450 Source: Based on VKF/AEAI UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated
  • 40. 40 Specific Storage Rules – Category 3 Flammable liquids: Large quantities Quantity Structural requirements >100 litres (F1, F2) >450 litres (F3, F4, F5) Flammable liquids can be stored together in a specific room built from material with a fire resistance period of 30 minutes and fire compartments. >1,000 litres Each substance must be isolated in a specific fire compartment. >2,000 litres Protection against lightning is mandatory. Source: Based on VKF/AEAI UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated
  • 41. 41 Specific Storage Rules – Category 3  For compatible substances (A and B), storage compartments should be divided into storage subareas separated by at least 3 metres.  For incompatible substances (A and C), storage compartments should be separated by at least 10 metres or by a firewall. A B Min. 3 m A C Min. 10 m A C Source: CSD UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated
  • 42. 42 Specific Storage Rules – Category 3  Natural ventilation is sufficient if:  The room has two openings directly connected to the ambient air.  One opening is placed at a maximum height of 10 cm above the ground.  Each opening requires at least 20 cm2 per square metre of floor area.  Forced ventilation: Air extractors might be needed to renew the air 3 to 5 times per hour.  Extraction from the upper or lower part of the premises is chosen according to the gas property.  The opening must be placed at a maximum height of 10 cm above the ground. Storage rooms must be properly ventilated Source: Suva UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated
  • 43. 43 Specific Storage Rules – Category 3  Forced ventilation is mandatory in large warehouses where liquids are stored in stacks on pallets.  The air replacement frequency (3 to 5 air exchanges per hour) is calculated based on 3 metres elevation. Storage rooms must be properly ventilated Source: ECA UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated
  • 44. 44 Specific Storage Rules – Category 3 Outdoor storage  Drums containing flammable liquids are preferably stored outdoors, so that any flammable vapour can readily disperse. Similar considerations may apply to the dispersion of vapours and fumes from drums containing toxic liquids or solids. In some cases, weather protection is provided by a roof.  The next slide provides recommendations on outdoor storage from the Hazardous Chemicals Handbook, including safety distances to neighbouring buildings.  As a comparison, the Swiss procedure for the evaluation of safety distances is presented on the next slide but one. UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated
  • 45. Outdoor storage: International recommendations  Label each drum and affix appropriate warnings (e.g. “Highly Flammable”).  Limit stack heights, e.g. 4.5 m for 200 litre drums, 5 m for drums stored on end and 4 m on pallets.  Segregate highly flammable liquids and mark the stacks. Classify the area as Zone 2. Place material >15 m away from any working building, facility building or plant and 7.5 m from plant boundaries and boundary fences.  Place stacks of combustible material >7.5 m away from buildings and 4 m from plant boundary fences.  Restrict the number of 180 litre drums to 1,500.  Provide >5 m clearance between adjacent stacks with access on three sides for fire fighting. 45 Specific Storage Rules – Category 3 Source: Hazardous Chemicals Handbook UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated
  • 46. 46 Specific Storage Rules – Category 3 (Swiss Procedure)  Access must be limited to authorized persons (a fence is mandatory, surveillance might be needed).  A safety distance to neighbouring buildings must be observed, depending on the category, the volume of liquids and the risks for the neighbourhood. Outdoor storage Buried or unburied tanks, stored outside a building or installation Neighbouring building (risk evaluation) Safety distance Outdoor storage (volume and danger class) Source: Based on ECA UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated
  • 47. 47 Specific Storage Rules – Category 3 (Swiss Procedure) Outdoor storage: Evaluation of the neighbourhood risk Neighbouring building – Activity Neighbouring building – Type Low danger (Production, treatment and storage of non-flammable material) Medium danger (Engineering workshops, car repair, offices, apartments) High danger (Storage/Treatment of hazardous materials, wood processing, printing, buildings with many occupants) Specifically resistant to fire Low Low Low Non-flammable (concrete) Low Medium High Flammable (wood) Medium High High UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated
  • 48. 48 Specific Storage Rules – Category 3 (Swiss Procedure) Outdoor storage: Safety distance for storage in containers [Metres] Categories F1 and F2 Categories F3, F4 and F5 Risk evaluation: Neighbouring building <5,000 l 5,000- 50,000 l >50,000 l <5,000 l 5,000- 50,000 l >50,000 l Low 5 10 15 - 5 8 Medium 10 15 20 5 8 12 High 15 20 25 8 12 15 UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated
  • 49. 49 Specific Storage Rules – Category 3 (Swiss Procedure) Outdoor storage: Safety distance for storage in tanks [Metres] Categories F1 and F2 Categories F3, F4 and F5 Risk evaluation: Neighbouring building Overpressure resistant tank <500 m3 >500 m3 Overpressure resistant tank <500 m3 >500 m3 Low 12 20 30 6 10 15 Medium 16 25 35 8 12 18 High 20 30 40 10 15 20 UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated
  • 50. 50 Specific Storage Rules: Flammable Liquids – Exercise What are the main dangers related to flammable substances? Provide four storage measures. UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated
  • 51. 51 Specific Storage Rules: Flammable Liquids – Exercise  Main dangers:  Flammability of the substance  Potentially explosive vapours  Storage measures: Min. 10 m Source: SUVA Neighbouring building (risk evaluation) Safety distance Outdoor storage (volume and danger class) Source: Suva Source: Based on ECA Source: CSD UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated
  • 52. 52 Specific Storage Rules – Category 4.1 Storage Category 4.1: Flammable solids  Dust deposits must be avoided and regularly cleaned.  Proximity to ignition sources must be avoided.  For quantities over 1,000 kg, the substances must be isolated in a fire compartment. SPECIFIC DANGERS - Fire can smoulder for days or weeks, unnoticed, before actual flames are visible. - Consider that even non-flammable solids can be explosive (dust or flour). UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated Source: Shutterstock
  • 53. 53 Specific Storage Rules – Category 4.2 Storage Category 4.2: Pyrophoric (auto-flammable) substances  Must never be stored outdoors  Must be protected from any heat source, the ambient temperature should be controlled  Must not be stored with combustible, explosive or flammable substances  For quantities over 1,000 kg, the substances must be isolated in a fire compartment. SPECIFIC DANGERS - Can ignite very fast when in contact with the air, even in very low quantities - Examples: phosphor, freshly prepared metallic powders UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated
  • 54. 54 Specific Storage Rules – Category 4.3 Storage Category 4.3: Water reactive substances  Must be stored in a dry place in hermetically closed containers  Must not be stored with halogens (fluorine, chlorine, bromine)  For quantities over 100 kg, the substances must be isolated in a fire compartment.  Specific extinguishers must be available and the sign “Do not extinguish with water” must be visible. SPECIFIC DANGERS - Substances which in contact with water emit flammable gases that can ignite spontaneously - Examples: calcium, zinc powder UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated
  • 55. 55 Specific Storage Rules – Category 5 Storage Category 5: Oxidizing substances/organic peroxides  Must not be stored with combustibles (even non-hazardous substances, wood or paper) or caustic substances  Small quantities (less than 100 kg), can be stored in the same room as other substances, but in a separate specific metal box or cupboard. Some organic peroxides must be refrigerated.  For quantities over 100 kg, the substances must be isolated in a fire compartment. SPECIFIC DANGERS - Create highly flammable or explosive mixes with any combustible material, flammable substance or just paper, sugar or wood - Examples: ferric nitrate, hydrogen peroxide, lead perchlorate UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated
  • 56. 56 Specific Storage Rules – Category 6.1 Storage Category 6.1: Toxic substances  The storage premises must be secured and only accessible to authorized persons (key or code).  For quantities over 1,000 kg, the substances must be isolated in a fire compartment. SPECIFIC DANGERS - Can be very harmful, even fatal, in very small quantities UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated
  • 57. 57 Specific Storage Rules – Category 8 Storage Category 8: Corrosive and caustic substances  Must not be stored with substances that create toxic gases with acids or with combustive and oxidizing substances  Containers and catch basins must be resistant to corrosion (special plastics or resin).  Acids and bases must be physically separated and stored on distinct catch basins.  For quantities over 1,000 kg, the substance must be isolated in a fire compartment. SPECIFIC DANGERS - Can be very harmful, even fatal, in case of contact with the skin, the eyes or in case of ingestion or inhalation of vapours UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated
  • 58. 58 Storage of Hazardous Waste The same rules apply! Store hazardous waste in the same way you would store the substance.  Adequate labelling  Suitable storage premises  Proper storage conditions  … UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated
  • 59. 59 In Case of an Accident Accident Reaction Required material Spillage and leakage Cover the liquid with absorbent material. The absorbent material used must be treated as hazardous waste. Confine the liquid. Evacuate the area. Absorbent material (e.g. sand) Physical barriers Contact with eye or skin Rinse abundantly. Contact medical assistance. Eye wash facility, shower (at least direct access to water) Phone Inhalation Breath fresh air and contact medical assistance. Phone Onset of fire Extinguish if possible. Contact rescue services. Fire blanket, extinguisher (specific to the chemicals stored)UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated
  • 60. Examples UNIDO│IAMC Toolkit│Images may not be copied, transmitted or manipulated 60
  • 61. 61 What Is Correct, What Is Not?  Acid storage and transfer to operation area  Correct:  Appropriate tank in terms of material and stability  Wrong:  No label, no hazard warning  No catch basin Source: CSD UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated
  • 62. 62 What Is Correct, What Is Not?  Hydrochloric acid stored in five 200- litre containers  Correct:  Appropriate containers in terms of material and stability  Wrong:  Direct sun  No catch basin  Danger is not clearly indicated Source: CSD UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated
  • 63. 63 What Is Correct, What Is Not?  Paint and flammable substances stored in a metal cupboard in an operation area  Correct:  The place of each substance is labelled.  The cupboard is made of non-flammable material (metal).  Wrong:  The labels are not standard labels (some information is missing).  Some containers do not have any label.  To be checked:  Retention capacity might not be sufficient. Source: CSD UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated
  • 64. 64 Additional Information  Hazardous substances are stored in different ways, usually on racks or in stacks. As long as the storage premises are small, the type of storage has no critical impact in case of a fire or a major accident.  However, the larger the quantities stored, the greater influence the type of storage premises will have on the fire (accident) event.  The type of storage has a direct influence on the safety measures to implement. UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated
  • 65. 65 Additional Information - Storage Rooms Type of storage Main dangers Measures High-rack storage - Very high influence of the packaging (wooden pallets, cardboard, plastic films) - Storage location not always easily accessible - Stack effect which can lead to the rapid propagation of a fire - When the storage height exceeds 7.5 m, the rules should be stricter (extinguishing installations might be required). Stacked storage - Origin of the fire often inaccessible - Collapse - Limit the partial storage areas to 100 m2. - Impose minimum distances of 2.5 m between stacks. - Limit the width per stack to a maximum of four pallets. - Limit the height per stack to 5 or 6 m. Bottle storage - Bursting of pressure vessels (especially in case of an increase in temperature) - Propagation of the fire by bottle or aerosol bombs projected in the air - Propagation of gases - Store outdoors or in a fire compartment. - Implement ventilation measures. - If necessary, install a gas detector. - If necessary, provide extinguishing installations - Protect against explosions. Storage at very low temperatures - Frostbites - Asphyxiation - Gas propagation - Explosion - Hypothermia - Temperature monitoring - Storage in a fire compartment - Ventilation measures - Protection against explosions - If necessary, install a gas alarm unitSource: Based on FOEN UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated
  • 66. 66 Key messages A Storage Concept aims at :  Matching local conditions and measures to the hazards of stored products  Identifying conflicts and adjustment of storage  Complying with legal requirements Technical Solutions should be applied to adequately manage storage rules. Specific rules for each storage category should be established. UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated
  • 67. Sources UNIDO│IAMC Toolkit│Images may not be copied, transmitted or manipulated 67
  • 68. Fusce posuere, magna sed pulvinar ultricies, purus lectus malesuada libero, sit amet magna eros quis (ARIAL 32). Sources  CSD Engineers, Switzerland/ISSPPRO, Germany, 2015  Vereinigung Kantonaler Feuerversicherungen: Directive de protection incendie, liquides inflammables, 2003 (http://www.vkf.ch) (Switzerland)  United Nations: Globally Harmonized System of Classification and Labelling of Chemicals (GHS), 2003, last revision 2013  Carson, P., Mumford, C.: Hazardous Chemicals Handbook (Second Edition), 2002  United Nations: UN Recommendations on the Transport of Dangerous Goods, last revision 2013 68UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated
  • 69. Fusce posuere, magna sed pulvinar ultricies, purus lectus malesuada libero, sit amet magna eros quis (ARIAL 32). Sources  FOEN: Guide «Entreposage des matières dangereuses», Switzerland, 2011  VKF/AEAI: Directive protection incendie, liquides inflammables, Switzerland, 2003  VKF/AEAI: Distances de sécurité, compartiments coupe-feu, Switzerland, 2003  Suva: Liste de contrôle – Stockage de liquides facilement inflammables, Switzerland, 2011  Sicherheitsinstitut: Lagerung gefährlicher Stoffe, Leitfaden für die Praxis, Überarbeitete Auflage 2011, Switzerland, 2011  Neosys: Formation matières dangereuses, Switzerland, 2011 69UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated
  • 70. Fusce posuere, magna sed pulvinar ultricies, purus lectus malesuada libero, sit amet magna eros quis (ARIAL 32). Images  CSD Engineers, Switzerland, 2015  United Nations Industrial Development Organization (UNIDO), 2015  United Nations: Globally Harmonized System of Classification and Labelling of Chemicals (GHS), 2003, last revision 2013  FOEN: Guide «Entreposage des matières dangereuses», Switzerland, 2011  Suva: Liste de contrôle – Stockage de liquides facilement inflammables, Switzerland, 2011 70UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated
  • 71. Fusce posuere, magna sed pulvinar ultricies, purus lectus malesuada libero, sit amet magna eros quis (ARIAL 32). Images  ECA: Incendie et éléments naturels: Distances de sécurité. Cours spécialiste en protection incendie AEAI, Switzerland, 2011  ECA Incendie et éléments naturels: Installations sprinklers, Switzerland, 2008  Suva: Santé et sécurité au travail lors de l’emploi de solvants, Switzerland, 2012  Suva: Bouteilles à gaz – Entrepôts, rampes, systèmes de distribution de gaz, Switzerland, 2007  Shutterstock, USA, 2015 71UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated
  • 72. 72 This presentation was prepared with the requested diligence and with the generally accepted principles of the relevant field. If a third party uses the contents of the presentation in order to take decisions, the authors disclaim any liability for any kind of direct or indirect (consequential) damage. Disclaimer UNIDO│IAMC Toolkit | Images may not be copied, transmitted or manipulated