The document outlines PL/SQL exception errors, categorizing them into compilation and runtime errors, with a focus on the exception-handling section that allows programmers to manage exceptions. It distinguishes between built-in exceptions, such as no_data_found and too_many_rows, and user-defined exceptions, providing examples of how to implement error handling in PL/SQL blocks. Additionally, the document elaborates on the necessary structure for handling exceptions effectively within the program.