This document is a thesis submitted by Nicholas J. Sharp to the University of Manchester for a Doctor of Philosophy degree in engineering and physical sciences in 2006. The thesis proposes new option-theoretic models for valuing mortgages and mortgage-backed securities. It develops partial differential equation models for valuing fixed-rate and adjustable-rate mortgages by accounting for factors like house prices, interest rates, prepayment, and default. Numerical techniques are presented for solving the PDE models. The thesis also introduces new prepayment models using concepts from occupation-time derivatives to improve mortgage valuation.