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3.20 Balance the following:

   a) COMBUSTION

       C3H6 + O2  CO2 + H2O

       2C3H6 + 9O2  6CO2 + 6H2O

   b) DECOMPOSITION

       NH4NO3  N2O + H2O

       NH4NO3  N2O + 2H2O

   c) COMBUSTION

       C5H6O + O2  CO2 + H2O

       C5H6O + 6O2  5CO2 + 3H2O

   d) COMBINATION

       N2 + H2  NH3

       N2 + 3H2  2NH3

   e) COMBINATION

       K2O + H2O  KOH

       K2O + H2O  2KOH
3.34

   a) Mass of 5.50x10-3 moles of CdS

       Cd  112
                                                   144 gCdS
       S  32               5.76 x10 −3 molCdS *            = 0.829 gCdS
                                                    molCdS
                144

   b) Moles of NH4Cl in 112.6g

       N  14
       H1x4=4
       Cl  35.5

                53.5


                                 1molNH 4Cl
       112.6 gNH 4Cl *                        = 2.10 gNH 4Cl
                                 53.5 gnH 4Cl

   c) Molecules in 1.305 x 10-2 moles of C6H6


                 −2    6.02 *10 23 molecules
 1.305 *10 molC6 H 6 *                       = 7.86 *10 23 molecules
                               mol
   d) Oxygen atoms in 4.88 x 10-3 mol Al(NO3)

           −3                6.02 *10 23 molecules 9 O atoms
  4.88 *10 molAl ( NO3 ) 3 *                      *          = 2.64 *10 23 O atoms
                                     mol            molecule
3.58 C6H12O6  2C2H5OH + 2CO2

                                  2 mol CO 2
   a)   0.400 mol EtOH *                     = 0.800 mol CO 2
                                 1 mol EtOH

   b)
        Molecule C6H12O6                  C2H5OH                 CO2
                 C         12   6    72   C        12   6   24   C     12   1   12
                 O         16   6    96   O        16   1   16   O     16   2   32
                 H         1    12   12   H        1    6   6

        Total                        18                     45                  44
                                     0

                  1 mol EtOH 1 mol glucose 180 g glucose
 7.5 g EtOH *               *             *              = 15 g glucose
                   45 g EtOH 2 mol EtOH 1 mol glucose

   c)




                1 mol EtOH 2 mol CO 2 44 g CO 2
7.5 g EtOH *              *          *           = 7.3 g glucose
                 45 g EtOH 2 mol EtOH 1 mol CO 2
3.60

           a) Balance:   Fe2O3 + CO  Fe + CO2

           Fe2O3 + 3CO  2Fe + 3CO2

           b)

                         1000g 1 mol Fe 2 O 3     3 mol CO      28 g CO
  0.150 Kg Fe 2 O 3 *         *                *              *         = 78.95 g CO
                          1 Kg 159.6 g Fe 2 O 3 1 mol Fe 2 O 3 mol CO

           c)

           grams Fe:

                          1000g 1 mol Fe 2 O 3     2 mol Fe      55.8 g Fe
    0.150 Kg Fe 2 O 3 *        *                *              *           = 104.9 g Fe
                           1 Kg 159.6 g Fe 2 O 3 1 mol Fe 2 O 3 mol Fe


           grams CO2


                      1000g 1 mol Fe 2 O 3    3 mol CO 2 44 g CO 2
0.150 Kg Fe 2 O 3 *        *                *              *         = 124.0 g CO 2
                       1 Kg 159.6 g Fe 2 O 3 1 mol Fe 2 O 3 mol CO 2



           d)

           Fe2O3 + 3CO  2Fe + 3CO2
            150g + 78.9g = 104.9g +124g
               228.9g    =   228.9 g

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H2 Answers

  • 1. 3.20 Balance the following: a) COMBUSTION C3H6 + O2  CO2 + H2O 2C3H6 + 9O2  6CO2 + 6H2O b) DECOMPOSITION NH4NO3  N2O + H2O NH4NO3  N2O + 2H2O c) COMBUSTION C5H6O + O2  CO2 + H2O C5H6O + 6O2  5CO2 + 3H2O d) COMBINATION N2 + H2  NH3 N2 + 3H2  2NH3 e) COMBINATION K2O + H2O  KOH K2O + H2O  2KOH
  • 2. 3.34 a) Mass of 5.50x10-3 moles of CdS Cd  112 144 gCdS S  32 5.76 x10 −3 molCdS * = 0.829 gCdS molCdS 144 b) Moles of NH4Cl in 112.6g N  14 H1x4=4 Cl  35.5 53.5 1molNH 4Cl 112.6 gNH 4Cl * = 2.10 gNH 4Cl 53.5 gnH 4Cl c) Molecules in 1.305 x 10-2 moles of C6H6 −2 6.02 *10 23 molecules 1.305 *10 molC6 H 6 * = 7.86 *10 23 molecules mol d) Oxygen atoms in 4.88 x 10-3 mol Al(NO3) −3 6.02 *10 23 molecules 9 O atoms 4.88 *10 molAl ( NO3 ) 3 * * = 2.64 *10 23 O atoms mol molecule
  • 3. 3.58 C6H12O6  2C2H5OH + 2CO2 2 mol CO 2 a) 0.400 mol EtOH * = 0.800 mol CO 2 1 mol EtOH b) Molecule C6H12O6 C2H5OH CO2 C 12 6 72 C 12 6 24 C 12 1 12 O 16 6 96 O 16 1 16 O 16 2 32 H 1 12 12 H 1 6 6 Total 18 45 44 0 1 mol EtOH 1 mol glucose 180 g glucose 7.5 g EtOH * * * = 15 g glucose 45 g EtOH 2 mol EtOH 1 mol glucose c) 1 mol EtOH 2 mol CO 2 44 g CO 2 7.5 g EtOH * * * = 7.3 g glucose 45 g EtOH 2 mol EtOH 1 mol CO 2
  • 4. 3.60 a) Balance: Fe2O3 + CO  Fe + CO2 Fe2O3 + 3CO  2Fe + 3CO2 b) 1000g 1 mol Fe 2 O 3 3 mol CO 28 g CO 0.150 Kg Fe 2 O 3 * * * * = 78.95 g CO 1 Kg 159.6 g Fe 2 O 3 1 mol Fe 2 O 3 mol CO c) grams Fe: 1000g 1 mol Fe 2 O 3 2 mol Fe 55.8 g Fe 0.150 Kg Fe 2 O 3 * * * * = 104.9 g Fe 1 Kg 159.6 g Fe 2 O 3 1 mol Fe 2 O 3 mol Fe grams CO2 1000g 1 mol Fe 2 O 3 3 mol CO 2 44 g CO 2 0.150 Kg Fe 2 O 3 * * * * = 124.0 g CO 2 1 Kg 159.6 g Fe 2 O 3 1 mol Fe 2 O 3 mol CO 2 d) Fe2O3 + 3CO  2Fe + 3CO2 150g + 78.9g = 104.9g +124g 228.9g = 228.9 g