Carbon Capture from power                                                        Established expertise on storage
      Plant and atmosphere
    Science and Innovation Award £4M EP/F034520/1




    CCS:                                         Biochar:
    reduced CO2 emissions                        negative CO2 emissions from
    from fossil mega-sources                     biomass mini-sources
s.haszeldine@ed.ac.uk        UK CCS Community, London 4 Nov 2009                 1   s.haszeldine@ed.ac.uk                 UK CCS Community, London 4 Nov 2009           2




                                                                   North                                     Capture methods
                                                                                     •     Cryogenic distillation – mature
                                                                   Sea               •     Liquid absorption (amines) – rollout and testing
                                                                    rim:
                                                                                     •     Adsorption (CO2, O2, H2 – pre or post combustion)
                                                                   CCS                      – Pressure swing adsorption (PSA) processes
                                                                                            – Novel packings (monoliths)
                                                                    grid                    – Novel optimized materials

                                                                     UK and          •     Membranes (CO2, O2, H2 – pre or post combustion)
                                                                    Scotland                – Novel optimized materials
                                                                    can offer               – Mixed matrix materials
                                                                    offshore
                                                                     storage         •     Looping post combustion gas or coal: carrier, fluid dynamics
                                                                   capacity to
                                                                      EU 27                      Basic science ==> materials ==> test performance ==> industrial scale
s.haszeldine@ed.ac.uk        UK CCS Community, London 4 Nov 2009                 3   s.haszeldine@ed.ac.uk                 UK CCS Community, London 4 Nov 2009           4




         New methods of industrial                                                              Amine optimisation (Graeme White)
           scale CO2 capture
      1 new staff University of Edinburgh:
                     Dr




      2 new staff Heriot-Watt University



                                                                                         Gas-Liquid Contacting Column Optimise internal packing to
      Amines, Engineered microporous solids, chemical looping                            ensure good gas-liquid contact to gain maximum mass transfer
                                                                                         efficiency
s.haszeldine@ed.ac.uk        UK CCS Community, London 4 Nov 2009                 5   s.haszeldine@ed.ac.uk                 UK CCS Community, London 4 Nov 2009           6




                                                                                                                                                                             1
Pressure swing (Stefano Brandani)                                                            Chemical looping (Raffaella Ocone)
                                                                                                • Combining power generation with CO2 separation
                                                                                                • CCL low cost, high efficiency
                                                                                              N2, O2
                                                                                                                MxO y


                                                                                                                                   CO2 + H2O




                                                                                                 Air
                                                                                               Reactor
                                                                                                                          Fuel
                                                                                                                         Reactor


                                     !                                                                                                          Most common set-up:
                        "                                                                                                                    Air Reactor  CFB
                            #                                                                   Air
                                                                                                               MxO y-1
                                                                                                                           Fuel         Fuel Reactor   Bubbling Bed
                   !                                                                                                                     Oxygen carrier MCO3, MOx
s.haszeldine@ed.ac.uk                 UK CCS Community, London 4 Nov 2009          7   s.haszeldine@ed.ac.uk                          UK CCS Community, London 4 Nov 2009    8




                                Biochar                                                                                  Dimensions
      Proposition:                                                                        Three new lecturer staff, UK and international links
      Anthropogenic emissions are committed to > 2C rise                                  Dr Simon Shackley (ex-Tyndall) - Techno-social, also CCS
      Extracting CO2 from atmosphere is desirable                                         Dr Saran Sohi (ex-Rothamsted) - Soil science
      Storing carbon in soil can maintain / increase fertility                            Dr Ondrej Masek (ex-Cranfield) - pyrolysis engineering
                        Slow pyrolysis (200-800 C) of biomass,                            3 x PDRA Peter Brownsort, Miranda Prendergast-Miller, Andy Cross
                   Producing ‘charcoal’ intended for application to soil
                        Impact ambitions globally : 1 Gt C /yr                            6 - 12 PhD - 2 in place

                                                                                       UK Biochar Research Centre @ Edinburgh




s.haszeldine@ed.ac.uk                 UK CCS Community, London 4 Nov 2009          9   s.haszeldine@ed.ac.uk                          UK CCS Community, London 4 Nov 2009   10




                            Example activity                                                                        Co-firing BECS
                                                                                          UK mandates 3-5% biomass in central power plant
                                                                                          Drax is planning 10% by 2011
                                                                                          Co-fired plants tested to 10% , progressing to 30%




    UK slow pyrolysis unit                         Field trials : UK + 7% yield

   Since January 2009, research sponsorship £ 400k
   from: DEFRA, Shell, ProNatura, C Gold ….
                                                                                          If CCS (90%) fitted to co-fired plant, ==> neutral, potentially -ve
   Dedicated UK laboratory: under construction
s.haszeldine@ed.ac.uk                 UK CCS Community, London 4 Nov 2009         11   s.haszeldine@ed.ac.uk                          UK CCS Community, London 4 Nov 2009   12




                                                                                                                                                                                 2
Carbon Capture Interactive
Public Understanding $ %&' ' ()%*




s.haszeldine@ed.ac.uk   UK CCS Community, London 4 Nov 2009   13




                                                                   3

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Haszeldine - Royal Academy Engineering, London 4 Nov 2009

  • 1. Carbon Capture from power Established expertise on storage Plant and atmosphere Science and Innovation Award £4M EP/F034520/1 CCS: Biochar: reduced CO2 emissions negative CO2 emissions from from fossil mega-sources biomass mini-sources s.haszeldine@ed.ac.uk UK CCS Community, London 4 Nov 2009 1 s.haszeldine@ed.ac.uk UK CCS Community, London 4 Nov 2009 2 North Capture methods • Cryogenic distillation – mature Sea • Liquid absorption (amines) – rollout and testing rim: • Adsorption (CO2, O2, H2 – pre or post combustion) CCS – Pressure swing adsorption (PSA) processes – Novel packings (monoliths) grid – Novel optimized materials UK and • Membranes (CO2, O2, H2 – pre or post combustion) Scotland – Novel optimized materials can offer – Mixed matrix materials offshore storage • Looping post combustion gas or coal: carrier, fluid dynamics capacity to EU 27 Basic science ==> materials ==> test performance ==> industrial scale s.haszeldine@ed.ac.uk UK CCS Community, London 4 Nov 2009 3 s.haszeldine@ed.ac.uk UK CCS Community, London 4 Nov 2009 4 New methods of industrial Amine optimisation (Graeme White) scale CO2 capture 1 new staff University of Edinburgh: Dr 2 new staff Heriot-Watt University Gas-Liquid Contacting Column Optimise internal packing to Amines, Engineered microporous solids, chemical looping ensure good gas-liquid contact to gain maximum mass transfer efficiency s.haszeldine@ed.ac.uk UK CCS Community, London 4 Nov 2009 5 s.haszeldine@ed.ac.uk UK CCS Community, London 4 Nov 2009 6 1
  • 2. Pressure swing (Stefano Brandani) Chemical looping (Raffaella Ocone) • Combining power generation with CO2 separation • CCL low cost, high efficiency N2, O2 MxO y CO2 + H2O Air Reactor Fuel Reactor ! Most common set-up: " Air Reactor CFB # Air MxO y-1 Fuel Fuel Reactor Bubbling Bed ! Oxygen carrier MCO3, MOx s.haszeldine@ed.ac.uk UK CCS Community, London 4 Nov 2009 7 s.haszeldine@ed.ac.uk UK CCS Community, London 4 Nov 2009 8 Biochar Dimensions Proposition: Three new lecturer staff, UK and international links Anthropogenic emissions are committed to > 2C rise Dr Simon Shackley (ex-Tyndall) - Techno-social, also CCS Extracting CO2 from atmosphere is desirable Dr Saran Sohi (ex-Rothamsted) - Soil science Storing carbon in soil can maintain / increase fertility Dr Ondrej Masek (ex-Cranfield) - pyrolysis engineering Slow pyrolysis (200-800 C) of biomass, 3 x PDRA Peter Brownsort, Miranda Prendergast-Miller, Andy Cross Producing ‘charcoal’ intended for application to soil Impact ambitions globally : 1 Gt C /yr 6 - 12 PhD - 2 in place UK Biochar Research Centre @ Edinburgh s.haszeldine@ed.ac.uk UK CCS Community, London 4 Nov 2009 9 s.haszeldine@ed.ac.uk UK CCS Community, London 4 Nov 2009 10 Example activity Co-firing BECS UK mandates 3-5% biomass in central power plant Drax is planning 10% by 2011 Co-fired plants tested to 10% , progressing to 30% UK slow pyrolysis unit Field trials : UK + 7% yield Since January 2009, research sponsorship £ 400k from: DEFRA, Shell, ProNatura, C Gold …. If CCS (90%) fitted to co-fired plant, ==> neutral, potentially -ve Dedicated UK laboratory: under construction s.haszeldine@ed.ac.uk UK CCS Community, London 4 Nov 2009 11 s.haszeldine@ed.ac.uk UK CCS Community, London 4 Nov 2009 12 2
  • 3. Carbon Capture Interactive Public Understanding $ %&' ' ()%* s.haszeldine@ed.ac.uk UK CCS Community, London 4 Nov 2009 13 3