Linear Forms In Logarithms And Applications Yann Bugeaud
Linear Forms In Logarithms And Applications Yann Bugeaud
Linear Forms In Logarithms And Applications Yann Bugeaud
Linear Forms In Logarithms And Applications Yann Bugeaud
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Yann Bugeaud
Linear Forms in Logarithms and Applications
The aim of this book is to serve as an introductory text to the theory of linear
forms in the logarithms of algebraic numbers, with a special emphasis on a
large variety of its applications. We wish to help students and researchers to
learn what is hidden inside the blackbox ‘Baker’s theory of linear forms in
logarithms’ (in complex or in p-adic logarithms) and how this theory applies to
many Diophantine problems, including the effective resolution of Diophantine
equations, the abc-conjecture, and upper bounds for the irrationality measure
of some real numbers.
Written for a broad audience, this accessible and self-contained book can be
used for graduate courses (some 30 exercises are supplied). Specialists will
appreciate the inclusion of over 30 open problems and the rich bibliography
of over 450 references.
ISBN 978-3-03719-183-5
www.ems-ph.org
Yann
Bugeaud
Linear
Forms
in
Logarithms
and
Applications
Yann Bugeaud
Linear Forms in
Logarithms
and Applications
IRMA Lectures in Mathematics
and Theoretical Physics 28
3. IRMA Lectures in Mathematics and Theoretical Physics 28
Edited by Christian Kassel and Vladimir G. Turaev
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4. IRMA Lectures in Mathematics and Theoretical Physics
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7. Preface
Hay que saber buscar aunque uno no sepa qué es lo que busca.
Roberto Bolaño
— Les maths, m’sieur, ça fonctionne toujours à côté de ses grolles.
Jean Amila
In 1748 Leonhard Euler published Introductio in analysin infinitorum where, among
several fundamental results, he established the relationship ei
D 1 and gave explicitly
the continued fraction expansions of e and e2
. He also made a conjecture concerning the
nature of quotients of logarithms of rational numbers, which can be formulated as follows:
For any two positive rational numbers r, s with r different from 1, the number log s=log r
is either rational (in which case there are non-zero integers a, b such that ra
D sb
)
or transcendental.
Recall that a complex number is called algebraic if it is a root of a non-zero polynomial
with integer coefficients and a complex number which is not algebraic is called transcen-
dental. Euler’s conjecture implies, for example, that 2
p
2
is irrational (if it were rational,
then log 2
p
2
divided by log 2, which is equal to
p
2, would be rational or transcendental).
It can be reformulated as follows:
If a is a positive rational number different from 1 and ˇ an irrational real algebraic
number, then aˇ
is irrational.
In 1900, David Hilbert proposed a list of twenty-three open problems and presented
ten of them in Paris at the second International Congress of Mathematicians. His seventh
problem expands the arithmetical nature of the numbers under consideration in Euler’s
conjecture and asks whether (observe that e
D . 1/ i
)
the expression ˛ˇ
for an algebraic base ˛ different from 0 and 1 and an irrational algebraic
exponent ˇ, e.g. the number 2
p
2
or e
, always represents a transcendental or at least an
irrational number.
Here and below, unless otherwise specified, by algebraic number we mean complex
algebraic number. Hilbert believed that the Riemann Hypothesis would be settled long
before his seventh problem. This was not the case: the seventh problem was eventually
8. vi Preface
solved in 1934, independently and simultaneously, by Aleksandr Gelfond and Theodor
Schneider, by different methods. They established that, for any non-zero algebraic numbers
˛1; ˛2; ˇ1; ˇ2 with log ˛1 and log ˛2 linearly independent over the rationals (here and
below, log denotes the principal determination of the logarithm function), we have
ƒ2 WD ˇ1 log ˛1 C ˇ2 log ˛2 6D 0:
Since the formulation is different, let us add some explanation. Under the hypotheses of
Hilbert’s seventh problem, the complex numbers log ˛ and log ˛ˇ
are linearly independent
over the rationals and, assuming furthermore that ˛ˇ
is algebraic, we derive from the
Gelfond–Schneider theorem that ˇ, equal to the quotient of the logarithm of ˛ˇ
by the
logarithm of ˛, cannot be algebraic, a contradiction.
Subsequently, Gelfond derived a lower bound for jƒ2j and, a few years later, he realized
that an extension of his result to linear forms in an arbitrarily large number of logarithms of
algebraic numbers would enable one to solve many challenging problems in Diophantine
approximation and in the theory of Diophantine equations.
This program was realized by Alan Baker in a series of four papers published between
1966 and 1968 in the journal Mathematika. He made the long awaited breakthrough, by
showing that, if ˛1; : : : ; ˛n are non-zero algebraic numbers such that log ˛1; : : : ; log ˛n are
linearly independent over the rationals, and if ˇ1; : : : ; ˇn are non-zero algebraic numbers,
then
ƒn WD ˇ1 log ˛1 C C ˇn log ˛n 6D 0:
In addition, he derived a lower bound for jƒnj, thereby giving the expected extension of the
Gelfond–Schneider theorem. In his work, Baker generated a large class of transcendental
numbers not previously identified and showed how the underlying theory can be used
to answer a wide range of Diophantine problems, including the effective resolution of
many classical Diophantine equations. He was awarded a Fields Medal in 1970 at the
International Congress of Mathematicians in Nice.
It then became clear that further progress, refinements, and extensions of the theory
would have important consequences. This area was at that time flourishing and developing
very rapidly, both from a theoretical point of view (with improvements obtained by Baker
and Feldman, among others, on the lower bounds for jƒnj) and regarding its applications.
A spectacular achievement was the proof by Robert Tijdeman in 1976 that the Catalan
equation xm
yn
D 1, in the integer unknowns x; y; m; n all greater than 1, has only
finitely many solutions (Preda Mihăilescu established in 2002 that 32
23
D 1 is the only
solution to this equation).
The aim of the present monograph is to serve as an introductory text to Baker’s theory
of linear forms in the logarithms of algebraic numbers, with a special emphasis on a large
variety of its applications, mainly to Diophantine questions. We wish to help students and
researchers to learn what is hidden inside the blackbox “Baker’s theory of linear forms
in logarithms” (in complex or in p-adic logarithms) and how this theory applies to many
Diophantine problems.
Chapter 1 gives the reader a concise historical introduction to the theory. In Chapter 2,
we gather several explicit lower bounds for jƒnj and its p-adic analogue, which were es-
tablished by Waldschmidt, Matveev, Laurent, Mignotte and Nesterenko, Yu, and Bugeaud
9. Preface vii
and Laurent, and which will be used in the subsequent chapters. In all but one of these
estimates, ˇ1; : : : ; ˇn are integers, a special case sufficient for most of the applications.
The lower bounds are then expressed in terms of the maximum B of their absolute values
and take the form
log jƒnj c.n; D/ .log 2A1/ : : : .log 2An/ .log 2B/;
where c.n; D/ is an explicit real number depending only on n and the degree D of the
algebraic number field generated by ˛1; : : : ; ˛n and Aj is the maximum of the absolute
values of the coefficients of the minimal defining polynomial of ˛j over the rational
integers, for j D 1; : : : ; n. The crucial achievements of Baker are the logarithmic
dependence on B and the fact that an admissible value for c.n; D/ can be explicitly
computed.
We consider in Chapter 3 Diophantine problems for which the reduction to linear
forms in complex logarithms is almost straightforward. These problems include explicit
lower bounds for the distance between powers of 2 and powers of 3, effective irrationality
measures for n-th roots of rational numbers, lower bounds for the greatest prime factor
of n.n C 1/, where n is a positive integer, perfect powers in linear recurrence sequences
of integers, etc.
Chapter 4 is devoted to applications to classical families of Diophantine equations. In
the works of Thue and Siegel, it was established that unit equations, Thue equations, and
super- and hyperelliptic equations have only finitely many integer solutions, but the proofs
were ineffective, in the sense that they did not yield upper bounds for the absolute values
of the solutions and, consequently, were of very little help for the complete resolution
of the equations. The theory of linear forms in logarithms induced dramatic changes in
the field of Diophantine equations and we explain how it can be applied to establish, in
an effective way, that unit equations, Thue equations, super- and hyperelliptic equations,
the Catalan equation, etc., have only finitely many integer solutions. This chapter also
contains a complete proof, following Bilu and Bugeaud [72], of an effective improvement
of Liouville’s inequality (which states that an algebraic number of degree d cannot be
approximated by rational numbers at an order greater than d) derived ultimately from an
estimate for linear forms in two complex logarithms proved in Chapter 11.
When the algebraic numbers ˛1; : : : ; ˛n occurring in the linear form ƒn are all rational
numbers very close to 1, the lower bounds for jƒnj can be considerably improved. Several
applications of this refinement are listed in Chapter 5. They include effective irrationality
measures for n-th roots of rational numbers close to 1 and striking results on the Thue
equation axn
byn
D c.
Chapter 6 presents various applications of the theory of linear forms in p-adic log-
arithms, in particular towards Waring’s problem and, again, to perfect powers in linear
recurrence sequences of integers. It also includes extensions of results established in
Chapter 4: unit equations, Thue equations, super- and hyperelliptic equations have only
finitely many solutions in the rational numbers, whose denominators are divisible by
prime numbers from a given, finite set, and, moreover, the size of these solutions can be
effectively bounded.
Primitive divisors of terms of binary recurrence sequences are discussed in Chapter 7.
We partially prove a deep result of Bilu, Hanrot, and Voutier [77] on the primitive
10. viii Preface
divisors of Lucas and Lehmer numbers and discuss some of its applications to Diophantine
equations. Then, following Stewart [400], we confirm a conjecture of Erdős and show
that, for every integer n 3, the greatest prime factor of 2n
1 exceeds some positive
real number times n
p
log n= log log n.
In Chapter 8, we follow Stewart and Yu [405] to establish partial results towards the
abc-conjecture, which claims that, for every positive real number , there exists a positive
real number ./, depending only on , such that, for all coprime, positive integers a; b;
and c with a C b D c, we have
c ./
Y
pjabc
p
1C
;
the product being taken over the distinct prime factors of abc. Specifically, we show
how to combine complex and p-adic estimates to prove the existence of an effectively
computable positive real number such that, for all positive coprime integers a; b; and c
with a C b D c, we have
log c
Y
pjabc
p
1=3
log
Y
pjabc
p
3
:
There are only a few known applications of the theory of simultaneous linear forms in
logarithms, developed by Loxton in 1986. Two of them are presented in Chapter 9. A first
gives us an upper bound for the number of perfect powers in the interval ŒN; N C
p
N,
for every sufficiently large integer N. A second shows that, under a suitable assumption,
a system of two Pellian equations has at most one solution.
Given a finite set of multiplicatively dependent algebraic numbers, we establish in
Chapter 10 that these numbers satisfy a multiplicative dependence relation with small
exponents. A key ingredient for the proof is a lower bound for the Weil height of a
non-zero algebraic number which is not a root of unity.
Full proofs of estimates for linear forms in two complex logarithms, which, in partic-
ular, imply lower estimates for the difference between integral powers of real algebraic
numbers, are given in Chapter 11. Analogous estimates for linear forms in two p-adic
logarithms, that is, upper estimates for the p-adic valuation of the difference between in-
tegral powers of algebraic numbers are given in Chapter 12. An estimate for linear forms
in an arbitrary number of complex logarithms is derived in Chapter 4 from the estimate
for linear forms in two complex logarithms established in Chapter 11. While the former
estimate is not as strong and general as the estimates stated in Chapter 2, it is sufficiently
precise for many applications.
We collect open problems in Chapter 13. The thirteen chapters are complemented by
six appendices, which, mostly without proofs, gather classical results on approximation
by rational numbers, the theory of heights, algebraic number theory, and p-adic analysis.
We have tried, admittedly without too much success, to curb our taste for extensive
bibliographies. No effort has been made towards exhaustivity, including in the list of
bibliographic references, and the topics covered in this textbook reflect somehow the
personal taste of the author.
11. Preface ix
Inevitably, there is some overlap between this monograph and the monograph [376]
of Shorey and Tijdeman, which, although over thirty years old, remains an invaluable
reference for anyone interested in Diophantine equations. In particular, the content of
Chapter 4 (except Section 4.1) is treated in [376] in much greater generality. There is also
some overlap with Sprindžuk’s book [386] and the monograph of Evertse and Győry [182].
Regarding the theory of linear forms in logarithms, Chapters 2 and 11 can be seen as an
introduction to the book of Waldschmidt [432]. As far as we are aware, the content of
Chapters 5, 7, 8, 9, and 12 and several other parts of the present monograph have never
appeared in books.
To keep this book reasonably short and accessible to graduate and post-graduate
students, the results are not proved in their greatest generality and proofs of the best
known lower bounds for linear forms in an arbitrary number of complex (resp., p-adic)
logarithms are not given.
Many colleagues sent me comments, remarks, and suggestions. I am grateful to all of
them. Special thanks are due to Samuel Le Fourn, who very carefully read the manuscript
and sent me many insightful suggestions.
This book was written while I was director of the ‘Institut de Recherche Mathématique
Avancée’.
17. Frequently used notation
log : unless otherwise specified, log z denotes the principal determination
of the logarithm of the non-zero complex number z, that is, writing
z D rei
with r positive and in . ; , we have log z D log rCi.
e : base of the natural logarithm.
deg : degree (of a polynomial, of an algebraic number).
det : determinant.
positive : strictly positive.
bxc : largest integer x.
dxe : smallest integer x.
fg : fractional part.
k k : distance to the nearest integer.
Card : cardinality (of a finite set).
perfect power : integer of the form ab
, with a 1 and b 2 integers.
p1 p2 : the set of all prime numbers ranged in increasing order.
q1 qs : a collection of s distinct prime numbers, not necessarily consecutive.
P Œn : greatest prime factor of the integer n, with P Œ0 D P Œ˙1 D 1.
!.n/ : number of distinct prime factors of the positive integer n, with
!.1/ D 0.
' : Euler totient function (Definition D.3).
: Möbius function (Definition D.3).
ˆd .X; Y / : homogeneous d-th cyclotomic polynomial.
h.˛/ : logarithmic Weil height of the algebraic number ˛ (Definition B.4).
L.P / : length of the polynomial P.X1; : : : ; Xn/ (Definition B.9).
j jp : p-adic absolute value, normalized such that jpjp D p 1
.
vp : p-adic valuation, normalized such that vp.p/ D 1.
S : finite, non-empty set of prime numbers (or, sometimes, of places of
an algebraic number field).
18. xvi Frequently used notation
ŒnS : S-part of the non-zero integer n, defined by ŒnS D
Q
p2S jnj 1
p .
S-unit : rational number whose numerator and denominator are only com-
posed of prime numbers in S.
integral S-unit : rational integer being an S-unit.
a b : the quantity a is less than b times an absolute, positive, effectively
computable real number.
a c1;:::;cn
b : the quantity a is less than b times an effectively computable, positive,
real number, which depends at most on c1; : : : ; cn.
a ineff
b : the quantity a is less than b times an absolute, positive real number.
logp; expp : p-adic logarithm and p-adic exponential functions.
SN : set of permutations of f1; : : : ; N g.
eK; fK : ramification index and residue degree of a p-adic field K.
a; b; c; p : ideals of an algebraic number field.
ep; fp : ramification index and residue degree of an ideal p.
: Galois conjugacy.
K, OK, O
K, MK,
M1
K , DK, hK :
an algebraic number field, its ring of integers, group of units, set of
places, set of infinite places, discriminant, and class number.
19. Chapter 1
Brief introduction to linear forms in logarithms
We start this textbook with a concise introduction to the theory of linear forms in
logarithms. For much more comprehensive historical surveys and many bibliographic
references, the reader is directed to the introductory text [441] and the monographs
[28, 38, 141, 243, 419, 432]. Throughout, unless otherwise specified, log z denotes the
principal determination of the logarithm of the non-zero complex number z, that is, writ-
ing z D rei
with r positive and in . ; , we have log z D log r C i. In particular,
log. 1/ is equal to i.
1.1. Linear forms in complex logarithms
A complex number is called algebraic if it is a root of a non-zero polynomial with integer
coefficients. A complex number which is not algebraic is called transcendental. Rational
numbers and their integer roots are obvious examples of algebraic numbers. The first
examples of transcendental numbers were given, and even in a totally explicit form, by
Liouville [264] in 1844, in a note where he proved that a real algebraic irrational number
cannot be too close, in a suitable sense, to rational numbers; see Theorem A.5 for a precise
formulation.
It is one thing to construct transcendental numbers; it is another, much more difficult
one, to prove the transcendence of some explicitly given complex numbers. The first
result in this direction is the proof of the transcendence of e, obtained by Hermite in 1873.
Shortly thereafter, in 1882, Lindemann established that is transcendental. The now
famous Hermite–Lindemann theorem reads as follows.
Theorem 1.1. For any non-zero complex number ˇ, at least one of the two numbers ˇ
and eˇ
is transcendental.
Theorem 1.1 includes the transcendence of e (take ˇ D 1) and that of (take ˇ D i).
It also shows that log 2 is transcendental and, more generally, that any determination of
the logarithm of an algebraic number different from 0 and 1 is transcendental.
In 1885 Weierstrass extended Theorem 1.1 as follows.
Theorem 1.2. Let n 2 be an integer. Let ˛1; : : : ; ˛n be distinct algebraic numbers.
Then, e˛1
; : : : ; e˛n
are linearly independent over the field of algebraic numbers.
Sincemonomialsine˛1
; : : : ;e˛n
areexponentialsofintegralcombinationsof ˛1; : : : ; ˛n,
it is easy to show that Theorem 1.2 is equivalent to the following statement: If n 2
20. 2 1. Brief introduction to linear forms in logarithms
and ˛1; : : : ; ˛n are algebraic numbers that are linearly independent over the field of ratio-
nal numbers, then e˛1
; : : : ; e˛n
are algebraically independent over the field of algebraic
numbers (this means that no non-zero polynomials with algebraic coefficients vanish at
.e˛1
; : : : ; e˛n
/).
In 1900, David Hilbert proposed a list of twenty-three open problems and presented ten
of them in Paris at the second conference of the International Congress of Mathematicians.
His seventh problem is the following (observe that e
D . 1/ i
):
The expression ˛ˇ
for an algebraic base ˛ different from 0 and 1 and an irrational
algebraic exponent ˇ, e.g. the number 2
p
2
or e
, always represents a transcendental or
at least an irrational number.
This problem was solved in 1934 independently and simultaneously by Gelfond [197]
and Schneider [359], by different methods.
Theorem 1.3. For any non-zero algebraic numbers ˛1; ˛2; ˇ1; ˇ2 with log ˛1 and log ˛2
linearly independent over the rationals, we have
ˇ1 log ˛1 C ˇ2 log ˛2 6D 0:
Theorem 1.3 was generalized to linear combinations of n logarithms of algebraic
numbers by Baker [16,17] in 1966 and 1967.
Theorem 1.4. Let n 2 be an integer. Let ˛1; : : : ; ˛n be non-zero algebraic numbers
and log any fixed determination of the logarithm function. If log ˛1; : : : ; log ˛n are
linearly independent over the rationals, then they are linearly independent over the field
of algebraic numbers.
Shortly thereafter, Baker [18] extended his previous result as follows.
Theorem 1.5. Let n be a positive integer. Let ˛1; : : : ; ˛n be non-zero algebraic numbers
and log ˛1; : : : ; log ˛n any determinations of their logarithms. If log ˛1; : : : ; log ˛n are
linearly independent over the rationals, then 1; log ˛1; : : : ; log ˛n are linearly independent
over the field of algebraic numbers.
It readily follows from Theorem 1.5 that the complex number eˇ0
˛ˇ1
1 ˛ˇn
n is tran-
scendental for all non-zero algebraic numbers ˛1; : : : ; ˛n, ˇ0; : : : ; ˇn. Furthermore,
Theorem 1.5 includes Theorem 1.1.
Theorems 1.3 to 1.5 show that any expression of the form
ˇ0 C ˇ1 log ˛1 C C ˇn log ˛n; (1.1)
where ˛1; : : : ; ˛n, ˇ1; : : : ; ˇn are non-zero algebraic numbers and ˇ0 is algebraic, vanishes
only in trivial cases. A natural question is then to bound from below its absolute value
(when non-zero).
For the sake of simplification, we assume in the discussion below that the algebraic
numbers involved are all rational numbers. Let n 2 be an integer. For j D 1; : : : ; n,
let xj
yj
be a non-zero rational number, bj a non-zero integer, and set
B WD maxf3; jb1j; : : : ; jbnjg and Aj WD maxf3; jxj j; jyj jg: (1.2)
21. 1.1. Linear forms in complex logarithms 3
We consider the rational number
ƒ WD
x1
y1
b1
xn
yn
bn
1: (1.3)
Since we wish to bound jƒj from below, we may assume that jƒj 1
2
. Then, the linear
form in logarithms of rational numbers , defined by
WD log.1 C ƒ/ D b1 log
x1
y1
C C bn log
xn
yn
;
satisfies
jƒj
2
jj 2jƒj:
A trivial estimate of the denominator of (1.3) gives that ƒ D 0 or
log jƒj
n
X
jD1
jbj j log maxfjxj j; jyj jg B
n
X
jD1
log Aj : (1.4)
The dependence on the Aj ’s in (1.4) is very satisfactory, unlike the dependence on B. For
applications to Diophantine problems, we require a better estimate in terms of B than the
one given in (1.4), even if it comes with a weaker one in terms of the Aj ’s. For example,
replacing B by o.B/ is sufficient in many cases (see, for example, Theorems 3.10, 3.13,
and 4.9), but not in all cases (see, for example, Theorems 3.3, 3.4, and 5.1). The next
lemma shows that B cannot be replaced by o.log B/.
Lemma 1.6. Let n; a1; : : : ; an be integers, all of which are greater than or equal to 2.
Set A D maxfa1; : : : ; ang. Then, for every integer B greater than 2n log A, there exist
rational integers b1; : : : ; bn with
0 maxfjb1j; : : : ; jbnjg B
and
jab1
1 abn
n 1j
2n log A
Bn 1
:
Lemma 1.6 is a direct consequence of the Dirichlet Schubfachprinzip applied to the
points b1 log a1 C C bn log an with 0 b1; : : : ; bn B, which all lie in the interval
Œ0; nB log A.
The first effective improvement of (1.4) was obtained by Gelfond [198] in 1935 in the
case n D 2. He proved that, for multiplicatively independent positive rational numbers
x1
y1
; x2
y2
, for an arbitrary positive real number , and for all integers b1; b2, not both 0, we
have ˇ
ˇ
ˇ
x1
y1
b1
x2
y2
b2
1
ˇ
ˇ
ˇ x1
y1
;
x2
y2
; exp .log B/5C
;
where B D maxf3; jb1j; jb2jg. Throughout this book, the notation a c1;:::;cn
b
(resp., a ineff
c1;:::;cn
b) means that the quantity a is greater than b times an effectively
computable positive real number (resp., a positive real number), which depends at most
22. 4 1. Brief introduction to linear forms in logarithms
on c1; : : : ; cn. Subsequently, Gelfond improved his own result and totally explicit estimates
were provided by Schinzel [354] in 1967.
Gelfond [200] also gave an estimate valid for a linear form in an arbitrary number of
logarithms.
Theorem 1.7. Let n 2 be an integer and a1; : : : ; an positive rational numbers which are
multiplicatively independent. Let ı be a positive real number. Let b1; : : : ; bn be rational
integers, not all zero, and set B D maxf3; jb1j; : : : ; jbnjg. Then, we have
jab1
1 abn
n 1j ineff
n;a1;:::;an; ı exp. ıB/:
The proof of Theorem 1.7, which rests on a theorem of Siegel, does not enable us to
compute effectively the implicit numerical constant. In his book Gelfond [200] pointed
out the importance of getting an effective version of Theorem 1.7.
For n 3, the first non-trivial effective lower bound for the quantity ƒ defined in (1.3)
was given by Baker [16] in 1966. With B as in (1.2), he obtained that either ƒ D 0 or, for
every positive real number , we have
ˇ
ˇ
ˇ
x1
y1
b1
xn
yn
bn
1
ˇ
ˇ
ˇ n;
x1
y1
;:::; xn
yn
; exp .log B/nC1C
:
His result is much more general and applies to expressions of the form (1.1).
Shortly thereafter, Feldman [185,186] established the following refinement of Baker’s
lower bound.
Theorem 1.8. Let n 2 be an integer and a1; : : : ; an positive rational numbers which
are multiplicatively independent. Let b1; : : : ; bn be rational integers, not all zero, and
set B D maxf3; jb1j; : : : ; jbnjg. Then, there exists a positive, effectively computable real
number C, depending only on n; a1; : : : ; an, such that
jab1
1 abn
n 1j exp. C log B/ D B C
: (1.5)
Lemma 1.6 shows that the dependence on B in the estimate (1.5) is essentially best
possible, but, for applications, it is much desirable to determine precisely how C depends
on the rational numbers a1; : : : ; an.
A first explicit result in this direction was given by Baker [19] in 1968. Throughout
this chapter, the height of an algebraic number is the naïve height, that is, the maximum of
the absolute values of the coefficients of its minimal defining polynomial over the integers.
We reproduce below a consequence of the main theorem of [19].
Theorem 1.9. Assume that n 2 and that ˛1; : : : ; ˛n are non-zero algebraic numbers,
whose degrees do not exceed D and whose heights do not exceed A, where D 4 and
A 4. Let ı be a real number with 0 ı 1. Let b1; : : : ; bn be rational integers, not
all zero, and set B D maxf3; jb1j; : : : ; jbnjg. If
j˛b1
1 ˛bn
n 1j
e ınB
2
;
then
B .4.nC1/2
ı 1
D2.nC1/
log A/.2nC3/2
:
23. 1.1. Linear forms in complex logarithms 5
In many applications, especially to classical families of Diophantine equations, we are
led to bound from below expressions of the form j˛b1
1 ˛bn
n ˛nC1 1j, where ˛nC1 has a
large height; see Chapter 4. In this respect, Theorem 1.9 is not plainly satisfactory, since
˛1; : : : ; ˛n play the same rôle, irrespective of their height and their exponent. Its following
refinement, established by Baker [26], appears to be very useful.
Theorem 1.10. Assume that n 1 and let ˛1; : : : ; ˛nC1 be non-zero algebraic numbers
of degree at most D. Let the heights of ˛1; : : : ; ˛n and ˛nC1 be at most A and AnC1
respectively, where A 2 and AnC1 2. Let ı be a positive real number. Let b1; : : : ; bn
be integers, not all zero, and set B D maxf3; jb1j; : : : ; jbnjg. If
0 j˛b1
1 ˛bn
n ˛nC1 1j e ıB
;
then
B n;D;A;ı log AnC1:
In the present textbook, we give a complete proof of Theorem 1.10. We derive it from
a lower bound for linear forms in two logarithms; see Section 4.1.
In 1975, Baker [27] established a subsequent refinement of Theorem 1.8.
Theorem 1.11. Assume that n 2 and that ˛1; : : : ; ˛n are non-zero algebraic numbers,
whose degrees do not exceed D. Assume that, for j D 1; : : : ; n, the height of ˛j does
not exceed Aj , where Aj 2. Let b1; : : : ; bn be rational integers, not all zero, and set
B D maxf3; jb1j; : : : ; jbnjg. If ˛b1
1 ˛bn
n is not equal to 1, then
j˛b1
1 ˛bn
n 1j B C… log …
; (1.6)
where
… D log A1 log An
and C is an effectively computable real number depending only on n and D.
As was pointed out by Baker below the statement of his theorem, it would be of much
interest to eliminate log … in (1.6). Also, Theorem 1.11 does not include Theorems 1.9
and 1.10, nor the main result of Baker’s paper [25].
The deletion of the log … factor (which is mainly interesting from a theoretical point of
view, but also has several applications, see, for example, Theorem 3.6) has been achieved
independently by Wüstholz [440] and by Philippon and Waldschmidt [329]. Thus, at the
end of the ’80s, it was established that, with ƒ, A1; : : : ; An, and B as in (1.2) and (1.3),
there exists an effectively computable real number c.n/, depending only on the number n
of rational numbers involved in (1.3), such that the lower estimate
log
ˇ
ˇ
ˇ
x1
y1
b1
xn
yn
bn
1
ˇ
ˇ
ˇ c.n/ log A1 log An log B (1.7)
holds, when ƒ is non-zero. Since then, several authors have managed to considerably
reduce the value of the real number c.n/. However, it remains an open problem to replace
the product log A1 log An by the sum log A1 C C log An; see Chapter 13.
24. 6 1. Brief introduction to linear forms in logarithms
1.2. Linear forms in p-adic logarithms
Let p be a prime number. In parallel with the development of the theory of linear forms
in complex logarithms, progress has been regularly made towards its p-adic analogue.
For a non-zero rational number x, let vp.x/ denote the exponent of p in the decompo-
sition of x as a product of prime powers. With ƒ; A1; : : : ; An, and B as in (1.2) and (1.3),
a trivial estimate shows that
vp
x1
y1
b1
xn
yn
bn
1
log.2Ab1
1 Abn
n /
log p
1 C
B
log p
n
X
j D1
log Aj : (1.8)
The theory of p-adic linear forms in logarithms gives a much better result in terms of the
dependence on B, namely, that there exists an effectively computable real number c0
.n/,
depending only on the number n of rational numbers involved, such that the upper estimate
vp
x1
y1
b1
xn
yn
bn
1
c0
.n/ p log A1 log An log B (1.9)
holds, when ƒ is non-zero. In terms of B, this is much better than (1.8) and analogous
to (1.7). One of the major open problems in the theory is to remove (or at least to improve)
the dependence on p in (1.9), which remains very unsatisfactory and is ultimately a
consequence of the fact that the radius of convergence of the p-adic exponential function
is finite.
A good reference for an historical introduction is [448]. Mahler [278] established
in 1932 the p-adic analogue of the Hermite–Lindemann theorem and three years later [280]
the p-adic analogue of the Gelfond–Schneider theorem. Gelfond [199] proved a quan-
titative estimate for linear forms in two p-adic logarithms, which was later refined by
Schinzel [354].
Estimates for linear forms in an arbitrary number of p-adic logarithms were obtained by
Brumer [99], Sprindžuk [384,385], Coates [149], Kaufman [238], Baker and Coates [34],
van der Poorten [335], Dong [168,169], and Yu [443,445–447], among others.
1.3. Linear forms in elliptic logarithms
A few years after the birth of the theory of linear forms in logarithms, it was realized
that the techniques used in the proofs can be applied to any commutative algebraic group.
Initial steps towards the derivation of elliptic analogues were made by Baker [23], who
considerably extended earlier results of Schneider [360]. Elliptic curves with complex mul-
tiplication were studied by Masser [284] in 1975 and, a year later, Coates and Lang [151]
established the first lower bounds in the case of Abelian varieties with complex multi-
plication. Subsequently, Philippon and Waldschmidt [330] and Hirata-Kohno [229,230]
obtained rather general statements.
In the case of elliptic logarithms, the first totally explicit estimates were given by
David [162]. These have applications to the complete determination of the integral points
on an elliptic curve, as is very well explained by Stroeker and Tzanakis [408], Gebel,
Pethő, and Zimmer [196], and Tzanakis [420,421].
25. 1.3. Linear forms in elliptic logarithms 7
Let n be a positive integer and E1; : : : ; En elliptic curves over an algebraic number
field K. For j D 1; : : : ; n, consider a Weierstrass model of Ej and }j the associated
Weierstrass function. Let uj be a complex number such that }j .uj / is in K [ f1g.
Such a complex number uj is an elliptic logarithm of an algebraic point of Ej . Also,
let ˇ0; ˇ1; : : : ; ˇn be elements of K. Let B 3 denote an upper bound for the heights
of ˇ0; ˇ1; : : : ; ˇn.
Set
ƒe WD ˇ0 C ˇ1u1 C C ˇnun:
David and Hirata-Kohno [163] established that there exists an effectively computable
positive real number c, which depends only on K; n; u1; : : : ; un and the curves E1; : : : ; En,
such that we have jƒej B c
if ƒe is non-zero.
For the state-of-the-art and generalisations to Abelian varieties, the reader is directed
to [163] and to Gaudron’s papers [192–194].
Lower bounds for linear forms in p-adic elliptic logarithms were given by Rémond
and Urfels [345] and Hirata-Kohno and Takada [232]; see also Fuchs and Pham [189].
27. Chapter 2
Lower bounds for linear forms
in complex and p-adic logarithms
We list below several estimates for linear forms in complex and p-adic logarithms, which
will be used throughout the book. We give only few bibliographic references and direct
the reader to the monograph of Waldschmidt [432] for further information, in particular
to its Section 10.4. Most of the results quoted are corollaries of more precise estimates, so
the reader wishing to apply the theory of linear forms in logarithms should better consult
the original papers to find the sharpest bounds available to date.
In this chapter we write completely explicit estimates. This will, however, not be
the case for most of the results presented in the next chapters, where we will often make
no effort to give explicit values for the numerical constants. Throughout, h denotes the
(logarithmic) Weil height; see Definition B.4.
2.1. Lower bounds for linear forms in complex logarithms
We start with a general theorem of Waldschmidt [430,432] on inhomogeneous linear forms
in logarithms of algebraic numbers with algebraic coefficients.
Theorem 2.1. Let n 1 be an integer. Let ˛1; : : : ; ˛n be non-zero algebraic numbers. Let
log ˛1; : : : ; log ˛n be determinations of their logarithm and assume that log ˛1; : : : ; log ˛n
are linearly independent over the rationals. Let ˇ0; : : : ; ˇn be algebraic numbers, not
all zero. Let D be the degree over Q of the number field Q.˛1; : : : ; ˛n; ˇ0; : : : ; ˇn/.
Let E; E
, and A1; : : : ; An be real numbers with
E
E1=D
e1=D
; E
e; E
D
log E
;
and
log Aj max
n
h.˛j /;
E
D
j log ˛j j;
log E
D
o
; 1 j n:
Let B
be a real number with
B
E
; B
max
1jn
D log Aj
log E
; log B
max
0j n
h.ˇj /:
28. 10 2. Lower bounds for linear forms in complex and p-adic logarithms
Then, we have
log jˇ0 C ˇ1 log ˛1 C C ˇn log ˛nj
2nC25
n3nC9
DnC2
log A1 : : : log An log B
log E
.log E/ n 1
:
Assume that we are in the homogeneous rational case, that is, assume that ˇ0 D 0
and ˇ1; : : : ; ˇn are rational integers b1; : : : ; bn with bn ¤ 0. Let B0
be a real number
satisfying
B0
E
; B0
max
1j n 1
n jbnj
log Aj
C
jbj j
log An
o
:
Then, we have
log jb1 log ˛1 C C bn log ˛nj
2nC26
n3nC9
DnC2
log A1 : : : log An log B0
log E
.log E/ n 1
:
In particular, choosing E D e and E
D 3D, we get
log jb1 log ˛1 C C bn log ˛nj
2nC26
n3nC9
DnC2
log.3D/ log A1 : : : log An log B0
:
Proof. This follows from Theorem 9.1 of [432], taking into account Remark 3 on page 303
and Proposition 9.18 of [432].
By Proposition 9.21 of [432], the assumption in Theorem 2.1 that log ˛1; : : : ; log ˛n are
linearly independent over the rationals can be relaxed to the assumptions ˇ0 Cˇ1 log ˛1 C
C ˇn log ˛n ¤ 0 and
D3
.log B0/.log Aj /.log E
/ .log D/.log E/2
; 1 j n;
where B0 D B
in the general case and B0 D B0
in the homogeneous rational case.
Theorem 2.1 plainly includes Theorem 1.5. It also contains Theorem 1.11 and the
lower bound (1.7). Taking n 2 and bn D 1 in the homogeneous rational case of
Theorem 2.1 and setting B WD maxf3; jb1j; : : : ; jbn 1jg, we get
log jb1 log ˛1 C C bn 1 log ˛n 1 C log ˛nj n;D log A1 : : : log An log
B
log An
:
This has many important applications, in particular to Diophantine equations; see Theo-
rems 4.1, 4.3, and 4.5. Assuming that there exists a real number ı such that 0 ı 1
2
and jb1 log ˛1 C C bn 1 log ˛n 1 C log ˛nj e ıB
, we deduce that
B n;D ı 1
log A1 : : : log An 1 log ı 1
log.Dn 1
A1 : : : An 1/
log An:
This (and the discussion below explaining how the linear form (2.1) and the quantity (2.2)
are related) shows that Theorem 2.1 also contains Theorem 1.10.
In the homogeneous rational case, a result similar to Theorem 2.1 was proved in-
dependently by Baker and Wüstholz [37, 38]. Since their estimate (which has a better
29. 2.1. Lower bounds for linear forms in complex logarithms 11
dependence on n than in Theorem 2.1, namely the factor n3n
is replaced by n2n
) does not
include the useful parameters E and B0
, and is superseded by Theorem 2.2 below, we do
not quote it.
The parameter E originates in papers by Shorey [367, 368] and is of interest when
˛1; : : : ; ˛n are real and very close to 1, in which case it can be chosen to be very large.
By assumption, log E cannot exceed D min1j n log Aj . However, in some cases, it can
be taken close to this quantity. To see this in the homogeneous rational case, assume that,
for j D 1; : : : ; n, we have ˛j D 1 C 1
xj
, for an integer xj 3. Then, setting
E D E
D min
1j n
xj and Aj D xj C 1; 1 j n;
we see that, since B0
E, Theorem 2.1 implies the lower bound
log jb1 log ˛1 C Cbn log ˛nj n
log A1 : : : log An
.min1j n log Aj /n 1
log maxf3; jb1j; : : : ; jbnjg:
In the most favourable cases, for example when there exists a real number M such that
max1j n xj .min1j n xj /M
, we get
log jb1 log ˛1 C C bn log ˛nj n Mn 2
max
1j n
log Aj
log maxf3; jb1j; : : : ; jbnjg;
thus replacing the product of the log Aj , as it occurs in the statement of Theorem 2.1, with
their maximum. Further explanations are given below Theorem 2.5, in Chapter 5, and in
Section 10.4.3 of [432].
In the course of this textbook, we mention in passing a few applications of the first
assertion of Theorem 2.1 (at the beginning of Section 3.3 and in Section 3.10), but we
only apply estimates for homogeneous linear forms in logarithms with integer coefficients.
Therefore, we focus our attention on the second assertion of Theorem 2.1 and its subsequent
improvements and refinements.
Let n 2 be an integer. Let ˛1; : : : ; ˛n be non-zero algebraic numbers. Let b1; : : : ; bn
be integers. Let log ˛1; : : : ; log ˛n be any determination of the logarithms of ˛1; : : : ; ˛n.
The theory of linear forms in logarithms provides us with lower bounds for the absolute
value of the linear form
b1 log ˛1 C C bn log ˛n; (2.1)
when it is non-zero. This yields lower bounds for the quantity
j˛b1
1 : : : ˛bn
n 1j; (2.2)
which occurs frequently in Diophantine questions. We choose below to mainly consider
quantities of the form (2.2) and not (2.1). When ˛1; : : : ; ˛n are all real numbers, both
forms are essentially equivalent since log.1 C x/ D x C O.x2
/ in the neighborhood of
the origin. This is however not the case when complex non-real numbers are among
˛1; : : : ; ˛n. Indeed, denoting by log the principal determination of the logarithm, to say
that (2.2) is small does not imply that b1 log ˛1 C C bn log ˛n is close to 0, but merely
30. 12 2. Lower bounds for linear forms in complex and p-adic logarithms
that b1 log ˛1 C C bn log ˛n is close to an integer multiple of 2i. Precisely, we derive
the existence of an integer b0 with jb0j jb1j C C jbnj and such that the linear form
b0 log. 1/ C b1 log ˛1 C C bn log ˛n
is close to 0.
The next statement is a corollary of the, at present time, best known general estimate,
due to Matveev [290, 291]. The crucial improvement on the earlier results [37, 430]
concerns the dependence on the number n of logarithms: it is exponential in n, and not of
the form ncn
as in the earlier estimates.
Theorem 2.2. Let n 1 be an integer. Let ˛1; : : : ; ˛n be non-zero algebraic numbers.
Let D be the degree over Q of a number field containing ˛1; : : : ; ˛n. Let A1; : : : ; An be
real numbers with
log Aj max
n
h.˛j /;
j log ˛j j
D
;
0:16
D
o
; 1 j n:
Let b1; : : : ; bn be integers and set
B D maxfjb1j; : : : ; jbnjg
and
B00
D max
n
1; max
n
jbj j
log Aj
log An
W 1 j n
oo
:
Then, we have
log j˛b1
1 : : : ˛bn
n 1j 330nC4
.nC1/5:5
DnC2
log.eD/ log A1 : : : log An log.enB/
(2.3)
and, if n 2 and ˛1; : : : ; ˛n are all real numbers, we get the better lower bound
log j˛b1
1 : : : ˛bn
n 1j 2 30nC3
n4:5
DnC2
log.eD/ log A1 : : : log An log.eB/:
(2.4)
The same statements hold with B replaced by maxfB00
; nB=.D log An/g in (2.3) and
with B replaced by B00
in (2.4).
Proof that Theorem 2.2 follows from Matveev’s results. Inequality (2.4) with B replaced
or not by B00
is an immediate consequence of Corollary 2.3 of Matveev [291]. Denote
by log the principal determination of the logarithm. If j˛b1
1 : : : ˛bn
n 1j 1
2
, then there
exists an integer b0, with jb0j n B, such that
WD jb0 log. 1/ C b1 log ˛1 C C bn log ˛nj
satisfies j˛b1
1 : : : ˛bn
n 1j
2
. Noticing that j log. 1/j D and h. 1/ D 0, we set
log A0 D
D
and deduce (2.3) from Corollary 2.3 of Matveev [291].
Since
jb0j
log A0
log An
nB
D log An
;
we see that B can be replaced by maxfB00
; nB=.D log An/g in (2.3).
31. 2.1. Lower bounds for linear forms in complex logarithms 13
We stress that the definition of B0
in Theorem 2.1 is slightly different from that of B00
in Theorem 2.2. The lower bound (2.4) with B00
in place of B is crucial for the proof of
Theorem 3.8.
Many Diophantine problems can be reduced to lower bounds for linear forms in two or
three logarithms. While, in the case of three logarithms, we do not have very satisfactory
estimates (but see [298]), Laurent, Mignotte, and Nesterenko [254] obtained in 1995 rather
sharp lower bounds for linear forms in two logarithms. The quality of their result is an
illustration of the method of interpolation determinants, which was introduced in this
context by Laurent [252]. The current best known estimates have been established by
Laurent in 2008 in [253]. We display below an estimate obtained in Corollary 1 of [253]
and three consequences of the main result of [254].
Theorem 2.3. Let ˛1 and ˛2 be multiplicatively independent algebraic numbers. Set
D0
D ŒQ.˛1; ˛2/ W Q=ŒR.˛1; ˛2/ W R. Let A1 and A2 be real numbers such that
log Aj max
n
h.˛j /;
1
D0
;
j log ˛j j
D0
o
; j D 1; 2:
Let b1 and b2 be integers, not both zero, and set
log B0
D max
n
log
jb1j
D0 log A2
C
jb2j
D0 log A1
C 0:21;
20
D0
; 1
o
:
Then, we have the lower bound
log jb1 log ˛1 C b2 log ˛2j 25:2 D04
.log A1/.log A2/.log B0
/2
: (2.5)
For n D 2, the numerical constant in (2.4) exceeds 109
. It has been substantially
reduced in Theorem 2.3. This is crucial for applications to the complete resolution of
Diophantine equations. Very roughly speaking, when a Diophantine problem can be
reduced to linear forms in only two logarithms, then it can (often, this is not always true!
See Problem 13.12) be completely solved.
A weaker version (weaker only in terms of the numerical constants) of Theorem 2.3
is proved in this book; see Theorem 11.1. Note also that, unlike in Theorem 2.3, the
algebraic numbers ˛1 and ˛2 are not assumed to be multiplicatively independent in
Theorem 11.1. This allows us to deduce directly from Theorem 2.3 a slightly weaker
version of Theorem 2.6, see Theorem 11.3.
Observe that the dependence on B0
in Theorem 2.3 is not best possible and worse
than in Theorems 2.1 and 2.2, since log B0
occurs squared. Gouillon [202] established
a lower bound for jb1 log ˛1 C b2 log ˛2j, where the dependence on B0
occurs through a
factor .log B0
/ only. His numerical constants being not so small, it is better for most of
the applications to use the bounds established in [253, 254]. However, to have the best
possible dependence in B0
is essential for the proofs of Theorems 3.3 and 5.1.
As in Theorem 2.1, an extra parameter E was introduced in [254]. We reproduce
below Corollaire 3 of [254].
Theorem 2.4. Let ˛1 and ˛2 be multiplicatively independent positive real algebraic
numbers. Let D be the degree of the number field Q.˛1; ˛2/. Let A1 and A2 be real
32. 14 2. Lower bounds for linear forms in complex and p-adic logarithms
numbers such that
log Aj max
n
h.˛j /;
1
D
;
j log ˛j j
D
o
; j D 1; 2:
Let b1 and b2 be integers, not both zero. Let E be a real number with
E 1 C min
nD log A1
j log ˛1j
;
D log A2
j log ˛2j
o
(2.6)
and set
log B0
D max
n
log
jb1j
D log A2
C
jb2j
D log A1
C log log E C 0:47;
10 log E
D
;
1
2
o
:
Assume furthermore that 2 E minfA3D=2
1 ; A3D=2
2 g. Then,
log jb1 log ˛1 C b2 log ˛2j 35:1D4
.log A1/.log A2/.log B0
/2
.log E/ 3
:
In [254], the authors defined the parameter E to be equal to the right hand side of (2.6).
However, it easily follows from the proof that Theorem 2.4 as stated is correct.
A weaker version (weaker only in terms of the numerical constants) of Theorem 2.4 is
proved in this book; see Theorem 11.2.
The following consequence of Theorem 2.4 emphasizes the rôle of the parameter E in
a particular case which occurs frequently in applications.
Theorem 2.5. Let x1; x2; y1; y2 be positive integers with x1 2, x1 ¤ y1, and
y2 x2 6
5
y2. Let b be a positive integer and assume that .x1
y1
/b
¤ x2
y2
. Define
the parameter by
x2
y2
D 1 C x
2 :
Then, we have log x2 1 and
log
ˇ
ˇ
ˇ
y1
x1
b x2
y2
1
ˇ
ˇ
ˇ
35:2
.log x1/
max
n
1 C
log b
log x2
; 10
o2
: (2.7)
Since x2
y2
1, we always have 1. The estimate is stronger when is very close
to 1, that is, when x2
y2
is very close to 1. Under the assumption of Theorem 2.5, we get
instead of (2.5) a lower bound of the form
.log A1/.log A2/
log.x2
y2
1/
.log B0
/2
;
with A1 D maxfx1; 3g and A2 D maxfx2; 3g. This crucial improvement upon the
“classical” estimate (2.5) turns out to have many spectacular applications, some of which
being given in Chapter 5; see Theorems 5.2, 5.4, and 5.6.
Proof of Theorem 2.5 assuming Theorem 2.4. If y1 x1, then the left hand side of (2.7)
exceeds log.y1
x1
1/, thus it exceeds log x1 and (2.7) holds.
If y1 x1 and x1 5, then .y1
x1
/b
4
5
and (2.7) holds since x2
y2
6
5
.
33. 2.1. Lower bounds for linear forms in complex logarithms 15
If x1 y1 and x1
y1
and x2
y2
are multiplicatively dependent, then there exist coprime
positive integers c; d and positive integers u; v such that x1
y1
D . c
d
/u
and x2
y2
D . c
d
/v
. We
then get
ˇ
ˇ
ˇ
y1
x1
b x2
y2
1
ˇ
ˇ
ˇ D
ˇ
ˇ
ˇ
d
c
ub v
1
ˇ
ˇ
ˇ
1
maxfc; dg
1
x1
;
and the theorem holds.
Thus, we assume that x1
y1
and x2
y2
are multiplicatively independent, x1 y1, and
x1 6. Observe that (2.7) holds if x1 x
2 =2. To see this, it suffices to observe that,
since y1 x1, we then get
0
y1
x1
b x2
y2
1
1
x1
1 C
1
x
2
1
1
2x1
;
which implies that
ˇ
ˇ
ˇ
y1
x1
b x2
y2
1
ˇ
ˇ
ˇ
1
2x1
:
Thus, in the sequel, we assume that x
2 2x1. We apply Theorem 2.4 with ˛1 D x1
y1
and ˛2 D x2
y2
. Then, D D1, A1 Dx1 and A2 Dx2 (note that the assumption y2 x2 6
5
y2
implies that x2 6). Furthermore, we set
E D x
2 :
Observe that E 5, since 5x2 6y2. This proves the first assertion of the theorem.
Furthermore, we have E minfx3=2
1 ; x3=2
2 g, since x1 6 and 1.
We deduce from log.1 C x
2 / x
2 that
1 C
log x2
log x2
y2
D 1 C
log x2
log.1 C x
2 /
1 C x
2 log x2 E:
Furthermore, we may assume that
ˇ
ˇ
ˇ
y1
x1
b x2
y2
1
ˇ
ˇ
ˇ x 10
1 ;
since otherwise the theorem clearly holds. Using this inequality and 5 x
2 2x1, we
deduce that
b log
x1
y1
log
x2
y2
C 2x 10
1 x
2 C 211
x 10
2 2x
2 ;
thus
1 C
log x1
log x1
y1
1 C
b
2
x
2 log x1 E;
since x1 6. Consequently, we have checked that
E 1 C min
nlog x1
log x1
y1
;
log x2
log x2
y2
o
:
34. 16 2. Lower bounds for linear forms in complex and p-adic logarithms
The assumptions of Theorem 2.4 are then satisfied and we derive that
log
ˇ
ˇ
ˇlog
x2
y2
b log
x1
y1
ˇ
ˇ
ˇ 35:1 .log x1/
log x2
log E
log B0
log E
2
35:1
.log x1/
log B0
log E
2
;
where
log B0
log E
D max
(
log b
log x2
C 1
log x1
log E
C
log log E C 0:47
log E
; 10
)
max
n
1 C
log b
log x2
; 10
o
:
We conclude by using that every real number z with jzj 1
2
satisfies j log.1 C z/j 2jzj.
This completes the proof of the theorem.
For some applications, we need a lower bound for quantities of the shape j˛b
1j,
where ˛ is a complex algebraic number of modulus 1. Such an estimate does not follow
from Theorem 2.3, since in its statement ˛1 and ˛2 are assumed to be multiplicatively
independent. We display a consequence of Théorème 3 of [254].
Theorem 2.6. Let ˛ be a complex algebraic number of modulus 1 which is not a root of
unity. Let b be a positive integer. Set
D0
D
ŒQ.˛/ W Q
2
; log A D max
n 20
D0
; 11
j log ˛j
D0
C h.˛/
o
;
and
log B0
D max
n 17
D0
;
1
10
p
D0
; log
b
25
C 2:35 C
5:1
D0
o
:
Then, we have
log j˛b
1j 9.D0
/3
.log A/.log B0
/2
:
Proof that Theorem 2.6 follows from Théorème 3 of [254]. Recall that log denotes the
principal determination of the logarithm. If j˛b
1j 1
3
, then there exists an integer b0
with jb0j b such that
j˛b
1j
jb0 log. 1/ C b log ˛j
2
:
We then use the inequalities
1
2D0 log A
C
1
68:9
1
40
C
1
68:9
1
25
to get from Théorème 3 of [254] that
log jb0 log. 1/ C b log ˛j 8:87.D0
/3
.log A/.log B0
/2
:
This yields the desired estimate.
35. 2.2. Multiplicative dependence relations between algebraic numbers 17
2.2. Multiplicative dependence relations between algebraic numbers
The results displayed in the previous section provide us with lower bounds for the quantity
jb1 log ˛1 C C bn log ˛nj;
when it is non-zero. However, in some situations, we derive linear forms in logarithms
that are equal to zero. It is then often useful to find rational integers b0
1; : : : ; b0
n, not all
zero, with small absolute values and such that
b0
1 log ˛1 C C b0
n log ˛n D 0:
A result of this type was given by Loxton and van der Poorten [271]. We quote below a
version of Waldschmidt [432].
Theorem 2.7. Let m 2 be an integer and ˛1; : : : ; ˛m multiplicatively dependent non-
zero algebraic numbers. Let log ˛1; : : : ; log ˛m be any determination of their logarithms.
Let D bethedegreeofthe numberfieldgeneratedby ˛1; : : : ; ˛m over Q. Forj D 1; : : : ; m,
let Aj be a real number satisfying
log Aj max
n
h.˛j /;
j log ˛j j
D
; 1
o
:
Then there exist rational integers n1; : : : ; nm, not all zero, such that
n1 log ˛1 C C nm log ˛m D 0
and
jnj j 11.m 1/D3
m 1 .log A1/ .log Am/
log Aj
; for j D 1; : : : ; m.
A full proof of Theorem 2.7, together with additional references, is given in Chapter 10.
Theorem 2.7 is used in the proof of Theorem 3.16.
2.3. Lower bounds for linear forms in p-adic logarithms
Let p be a prime number and K an algebraic number field. Let OK denote the ring
of integers of K. Let p be a prime ideal in K, lying above the prime number p, and
denote by ep its ramification index, that is, the exponent of p in the decomposition of
the ideal pOK in a product of prime ideals; see Section B.1. For a non-zero algebraic
number ˛ in K, let vp.˛/ denote the exponent of p in the decomposition of the fractional
ideal ˛OK in a product of prime ideals and set
vp.˛/ D
vp.˛/
ep
:
This defines a valuation vp on K which extends the p-adic valuation vp on Q normalized
in such a way that vp.p/ D 1.
36. 18 2. Lower bounds for linear forms in complex and p-adic logarithms
Let ˛1; : : : ; ˛n be elements of K and b1; : : : ; bn non-zero rational integers. We look
for an upper bound for the quantity
vp.˛b1
1 : : : ˛bn
n 1/;
where b1; : : : ; bn denote rational integers, not all zero, when ˛b1
1 : : : ˛bn
n is not equal to 1.
We begin with an easy estimate.
Theorem 2.8. Let p be a prime number, b 2 an integer, and ˛ an algebraic number of
degree D. If ˛b
is not equal to 1, then
vp.˛b
1/
log b
log p
C 2D
pD
1
log p
h.˛/ C 2D
log 2
log p
:
The proof of Theorem 2.8 is given in Section B.3. Theorem 2.8 is trivial unless
vp.˛/ D 0, in which case the factor .pD
1/ corresponds to the upper bound for the
smallest positive integer s such that vp.˛s
1/ is positive. The dependence on p in
Theorem 2.8 was slightly improved by Yamada [442] by means of a subtle variation
of the proof of the main estimate of [129] for linear forms in two p-adic logarithms.
Yamada’s result, reproduced as Theorem 12.3 and established in Chapter 12, has a striking
application to an old conjecture of Erdős; see Theorem 7.11.
The next result is a slight simplification of the estimate given on page 190 of Yu’s
paper [449].
Theorem 2.9. Let p be a prime number and ˛1; : : : ; ˛n algebraic numbers in an algebraic
number field of degree D. Let b1; : : : ; bn denote rational integers such that ˛b1
1 : : : ˛bn
n is
not equal to 1. Let A1; : : : ; An; B be real numbers with
log Aj max
n
h.˛j /;
1
16e2D2
o
; 1 j n;
and
B maxfjb1j; : : : ; jbnj; 3g:
If n 2, then we have
vp.˛b1
1 : : : ˛bn
n 1/.16eD/2.nC1/
n5=2
.log.2nD//2
Dn pD
1
.log p/2
log A1 : : : log An log B:
Theorem 2.9 allows us to improve slightly the dependence on p in Theorem 2.8; see
also Theorem 12.3. Note that (as in Theorems 2.10 and 2.11, but unlike in Theorem 2.12
and in [443]) we do not assume that vp.˛j / D 0 for j D 1; : : : ; n.
The factor .pD
1/ in Theorem 2.9 and in Theorems 2.10 to 2.12 is ultimately due to
the fact that the radius of convergence of the p-adic exponential function is finite, equal
to p 1=.p 1/
. Removing it is a major open problem in the theory. This can be done under
the rather restrictive assumption that vp.˛j 1/ 0 for j D 1; : : : ; n; see [168,169].
Theorem 2.9 should be compared with Theorem 2.2. We have exactly the same de-
pendence on the parameters n, log A1; : : : ; log An, and B. A crucial point in Theorem 2.9
is the dependence on n, which is essential in the proofs of Theorems 8.2 and 8.3 towards
37. 2.3. Lower bounds for linear forms in p-adic logarithms 19
the abc-conjecture. These proofs also require an estimate for vp.˛b1
1 : : : ˛bn
n 1/ with a
(slightly) better dependence on p. For this reason, we quote the result stated on page 30
of [446].
Theorem 2.10. We keep the notation of Theorem 2.9. If n 1, then we have
vp.˛b1
1 : : : ˛bn
n 1/ 12
pD
1
log p
6.n C 1/D
2.nC1/
log.e5
nD/
max
nh.˛1/
log p
; 1
o
max
nh.˛n/
log p
; 1
o
log B:
Yu [449] obtained an improvement of Theorem 2.10, with a better dependence on n,
namely with nn
in place of .n C 1/2n
. We refer to [449] for a precise statement.
The next statement, extracted from page 191 of Yu’s paper [449], is the p-adic analogue
of the main result of [25].
Theorem 2.11. We keep the notation of Theorem 2.9. Let Bn be a real number such that
B Bn jbnj:
Assume that
vp.bn/ vp.bj /; j D 1; : : : ; n:
Let ı be a real number with 0 ı 1
2
. Then, we have
vp.˛b1
1 : : : ˛bn
n 1/ .16eD/2.nC1/
n3=2
.log.2nD//2
Dn pD
1
.log p/2
max
n
.log A1/ .log An/.log T /;
ıB
Bnc0.n; D/
o
; (2.8)
where
T D
Bn
ı
c1.n; D/p.nC1/D
.log A1/ .log An 1/
and
c0.n; D/ D .2D/2nC1
log.2D/ log3
.3D/; c1.n; D/ D 2e.nC1/.6nC5/
D3n
log.2D/:
In particular, we get either
B 2Bn.log A1/ .log An/ c0.n; D/ (2.9)
or
vp.˛b1
1 : : : ˛bn
n 1/ .16eD/2.nC1/
n3=2
.log.2nD//2
Dn pD
.log p/2
.log A1/ .log An/ max
n
1; log
c1.n; D/p.nC1/D
B
c0.n; D/ log An
o
: (2.10)
38. 20 2. Lower bounds for linear forms in complex and p-adic logarithms
The formulation of Theorem 2.11 looks complicated, but it essentially corresponds to
the introduction of the parameter B0
in Theorem 2.1 above. To get the second statement,
we have selected
ı0 D
.log A1/ .log An/Bn
B
c0.n; D/
and distinguished the two cases ı0 1
2
, which gives (2.9), and ı0 1
2
, which, by (2.8)
with ı D ı0, gives (2.10).
In the special case bn D 1, the statements of Theorems 2.2 and 2.11 can be merged;
see Theorem 3.2.8 of [183].
As for linear forms in complex logarithms, the case n D 2 is very important for
applications. The next theorem reproduces one of the corollaries of the main result
of [129].
Theorem 2.12. Let p be a prime number. Let ˛1 and ˛2 be multiplicatively independent
algebraic numbers with vp.˛1/ D vp.˛2/ D 0. Set D D ŒQ.˛1; ˛2/ W Q. Let A1 and A2
be real numbers with
log Aj max
n
h.˛j /;
log p
D
o
; j D 1; 2:
Let b1 and b2 be positive integers and set
log B0
D max
n
log
b1
D log A2
C
b2
D log A1
C log log p C 0:4;
10 log p
D
; 10
o
:
Then, we have the upper bound
vp.˛b1
1 ˛b2
2 /
24p.pD
1/
.p 1/.log p/4
D4
.log A1/.log A2/ .log B0
/2
: (2.11)
The assumption that ˛1 and ˛2 are multiplicatively independent is not really restrictive
for the applications and is useful to get small numerical values in (2.11). The assumption
that ˛1 and ˛2 are p-adic units is not restrictive. Indeed, if only one among vp.˛1/
and vp.˛2/ is positive, then vp.˛b1
1 ˛b2
2 / D 0, while, if both of them are positive,
then vp.˛b1
1 ˛b2
2 / is bounded from below by a positive real number times the minimum
of b1 and b2.
A version of Theorem 2.12 (which is weaker only in terms of the numerical constants)
is proved in this book; see Theorem 12.1.
Unlike Theorem 2.9, Theorem 2.12 cannot be applied to bound vp.˛b
1/ from above
because of the assumption of multiplicative independence, but see Theorem 12.3.
Theorem 2.12 should be compared with Theorem 2.3. In particular, the numerical
constant is very small and the quantity log B0
also occurs squared.
We end this section with an improvement of Theorem 2.12 when ˛1 and ˛2 are rational
numbers which are p-adically close to 1.
Let x1
y1
and x2
y2
be non-zero rational numbers. Theorem 2.13 below, originated in [109],
provides an explicit upper bound for the p-adic valuation of the difference between integer
powers of x1
y1
and x2
y2
.
39. 2.3. Lower bounds for linear forms in p-adic logarithms 21
We suppose that there exist a positive integer g and a real number E with E 1C 1
p 1
and
vp
x1
y1
g
1
E; (2.12)
and at least one of the two following conditions
vp
x2
y2
g
1
E (2.13)
or
vp
x2
y2
g
1
1 and vp.b2/ vp.b1/ (2.14)
is satisfied. For instance, if p is an odd prime number, then (2.12) and (2.13) hold with
g D 1 if x1
y1
and x2
y2
are both congruent to 1 modulo p2
.
We stress that the assumption “(2.13) or (2.14) holds” is more restrictive than the
assumption “vp..x2
y2
/g
1/ 0” made in [109]. However, it seems that the latter
assumption is not sufficient to derive Theorem 2 from Theorem 1 in [109], a fact which
has been overlooked in [109].
Theorem 2.13. Let x1
y1
and x2
y2
be multiplicatively independent rational numbers. Let
b1; b2 be positive integers. Assume that there exist a positive integer g and a real
number E greater than 1 C 1
p 1
such that (2.12) holds, as well as (2.13) or (2.14). Let
A1; A2 be real numbers with
log Aj maxflog jxj j; log jyj j; E log pg; j D 1; 2;
and put
log B0
D max
n
log
b1
D log A2
C
b2
D log A1
C log.E log p/ C 0:4; 6 E log p; 5
o
:
Then, we have the upper bound
vp
x1
y1
b1
x2
y2
b2
36:1 g
E3 .log p/4
.log A1/.log A2/.log B0
/2
; (2.15)
if p is odd or if p D 2 and v2.x2
y2
1/ 2.
Observe that, if x1
y1
and x2
y2
are both congruent to 1 modulo p3
, then we can take E D 3
in Theorem 2.13 and the right hand side of (2.15) can be bounded independently of p.
A weaker version of Theorem 2.13 is proved in this book; see Theorem 12.2.
The parameter E in Theorem 2.13 should be compared with the parameter E in
Theorems 2.1 and 2.4. Let us illustrate its importance with the following example taken
from [117] (see also Exercise 6.11). Apply Theorem 2.13 with the prime number p to
bound from above the p-adic valuation v of .x
y
/b
.1 C cpk
/, for positive integers k, b,
c, x, y, M with k 3, 1 c pMk
, x pk
, and gcd.p; b/ D 1. The latter assumption
implies that, if v 1, then the p-adic valuations of .x
y
/b
1 and x
y
1 are positive
40. 22 2. Lower bounds for linear forms in complex and p-adic logarithms
and equal. Consequently, pk
divides x
y
1 and we apply Theorem 2.13 with g D 1,
A1 D p.MC1/k
, A2 D maxfx; yg, and E D k to get
v
36:1
log p
log A1
E.log p/
.log A2/ .6 C log b/2
;
thus
v
36:1.M C 1/
log p
.log A2/ .6 C log b/2
:
This upper bound is independent of k. It considerably improves the upper bound given
by (2.11) and can be viewed as an analogue of Theorem 2.5 (with 1
replaced with M C1).
2.4. Notes
F Linear forms in one logarithm have been studied by Mignotte and Waldschmidt [300].
Let ˛ be an algebraic number of degree D 2 and of small height. In their lower bound
for j˛ 1j (that is, for j log ˛j), the dependence on D is much better than the one given
by Liouville’s inequality Theorem B.10; see also [134]. Amoroso [7] proved that these
results are essentially sharp; see also [171]. A p-adic analogue has been worked out
in [105].
F In the homogeneous rational case, a complete proof of Theorem 2.1 up to the dependence
on n of the numerical constant has been given by Waldschmidt in [433]. Nesterenko [316]
has written a detailed proof of Theorem 2.2 in the special case where ˛1; : : : ; ˛n are rational
numbers. Aleksentsev [5] established an estimate of a similar strength as Theorem 2.2.
F There is a large gap between the size of the numerical constants in the best known lower
bounds for linear forms in two and in three logarithms. For applications to Diophantine
problems, it would be of greatest interest to improve the lower estimates for linear forms
in three logarithms; see [298] for a step in this direction.
F Bugeaud [111] obtained lower bounds for linear forms in two logarithms and simul-
taneously for several p-adic valuations; see [52,54,111] for applications to Diophantine
equations.
F Simultaneous linear forms in logarithms are discussed in Chapter 9.
41. Chapter 3
First applications
This chapter is principally devoted to Diophantine problems from which one can derive a
linear form in complex logarithms in an almost obvious way, or, at least, in an easy way.
We have listed them in increasing order of difficulty.
We postpone to Chapter 4 applications of the theory of linear forms in complex
logarithms to classical families of Diophantine equations, including unit equations, Thue
equations, elliptic equations, etc.
3.1. On the distance between powers of 2 and powers of 3
One of the simplest applications of the theory of linear forms in complex logarithms shows
that the distance between a power of 2 and the power of 3 closest to it tends to infinity
when the power of 2 tends to infinity. In addition, it provides us with an explicit lower
bound for this distance. Of course, and this will be clear in Section 3.3, the integers 2
and 3 can be replaced by any pair of multiplicatively independent positive integers.
Theorem 3.1. For all positive integers m and n, we have
j2m
3n
j 2m
.em/ 8:4108
:
Proof. Let n 2 be an integer and define m and m0
by the conditions
2m0
3n
2m0
C1
and j3n
2m
j D minf3n
2m0
; 2m0
C1
3n
g:
Then, m is equal to m0
or to m0
C 1 and
j2m
3n
j 2m
; .m 1/ log 2 n log 3 .m C 1/ log 2: (3.1)
The problem of finding a lower bound for j2m
3n
j clearly reduces to this case. Also, we
have m n. To show that 2m
cannot be too close to 3n
, it is sufficient to prove that the
quantity
ƒ WD 3n
2 m
1
is not too small in absolute value. Such a result is a direct consequence of Theorem 2.2,
which, applied with ˛1 D 3; A1 D 3; ˛2 D 2; A2 D 2, gives that
log jƒj 305
211=2
.log 2/ .log 3/ .log em/:
42. 24 3. First applications
We conclude that
j3n
2 m
1j .em/ 8:4108
;
and the theorem is established.
As an application of Theorem 3.1, we list all the powers of 3 which differ from a power
of 2 by at most 20. Our main auxiliary tool is the theory of continued fractions, briefly
explained in Appendix A.
Theorem 3.2. The only solutions in positive integers m; n with n 4 to the inequality
j2m
3n
j 20 (3.2)
are given by j26
34
j D 17 and j28
35
j D 13.
Proof. Let n 6 and m be integers satisfying (3.2). Applying Theorem 3.1 to Inequal-
ity (3.2), we get
20 2m
.em/ 8:4108
;
which implies
log 20 m log 2 8:4 108
.1 C log m/;
giving m 4 1010
and
n
.m C 1/.log 2/
log 3
3 1010
;
by (3.1). Since j log.1 C x/j 2jxj for any real number x with jxj 1
2
, the inequality
j2m
3n
j 20 implies
ˇ
ˇ
ˇ
ˇ
log 3
log 2
m
n
ˇ
ˇ
ˇ
ˇ
40
n log 2
3 n
: (3.3)
Observe that the right-hand side of (3.3) is less than 1
2n2 , since n 6. By Theorem A.2,
the rational number m
n
is a convergent of the continued fraction expansion of WD log 3
log 2
.
Furthermore, for n N WD 3 1010
, the smallest value of jm nj is obtained for the
last convergent of the continued fraction expansion of with denominator less than N .
The computation of this expansion shows that
ˇ
ˇ
ˇ
ˇ
log 3
log 2
m
n
ˇ
ˇ
ˇ
ˇ 9:6 10 18
; for 0 n 3 1010
:
Comparing (3.3) with this estimate, we deduce that n 36. A rapid verification in the
range 6 n 36 completes the proof that (3.2) has no solution with n 6.
43. 3.2. Effective irrationality measures for quotients of logarithms of integers 25
3.2. Effective irrationality measures for quotients
of logarithms of integers
Let a and b be multiplicatively independent positive rational numbers. It follows straight-
forwardly from the first assertion of Theorem 2.1 that the real number log a
log b
is transcendental
and, by arguing as in the proof of Theorem 3.1, we show that it is not a Liouville number
(see Definition A.6) and give an effective upper bound for its irrationality exponent (see
Definition A.3).
Theorem 3.3. Let a1; a2; b1; b2 be positive integers such that the rational numbers a1
a2
and b1
b2
are multiplicatively independent. Then, the effective irrationality exponent of the
real number .log a1
a2
/=.log b1
b2
/ satisfies
eff
log a1
a2
log b1
b2
.log maxfa1; a2g/ .log maxfb1; b2g/:
A strengthening of Theorem 3.3 in the special case where a1
a2
and b1
b2
are rational
numbers close to 1 is given in Section 5.1.
Proof. Let p
q
be a convergent to .log a1
a2
/=.log b1
b2
/ with q 2. Since an irrational
real number and its inverse have the same irrationality exponent, we can assume that
j log a1
a2
j j log b1
b2
j. It then follows from Theorem 2.1 (or from Theorem 2.2) that
log
ˇ
ˇ
ˇ
ˇq log
a1
a2
p log
b1
b2
ˇ
ˇ
ˇ
ˇ .log maxfa1; a2g/ .log maxfb1; b2g/ .log q/:
Thus, there exists an effectively computable, absolute real number C such that
ˇ
ˇ
ˇ
ˇ
log a1
a2
log b1
b2
p
q
ˇ
ˇ
ˇ
ˇ D
jq log a1
a2
p log b1
b2
j
q log b1
b2
q C.log maxfa1;a2g/ .log maxfb1;b2g/
:
This proves the theorem.
The fact that the dependence on B in Theorem 2.2 occurs through the factor .log B/ and
not through the factor .log B/2
, as in Theorem 2.3, is crucial for the proof of Theorem 3.3.
3.3. On the distance between two integral S-units
For a finite set S of prime numbers, an integral S-unit is, by definition, an integer all of
whose prime factors are in S. The following result extends Theorem 3.1. It was proved
by Tijdeman [414] in 1973.
Theorem 3.4. Let S denote a finite, non-empty set of prime numbers and .xj /j 1 the
increasing sequence of all positive integers whose prime factors belong to S. There exists
an effectively computable real number C, depending only on S, such that
xj C1 xj xj .log 2xj / C
; j 1:
44. 26 3. First applications
Proof. Write S D fq1; : : : ; qsg, where q1; : : : ; qs are prime numbers and q1 qs.
Let u; v with 3 u v be two consecutive elements in the sequence .xj /j 1 and write
u D
s
Y
iD1
qui
i ; v D
s
Y
iD1
qvi
i :
Without any loss of generality, we can assume that s 2, v 2u, and that u and v are
coprime. Thus, for every i D 1; : : : ; s, at least one of ui ; vi is zero. Set
ƒ WD
s
Y
iD1
qvi ui
i 1 D
v
u
1:
Put B D maxf3; jv1 u1j; : : : ; jvs usjg and observe that
2B=3
qB=3
1 v 2u: (3.4)
It follows from Theorem 2.2 that
log ƒ 30sC4
s5
s
Y
iD1
log qi
.log eB/:
Combined with (3.4), this gives
log
v
u
1
30sC4
s5
s
Y
iD1
log qi
log
3e log.2u/
log 2
:
Taking the exponential of both sides and multiplying by u, we get the assertion of the
theorem.
In view of the next result, established by Tijdeman [415] in 1974, Theorem 3.4 is
essentially best possible.
Theorem 3.5. Let P be an integer and S a finite set of at least two distinct prime numbers
all being at most equal to P . Let .xj /j 1 be the increasing sequence of all positive
integers whose prime divisors belong to S. There exists an effectively computable real
number C, depending only on P , such that
xj C1 xj xj .log 2xj / C
; j 1:
It is an open problem of Erdős to establish that, for S being the set of all prime numbers
less than P , Theorem 3.5 holds with a real number C D C.P / which tends to infinity
with P .
3.4. Effective irrationality measures for n-th roots
of algebraic numbers
We have seen in Theorem 3.3 how the theory of linear forms in logarithms can be applied
to give an effective upper bound for the irrationality exponent of certain transcendental
real numbers. The next result addresses a special class of real algebraic numbers.
45. 3.5. On the greatest prime factor of values of integer polynomials 27
Theorem 3.6. Let n 3 be an integer and a positive, real algebraic number. Then, the
effective irrationality exponent of n
p
satisfies
eff. n
p
/ log n:
Furthermore, if a; b are integers with 1 b a, then we have
eff. n
p
a=b / .log a/.log n/;
and, if a 2n
, then we get
eff. n
p
a=b / 11000 log a: (3.5)
When n is sufficiently large in terms of , Theorem 3.6 improves the upper bound
eff. n
p
/ n deg./, given by Liouville’s Theorem A.5. It remains, however, very
far from Roth’s Theorem A.7, which asserts that . n
p
/ D 2 but gives no information
on eff. n
p
/.
In Section 5.2 we considerably strengthen Theorem 3.6 when is a rational number
very close to 1.
Proof. Let n 3 be an integer and a positive, real algebraic number. Let p
q
be a
convergent of n
p
with q 2. Observe that
ˇ
ˇ
ˇ
n
p
p
q
ˇ
ˇ
ˇ
1
2n maxf1; jjg
ˇ
ˇ
ˇ
p
q
nˇ
ˇ
ˇ:
It directly follows from Theorem 2.2 that
log
ˇ
ˇ
ˇ
p
q
nˇ
ˇ
ˇ C./.log q/.log n/;
where C./ is an effectively computable real number which can be expressed in terms of
the height and the degree of . If is the rational number a
b
with 1 b a, then C./ can
be taken to be an absolute real number times log a. This proves the first two statements of
the theorem.
For large values of n, we obtain a stronger result (not only numerically) by applying
Theorem 2.3. Indeed, if a; b are integers with 1 b a, it directly gives the lower bound
log
ˇ
ˇ
ˇn log
p
q
log
a
b
ˇ
ˇ
ˇ 25:2.log p/.log a/
max
n
log
2n
log a
C 0:21; 20
o2
;
if p is sufficiently large. From this and under the assumption a 2n
, we deduce (3.5).
3.5. On the greatest prime factor of values of integer polynomials
Let f .X/ be a non-zero integer polynomial with at least two distinct roots. Let n be an
integer. Using the theory of linear forms in logarithms, Shorey and Tijdeman [374] were
the first to give an effective lower bound for the greatest prime factor of f .n/ as n tends
46. 28 3. First applications
to infinity. In 1998 Tijdeman [418] noticed that, for the polynomial X.X C 1/, the use of
Theorem 2.2 allows us to improve the results of [374]. In his doctoral thesis, Haristoy [221]
extended Tijdeman’s result to an arbitrary polynomial f .X/. For an integer n, let denote
by P Œn its greatest prime factor with the convention that P Œ0 D P Œ˙1 D 1.
Theorem 3.7. Let f .X/ be an integer polynomial with at least two distinct roots. Then,
we have
P Œf .n/ f log log n
log log log n
log log log log n
; for n 107
: (3.6)
A result similar to Theorem 3.7 has been established in [217]; see also Chapter 8.
If we apply Theorem 2.1 (with a weaker dependence on the number of logarithms in
the linear form than in Theorem 2.2) instead of Theorem 2.2, then we would get the weaker
lower bound
P Œf .n/ f log log n; for n 100;
which was obtained in [374].
Proof. To avoid technical complications, we treat only the case of the polynomial X.X C1/.
For an integer n at least equal to 100, write
n.n C 1/ D pu1
1 : : : puk
k
;
where p1 p2 denotes the sequence of prime numbers in increasing order and the
integers u1; : : : ; uk are non-negative. There exist disjoint non-empty subsets I and J of
f1; : : : ; kg such that I [ J D f1; : : : ; kg and
n D
Y
i2I
pui
i ; n C 1 D
Y
j 2J
p
uj
j :
Then, there exist 1; : : : ; k in f˙1g such that
n C 1
n
1 D jp1u1
1 : : : pk uk
k
1j D
1
n
: (3.7)
Observe that
n C 1 2uj
; j D 1; : : : ; k;
thus
max
1j k
uj 2 log n: (3.8)
Since pj j log j , for j D 2; : : : ; k, by Theorem D.2, we deduce from (3.8) and
Theorems 2.2 and D.2 that there exist effectively computable, absolute real numbers
c1; c2; c3 such that
log jp1u1
1 : : : pk uk
k
1j ck
1 .log p1/ .log pk/ .log log n/
c
k log log k
2 .log log n/;
thus, by (3.7),
log n c
k log log k
3 log log n :
47. 3.5. On the greatest prime factor of values of integer polynomials 29
By Theorem D.2, this implies that
pk k log k log log n
log log log n
log log log log n
;
as asserted.
The general case of an arbitrary monic, integer polynomial with distinct roots ˛ and ˇ
rests on the same idea, but is technically more complicated. Let OK denote the ring
of integers of the algebraic number field K WD Q.˛; ˇ/ and h its class number. Let n
be an integer greater than j˛j and jˇj. Write the integer ideal .n ˛/.n ˇ/OK as a
product of powers of prime ideals and raise this equality to the power h. Then, the quantity
.n ˛/h
.n ˇ/ h
, which is equal to 1 C O.1
n
/, can, with the help of Proposition C.5, be
expressed as a product of powers of algebraic numbers in K whose heights are controlled.
It then follows from Theorem 2.2 that this product cannot be too close to 1, hence the
result. We leave the details to the reader.
Let S be a finite non-empty set of prime numbers. For a non-zero integer n, write
ŒnS WD
Y
p2S
jnj 1
p ;
where j jp is the p-adic absolute value normalized such that jpj 1
p D p. Said differently,
ŒnS is the greatest divisor of n, all of whose prime factors belong to S.
In 1984, Stewart [396] applied the theory of linear forms in logarithms to prove non-
trivial effective upper bounds for Œn.n C 1/ : : : .n C k/S , for any positive integer k. His
result was later extended by Gross and Vincent [205] as follows; see also [122].
Theorem 3.8. Let f .X/ be an integer polynomial with at least two distinct roots and S
a finite, non-empty set of prime numbers. There exist effectively computable positive real
numbers c1 and c2, depending only on f .X/ and S, such that, for every non-zero integer n
which is not a root of f .X/, we have
Œf .n/S c1jf .n/j1 c2
:
Proof. To avoid technical complications, we treat only the case of the polynomial X.X C1/.
We leave to the reader the details of the general case. Let n be an integer with jnj 2.
Write S D fq1; : : : ; qsg, where s is the cardinality of S and q1 qs. Let u1; : : : ; us
be non-negative integers and a an integer coprime with q1 qs such that
n.n C 1/ D qu1
1 : : : qus
s a:
There exist disjoint non-empty subsets I and J of f1; : : : ; sg such that I [J D f1; : : : ; sg
and integers a0
; a00
such that a D a0
a00
and
n D a0
Y
i2I
qui
i ; n C 1 D a00
Y
j2J
q
uj
j :
Then, there exist 1; : : : ; s in f˙1g such that
1
n
D
n C 1
n
1 D q1u1
1 : : : qsus
s
a00
a0
1 DW ƒ:
48. 30 3. First applications
Noticing that uj 2 log jnj for j D 1; : : : ; s, we deduce from Theorem 2.2 applied to ƒ
with the quantity B00
that there exists an effectively computable real number c3 such that
log jnj cs
3.log q1/ .log qs/.log maxfja0
j; ja00
j; 2g/ log
2.log jnj/.log qs/
log maxfja0j; ja00j; 2g
:
This shows that there exists an effectively computable positive real number c4, depending
only on the set S, such that
maxfja0
j; ja00
j; 2g jnjc4
:
If jnj 21=c4
, then we get a maxfja0
j; ja00
j; 2g jnjc4
and
Œn.n C 1/S D qu1
1 : : : qus
s D
n.n C 1/
a
n.n C 1/
jnjc4
.n.n C 1//1 c4=3
;
which gives the desired result.
We now explain how a suitable version of Theorem 3.8 with explicit values for c1 and c2
implies Theorem 3.7. Observe that, setting C WD cs
3.log q1/ .log qs/, an admissible
value for c4 is given by
c4 D c5C 1
.log.C log qs// 1
;
for some suitable absolute real number c5. If S is the set composed of the first s prime
numbers, then it follows from Theorem D.2 that c4 exceeds c
s log log s
6 for some absolute
real number c6. If P Œn.n C 1/ D ps, then maxfja0
j; ja00
j; 2g D 2 and jnjc4
2, thus,
log jnj 2c
s log log s
6 :
Combined with Theorem D.2, this gives
P Œn.n C 1/ log log n
log log log n
log log log log n
;
and we recover Theorem 3.7.
3.6. On the greatest prime factor of terms
of linear recurrence sequences
Let k be a positive integer, a1; : : : ; ak and u0; : : : ; uk 1 be integers such that ak is non-zero
and u0; : : : ; uk 1 are not all zero. Put
un D a1un 1 C C akun k; for n k:
The sequence .un/n0 is a linear recurrence sequence of integers of order k. Its companion
(or, characteristic) polynomial
G.z/ WD zk
a1zk 1
ak
49. 3.6. On the greatest prime factor of terms of linear recurrence sequences 31
factors as
G.z/ D
t
Y
iD1
.z ˛i /`i
;
where ˛1; : : : ; ˛t are distinct algebraic numbers, ordered in such a way that j˛1j
j˛t j, and `1; : : : ; `t are positive integers. Then, (see e.g. [179] or Chapter C of [376])
there exist polynomials f1.X/; : : : ; ft .X/ of degrees less than `1; : : : ; `t , respectively,
and with coefficients in Q.˛1; : : : ; ˛t /, such that
un D f1.n/˛n
1 C C ft .n/˛n
t ; for n 0:
The recurrence sequence .un/n0 is said to be degenerate if there are integers i; j with
1 i j t such that ˛i
˛j
is a root of unity. We say that .un/n0 has a dominant root
if j˛1j j˛2j and f1.X/ is not the zero polynomial.
The next result was established in [399]; see also [395].
Theorem 3.9. Let u WD .un/n0 be a recurrence sequence of integers given by
un D f1.n/˛n
1 C C ft .n/˛n
t ; for n 0;
and having a dominant root ˛1. For any integer n greater than 100 and such that un is
not equal to f1.n/˛n
1 , the greatest prime factor of un satisfies
P Œun u log n
log log n
log log log n
: (3.9)
Proof. We establish a slightly more general result. We consider a sequence of non-zero
integers v WD .vn/n0 with the property that there are in .0; 1/ and a positive real
number C such that
jvn f .n/˛n
j C j˛jn
; n 0;
where f .X/ is a non-zero polynomial whose coefficients are algebraic numbers and ˛
is an algebraic number with j˛j 1. Clearly, a recurrence sequence having a dominant
root ˛ has the above property.
Let p1; p2; : : : be the sequence of prime numbers in increasing order. Let n be a
positive integer such that f .n/ is non-zero and vn ¤ f .n/˛n
. Assume that the greatest
prime factor of vn is equal to pk, that is, assume that
vn D pr1
1 prk
k
;
where r1; : : : ; rk are non-negative integers and rk 1. Then, we have
ƒ WD jpr1
1 prk
k
f .n/ 1
˛ n
1j Cjf .n/j 1
j˛j. 1/n
;
and, since 1, we get
log ƒ v . n/:
As vn ¤ f .n/˛n
, the quantity ƒ is non-zero and Theorem 2.2 implies that
log ƒ v ck
1 .log p1/ .log pk/ .log n/2
;
50. 32 3. First applications
where c1 is an effectively computable, positive, absolute real number. Comparing both
estimates for log ƒ, we obtain that
n v .c1 log pk/k
.log n/2
;
thus, by Theorem D.2,
log n v
pk
log pk
log log pk:
This implies that
P Œvn D pk v log n
log log n
log log log n
;
and the theorem is established.
The lower bound for P Œun in (3.9) is of similar strength as the one for P Œf .n/ in
Theorem 3.7, since junj grows exponentially fast in n. Both proofs show that f in (3.6)
and u in (3.9) can be replaced by .1 /, for any positive and any sufficiently large
integer n.
3.7. Perfect powers in linear recurrence sequences
We continue the study of arithmetical properties of linear recurrence sequences of integers
having a dominant root and show that no term of such a sequence can be a very large
power of an integer greater than one.
Theorem 3.10. Let u WD .un/n0 be a recurrence sequence of integers given by
un D f1.n/˛n
1 C C ft .n/˛n
t ; for n 0;
and having a dominant root ˛1. Assume that ˛1 is a simple root, that is, the polynomial
f1.X/ is equal to a non-zero algebraic number f1. Then, the equation
un D yq
;
in integers n; y; q with q a prime number, jyj 2, and un ¤ f1˛n
1 , implies that
q u 1:
Theorem 3.10 was proved in [372]; see also [190,325]. More can be said in the case
of binary recurrence sequences, see Section 6.9.
Proof. We establish a slightly more general result. We consider a sequence of non-zero
integers v WD .vn/n0 with the property that there are in .0; 1/ and a positive real
number C such that
jvn f ˛n
j C j˛jn
; n 0;
where f is a non-zero algebraic number and ˛ is an algebraic number with j˛j 1.
Let n; y; q with q a prime number be such that vn D yq
, jyj 2, and vn ¤ f ˛n
.
Then, we have
jf 1
˛ n
yq
1j
C
jf j
j˛j. 1/n
: (3.10)
51. 3.7. Perfect powers in linear recurrence sequences 33
There exist integers k and r such that n D kq C r with jrj q
2
. Rewriting (3.10) as
ƒ WD
ˇ
ˇ
ˇf 1
y
˛k
q
˛ r
1
ˇ
ˇ
ˇ
C
jf j
j˛j. 1/n
;
we observe that
log ƒ v . n/: (3.11)
By Theorem B.5, the height of ˛k
y
is bounded from above by the sum of log jyj and k
times the height of ˛. Since
q log jyj v n .k C 1/q and
kq
2
n v q log jyj; (3.12)
we get that h.˛k
=y/ v log jyj. It then follows from Theorem 2.2 that
log ƒ v .log jyj/.log q/;
which, combined with (3.11) and (3.12), gives
q log jyj v n v .log jyj/.log q/;
and we get q v 1. This proves the theorem.
We point out a very special case of Theorem 3.10.
Corollary 3.11. Let ˛ and ˇ be algebraic integers such that ˛ C ˇ, ˛ˇ are rational
integers and ˛ jˇj. Then, the equation
˛n
ˇn
˛ ˇ
D yq
.resp., ˛n
C ˇn
D yq
/; (3.13)
in integers n; y; q with jyj 2 and q a prime number, implies that
q ˛;ˇ 1:
Let us discuss a celebrated example of resolution of equations of the form (3.13),
namely the determination of all the perfect powers among the Fibonacci and Lucas num-
bers. Set D 1C
p
5
2
and observe that 1
D 1
p
5
2
. Let the integer sequences .Fn/n0
and .Ln/n0 be defined respectively by
Fn D
n
. 1
/n
. 1/
; Ln D n
C . 1
/n
;
so that the first elements of the Fibonacci sequence .Fn/n0 and of the Lucas sequence
.Ln/n0 are given by
0; 1; 1; 2; 3; 5; 8; 13; 21; 34; 55; 89; 144; 233; : : :
and
2; 1; 3; 4; 7; 11; 18; 29; 47; 76; : : : ;
respectively. The Fibonacci sequence is an emblematic example of a Lucas–Lehmer
sequence (see Section 7.2). The following result has been established in [137].
53. CHAPTER VI.
ATTRACTION OF COHESION.
In previous chapters one kind of attraction—viz., that of gravitation, has been discussed and
illustrated in a popular manner, and pursuing the examination of the invisible, active, and real forces
of nature, the attraction of cohesion will next engage our attention. There is a peculiar satisfaction in
pursuing such investigations, because every step is attended by a reasonable proof; there is no
ghostly mystery in philosophic studies; the mind is not suddenly startled at one moment with that
which seems more than natural; it is not carried away in an ecstasy of wonder and awe, as in the so-
called spirit-rapping experiments, to be again rudely brought back to the material by the disclosure of
trickeries of the most ludicrous kind, such as those lately exposed by M. Jobert de Lamballe, at the
Academy of Sciences at Paris. This gentleman has unmasked the effrontery of the spirit-rappers by
merely stripping the stocking from the heel of a young girl of fourteen. M. Velpeau declares that the
rapping is produced by the muscles of the heel and knee acting in concert, and quotes the case of a
lady once celebrated as a medium, who has the power of producing the most curious and interesting
music with the tendons of the thigh. This music is said to be loud enough to be heard from one end
of a long room to the other, and has often played a conspicuous part in the revelations made by the
medium. M. Jules Clocquet also explained the method by which the famous girl pendulum had so long
abused the credulity of the Paris public. This girl, whose self-styled faculty is that of striking the hour
at any time of the day or night, was attended at the Hospital St. Louis by M. Clocquet, who states that
the vibrations in this case were produced by a rotatory motion in the lumbar regions of the vertebral
column. The sound of these (à la rattlesnake) was so powerful, that they might be distinctly heard at
a distance of twenty-five feet.
In studying the powers of nature, which the most sceptical mind allows must exist, there is an
abundant field for experiment without attempting the exploits of Macbeth's witches, or the fanciful
powers of Manfred; and, returning to the theme of our present chapter, it may be asked, how is
cohesion defined? and the answer may be given, by directing attention to the three physical
conditions of water, which assumes the form of ice, water, or steam.
In the Polar regions, and also in the Alpine and other mountains where glaciers exist, there the
traveller speaks of ice twenty, thirty, forty, nay, three hundred feet in thickness. Here the withdrawal
of a certain quantity of heat from the water evidently allows a new force to come into full play. We
may call it what we like; but cohesion, from the Latin cum, together, and hæreo, I stick or cleave,
appears to be the best and most rational term for this power which tends to make the atoms or
particles of the same kind of matter move towards each other, and to prevent them being separated
or moved asunder. That it is not merely hypothetical is shown by the following experiments.
If two pieces of lead are cast, and the ends nicely scraped, taking care not to touch the surfaces with
the fingers, they may by simple pressure be made to cohere, and in that state of attraction may be
lifted from the table by the ring which is usually inserted for convenience in the upper piece of lead;
they may be hung for some time from a proper support, and the lower bit of lead will not break away
from the upper one; they may even be suspended, as demonstrated by Morveau, in the vacuum of an
air-pump, to show that the cohesion is not mistaken for the pressure of the atmosphere, and no
separation occurs. And when the union is broken by physical force, it is surprising to notice the limited
number of points, like pin points, where the cohesion has occurred; whilst the weight of the lump of
lead upheld against the force of gravitation reminds one forcibly of the attraction of a mass of soft
iron by a powerful magnet, and leads the philosophic inquirer to speculate on the principle of
cohesion being only some masked form of magnetic or electrical attraction. (Fig. 75.)
54. Fig. 75.
a a. Two pieces of lead,
scraped clean at the surfaces
b b. c. Stand, supporting the
two pieces of lead attached to
each other by cohesion.
A fine example of the same force is shown in the use of a pair of flat iron
surfaces, planed by the celebrated Whitworth, of Manchester. These surfaces
are so true, that when placed upon each other, the upper one will freely
rotate when pushed round, in consequence of the thin film of air remaining
between the surfaces, which acts like a cushion, and prevents the metallic
cohesion. When, however, the upper plate is slid over the lower one
gradually, so as to exclude the air, then the two may be lifted together,
because cohesion has taken place. (Fig. 76.)
Fig. 76.
a. Whitworth's planes, with film of air between them. b.
Film of air excluded when cohesion occurs.
A glass vessel is a good example of cohesion. The materials of which it is composed have been soft
and liquid when melted in the fire, and on the removal of the excess of heat it has become hard and
solid, in consequence of the attractive force of cohesion binding the particles together; in the absence
of such a power, of course, the material would fall into the condition of dust, and a mere shapeless
heap of silicates of potash and lead would indicate the place where the moulded and coherent glass
would otherwise stand.
55. A lump of lead, six inches long by four broad, and half an inch thick, may be supported by dexterously
taking off a thick shaving with a proper plane, and after pressing an inch or more of the strip on the
planed surface of the large lump of lead, the cohesion is so powerful that the latter may be lifted from
the table by the strip of metal.
The bullets projected from Perkins' steam-gun, at the rate of three hundred per minute, are thrown
with such violence, that, when received on a thick plate of lead backed up with sheet iron, a cold
welding takes place between the two surfaces of metal in the most perfect manner, just as two soft
pieces of the metal potassium may be squeezed and welded together. The surfaces of an apple torn
asunder will not readily cohere, but if cut with a sharp knife, cohesion easily occurs; so with a wound
produced by a jagged surface, it is difficult to make the parts heal, whereas some of the most
desperate sabre-cuts have been healed, the cohesion of the surfaces of cut flesh being very rapid;
hence, if the top of a finger is cut off, it may be replaced, and will grow, in consequence of the natural
cohesion of the parts.
The art of plating copper with silver, which is afterwards gilt, and then drawn out into flattened wire
for the manufacture of gold lace and epaulets, usually termed bullion, is another example of the
wonderful cohesion of the particles of gold, of which a single grain may be extended over the finest
plate wire measuring 345 feet in length.
The process of making wax candles is a good illustration of the attraction of cohesion; they are not
generally cast in moulds, as most persons suppose, but are made by the successive applications of
melted wax around the central plaited wick. Other examples of cohesion are shown by icicles, and
also stalagmites; which latter are produced by the gradual dropping of water containing chalk
(carbonate of lime) held in solution by the excess of carbonic acid gas; the solvent gradually
evaporates, and leaves a series of calcareous films, and these cohere in succession, producing the
most fantastic forms, as shown in various remarkable caverns, and especially in the cave of Arta, in
the island of Majorca.
In metallic substances the cohesion of the particles assumes an important bearing in the question of
relative toughness and power of resisting a strain; hence the term cohesion is modified into that of
the property of tenacity.
The tenacity of the different metals is determined by ascertaining the weight required to break wires
of the same length and gauge. Iron appears to possess the property of tenacity in the greatest, and
lead in the least degree. (Fig. 77.)
56. Fig. 77.
b. Pan supported by leaden wire broken by a weight which the iron wire at a easily supports.
The tenacity of iron is taken advantage of in the most scientific manner by the great engineers who
have constructed the Britannia Tube, and that eighth wonder of the world, the Leviathan, or Great
Eastern steam-ship. In both of these sublime embodiments of the genius and industrial skill of Great
Britain the advantage of the cellular principle is fully recognised. The magnitude of this colossal ship is
better realized when it is remembered that the Great Eastern is six times the size of the Duke of
Wellington line-of-battle ship, that her length is more than three times that of the height of the
Monument, while in breadth it is equal to the width of Pall Mall, and that a promenade round the deck
will afford a walk of more than a quarter of a mile. Up to the water-mark the hull is constructed with
an inner and outer shell, two feet ten inches apart, each of three-quarter-inch plate; and between
them, at intervals of six feet, run horizontal webs of iron plates, which convert the whole into a series
of continuous cells or iron boxes. (Fig. 78.)
Fig. 78.
Transverse section of Great Eastern, showing the cellular construction from keel to water-line, a a.
This double ship is useful in various ways; in the first place, the danger arising from collision is
diminished, as it is supposed that the outer web only would be broken through or damaged; so that
57. the water would not then rush into the steam-ship, but merely fill the space between the shells. In
the second place, if there should be any difficulty in procuring ballast, the space can be filled with
2500 tons of water, or again pumped out, according to the requirements of the vessel. The strength
of a continued cellular construction can be easily imagined, and may be well illustrated by a thin sheet
of common tin plate. If the ends be rested on blocks of wood, so as to lap over the wood about one
inch, they are easily displaced, and the mimic bridge broken down from its supports by the addition to
the centre of a few ounce weights; whilst the same tin plate rolled up in the figure of a tube, and
again rested on the same blocks, will now support many pounds weight without bending or breaking
down. (Fig. 79.)
Fig. 79.
a. Flat tin plate, breaking down with a few ounce weights. b. Same tin plate rolled up supports a very
heavy weight.
The deck of the ship is double or cellular, after the plan of Stephenson in the Britannia Tubular Bridge,
and is 692 feet in length. The tonnage register is 18,200 tons, and 22,500 tons builder's measure; the
hull of the Great Eastern is considered to be of such enormous tenacity, that, if it were supported by
massive blocks of stone six feet square, placed at each end, at stem and stern, it would not deflect,
curve, or bend down in the middle more than six inches even with all her machinery, coals, cargo, and
living freight.
In adducing remarkable instances of the adhesive power and tenacity of inorganic matter, it may not
be altogether out of place to allude to the strength and force of living matter, or muscular power. It is
stated that Dr. George B. Winship, of Roxbury in America, a young physician, twenty-five years old,
and weighing 143 pounds, is the strongest man alive; in fact, quite the Samson of the nineteenth
century. He can raise a barrel of flour from the floor to his shoulders; can raise himself with either
little finger till his chin is half a foot above it; can raise 200 pounds with either little finger; can put up
a church bell of 141 pounds; can lift with his hands 926 pounds dead weight without the aid of straps
or belts of any kind. As compared with Topham, the Cornish strong man, who could raise 800 pounds,
or the Belgic one, his power is greater; and as the use of straps and belts increases the power of
lifting by about four times, it is stated that Winship could lift at least 2500 pounds weight.
With these illustrations of cohesion we may return again to the abstract consideration of this power
with reference to water, in which we have noticed that the antagonist to this kind of attraction is the
force or power termed caloric or heat. The latter influence removes the frozen bands of winter and
converts the ice to the next condition, water. In this state cohesion is almost concealed, although
there is just a slight excess to hold even the particles of water in a state of unity, and this fact is
beautifully illustrated by the formation of the brilliant diamond drops of dew on the surfaces of various
leaves, as also in the force and power exercised by great volumes of water, which exert their mighty
strength in the shape of breaker-waves, dashing against rocks and lighthouses, and making them
tremble to their very base by the violence of the shock; here there must be some unity of particles, or
the collective strength could not be exerted, it would be like throwing a handful of sand against a
58. Fig. 80.
a. Ordinary glass water
hammer. b. Copper tube ditto,
showing exhausting syringe
at d, the height of the water
at b, and the end to be placed
in the fire at c.
window—a certain amount of noise is produced, but the glass is not
fractured; whilst the same sand united by any glutinous material, would
break its way through, and soon fracture the brittle glass. It is so usual to
see the particles of water easily separated, that it becomes difficult to
recognise the presence of cohesion; but this bond of union is well illustrated
in the experiment of the water hammer. The little instrument is generally
made of a glass tube with a bulb at one end; in this bulb the water which it
contains is boiled, and as the steam issues from the other extremity, drawn
out to a capillary tube, the opening is closed by fusion with the heat of a
blowpipe flame. As the water cools the steam condenses, and a vacuum, so
far as air is concerned, is produced; if now the tube is suddenly inverted, the
whole of the water falls en masse, collectively, and striking against the
bottom of the tube, produces a metallic ring, just as if a piece of wood or
metal were contained within the tube. If the end to which the water falls is
not well cushioned by the palm of the hand, the water hammers itself
through and breaks away that part of the glass tube. Hence it is better to
construct the water hammer of copper tube, about three-quarters of an inch
in diameter and three feet long; at one end a female screw-piece is inserted,
into which a stop-cock is fitted; when the tube is filled to the height of about
six inches with water, and shaken, the air divides the descending volume of
water, and the ordinary splashing sound is heard; there is no unity or
cohesion of the parts; if, however, the end of the copper tube is thrust into a
fire and the water boiled so that steam issues from the cock, which is then
closed, and the tube removed and cooled, a smart blow is given, and
distinctly heard when the copper tube is rapidly inverted or shaken so as to
cause the water to rise and fall. The experiment may be rendered still more
instructive by turning the cock and admitting the air, which rushes in with a
whizzing sound, and on shaking the tube the metallic ring is no longer heard,
but it may be again restored by attaching a small air syringe or hand pump,
and removing the air by exhaustion. (Fig. 80.)
In the fluid condition water still possesses a surplus of cohesion over the
antagonistic force of heat; when, however, the latter is applied in excess,
then the quasi-struggle terminates; the heat overpowers the cohesive
attraction, and converts the water into the most willing slave which has ever
lent itself to the caprices of man—viz., into steam—glorious, useful steam:
and now the other end of the chain is reached, where heat triumphs; whilst
in solids, such as ice, cohesion is the conqueror, and the intermediate link is displayed in the fluid
state of water. If any fact could give an idea of the gigantic size of the Great Eastern, it is the force of
the steam which will be employed to move it at the rate of about eighteen miles per hour with a
power estimated at the nominal rate of 2600 horses, but absolutely of at least 12,000 horses. This
steam power, coupled with the fact that she has been enormously strengthened in her sharp,
powerful bows, by laying down three complete iron decks forward, extending from the bows
backward for 120 feet, will demonstrate that in case of war the Great Eastern may prove to be a
powerful auxiliary to the Government. These decks will be occupied by the crew of 300 or 400 men,
and with this large increase of strength forward, the Great Eastern, steaming full power, could
overtake and cut in two the largest wooden line-of-battle ship that ever floated. Should war unhappily
spread to peaceful England, and the enormous power of this vessel be realized, her name would not
inappropriately be changed from the Great Eastern to the Great Terror of the ocean. The Times very
properly inquires, What fleet could stand in the way of such a mass, weighing some 30,000 tons, and
driven through the water by 12,000 horse-power, at the rate of twenty-two or twenty-three miles per
hour. To produce the steam, 250 tons of coal per diem will be required, and great will be the
59. honourable pride of the projectors when they see her fairly afloat, and gliding through the ocean to
the Far West.
A good and striking experiment, displaying the change from the liquid to the vapour state, is shown
by tying a piece of sheet caoutchouc over a tin vessel containing an ounce or two of water. When this
boils, the india-rubber is distended, and breaks with a loud noise; or in another illustration, by pouring
some ether through a funnel carefully into a flask placed in a ring stand. If flame is applied to the
orifice, no vapour issues that will ignite, provided the neck of the flask has not been wetted with the
ether. When, however, the heat of a spirit-lamp is applied, the ether soon boils, and now on the
application of a lighted taper, a flame some feet in length is produced, which is regulated by the spirit-
lamp below, and when this is removed, the length of the flame diminishes immediately, and is totally
extinguished if the bottom of the flask is plunged into cold water; the withdrawal of the heat restores
the power of cohesion. Another illustration of the vast power of steam will be shortly displayed in the
Steam Ram; and, Supposing, says the Times, the new steam ram to prove a successful design, the
finest specimens of modern men-of-war will be reduced by comparison to the helplessness of cock
boats. Conceive a monstrous fabric floating in mid-channel, fire proof and ball proof, capable of
hurling broadsides of 100 shot to a distance of six miles; or of clapping on steam at pleasure and
running down everything on the surface of the sea with a momentum utterly irresistible.
This terrible engine of destruction is expected to be itself indestructible. We are told that she may be
riddled with shot (supposing any shot could pierce her sides), that she may have her stem and her
stern cut to pieces, and be reduced apparently to a shapeless wreck, without losing her buoyancy or
power. Supposing that she relies upon the shock of her impact instead of fighting her guns, it is
calculated that she would sink a line-of-battle ship in three minutes, so that a squadron as large as
our whole fleet now in commission would be destroyed in about one hour and a quarter.
60. CHAPTER VII.
ADHESIVE ATTRACTION.
The term cohesion must not be confounded with that of adhesion, which refers to the clinging to or
attraction of bodies of a dissimilar kind. The late Professor Daniell defines cohesion to be an attraction
of homogeneous (ὁμος, like, and γενος, kind) or similar particles; adhesion to be an attraction
subsisting between particles of a heterogeneous, ετερος, different, and γενος, kind.
There are numerous illustrations of adhesion, such as mending china, and the use of glue, or paste, in
uniting different surfaces, or mortar, in building with bricks; it is also well shown at the lecture table
by means of a pair of scales, one scale-pan of which being well cleaned with alkali at the bottom, may
then be rested on the surface of water contained in a plate; the adhesion between the water and the
metal is so perfect, that many grain weights may be placed in the other pan before the adhesion is
broken; and after breakage, if the pan be again placed on the water, and a few grains removed from
the other, so as to adjust the two pans, and make them nearly equal, a drop of oil of turpentine being
added, instantly spreads itself over the water, and breaking the adhesion between the latter and the
metal, the scale-pan is immediately and again broken away, as the adhesion between the turpentine
and the metal is not so great as that of water and metal. The adhesion of air and water is well
displayed in an apparatus recommended for ventilating mines, in which a constant descending stream
of water carries with it a quantity of air, which being disengaged, is then forced out of a proper
orifice. The same kind of adhesion between air and water is displayed in the ancient Spanish Catalan
forge, where the blast is supplied to the iron furnace on a similar principle, only, a natural cascade is
taken advantage of instead of an artificial fall of water through a pipe.
The adhesion of air and water becomes of some value when a river flows through a large and
crowded city, because the water in its passage to and fro, must necessarily drag with it, a continuous
column of air, and assist in maintaining that constant agitation of the air which is desirable as a
preventive to any accumulation of noxious air charged with fœtid odours, arising from mud banks or
from other causes. The fact of adhesion, existing between water and air, is readily shown, by resting
one end of a long glass tube, of at least one inch diameter, on a block of wood one foot high. If water
is allowed to flow down the tube, so as to leave a sufficient space of air above it, the adhesion
between the two ancient elements becomes apparent, directly a little smoke is produced, near the top
end of the glass tube resting on the block of wood. The smoke, which has a greater tendency to rise
than to fall, is dragged down the glass tube, and accompanies the water as it flows from the higher to
the lower level. The same truth is also illustrated in horizontal troughs or tubes through which water
is caused to flow.
The adhesion between air and glass is so great, that it is absolutely necessary to boil the mercury in
the tubes of the best barometers; and if this is not carefully attended to, the adhering air between the
glass and mercury gradually ascends to, and destroys, the Torricellian vacuum at the top of the
barometer tube. Even after the mercury is boiled, the air will creep up in course of years; and in order
to prevent its passage between the glass and quicksilver, it has been recommended, that a platinum
ring should be welded on to the end of the glass tube, because mercury has the power of wetting or
enfilming the metal platinum, and the two being in close contact, would, as it were, shut the only
door by which the air could enter the barometer tube.
61. Fig. 81.
Model of the apparatus for drawing down air. a, cistern of water, supplied by ball-cock, and kept at one
level, so that the water just runs down the sides of the tube, and draws down the air in the centre, b c.
The vessel to which the air and water are conveyed by a gutta-percha tube, t. There is another ball-
cock to permit the waste water to run away when it reaches a certain level; the end of the pipe always
dips some inches into this water, whilst the air escapes from the jet, d.
62. CHAPTER VIII.
CAPILLARY ATTRACTION.
This kind of attraction is termed capillary, in consequence of tubes, of a calibre, or bore, as fine as
hair, attracting and retaining fluids.
If water is poured into a glass, the surface is not level, but cupped at the edges, where the solid glass
exerts its adhesive attraction for the liquid, and draws it from the level. If the glass be reduced to a
very narrow tube, having a hair-like bore, the attraction is so great that the water is retained in the
tube, contrary to the force of gravitation. Two pieces of flat glass placed close together, and then
opened like a book, draw up water between them, on the same principle. A mass of salt put on a
plate containing a little water coloured with indigo displays this kind of attraction most perfectly, and
the water is quickly drawn up, as shown by the blue colour on the salt. A little solution of the
ammonio-sulphate of copper imparts a finer and more distinct blue colour to the salt. A piece of dry
Honduras mahogany one inch square, placed in a saucer containing a little turpentine, is soon found
to be wet with the oil at the top, which may then be set on fire.
Almost every kind of wood possesses capillary tubes, and will float, on account of these minute
vessels being filled with air; if, however, the air is withdrawn, then the wood sinks, and by boiling a
ball made of beech wood in water, and then placing it under the vacuum of an air pump in other cold
water, it becomes so saturated with water that it will no longer float. A remarkable instance of the
same kind is mentioned by Scoresby, in which a boat was pulled down by a whale to a great depth in
the ocean, and after coming to the surface it was found that the wood would neither swim nor burn,
the capillary pores being entirely filled with salt water.
A piece of ebony sinks in water on account of its density, closeness, and freedom from air. A gauge
made of a piece of oak, with a hole bored in it of one inch diameter, accurately receives a dry plug of
willow wood which will not enter the orifice after it is wetted. Millstones are split by inserting wedges
of dry hard wood, which are afterwards wetted and swelled, and burst the stone asunder. One of the
most curious instances of capillary attraction is shown in the currying of leather, a process which is
intended to impart a softness and suppleness to the skin, in order that it may be rendered fit for the
manufacture of boots, harness, machine bands, c. The object of the currier is to fill the pores of the
leather with oil, and as this cannot be done by merely smearing the surface, he prepares the way for
the oil by wetting the leather thoroughly with water, and whilst the skin is damp, oil is rubbed on, and
it is then exposed to the air; the water evaporates at ordinary temperatures, but oil does not; the
consequence is that the pores of the leather give up the water, which disappears in evaporation, and
the oil by capillary attraction is then drawn into the body of the leather, the oil in fact takes the place
vacated by the water, and renders the material very supple, and to a considerable extent waterproof.
In paper making, the pores of this material, unless filled up or sized, cause the ink to blot or spread
by capillary attraction. The porosity of soils is one of the great desideratums of the skilful agriculturist,
and drainage is intended to remove the excess of water which would fill the pores of the earth, to the
exclusion of the more valuable dews and rains conveying nutritious matter derived from manures and
the atmosphere.
A cane is an assemblage of small tubes, and if a piece of about six inches in length (cut off, of course,
from the joints) be placed in a bottle of turpentine, the oil is drawn up and may be burnt at the top; it
is on this principle that indestructible wicks of asbestos, and wire gauze rolled round a centre core,
are used in spirit lamps. Oil, wax, and tallow, all rise by capillary attraction in the wicks to the flame,
where they are boiled, converted into gas, and burnt.
63. Fig. 82.
Geber's filter. a. The solution of acetate of
lead. b. The dilute sulphuric acid. c. The
clear liquid, separated from the sulphate of
lead in b.
Fig. 83.
Prawn syphon.
The capillary attraction of skeins of cotton for water was known
and appreciated by the old alchemists; and Geber, one of the
most ancient of these pioneers of science, and who lived about
the seventh century, describes a filter by which the liquid is
separated from the solid. This experiment is well displayed by
putting a solution of acetate of lead into a glass, which is placed
on the highest block of a series of three, arranged as steps. Into
this glass is placed the short end of a skein of lamp cotton,
previously wetted with distilled water; the long end dips into
another glass below, containing dilute sulphuric acid, and as the
solution of lead passes into it, a solid white precipitate of sulphate
of lead is formed; then another skein of wetted cotton is placed in
this glass, the long end of which passes into the last glass, so
that the clear liquid is separated and the solid left behind. (Fig.
82.)
In this filter the lamp cotton acts as a syphon
through the capillary pores which it forms. On
the same principle, a prawn may be washed in
the most elegant manner (as first shown by
the late Duke of Sussex), by placing the tail,
after pulling off the fan part, in a tumbler of
water, and allowing the head to hang over,
when the water is drawn up by capillary
attraction, and continues to run through the
head. (Fig. 83.)
The threads of which linen, cotton, and woollen cloths are made are small cords,
and the shrinkage of such textile fabrics, is well known and usually inquired about,
when a purchase is made; here again capillary attraction is exerted, and the fabric
contracts in the two directions of the warp and woof threads; thus, twenty-seven
yards of common Irish linen will permanently shrink to about twenty-six yards in
cold water. In these cases the water is attracted into the fibres of the textile
material, and causing them to swell, must necessarily shorten their length, just as
a dry rope strained between two walls for the purpose of supporting clothes, has
been known to draw the hooks after being suddenly wetted and shortened by a
shower of rain.
In order to tighten a bandage, it is only necessary to wind the dry linen round the
limbs as close as possible, and then wet it with water, when the necessary
shrinkage takes place.
If a piece of dry cotton cloth is tied over one end of a lamp glass, the other may
be thrust into, or removed from the basin of water very easily, but when the cotton
is wetted, the fibres contract and prevent air from entering, so that the glass
retains water just as if it were an ordinary gas jar closed with a glass stopper.
A Spanish proverb, expressing contempt, says, go to the well with a sieve, but even this seeming
impossibility is surmounted by using a cylinder of wire gauze, which may be filled with water, and by
means of the capillary attraction between the meshes of the copper-wire gauze and the water, the
whole is retained, and may be carefully lifted from a basin of water; the experiment only succeeds
when the air is completely driven out of the interstices of the gauze, and the little cylinder completely
filled with water; this may be done by repeatedly sinking and drawing out the cylinder, or still more
effectually, by first wetting it with alcohol and then dipping the cylinder in water.
64. Fig. 84.
a. Basin of water. b. Cylinder of wire
gauze closed at both ends with
gauze. When full of water it may be
lifted from the basin by the handle, c.
A balloon, made of cotton cloth, cannot be inflated by means of a pair
of bellows, but if the balloon is wetted with water, then it may be
swelled out with air just as if it had been made of some air-tight
material; hence the principle of varnishing silk or filling the pores with
boiled oil, when it is required in the manufacture of balloons.
Biscuit ware, porous tubes for voltaic batteries, alcarrazas, or water
coolers, are all examples of the same principle.
Whilst speaking most favourably of the benevolent labours of many
gentlemen (beginning with Mr. Gurney) who have erected Drinking
Fountains in London's dusty atmosphere and crowded streets, it must
not be forgotten that pious Mohammedans have, in bygone times,
already set us the example in this respect; and in the palmy days of
many of the Moorish cities, the thirsty citizen could always be refreshed
by a draught of cool water from the porous bottles provided and
endowed by charitable Mussulmans, and placed in the public streets.
Fig 85.
Moorish niche and porous earthenware bottle, containing water.
65. CHAPTER IX.
CRYSTALLIZATION.
Fig. 86.
Crystals of snow.
It has been already stated that the force of cohesion binds the similar particles of substances
together, whether they be amorphous or shapeless, crystalline or of a regular symmetrical and
mathematical figure. The term crystal was originally applied by the ancients to silica in the form of
what is usually termed rock crystal, or Brazilian pebble; and they supposed it to be water which had
been solidified by a remarkable intensity of cold, and could not be thawed by any ordinary or summer
heat. Indeed, this idea of the ancients has been embodied (to a certain extent) in the shape of
artificial ice made by crystallizing large quantities of sulphate of soda, which was made as flat as
possible, and upon which skaters were invited to describe the figure of eight, at the usual admittance
fee, representing twelve pence. A crystal is now defined to be an inorganic body, which, by the
operation of affinity, has assumed the form of a regular solid terminated by a certain number of
planes or smooth surfaces.
Thousands of minerals are discovered in the crystallized state—such as cubes of iron pyrites
(sulphuret of iron) and of fluor spar (fluoride of calcium), whilst numerous saline bodies called salts
are sold only in the form of crystals. Of these salts we have excellent examples in Epsom salts
(sulphate of magnesia), nitre (nitrate of potash), alum (sulphate of alumina), and potash; the term
salt being applied specially to all substances composed of an acid and a base, as also to other
combinations of elements which may or may not take a crystalline form. Thus, nitre is composed of
nitric acid and potash; the first, even when much diluted, rapidly changes paper, dipped in tincture of
litmus and stained blue, to a red colour, whilst potash shows its alkaline nature, by changing paper,
stained yellow with tincture of turmeric, to a reddish-brown. The latter paper is restored to its original
yellow by dipping it into the dilute nitric acid, whilst the litmus paper regains its delicate blue colour
by being passed into the alkaline solution. An acid and an alkali combine and form a neutral salt, such
as nitre, which has no action whatever on litmus or turmeric; whilst the element iodine, which is not
an acid, unites with the metallic element potassium, and therefore not an alkali, and forms a salt that
66. crystallizes in cubes called iodide of potassium. Again, cane sugar, which is composed of charcoal,
oxygen, and hydrogen, crystallizes in hard transparent four-sided and irregular six-sided prisms, but is
not called a salt. Silica or sand is found crystallized most perfectly in nature in six-sided pyramids, but
is not a salt; it is an acid termed silicic-acid. Sand has no acid taste, because it is insoluble in water,
but when melted in a crucible with an alkali, such as potash, it forms a salt called silicate of potash.
Magnesia, from being insoluble, or nearly so, in water, is all but tasteless, and has barely any alkaline
reaction, yet it is a very strong alkaline base; 20.7 parts of it neutralize as much sulphuric acid as 47
of potash. A salt is not always a crystallizable substance, and vice versa. The progress of our chemical
knowledge has therefore demanded a wider extension and application of the term salt, and it is not
now confined merely to a combination of an acid and an alkali, but is conferred even on compounds
consisting only of sulphur and a metal, which are termed sulphur salts.
So also in combinations of chlorine, iodine, bromine, and fluorine, with metallic bodies, neither of
which are acid or alkaline, the term haloid salts has been applied by Berzelius, from the Greek ( αλς,
sea salt, and ειδος form), because they are analogous in constitution to sea salt; and the mention of
sea salt again reminds us of the wide signification of the term salt, originally confined to this
substance, but now extended into four great orders, as defined by Turner:—
Order I. The oxy-salts.—This order includes no salt the acid or base of which is not an oxidised body
(ex., nitrate of potash).
Order II. The hydro-salts.—This order includes no salt the acid or base of which does not contain
hydrogen (ex., chloride of ammonium).
Order III. The sulphur salts.—This order includes no salt the electro-positive or negative ingredient of
which is not a sulphuret (ex., hydrosulphuret of potassium).
Order IV. The haloid salts.—This order includes no salt the electro-positive or negative ingredient of
which is not haloidal. (Exs., iodide of potassium and sea salt). To fix the idea of salt still better in the
youthful mind, it should be remembered that alabaster, of which works of art are constructed, or
marble, or lime-stone, or chalk, are all salts, because they consist of an acid and a base.
In order to cause a substance to crystallize it is first necessary to endow the particles with freedom of
motion. There are many methods of doing this chemically or by the application of heat, but we cannot
by any mechanical process of concentration, compression, or division, persuade a substance to
crystallize, unless perhaps we except that remarkable change in wrought or fibrous iron into
crystalline or brittle iron, by constant vibration, as in the axles of a carriage, or by attaching a piece of
fibrous iron to a tilt hammer.
If we powder some alum crystals they will not again assume their crystalline form; if brought in
contact there is no freedom of motion. It is like placing some globules of mercury on a plate. They
have no power to create motion; their inertia keeps them separated by certain distances, and they do
not coalesce; but incline the plate, give them motion, and bring them in contact, they soon unite and
form one globule. The particles of alum are not in close contact, and they have no freedom of motion
unless they are dissolved in water, when they become invisible; the water by its chemical power
destroys the mechanical aggregation of the solid alum far beyond any operation of levigation. The
solid alum has become liquid, like water; the particles are now free to move without let or hindrance
from friction. A solution, (from the Latin solvo, to loosen) is obtained. The alum must indeed be
reduced to minute particles, as they are alike invisible to the eye whether assisted by the microscope
or not. No repose will cause the alum to separate; the solvent power of the water opposes
gravitation; every part of the solution is equally impregnated with alum, and the particles are diffused
at equal distances through the water; the heavy alum is actually drawn up against gravity by the
water.
67. Fig. 87.
r r. Ring-stand. s s. Spirit-lamps. a. Flask
containing boiling solution of alum.—
Solution. b. Funnel, with a bit of lamp-cotton
stuffed in the bottom.—Filtration. c.
Evaporating dish.—Evaporation. d. Drop on
glass.—Crystallization.
Fig. 88.
How, then, is the alum to be brought back again to the solid state? The answer is simple enough. By
evaporating away the excess of water, either by the application of heat or by long exposure to the
atmosphere in a very shallow vessel, the minute atoms of the alum are brought closer together, and
crystallization takes place. The assumption of the solid state is indicated by the formation of a thin
film (called a pellicle) of crystals, and is further and still more satisfactorily proved by taking out a
drop of the solution and placing it on a bit of glass, which rapidly becomes filled with crystals if the
evaporation has been carried sufficiently far (Fig. 87).
After evaporating away sufficient water, the dish is placed on one side and allowed to cool, when
crystals of the utmost regularity of form are produced, and, denoted by a geometrical term, are called
octohedral or eight-sided crystals, when in the utmost state of perfection (Fig. 88).
The science of
crystallography is too
elaborate to be discussed at
length in a work of this kind;
the various terms connected
with crystals will therefore
only be explained, and
experiments given in
illustration of the formation of
various crystals.
When the apices—i.e., the
tips or points of crystals—are
cut off, they are said to be
truncated; and the same
change occurs on the edges
of numerous crystals.
If some of the salt called chloride of calcium in the dry and
amorphous state is exposed to the air, it soon absorbs water, or
what is termed deliquesces: the same thing occurs with the
crystals of carbonate of potash, and if four ounces are weighed
out in an evaporating dish, and then exposed for about half an
hour to the air, a very perceptible increase in weight is observed
by the assistance of the scales and grain weights. Deliquescence
is a term from the Latin deliqueo, to melt, and is in fact a gradual
melting, caused by the absorption of water from the atmosphere. The reverse of this is illustrated
with various crystals, such as Glauber's salt (sulphate of soda), or common washing soda (carbonate
of soda); if a fine clear crystal is taken out of the solution, called the mother liquor, in which it has
been crystallized, wiped dry, and placed under a glass shade, this salt may remain for a long period
without change, but if it receive one scratch from a pin, the door is opened apparently for the escape
of the water which it contains, chemically united with the salt, and called water of crystallization; the
white crystal gradually swells out, the little quasi sore from the pin-scratch spreads over the whole,
which becomes opaque, and crumbling down falls into a shapeless mass of white dust; this change is
called efflorescence, from effloresco, to blow as a flower—caused by the abstraction from them of
chemically-combined water by the atmosphere. With reference to the preservation of crystals,
Professor Griffiths recommends them to be oiled and wiped, and placed under a glass shade, if of a
deliquescent nature; or if efflorescent, they are perfectly preserved by placing them under a glass
shade with a little water in a cup to keep the air charged with moisture and prevent any drying up of
the crystal.
68. Fig. 89.
Deliquescent crystals may be preserved by placing them, when dry, in naphtha, or any liquor in which
they are perfectly insoluble. Some salts, like Glauber's salts, contain so much water of crystallization
that when subjected to heat they melt and dissolve in it, and this liquefaction of the solid crystal is
called watery fusion. Other salts, such as bay salt, chlorate of potash, c., when heated, fly to
pieces, with a sharp crackling noise, which is due sometimes, to the unequal expansion of the
crystalline surface, or the sudden conversion of the water (retained in the crystal by capillary
attraction) into steam; thus nitre behaves in this manner, and frequently retains water in capillary
fissures, although it is an anhydrous salt, or salt perfectly free from combined water. The crackling
sound is called decrepitation, and is well illustrated by throwing a handful of bay salt on a clear fire;
but this property is destroyed by powdering the crystals.
Many substances when melted and slowly cooled concrete into the most perfect crystals; in these
cases heat alone, the antagonist to cohesion, is the solvent power. Thus, if bismuth be melted in a
crucible, and when cooling, and just as the pellicle (from pellis, a skin or crust) is forming on the
surface, if two small holes are instantly made by a rod of iron and the liquid metal poured out from
the inside (one of the holes being the entrance for the air, the other the exit for the metal); on
carefully breaking the crucible, the bismuth is found to be crystallized in the most lovely cubes.
Sulphur, again, may be crystallized in prismatic crystals by pursuing a similar plan; and the great
blocks of spermaceti exhibited by wax chandlers in their windows, are crystallized in the interior and
prepared on the same principle.
There are other modes of conferring the crystalline state upon substances—viz., by elevating them
into a state of vapour by the process called sublimation (from sublimis, high or exalted), the lifting up
and condensation of the vapour in the upper part of a vessel; a process perfectly distinct from that of
distillation, which means to separate drop by drop. Both of these processes are very ancient, and
were invented by the Arabian alchemists long antecedent to the seventh century. Examples of
sublimation are shown by heating iodine, and especially benzoic acid; with the latter, a very elegant
imitation of snow is produced, by receiving the vapour, on some sprigs of holly or other evergreen, or
imitation paper snowdrops and crocuses, placed in a tasteful manner under a glass vessel. The
benzoic acid should first be sublimed over the sprigs or artificial flowers in a gas jar, which may be
removed when the whole is cold, and a clear glass shade substituted for it. (Fig. 89.)
All electro deposits on metals are more or less crystalline; and copper or
silver may be deposited in a crystalline form by placing a scraped stick of
phosphorus in a solution of sulphate of copper or of nitrate of silver. The
phosphorus takes away the oxygen from the metal, or deoxidizes the
solution, and the copper or silver reappears in the metallic form. The surface
of the phosphorus must not be scraped in the air, but under water, when the
operation is perfectly safe.
A singular and almost instantaneous crystallization can be produced by
saturating boiling water with Glauber's salt, of which one ounce and a half of
water will usually dissolve about two ounces; having done this, pour the
solution, whilst boiling hot, into clean oil flasks, or vials of any kind,
previously warmed in the oven, and immediately cork them, or tie strips of
wetted bladder, over the orifices of the flasks or vials, or pour into the neck a
small quantity of olive oil, or close the neck with a cork through which a
thermometer tube has been passed. When cold, no crystallization occurs
until atmospheric air is admitted; and it was formerly believed that the
pressure of the air effected this object, until some one thought of the oil, and
now the theory is modified, and crystallization is supposed to occur in
consequence of the water dissolving some air which causes the deposit of a
minute crystal, and this being the turning point, the whole becomes solid.
However the fact may be explained, it is certain that when the liquid refuses
69. a. Gas-jar, with stopper open
at first, to be shut when the
lamp is withdrawn. b. Wooden
stand, with hole to carry the
cup c, containing the benzoic
acid, heated below by the
spirit-lamp, s. f. Flowers or
sprigs arranged on pieces of
rock or mineral.
Fig. 90.
a. The inner cylinder which contains the
freezing mixture. b b. The outer one
containing spring water. c c. The ice slipping
away from the inner cylinder.
to crystallize on the admission of air, the solidification occurs directly a
minute crystal of sulphate of soda, or Glauber's salt, is dropped into the
vessel.
When the crystallization is accomplished, the whole mass is usually so
completely solidified, that on inverting the vessel, not a drop of liquid falls
out.
It may be observed that the same mass of salt will answer any number of
times the same purpose. All that is necessary to be done, is to place the vial
or flask, in a saucepan of warm water, and gradually raise it to the boiling
point till the salt is completely liquefied, when the vessel must be corked and
secured from the air as before. When the solidification is produced much heat is generated, which is
rendered apparent by means of a thermometer, or by the insertion of a copper wire into the pasty
mass of crystal in the flask, and then touching an extremely thin shaving or cutting of phosphorus,
dried and placed on cotton wool. Solidification in all cases produces heat. Liquefaction produces cold.
In Masters's freezing apparatus certain measured quantities of
crystallized sal-ammoniac, nitre, and nitrate of ammonia, are
placed in a metallic cylinder, surrounded with a small quantity of
spring water contained in an outer vessel. Directly the crystals are
liquefied by the addition of water, intense cold is produced, which
freezes the water and forms an exact cast of the inner cylinder in
ice, and this may afterwards be removed, by pouring away the
liquefied salts, and filling the inner cylinder, with water of the
same temperature as the air, which rapidly thaws the surrounding
ice, and allows it to slip off into any convenient vessel ready to
receive it. (Fig. 90.)
For an ingenious method of obtaining large and perfect crystals of
almost any size, experimentalists are indebted to Le Blanc. His
method consists in first procuring small and perfect crystals—say,
octohedra of alum—and then placing them in a broad flat-
bottomed pan, he pours over the crystals a quantity of saturated
solution of alum, obtained by evaporating a solution of alum until
a drop taken out crystallizes on cooling. The positions of the
crystals are altered at least once a day with a glass rod, so that
all the faces may be alternately exposed to the action of the
solution, for the side on which the crystal rests, or is in contact
with the vessel, never receives any increment. The crystals will
thus gradually grow or increase in size, and when they have done
so for some time, the best and most symmetrical, may be
removed and placed separately, in vessels containing some of the
same saturated solution of alum, and being constantly turned
they may be obtained of almost any size desired.
Unless the crystals are removed to fresh solutions, a reaction
takes place, in consequence of the exhaustion of the alum from
the water, and the crystal is attacked and dissolved. This action is first perceptible on the edges and
angles of the crystal; they become blunted and gradually lose their shape altogether. By this method
crystals may be made to grow in length or breadth—the former when they are placed upon their
sides, the latter if they be made to stand upon their bases.
On Le Blanc's principle, beautiful crystal baskets are made with alum, sulphate of copper, and
bichromate of potash. The baskets are usually made of covered copper wire, and when the salts
70. crystallize on them as a nucleus or centre, they are constantly removed to fresh solutions, so that the
whole is completely covered, and red, white, and blue sparkling crystal baskets formed. They will
retain their brilliancy for any time, by placing them under a glass shade, with a cup containing a little
water.
The sketch below affords an excellent illustration of some of Nature's remarkable concretions in the
peculiar columnar structure of basalt.
Fig. 91.
The Giant's Causeway.
71. CHAPTER X.
CHEMISTRY.
Fig 92
Alchemists at work
There is hardly any kind of knowledge which has been so slowly acquired as that of chemistry, and
perhaps no other science has offered such fascinating rewards to the labour of its votaries as the
philosopher's stone, which was to produce an unfailing supply of gold; or the elixir of life, that was to
give the discoverer of the gold-making art the time, the prolonged life, in which he might spend and
enjoy it.
Hundreds of years ago Egypt was the great depository of all learning, art, and science, and it was to
this ancient country that the most celebrated sages of antiquity travelled.
Hermes, or Mercurius Trismegistus, the favourite minister of the Egyptian king Osiris, has been
celebrated as the inventor of the art of alchemy, and the first treatise upon it has been attributed to
Zosymus, of Chemnis or Panopolis. The Moors who conquered Spain were remarkable for their
learning, and the taste and elegance with which they designed and carried out a new style of
architecture, with its lovely Arabesque ornamentation. They were likewise great followers of the art of
alchemy, when they ceased to be conquerors, and became more reconciled to the arts of peace.
Strange that such a people, thirsting as they did in after years for all kinds of knowledge, should have
72. destroyed, in the persons of their ancestors, the most numerous collection of books that the world
had ever seen: the magnificent library of Alexandria, collected by the Ptolemies with great diligence
and at an enormous expense, was burned by the orders of Caliph Omar; whilst it is stated that the
alchemical works had been previously destroyed by Diocletian in the fourth century, lest the Egyptians
should acquire by such means sufficient wealth to withstand the Roman power, for gold was then, as
it is now, the sinews of war.
Eastern historians relate the trouble and expense incurred by the succeeding Caliphs, who, resigning
the Saracenic barbarism of their ancestors, were glad to collect from all parts the books which were to
furnish forth a princely library at Bagdad. How the learned scholar sighs when he reads of seven
hundred thousand books being consigned to the ignominious office of heating forty thousand baths in
the capital of Egypt, and of the magnificent Alexandrian Library, a mental fuel for the lamp of learning
in all ages, consumed in bath furnaces, and affording six months' fuel for that purpose. The Arabians,
however, made amends for these barbarous deeds in succeeding centuries, and when all Europe was
laid waste under the iron rule of the Goths, they became the protectors of philosophy and the
promoters of its pursuits; and thus we come to the seventh century, in which Geber, an Arabian prince
lived, and is stated to be the earliest of the true alchemists whose name has reached posterity.
Without attempting to fill up the alchemical history of the intervening centuries, we leap forward six
hundred years, and now find ourselves in imagination in England, with the learned friar, Roger Bacon,
a native of Somersetshire, who lived about the middle of the thirteenth century; and although the
continual study of alchemy had not yet produced the stone, it bore fruit in other discoveries, and
Roger Bacon is said, with great appearance of truth, to have discovered gunpowder, for he says in
one of his works:—From saltpetre and other ingredients we are able to form a fire which will burn to
any distance; and again alluding to its effects, a small portion of matter, about the size of the
thumb, properly disposed, will make a tremendous sound and coruscation, by which cities and armies
might be destroyed. The exaggerated style seems to have been a favourite one with all philosophers,
from the time of Roger Bacon to that of Muschenbroek of the University of Leyden, who accidentally
discovered the Leyden jar in the year 1746, and receiving the first shock, from a vial containing a little
water, into which a cork and nail had been fitted, states that he felt himself struck in his arms,
shoulders, and breast, so that he lost his breath, and was two days before he recovered from the
effects of the blow and the terror; adding, that he would not take a second shock for the kingdom
of France. Disregarding the numerous alchemical events occurring from the time of Roger Bacon, we
again advance four hundred years—viz., to the year 1662, when, on the 15th of July, King Charles II.
granted a royal charter to the Philosophical Society of Oxford, who had removed to London, under the
name of the Royal Society of London for Promoting Natural Knowledge, and in the year 1665 was
published the first number of the Philosophical Transactions; this work contains the successive
discoveries of Mayow, Hales, Black, Leslie, Cavendish, Lavoisier, Priestley, Davy, Faraday; and since
the year 1762 has been regularly published at the rate of one volume per annum. With this preface
proceed we now to discuss some of the varied phenomena of chemical attraction, or what is more
correctly termed
CHEMICAL AFFINITY.
The above title refers to an endless series of changes brought about by chemical combinations, all of
which can be reduced to certain fixed laws, and admit of a simple classification and arrangement. A
mechanical aggregation, however well arranged, can be always distinguished from a chemical one.
Thus, a grain of gunpowder consists of nitre, which can be washed away with boiling water, of
sulphur, which can be sublimed and made to pass away as vapour, of charcoal, which remains behind
after the previous processes are complete; this mixture has been perfected by a careful proportion of
the respective ingredients, it has been wetted, and ground, and pressed, granulated, and finally dried;
all these mechanical processes have been so well carried out that each grain, if analysed, would be
similar to the other; and yet it is, after all, only a mechanical aggregation, because the sulphur, the
73. charcoal, and the nitre are unchanged. A grain of gunpowder moistened, crushed, and examined by a
high microscopic power, would indicate the yellow particles of sulphur, the black parts of charcoal,
whilst the water filtered from the grain of powder and dried, would show the nitre by the form of the
crystal. On the other hand, if some nitre is fused at a dull red heat in a little crucible, and two or three
grains of sulphur are added, they are rapidly oxidized, and combine with the potash, forming sulphate
of potash; and after this change a few grains of charcoal may be added in a similar manner, when
they burn brightly, and are oxidized and converted into carbonic acid, which also unites in like manner
with the potash, forming carbonate of potash; so that when the fused nitre is cooled and a few
particles examined by the microscope, the charcoal and sulphur are no longer distinguishable, they
have undergone a chemical combination with portions of the nitre, and have produced two new salts,
perfectly different in taste, gravity, and appearance from the original substances employed to produce
them. Hence chemical combination is defined to be that property which is possessed by one or more
substances, of uniting together and producing a third or other body perfectly different in its nature
from either of the two or more generating the new compound.
To return to our first experiment with the gunpowder: take sulphur, place some in an iron ladle, heat
it over a gas flame till it catches fire, then ascend a ladder, and pour it gently, from the greatest
height you can reach, into a pail of warm water: if this experiment is performed in a darkened room a
magnificent and continuous stream of fire is obtained, of a blue colour, without a single break in its
whole length, provided the ladle is gradually inclined and emptied. The substance that drops into the
warm water is no longer yellow and hard, but is red, soft, and plastic; it is still sulphur, though it has
taken a new form, because that element is dimorphous (δις twice, and μορφη a form), and, Proteus-
like, can assume two forms. Take another ladle, and melt some nitre in it at a dull red heat, then add
a small quantity of sulphur, which will burn as before; and now, after waiting a few minutes, repeat
the same experiment by pouring the liquid from the steps through the air into water; observe it no
longer flames, and the substance received into the water is not red and soft and plastic, but is white,
or nearly so, and rapidly dissolves away in the water. The sulphur has united with the oxygen of the
nitre and formed sulphuric acid, which combines with the potash and forms sulphate of potash; here,
then, oxygen, sulphur, and potassium, have united and formed a salt in which the separate properties
of the three bodies have completely disappeared; to prove this, it is only necessary to dissolve the
sulphate of potash in water, and after filtering the solution, or allowing it to settle, till it becomes quite
clear and bright, some solution of baryta may now be added, when a white precipitate is thrown
down, consisting of sulphate of baryta, which is insoluble in nitric or other strong acids. The behaviour
of a solution of sulphate of potash with a nitrate of baryta may now be contrasted with that of the
elements it contains; on the addition of sulphur to a solution of nitrate of baryta no change whatever
takes place, because the sulphur is perfectly insoluble. If a stream of oxygen gas is passed from a
bladder and jet through the same test, no effect is produced; the nitrate of baryta has already
acquired its full proportion of oxygen, and no further addition has any power to change its nature;
finally, if a bit of the metal potassium is placed in the solution of nitrate of baryta it does not sink,
being lighter than water, and it takes fire; but this is not in any way connected with the presence of
the test, as the same thing will happen if another bit of the metal is placed in water—it is the oxygen
of the latter which unites rapidly with the potassium, and causes it to become so hot that the
hydrogen, escaping around the little red-hot globules, takes fire; moreover, the fact of the combustion
of the potassium under such circumstances is another striking proof of the opposite qualities of the
three elements—sulphur, oxygen, and potassium—as compared with the three chemically combined
and forming sulphate of potash. The same kind of experiment may be repeated with charcoal; if some
powdered charcoal is made red-hot, and then puffed into the air with a blowing machine, numbers of
sparks are produced, and the charcoal burns away and forms carbonic acid gas, a little ash being left
behind; but if some more nitre be heated in a ladle, and charcoal added, a brilliant deflagration
(deflagro, to burn) occurs, and the charcoal, instead of passing away in the air as carbonic acid, is
now retained in the same shape, but firmly and chemically united with the potash of the nitre,
forming carbonate of potash, or pearl-ash, which is not black and insoluble in water and acids like
charcoal, but is white, and not only soluble in water, but is most rapidly attacked by acids with
74. effervescence, and the carbon escapes in the form of carbonic acid gas. Thus we have traced out the
distinction between mechanical aggregation and chemical affinity, taking for an example the
difference between gunpowder as a whole (in which the ingredients are so nicely balanced that it is
almost a chemical combination), and its constituents, sulphur, charcoal, and nitre, when they are
chemically combined; or, in briefer language, we have noticed the difference between the mechanical
mixture, and some of the chemical combinations, of three important elements. Our very slight and
partial examination of three simple bodies does not, however, afford us any deep insight into the
principles of chemistry; we have, as it were, only mastered the signification of a few words in a
language; we might know that chien was the French for dog, or cheval horse, or homme man; but
that knowledge would not be the acquisition of the French language, because we must first know the
alphabet, and then the combination of these letters into words; we must also acquire a knowledge of
the proper arrangement of these words into sentences, or grammar, both syntax and prosody, before
we can claim to be a French scholar: so it is with chemistry—any number of isolated experiments with
various chemical substances would be comparatively useless, and therefore the alphabet of
chemistry, or table of simple elements, must first be acquired. These bodies are understood to be
solids, fluids, and gases, which have hitherto defied the most elaborate means employed to reduce
them into more than one kind of matter. Even pure light is separable into seven parts—viz., red,
orange, yellow, green, blue, indigo, and violet; but the elements we shall now enumerate are not of a
compound, but, so far as we know, of an absolutely simple or single nature; they represent the
boundaries, not the finality, of the knowledge that may be acquired respecting them.
The elements are sixty-four in number, of which about forty are tolerably plentiful, and therefore
common; whilst the remainder, twenty-four, are rare, and for that reason of a lesser utility: whenever
Nature employs an element on a grand scale it may certainly be called common, but it generally
works for the common good of all, and fulfils the most important offices.
CLASSIFICATION OF THE ALPHABET OF CHEMISTRY.
13 Non-Metallic Bodies.
Name. Symbol.
Combining
proportion
or atomic
weight.
1.Oxygen O = 8
2.Hydrogen H = 1
3.Nitrogen N = 14
4.Chlorine Cl = 35.5
5.Iodine I = 127.1
6.Bromine Br = 80.0
7.Fluorine F = 18.9
8.Carbon C = 6
9.Boron B = 10.9
10.Sulphur Sv = 16
11.Phosphorus P = 32
12.Silicon Si = 21.3
13.Selenium Se = 39.5
51 Metals.
1. Aluminium Al = 13.7
2. Antimony Sb = 129
3. Arsenic As = 75
75. 4. Barium Ba = 68.5
5. Bismuth Bi = 213
6. Cadmium Cd = 56
7. Calcium Ca = 20
8. Cerium Ce = 47
9. Chromium Cr = 26.7
10. Cobalt Co = 29.5
11. Copper Cu = 31.7
12. Donarium
13. Didymium D
14. Erbium E
15. Gold Au = 197
16. Glucinum Gl
17. Iron Fe = 28
18. Ilmenium Il
19. Iridium Ir = 99
20. Lead Pb = 103.7
21. Lanthanium La
22. Lithium Li = 6.5
23. Magnesium Mg = 12.2
24. Manganese Mn = 27.6
25. Mercury Hg = 100
26. Molybdenum Mo = 46
27. Nickel Ni = 29.6
28. Norium
29. Niobium Nb
30. Osmium Os = 99.6
31. Platinum Pt = 98.7
32. Potassium K = 39.2
33. Palladium Pd = 53.3
34. Pelopium Pe
35. Rhodium R = 52.2
36. Rhuthenium Ru = 52.2
37. Silver Ag = 108.1
38. Sodium Na = 23
39. Strontium Sr = 43.8
40. Tin Sn = 59
41. Tantalum Ta = 184
42. Tellurium Te = 64.2
43. Terbium Tb
44. Thorium Th = 59.6
45. Titanium Ti = 25
46. Tungsten W[A]= 95
47. Uranium U = 60
48. Vanadium V = 68.6
76. 49. Yttrium Y
50. Zinc Zn = 32.6
51. Zirconium Zr = 22.4
(N.B. The elements printed in italics are at present unimportant.)
[A] From the mineral Wolfram, and now exceedingly valuable, as when alloyed with iron it is
harder than, and will bore through steel.
A few words will suffice to explain the meaning of the terms which head the names, letters, and
numbers of the Table of Elements. The names of the elements have very interesting derivations,
which it is not the object of this work to go into; the symbols are abbreviations, ciphers of the
simplest kind, to save time and trouble in the frequent repetition of long words, just as the signs +
plus, and - minus, are used in algebraic formulæ. For instance—the constant recurrence of water in
chemical combinations must be named, and would involve the most tedious repetition; water consists
of oxygen and hydrogen, and by taking the first letter of each word we have an instructive symbol,
which not only gives us an abbreviated term for water, but also imparts at once a knowledge of its
composition by the use of the letters, HO.
Again, to take a more complex example, such as would occur in the study of organic chemistry—a
sentence such as the hydrated oxide of acetule, is written at once by C4H4O2, the figures referring to
the number of equivalents of each element—viz., 4 equivalents of C, the symbol for carbon, 4 of H
(hydrogen), and 2 of O (oxygen).
The long word paranaphthaline, a substance contained in coal tar, is disposed of at once with the
symbols and figures C30H12.
The figures in the third column are, however, the most interesting to the precise and mathematically
exact chemist. They represent the united labours of the most painstaking and learned chemists, and
are the exact quantities in which the various elements unite. To quote one example: if 8 parts by
weight of oxygen—viz., the combining proportions of that element—are united with 1 part by weight
of hydrogen, also its combining number, the result will be 9 parts by weight of water; but if 8 parts of
oxygen and 2 parts of hydrogen were used, one only of the latter could unite with the former, and the
result would be the formation again of 9 parts of water, with an overplus of 1 equivalent of hydrogen.
It is useless to multiply examples, and it is sufficient to know that with this table of numbers the
figures of analysis are obtained. Supposing a substance contained 27 parts of water, and the oxygen
in this had to be determined, the rule of proportion would give it at once, 9: 27:: 8: 24. 9 parts of
water are to 27 parts as 8 of oxygen (the quantity contained in 9 parts of water) are to the answer
required—viz., 24 of oxygen. The names, symbols, and combining proportions being understood, we
may now proceed with the performance of many interesting
CHEMICAL EXPERIMENTS.
As the permanent gases head the list, they will first engage our attention, beginning with the element
oxygen—Symbol O, combining proportion 8. There is nothing can give a better idea of the enormous
quantity of oxygen present in the animal, vegetable, and mineral kingdoms, than the statement that it
represents one-third of the weight of the whole crust of the globe. Silica, or flint, contains about half
its weight of oxygen; lime contains forty per cent.; alumina about thirty-three per cent. In these
substances the element oxygen remains inactive and powerless, chained by the strong fetters of
chemical affinity to the silicium of the flint, the calcium of the lime, and the aluminum of the alumina.
If these substances are heated by themselves they will not yield up the large quantity of oxygen they
contain.
77. Nature, however, is prodigal in her creation, and hence we have but to pursue our search diligently to
find a substance or mineral containing an abundance of oxygen, and part of which it will relinquish by
what used to be called by the old alchemists the torture of heat. Such a mineral is the black oxide of
manganese, or more correctly the binoxide of manganese, which consists of one combining
proportion of the metal manganese—viz., 27.6, and two of oxygen—viz., 8 × 2 = 16. If three
proportions of the binoxide of manganese are heated to redness in an iron retort, they yield one
proportion (equal to 8) of oxygen, and all that has just been explained by so many words is
comprehended in the symbols and figures below:—
3 MnO2 = Mn3O4 + O.
Thus the 3 MnO2 represent the three proportions of the binoxide of manganese before heat is
applied, whilst the sign =, the sign of equation (equal to), is intended to show that the elements or
compounds placed before it produce those which follow it; hence the sequel Mn3O4 + O shows that
another compound of the metal and oxygen is produced, whilst the + O indicates the liberated
oxygen gas. The iron retort employed to hold the mineral should be made of cast iron in preference to
wrought iron, as the latter is very soon worn out by contact with oxygen at a red heat. A gun-barrel
will answer the purpose for an experiment on the small scale, to which must be adapted a cock and
piece of pewter tubing. Such a make-shift arrangement may do very well when nothing better offers;
but as a question of expense, it is probably cheaper in the end to order of Messrs. Simpson and
Maule, or of Messrs. Griffin, or of Messrs. Bolton, a cast-iron bottle, or cast-iron retort, as it is termed,
of a size sufficient to prepare two gallons of oxygen from the binoxide of manganese, which, with four
feet of iron conducting-pipe, and connected to the bottle with a screw, does not cost more than six
shillings—an enormous dip, perhaps, in the juvenile pocket, and therefore we shall indicate presently
a still cheaper apparatus for the same purpose. (Fig. 93.)
Fig. 93.
a. The iron bottle, containing the black oxide of manganese, with pipe passing to the pneumatic trough,
b b, in which is fixed a shelf, c, perforated with a hole, under which the end of the pipe is adjusted, and
the gas passes into the gas-jar, d.
The oxygen is conveyed to a square tin box provided with a shelf at one end, perforated with several
holes at least one inch in diameter, called the pneumatic trough; any wooden trough, butter or wash-
tub, foot-pan or bath, provided with a shelf, may be raised by the same title to the dignity of a piece
of chemical apparatus. The gas jar must be filled with water by withdrawing the stopper and pressing
it down into the trough, and when the neck is below the level of the water, the stopper is again
inserted, and the jar with the water therein contained lifted steadily on to the shelf, the entry of
atmospheric air being prevented by keeping the lower part of the gas jar, called the welt, under the
water. Sometimes the pneumatic trough contains so small a quantity of water that on raising the gas
jar to the shelf the liquid does not cover the bottom, and the air rushes up in large bubbles. Under
these circumstances it is better to provide a gallon stone jug full of water, so that when the jar is
78. being raised to the shelf it may be thrust into the trough (on the same principle as the crow and the
pitcher in the fable), and thus by its bulk (as the stones in the pitcher) raise the water to the proper
level. When the gas jar is about half filled with gas the jug may be withdrawn. This arrangement
saves the trouble of constantly adding and baling out water from the pneumatic trough. (Fig. 94.)
Fig. 94.
a a. Pneumatic trough, with gas jar raised to shelf; bubbles of air are rushing in at b, as the level of the
water is below the shelf—viz., at c c. d d. Same trough and gas jar with water kept over the shelf by the
introduction of the stone pitcher e, full of water.
There are other solid oxygenized bodies in which the affinities are less powerful, and hence a lower
degree of heat suffices to liberate the oxygen gas, and one of the most useful in this respect is the
salt termed chlorate of potash. If the substance is heated by itself, the temperature required to expel
the oxygen is almost as high as that demanded for the black oxide of manganese; but, strange to say,
if the two substances are reduced to powder, and mixed in equal quantities by weight, then a very
moderate increase of heat is sufficient to cause the chlorate of potash to give up its oxygen, whilst
the oxide of manganese undergoes no change whatever. It seems to fulfil only a mechanical office—
possibly that of separating each particle of chlorate of potash from the other, so that the heat attacks
the substance in detail, just as a solid square of infantry might repel almost any attack, whilst the
same body dispersed over a large space might be of little use; so with the chlorate of potash, which
undergoes rapid decomposition when mixed with and divided amongst the particles of the oxide of
manganese; less so with the red oxide of iron, and still less with sand or brick-dust. (Fig. 95.)
Fig. 95.
79. Preparation of oxygen from chlorate of potash and oxide of manganese.
KO.ClO5 = KCl + O6.
This curious fact is explained usually by reference to what is called catalytic action, or decomposition
by contact (κατα, downwards, and λυω, I unloosen), being a power possessed by a body of resolving
another into a new compound without undergoing any change itself. To make this term still clearer,
we may notice another example in linen rags, which may be exposed for any length of time to the
action of water without fear of conversion into sugar; if, however, oil of vitriol is first added to the
linen rags, and they are subsequently digested at a proper temperature with water, then the rags are
converted into sugar (the author has seen a specimen made of an old shirt); but, curious to relate,
the oil of vitriol is unchanged in the process, and if the process be commenced with a pound of acid,
the same quantity is discoverable at the end of the chemical decomposition of the linen rags, and
their conversion into sugar.
If a mixture of equal parts of oxide of manganese and chlorate of potash is placed in a clean Florence
flask, with a cork, and pewter, or glass tube attached, great quantities of oxygen are quickly liberated,
on the application of the heat of a spirit lamp. Such a retort would cost about fourpence, and if the
flask is broken in the operation it can be easily replaced by another, value one penny, as the same
cork and tube will generally suit a number of these cheap glass vessels. Corks may always be
softened by using either a proper cork squeezer, or by placing them under a piece of board or a flat
surface, and rolling and pressing the cork till quite elastic.
Whilst fitting the latter into the neck of a flask, it is perhaps safer to hold the thin and fragile vessel in
a cloth, so that if the flask breaks the chemical experiment may not be arrested for many days by the
severe cutting and wounding of the fingers. After the cork is fitted, it is to be removed from the flask
and bored with a cork borer. This useful tool is sold in complete sets to suit all sizes of glass tubes,
and the pewter or glass being inserted, the flask and tube will be ready for use, provided the tube is
bent to the proper curve. This is easy enough to perform with the pewter, but not quite so easy with
the glass tube, which must be held over the flame of a spirit lamp till soft, and then bent very
gradually to the proper curve. If a short length of the glass tube is heated, it bends too sharply, and
the convexity of the glass is flattened, whilst the internal diameter of the tube is lessened, so that at
least three inches in length should be warmed, and the heat must not be continued in one place only,
but should be maintained in the direction of the bend, the whole manipulation being conducted
without any hurry. (Fig. 96.)
Fig. 96.
a. The cork squeezer. b. The cork borers. c. The operation of bending the glass tube over the flame of
the spirit-lamp. d. The neck of the flask, with cork and tube bent and fitted complete for use.
80. Fig. 97.
Having filled a gas jar with oxygen, it may be removed from the pneumatic trough by sliding it into a
plate under the surface of the water, and to prevent the stopper being thrust out accidentally from the
jar by the upward pressure of the gas, whilst a little compressed, during the act of passing it into the
plate, it is advisable to hold the stopper of the jar firmly but gently, so that it cannot slip out of its
place. A number of jars of oxygen may be prepared and arranged in plates, all of which of course
must contain a little water, and enough to cover the welt of the jar.
EXPERIMENTS WITH OXYGEN GAS.
This gas was originally discovered by Priestley, in August, 1774, and was first obtained by heating red
precipitate—i.e., the red oxide of mercury.
HgO = Hg + O.
We leave these symbols and figures to be deciphered by the youthful philosopher with the aid of the
table of elements, c., and return to the experiments.
There are certain thin wax tapers like waxed cord, called bougies, which can be bent to any shape,
and are very convenient for experiments with the gases. If one of these tapers is bent as in Fig. 97,
then lighted and allowed to burn for some minutes, a long snuff is gradually formed, which remains in
a state of ignition when the flame of the taper is blown out. On plunging this into a jar of oxygen, it
instantly re-lights with a sort of report, and burns with greatly-increased brilliancy, as described by Dr.
Priestley in his first experiment with this gas, and so elegantly repeated by Professor Brande in his
refined dissertation on the progress of chemical science.
The 1st of August, 1774, is a red-letter day in the annals of chemical
philosophy, for it was then that Dr. Priestley discovered dephlogisticated air.
Some, sporting in the sunshine of rhetoric, have called this the birthday of
pneumatic chemistry; but it was even a more marked and memorable period;
it was then (to pursue the metaphor) that this branch of science, having
eked out a sickly and infirm infancy in the ill-managed nursery of the early
chemists, began to display symptoms of an improving constitution, and to
exhibit the most hopeful and unexpected marks of future importance. The
first experiment, which led to a very satisfactory result, was concluded as
follows:—A glass jar was filled with quicksilver, and inserted in a basin of the
same; some red precipitate of quicksilver was then introduced, and floated
upon the quicksilver in the jar; heat was applied to it in this situation with a
burning-lens, and to use Priestley's own words, I presently found that air was
expelled from it very readily. Having got about three or four times as much
as the bulk of my materials, I admitted water into it, and found that it was
not imbibed by it. But what surprised me more than I can well express was,
that a candle burned in this air with a remarkably vigorous flame, very much
like that enlarged flame with which a candle burns in nitrous air exposed to
iron or lime of sulphur (i.e., laughing gas); but as I had got nothing like this remarkable appearance
from any kind of air besides this peculiar modification of nitrous air, and I knew no nitrous acid was
used in the preparation of mercurius calcinatus, I was utterly at a loss how to account for it. (Fig.
98.)
81. Fig. 98.
a. Glass vessel full of mercury, containing the red precipitate at the top, and standing in the dish b, also
containing mercury. c. The burning-glass concentrating the sun's rays on the red precipitate, being
Priestley's original experiment.
Second Experiment.
The term oxygen is derived from the Greek (οζυς, acid, and γενναω, I give rise to), and was originally
given to this element by Lavoisier, who also claimed its discovery; and if this honour is denied him,
surely he has deserved equal scientific glory in his masterly experiments, through which he discovered
that the mixture of forty-two parts by measure of azote, with eight parts by measure of oxygen,
produced a compound precisely resembling our atmosphere. The name given to oxygen was founded
on a series of experiments, one of which will now be mentioned.
Place some sulphur in a little copper ladle attached to a wire, and called a deflagrating spoon, passed
through a round piece of zinc or brass plate and cork, so that the latter acts as an adjusting
arrangement to fix the wire at any point required. The combustion of the sulphur, previously feeble,
now assumes a remarkable intensity, and a peculiar coloured light is generated, whilst the sulphur
unites with the oxygen, and forms sulphurous acid gas. It produces, in fact, the same gas which is
formed by burning an ordinary sulphur match. This compound is valuable as a disinfectant, and is a
very important bleaching agent, being most extensively employed in the whitening of straw employed
in the manufacture of straw bonnets. It is an acid gas, as Lavoisier found, and this property may be
detected by pouring a little tincture of litmus into the bottom of the plate in which the gas jar stands.
The blue colour of the litmus is rapidly changed to red, and it might be thought that no further
argument could possibly be required to prove that oxygen was the acidifying agent, the more
particularly as the result is the same in the next illustration.
82. Fig. 99.
a. The deflagrating
spoon, b. The cork. c.
The zinc, or brass, or
tin plate. d d. The gas
jar.
Third Experiment.
Cut a small piece from an ordinary stick of phosphorus under water, take care to dry it properly with a
cloth, and after placing it in a deflagrating spoon, remove the stopper from the gas-jar, as there is no
fear of the oxygen rushing away, because it is somewhat heavier than atmospheric air; and then,
after placing the spoon with the phosphorus in the neck of the jar, apply a heated wire and pass the
spoon at once into the middle of the oxygen; in a few seconds a most brilliant light is obtained, and
the jar is filled with a white smoke; as this subsides, being phosphoric acid, and perfectly soluble in
water, the same litmus test may be applied, when it is in like manner changed to red. The acid
obtained is one of the most important constituents of bone.
Fourth Experiment.
A bit of bark-charcoal bound round with wire is set on fire either by holding it in the flame of a spirit-
lamp, or by attaching a small piece of waxed cotton to the lower part, and igniting this; the charcoal
may then be inserted into a bottle of oxygen, when the most brilliant scintillations occur. After the
combustion has ceased and the whole is cool, a little tincture of litmus may also be poured in and
shaken about, when it likewise turns red, proving for the third time the generation of an acid body,
called carbonic acid—an acid, like the others already mentioned, of great value, and one which Nature
employs on a stupendous scale as a means of providing plants, c., with solid charcoal. Carbonic acid,
a virulent poison to animal life, is, when properly diluted, and as contained in atmospheric air, one of
the chief alimentary bodies required by growing and healthy plants.
In three experiments acid bodies have been obtained; can we speculate on the result of the next?
83. Fifth Experiment.
Into a deflagrating spoon place a bit of potassium, set this on fire by holding it in the spoon in the
flame of a spirit-lamp, and then rapidly plunge the burning metal into a bottle of oxygen. A brilliant
ignition occurs in the deflagrating spoon for a few seconds, and there is little or no smoke in the jar.
The product this time is a solid, called potash, and if this be dissolved in water and filtered, it is found
to be clear and bright, and now on the addition of a little tincture of litmus to one half of the solution,
it is wholly unaffected, and remains blue; but if with the other half a small quantity of tincture of
turmeric is mixed, it immediately changes from a bright yellow solution to a reddish-brown, because
turmeric is one of the tests for an alkali; and thus is ascertained by the help of this and other tests
that the result of the combustion is not an acid, but an alkali. The experiment is made still more
satisfactory by burning another bit of potassium in oxygen and dissolving the product in water, and if
any portion of the reddened liquid derived from the sulphurous, phosphoric, and carbonic acids taken
from the previous experiments, be added to separate portions of the alkaline solution, they are all
restored to their original blue colour, because an acid is neutralized by an alkali; and the experiment is
made quite conclusive by the restoration of the reddened turmeric to a bright yellow on the addition
of a solution of either of the three acids already named. Moreover, an acid need not contain a fraction
of oxygen, as there is a numerous class of hydracids, in which the acidifying principle is hydrogen
instead of oxygen, such as the hydrochloric, hydriodic, hydro-bromic, and hydrofluoric acids.
Sixth Experiment.
A piece of watch-spring is softened at one end, by holding it in the flame of a spirit-lamp, and
allowing it to cool. A bit of waxed cotton is then bound round the softened end, and after being set on
fire, is plunged into a gas jar containing oxygen; the cotton first burns away, and then the heat
communicates to the steel, which gradually takes fire, and being once well ignited, continues to burn
with amazing rapidity, forming drops of liquid dross, which fall to the bottom of the plate—and also a
reddish smoke, which condenses on the sides of the jar; neither the dross which has dropped into the
plate, nor the reddish matter condensed on the jar, will affect either tincture of litmus or turmeric;
they are neither acid nor alkaline, but neutral compounds of iron, called the sesquioxide of iron
(Fe2O3), and the magnetic oxide (Fe3O4 = FeO.Fe2O3).
Seventh Experiment.
Some oxygen gas contained in a bladder provided with a proper jet may be squeezed out, and upon,
some liquid phosphorus contained in a cup at the bottom of a finger glass full of boiling water, when a
most brilliant combustion occurs, proving that so long as the principle is complied with—viz., that of
furnishing oxygen to a combustible substance—it will burn under water, provided it is insoluble, and
possesses the remarkable affinity for oxygen which belongs to phosphorus. The experiment should be
performed with boiling water, to keep the phosphorus in the liquid state; and it is quite as well to hold
a square foot of wire gauze over the finger glass whilst the experiment is being performed. (Fig. 100.)
Fig. 100.
a. Bladder containing oxygen, provided with a stop-cock and jet leading to, b, b. Finger glass containing
boiling water. c. The cup of melted phosphorus under the water. The gas escapes from the bladder
84. when pressed.
Eighth Experiment.
Oxygen is available from many substances when they are mixed with combustible substances, and
hence the brilliant effects produced by burning a mixture of nitre, meal powder, sulphur, and iron or
steel filings; the metal burns with great brilliancy, and is projected from the case in most beautiful
sparks, which are long and needle-shaped with steel, and in the form of miniature rosettes with iron
filings; it is the oxygen from the nitre that causes the combustion of the metal, the other ingredients
only accelerate the heat and rate of ignition of the brilliant iron, which is usually termed a gerb.
Ninth Experiment.
A mixture of nitrate of potash, powdered charcoal, sulphur, and nitrate of strontium, driven into a
strong paper case about two inches long, and well closed at the end with varnish, being quite
waterproof, may be set on fire, and will continue to burn under water until the whole is consumed;
the only precaution necessary being to burn the composition from the case with the mouth
downward, and if the experiment is tried in a deep glass jar it has a very pleasing effect. (Fig. 101.)
Fig. 101.
a. Case of red fire burning downwards, and attached by a copper wire to a bit of leaden pipe b, to sink
it. c c. Jar containing water.
The red-fire composition is made by mixing nitrate of strontia 40 parts by weight, flowers of sulphur
13 parts, chlorate of potash 5 parts, sulphuret of antimony 4 parts. These ingredients must first be
well powdered separately, and then mixed carefully on a sheet of paper with a paper-knife. They are
liable to explode if rubbed together in a mortar, on account of the presence of sulphur and chlorate of
potash, and the composition, if kept for any time, is liable to take fire spontaneously.
Tenth Experiment.
Some zinc is melted in an iron ladle, and made quite red hot; if a little dry nitre is thrown upon the
surface, and gently stirred into the metal, it takes fire with the production of an intense white light,
whilst large quantities of white flakes ascend, and again descend when cold, being the oxide of zinc,
85. and called by the alchemists the Philosopher's Wool (ZnO). In this experiment the oxygen from the
nitre effects the oxidation of the metal zinc.
Eleventh Experiment.
A mixture of four pounds of nitre with two of sulphur and one and a half of lamp black produces a
most beautiful and curious fire, continually projected into the air as sparks having the shape of the
rowel of a spur, and one that may be burnt with perfect safety in a room, as the sparks consume
away so rapidly, in consequence of the finely divided condition of the charcoal, that they may be
received on a handkerchief or the hand without burning them. The difficulty consists in effecting the
complete mixture of the charcoal. The other two ingredients must first be thoroughly powdered
separately, and again triturated when mixed, and finally the charcoal must be rubbed in carefully, till
the whole is of a uniform tint of grey and very nearly black, and as the mixture proceeds portions
must be rammed into a paper case, and set on fire; if the stars or pinks come out in clusters, and
spread well without other and duller sparks, it is a sign that the whole is well mixed; but if the sparks
are accompanied with dross, and are projected out sluggishly, and take some time to burn, the
mixture and rubbing in the mortar must be continued; and even that must not be carried too far, or
the sparks will be too small. N.B.—If the lamp-black was heated red hot in a close vessel, it would
probably answer better when cold and powdered.
Twelfth Experiment.
Into a tall gas jar with a wide neck project some red-hot lamp-black through a tin funnel, when a
most brilliant flame-like fire is obtained, showing that finely divided charcoal with pure oxygen would
be sufficient to afford light; but as the atmosphere consists of oxygen diluted with nitrogen,
compounds of charcoal with hydrogen, are the proper bodies to burn, to produce artificial light.
Thirteenth Experiment. The Bude Light.
This pretty light is obtained by passing a steady current of oxygen gas (escaping at a very low
pressure) through and up the centre pipe of an argand oil lamp, which must be supplied with a highly
carbonized oil and a very thick wick, as the oxygen has a tendency to burn away the cotton unless the
oil is well supplied, and allowed to overflow the wick, as it does in the lamps of the lighthouses. The
best whale oil is usually employed, though it would be worth while to test the value of Price's
Belmontine Oil for the same purpose. (Fig. 102.)
86. Fig. 102.
a. Reservoir of oil. b. The flexible pipe conveying oxygen to centre of the argand lamp.
Fourteenth Experiment. A Red Light.
Clear out the oil thoroughly from the Bude light apparatus; or, what is better, have two lamps, one for
oil, and the other for spirit; fill the apparatus with a solution of nitrate of strontia and chloride of
calcium in spirits of wine, and let it burn from the cotton in the same way as the oil, and supply it with
oxygen gas.
Fifteenth Experiment. A Green Light.
Dissolve boracic acid and nitrate of baryta in spirits of wine, and supply the Bude lamp with this
solution.
Sixteenth Experiment. A Yellow Light.
Dissolve common salt in spirits of wine, and burn it as already described in the Bude light apparatus.
Seventeenth Experiment. The Oxy-calcium Light.
This very convenient light is obtained in a simple manner, either by using a jet of oxygen as a
blowpipe to project the flame of a spirit lamp on to a ball of lime; or common coal-gas is employed
instead of the spirit lamp, being likewise urged against a ball of lime. By this plan one bag containing
oxygen suffices for the production of a brilliant light, not equal, however, to the oxy-hydrogen light,
which will be explained in the article on hydrogen. (Fig. 103.)
Fig. 103.
No. 1. a. Oxygen jet. b. The ball of lime, suspended by a wire. c. Spirit lamp. No. 2. d. Oxygen jet. e. Gas
(jet connected with the gas-pipe in the rear by flexible pipe) projected on to ball of lime, f.
Eighteenth Experiment.
To show the weight of oxygen gas, and that it is heavier than air, the stoppers from two bottles
containing it may be removed, one bottle may be left open for some time and then tested by a lighted
taper, when it will still indicate the presence of the gas, whilst the other may be suddenly inverted
over a little cup in which some ether, mixed with a few drops of turpentine, may be burning—the
flame burns with much greater brilliancy at the moment when the oxygen comes in contact with it.
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