1
B. Sc. Third Year
Semester-VI
1
Module-2 : Introduction of Syllabus
Dr. B. N. Gawade
M. Sc. CSIR-UGC-NET (JRF), Ph. D.
Assistant Professor
Department of Chemistry
Anandrao Dhonde Alias Babaji Mahavidyalaya, Kada.
Tal. Ashti. Dist. Beed - 414 202, Maharashtra, INDIA
Introduction of Syllabus
Welcome
DR. BABASAHEB AMBEDKAR MARATHWADA UNIVERSITY, AURANGABAD.
SYLLABUS
B.Sc. (Chemistry) THIRD YEAR
SEMESTER SYSTEM
SIXTH SEMESTER
[Effective from – June- 2015 onwards]
2
BNG-Chem Study Channel
B.Sc. (Chemistry) in Semester Pattern for Three Year Degree
Year Semester Paper
Number
Paper Title Hours Marks
Third VI
Paper – XVI Inorganic Chemistry 45 50
Paper – XVII Organic Chemistry 45 50
Paper – XVIII Lab. Course-VI 90 100
3
BNG-Chem Study Channel
B.Sc. CHEMISTRY
(Three Year Degree Course)
(45hrs) 3 Hrs/ Week
Paper XVII Organic Chemistry Sixth Semester
I. Heterocyclic Compounds 13 Hrs.
II. Carbohydrates 10 Hrs.
III. Synthetic Polymers 07 Hrs.
IV. Synthetic Dyes and Drugs 15Hrs.
Paper – XVIII
Lab. Course VI
Organic Chemistry &
Physical Chemistry
(45 Hrs)
(45 Hrs)
4
BNG-Chem Study Channel
Organic Chemistry [Theory] [Semester-VI]
Paper -XVII 45 Hrs. (3 Hrs/week)
B. SC. THIRD YEAR
1. Heterocyclic Compounds 13 Hrs.
 Introduction:
 Molecular orbital picture and aromatic characteristics of pyrrole,
 furan,
 thiophene
 and pyridine,
 Methods of synthesis and chemical reactions with particular
emphasis on the mechanism of electrophilic substitution.
5
BNG-Chem Study Channel
 Mechanism of nucleophilic substitution reactions in pyridine.
 Comparison of basicity of pyridine, piperidine and pyrrole.
 Condensed Heterocycles: Introduction,
 Preparation of Quinoline (Skraups Synthesis),
 Isoquinoline (Bischler - Napirlaski) and
 Indole (Fischer indole Synthesis).
6
BNG-Chem Study Channel
2. Carbohydrates 10 Hrs.
 Definition, Introduction and Classification.
 Monosaccharides – Interconversion of Glucose and Fructose,
 chain lengthening of aldoses,
 chain shortening of aldoses.
 Conversion of Glucose into mannose.
 Determination of open chain structure of glucose & pyranose ring structure of
glucose.
 Mechanism of Mutarotation and Introduction to
disaccharides (maltose, sucrose and lactose) and
 Polysaccharides (Starch and cellulose) without
involving structure determination.
7
BNG-Chem Study Channel
3. Synthetic Polymers. 07 Hrs.
 Introduction,
 Classification based on nature of synthesis (without mechanism) with
examples. (Addition and condensation polymers).
 Properties, uses and synthesis of polyvinyl chloride,
 polyvinyl acetate, polystyrene, polyacrylonitrile, Nylon-6 and Nylon-6, 6.
 Introduction to synthetic and natural rubber,
 properties, uses and synthesis of Buna-N,
 Neoprene and silicon rubber.
8
BNG-Chem Study Channel
4. Synthetic Dyes and Drugs 15 Hrs.
 Synthetic Dyes - Definition,
 colour and constitution (electronic concept) of dye,
 classification based on chemical constitution,
 synthesis of methyl orange, Congo red, malachite green, crystal violet, Alizarin and
indigo dyes.
 Synthetic Drugs - Definition,
 introduction, classification of drugs.
 Properties of ideal drug.
 Synthesis of chloromycetin, paracetamol, phenacetin,
and sulphaguanidine.
9
BNG-Chem Study Channel
B. SC. THIRD YEAR
Semester-VI
Organic Chemistry [Practical]
Paper-XVIII
Lab Course: VI Marks: 50
Organic Estimation :
i) Estimation of Carbonyl group by hydrazone formation method.
ii) Estimation of vitamin-C in commercial soft drink / Glucon-D.
iii) Estimation of ascorbic acid.
iv) Estimation of Saponification value of oil.
10
BNG-Chem Study Channel
Organic Preparation and its purity by TLC :
i) Preparation of Hydrazobenzene from azobenzene.
ii) Preparation of Phthalic anhydride from phthalic acid.
iii) Preparation of 2, 4 dinitrophenyl hydrazone of acetone.
iv) To prepare picrate of Naphthalene.
v) To prepare picrate of Anthracene.
11
BNG-Chem Study Channel
B. SC. THIRD YEAR
Semester -VI
Physical Chemistry [Practical]
Paper -XVIII
Lab Course: VI Marks: 50
*Instrumental:
1. Determine the Strength of HCl and CH3COOH in a given mixture by titrating against
strong base conductometrically.
2. Determine the strength of oxalic acid conductometrically using sodium hydroxide solution.
3. To determine empirical formula of ferric-5-sulphosalicylate.
4. Determine the amount of Fe+2
in the given solution potentiometrically.
12
BNG-Chem Study Channel
5. To determine the refractive indices of series of salt solutions and to find out
concentration of the salt in given unknown solution.
*Non-Instrumental:
1. To determine the interfacial tension between two immiscible liquids.
2. To study the effect of addition of an electrolyte NaCl / KCl on the solubility
of benzoic acid at room temperature.
3. To determine the standard free energy change ΔG0
and equilibrium constant
for the reaction. Cu + 2 Ag+
= Cu+2
+ 2Ag
13
BNG-Chem Study Channel
BNG-Chem Study Channel 14

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Module 2- Introduction of Chemistry Syllabus B. Sc.- III Year Semester-VI

  • 1. 1 B. Sc. Third Year Semester-VI 1 Module-2 : Introduction of Syllabus Dr. B. N. Gawade M. Sc. CSIR-UGC-NET (JRF), Ph. D. Assistant Professor Department of Chemistry Anandrao Dhonde Alias Babaji Mahavidyalaya, Kada. Tal. Ashti. Dist. Beed - 414 202, Maharashtra, INDIA Introduction of Syllabus Welcome
  • 2. DR. BABASAHEB AMBEDKAR MARATHWADA UNIVERSITY, AURANGABAD. SYLLABUS B.Sc. (Chemistry) THIRD YEAR SEMESTER SYSTEM SIXTH SEMESTER [Effective from – June- 2015 onwards] 2 BNG-Chem Study Channel
  • 3. B.Sc. (Chemistry) in Semester Pattern for Three Year Degree Year Semester Paper Number Paper Title Hours Marks Third VI Paper – XVI Inorganic Chemistry 45 50 Paper – XVII Organic Chemistry 45 50 Paper – XVIII Lab. Course-VI 90 100 3 BNG-Chem Study Channel
  • 4. B.Sc. CHEMISTRY (Three Year Degree Course) (45hrs) 3 Hrs/ Week Paper XVII Organic Chemistry Sixth Semester I. Heterocyclic Compounds 13 Hrs. II. Carbohydrates 10 Hrs. III. Synthetic Polymers 07 Hrs. IV. Synthetic Dyes and Drugs 15Hrs. Paper – XVIII Lab. Course VI Organic Chemistry & Physical Chemistry (45 Hrs) (45 Hrs) 4 BNG-Chem Study Channel
  • 5. Organic Chemistry [Theory] [Semester-VI] Paper -XVII 45 Hrs. (3 Hrs/week) B. SC. THIRD YEAR 1. Heterocyclic Compounds 13 Hrs.  Introduction:  Molecular orbital picture and aromatic characteristics of pyrrole,  furan,  thiophene  and pyridine,  Methods of synthesis and chemical reactions with particular emphasis on the mechanism of electrophilic substitution. 5 BNG-Chem Study Channel
  • 6.  Mechanism of nucleophilic substitution reactions in pyridine.  Comparison of basicity of pyridine, piperidine and pyrrole.  Condensed Heterocycles: Introduction,  Preparation of Quinoline (Skraups Synthesis),  Isoquinoline (Bischler - Napirlaski) and  Indole (Fischer indole Synthesis). 6 BNG-Chem Study Channel
  • 7. 2. Carbohydrates 10 Hrs.  Definition, Introduction and Classification.  Monosaccharides – Interconversion of Glucose and Fructose,  chain lengthening of aldoses,  chain shortening of aldoses.  Conversion of Glucose into mannose.  Determination of open chain structure of glucose & pyranose ring structure of glucose.  Mechanism of Mutarotation and Introduction to disaccharides (maltose, sucrose and lactose) and  Polysaccharides (Starch and cellulose) without involving structure determination. 7 BNG-Chem Study Channel
  • 8. 3. Synthetic Polymers. 07 Hrs.  Introduction,  Classification based on nature of synthesis (without mechanism) with examples. (Addition and condensation polymers).  Properties, uses and synthesis of polyvinyl chloride,  polyvinyl acetate, polystyrene, polyacrylonitrile, Nylon-6 and Nylon-6, 6.  Introduction to synthetic and natural rubber,  properties, uses and synthesis of Buna-N,  Neoprene and silicon rubber. 8 BNG-Chem Study Channel
  • 9. 4. Synthetic Dyes and Drugs 15 Hrs.  Synthetic Dyes - Definition,  colour and constitution (electronic concept) of dye,  classification based on chemical constitution,  synthesis of methyl orange, Congo red, malachite green, crystal violet, Alizarin and indigo dyes.  Synthetic Drugs - Definition,  introduction, classification of drugs.  Properties of ideal drug.  Synthesis of chloromycetin, paracetamol, phenacetin, and sulphaguanidine. 9 BNG-Chem Study Channel
  • 10. B. SC. THIRD YEAR Semester-VI Organic Chemistry [Practical] Paper-XVIII Lab Course: VI Marks: 50 Organic Estimation : i) Estimation of Carbonyl group by hydrazone formation method. ii) Estimation of vitamin-C in commercial soft drink / Glucon-D. iii) Estimation of ascorbic acid. iv) Estimation of Saponification value of oil. 10 BNG-Chem Study Channel
  • 11. Organic Preparation and its purity by TLC : i) Preparation of Hydrazobenzene from azobenzene. ii) Preparation of Phthalic anhydride from phthalic acid. iii) Preparation of 2, 4 dinitrophenyl hydrazone of acetone. iv) To prepare picrate of Naphthalene. v) To prepare picrate of Anthracene. 11 BNG-Chem Study Channel
  • 12. B. SC. THIRD YEAR Semester -VI Physical Chemistry [Practical] Paper -XVIII Lab Course: VI Marks: 50 *Instrumental: 1. Determine the Strength of HCl and CH3COOH in a given mixture by titrating against strong base conductometrically. 2. Determine the strength of oxalic acid conductometrically using sodium hydroxide solution. 3. To determine empirical formula of ferric-5-sulphosalicylate. 4. Determine the amount of Fe+2 in the given solution potentiometrically. 12 BNG-Chem Study Channel
  • 13. 5. To determine the refractive indices of series of salt solutions and to find out concentration of the salt in given unknown solution. *Non-Instrumental: 1. To determine the interfacial tension between two immiscible liquids. 2. To study the effect of addition of an electrolyte NaCl / KCl on the solubility of benzoic acid at room temperature. 3. To determine the standard free energy change ΔG0 and equilibrium constant for the reaction. Cu + 2 Ag+ = Cu+2 + 2Ag 13 BNG-Chem Study Channel