1.
Oil Refinery: Complete Process Overview &
Environmental Compliance
A comprehensive analysis of refinery operations, processes, equipment, and environmental
standards for industry professionals
August 2, 2025 | Technical Presentation Made with Genspark
2. Agenda
Presentation Outline
1 Sector Introduction
2 Key Products & Sub-sectors
3 Industry Production Processes
4 Crude Oil Distillation
5 Major Process Units
6 Equipment & Infrastructure
7 Emission Sources & Types
8 CEMS Technology
9 Environmental Compliance
10 Summary & Key Takeaways
Oil Refinery: Complete Process Overview & Environmental Compliance
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3. Sector Introduction
Overview
The oil refinery sector involves the process of transforming crude oil into useful
products such as gasoline, diesel, kerosene, jet fuel, and various petrochemical
feedstock. Refineries also produce by-products such as asphalt and lubricants. This
process is essential to meet the growing demand for energy and petroleum-based
products globally.
Sub-sectors
Primary: Petroleum Refining
Core processing of crude oil into fuels and basic petroleum products
Secondary: Petrochemicals
Production of chemicals derived from petroleum, serving as raw materials for plastics,
synthetics, and industrial chemicals
Secondary: Gas Processing
Separation and purification of natural gas components for commercial and industrial use
Secondary: Bitumen Production
Manufacturing of asphalt and other heavy residual products for construction and
infrastructure
Industry Importance
Essential for transportation fuels
Backbone of industrial manufacturing
Source for consumer product materials
Critical component of global energy security
Significant economic driver and employer
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5. Industry Production Process Overview
Oil refining is a complex 10-step process that transforms crude oil into valuable products. The process integrates physical separation, chemical
conversion, and quality control to create fuels, petrochemicals, and other petroleum-based products that meet industry standards.
Refinery Production Process Flow
Oil Refinery: Complete Process Overview & Environmental Compliance
1
Crude Oil Intake
Crude oil arrives via ships or
pipelines and is tested for
quality
2
Distillation
Oil is heated and separated into
fractions based on boiling
points
3
Fractionation Towers
Tall towers collect different
components like gas, petrol,
diesel
4
Conversion Processes
Cracking breaks big molecules;
Reforming improves petrol
quality
5
Treatment
Removes harmful substances
like sulfur to reduce pollution
6
Blending
Different fuels are mixed to
meet quality standards
7
Storage
Refined products are stored in
large tanks before delivery
8
By-Product Handling
Manages items like asphalt and
petroleum coke responsibly
9
Environmental Controls
Uses filters and scrubbers to
reduce emissions
10
Continuous Monitoring
Computers and sensors track
operations for efficiency and
safety
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6. Crude Oil Distillation Process
Distillation Process Overview
Crude oil distillation is the primary separation process in a refinery. The process
separates crude oil into different fractions based on their boiling points in a
distillation tower (column). Heated crude oil enters the tower where components with
different boiling points condense at different heights and are collected on trays,
resulting in the separation of various petroleum products.
Distillation Tower Fractions
20°C
TOP
Gases & Light Naphtha
Petroleum gases (C₁-C₄), used for LPG and petrochemical feedstock
70°C
Heavy Naphtha (Gasoline)
C₅-C₁₀ hydrocarbons, primary component for gasoline production
170°C
Kerosene
C₁₁-C₁₃ hydrocarbons, used for jet fuel and heating oil
270°C
Diesel/Gas Oil
C₁₄-C₂₀ hydrocarbons, used for diesel fuel and heating
>340°C
BOTTOM
Residuum
Heavy hydrocarbons used for lubricating oils, waxes, bitumen, and sent to vacuum
distillation
Distillation Process Steps
1 Crude oil is preheated using recovered heat from
other refinery processes
2 Preheated crude enters the furnace where it's
heated to 350-400°C
3 Hot crude enters the atmospheric distillation
column at flash zone
4 Lighter components rise as vapor while heavier
ones fall to the bottom
5 Components condense at different temperatures
on trays inside tower
6 Fractions are withdrawn at different heights and
sent for further processing
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7. Major Process Units
CDU (Crude Distillation Unit)
Separates crude oil into
fractions based on boiling
points. The primary separation
unit of a refinery.
Operates at atmospheric
pressure
Produces naphtha, kerosene,
diesel, and heavy residues
First major processing unit in
refineries
VDU (Vacuum Distillation Unit)
urther separates heavy residue
from CDU under vacuum to
prevent thermal cracking.
Operates at sub-atmospheric
pressure
Produces vacuum gas oil and
vacuum residue
Allows separation without
thermal degradation
Hydrocracker
Breaks down large
hydrocarbons into smaller
molecules using hydrogen, heat,
pressure and catalysts.
Produces diesel, jet fuel, and
naphtha
Uses high pressure (1500-3000
psi) and temperature
Converts heavy oil into more
valuable lighter products
FCC (Fluid Catalytic Cracking)
Converts heavy gas oils into
lighter, more valuable products
using catalysts without
hydrogen.
Major source of gasoline
production in refineries
Uses fluidized catalytic beds at
high temperatures
Produces gasoline, LPG and
other light products
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8. Equipment & Infrastructure
Common Process Equipment
Reactors
Hydrocracking, Catalytic Reforming
units that convert feedstocks into
desired products
Columns
Distillation, Absorption units that
separate different components
based on boiling points
Heat Exchangers
Transfer heat between fluids to
optimize energy usage and control
process temperatures
Compressors
Compress gases for various
processes and maintain system
pressure requirements
Storage Tanks
Store finished products,
intermediates, and raw materials in
specialized vessels
Furnaces & Heaters
Provide heat energy required for
distillation, cracking, and other
thermal processes
Pumps & Valves
Transport fluids throughout the
refinery and control flow rates and
directions
Control Systems
Monitor and regulate process
parameters like temperature,
pressure, and flow rates
Support Facilities
Utilities
Steam generation for distillation, cracking, and heat
transfer
Cooling water systems for condensers and heat
exchangers
Electricity for pumps, compressors, and control
systems
Nitrogen supply for purging and inerting operations
Emission Control Infrastructure
Flares and emission stacks for controlled waste gas
disposal
Scrubbers and filters to reduce air pollution
Continuous Emission Monitoring Systems (CEMS)
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9. Emission Sources & Types
Refinery Emission Sources
Oil refineries emit various pollutants during operations. These emissions are
categorized based on their source points and characteristics, each requiring specific
monitoring and control measures.
Emission Source Categories
Combustion Stacks
Boilers, Heaters, Furnaces: These devices burn fuel to generate heat for the refinery,
producing emissions primarily from fuel combustion.
Process Stacks
Distillation Units, Reactors, Hydrotreaters, FCC Units: Emissions arise from the
separation or chemical reactions involved in these processes.
Fugitive Emissions
Crushing, Packing, Equipment Leaks: Emissions occur due to leaks from valves, pumps,
and other equipment in the refinery infrastructure.
Types of Emissions
SOx (Sulfur
Oxides)
From combustion
processes of sulfur-
containing fuels
NOx (Nitrogen
Oxides)
From combustion and
high-temperature
processes
CO (Carbon
Monoxide)
Emitted during
incomplete
combustion
PM (Particulate
Matter)
From combustion and
chemical processes
VOC (Volatile
Organic
Compounds)
From fugitive
emissions, distillation,
and loading
Fuel Types Used in Refineries
Natural Gas: Primary fuel for combustion processes
Fuel Oil: Used in furnaces and heaters
Coal: Less common, used in specific processes
LPG: Alternative fuel for various units
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10. CEMS (Continuous Emission Monitoring System) Technology
What is CEMS?
CEMS (Continuous Emission Monitoring System) is the integrated system used to
measure flow, dust, concentration of air pollutants, and other parameters in industrial
exhaust gases. It's a critical technology for environmental compliance, providing real-
time data for regulatory reporting and process optimization.
CEMS Types
Extractive CEMS
Samples flue gases from
emission stacks and
analyzes them in a
laboratory-style system.
Technologies: NDIR (Non-
Dispersive Infrared), UV
Fluorescence,
Electrochemical Sensors
In-Situ CEMS
Measures gases directly in
the stack without
sampling, providing real-
time measurement.
Technologies: DOAS
(Differential Optical
Absorption), Tunable Diode
Laser, FTIR
Dilution-Based
CEMS
Gases are diluted before
analysis, often used for
higher-volume emissions
and complex gas mixtures.
Technologies: Dilution
probes, Multi-gas
analyzers, Heated sample
lines
Measurable Parameters
SO₂ (Sulfur Dioxide) NOx (Nitrogen Oxides) CO (Carbon Monoxide)
CO₂ (Carbon Dioxide) O₂ (Oxygen) PM (Particulate Matter)
Temperature Flow Rate
Technology Providers
E Emerson A ABB
S Siemens H Horiba
T
Thermo Fisher
Scientific
F Fuji Electric
Data Transmission & Validation
CEMS data is transmitted to regulatory bodies such as
the Central Pollution Control Board (CPCB) or State
Pollution Control Boards (SPCB) via secure data links.
The data undergoes validation using standard
reference methods and is integrated into
environmental monitoring portals for compliance
verification and reporting.
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11. Environmental Compliance Standards
Regulatory Overview
Oil refineries in India must comply with strict
environmental standards set by the Central Pollution
Control Board (CPCB) and state-level authorities like
Gujarat Pollution Control Board (GPCB). These
regulations enforce specific thresholds for emissions
to control air pollution.
Pollution Control Technologies
Scrubbers
Remove SO₂ and particulate matter from flue gases
Catalytic Converters
Reduce NOx emissions through chemical reactions
CEMS Implementation
Required for continuous monitoring and reporting
Note: Refineries must implement pollution control
technologies and use CEMS to ensure they meet regulatory
requirements. Data must be transmitted to CPCB/SPCB via
secure data links.
Emission Standards Comparison
Pollutant Fuel Type CPCB Limit (mg/Nm³) GPCB Limit
SO₂ Gas 50 50
SO₂ Liquid 850-1700 850
NOx Gas 250-350 150 ppm @15% O₂
NOx Liquid 350-450 150 ppm @15% O₂
CO All types 150 100
PM All types 50 50
Compliance Documentation
CPCB comprehensive industry document on refineries (1980s)
CPCB 2008 emission limits for refineries
Effluent discharge norms & load-based standards
CPCB directions for Oil Refineries and OCEMS
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12. Summary & Key Takeaways
Key Takeaways
Refinery Process Flow
The 10-step process from crude intake to final products forms the
backbone of refinery operations, with distillation being the critical
primary separation process.
Key Process Units
CDU, VDU, Hydrocracker, and FCC units are fundamental to
converting heavy crude fractions into valuable lighter products
through specialized processes.
Equipment & Infrastructure
Refineries rely on specialized equipment including reactors,
columns, heat exchangers, and compressors, all arranged in a
strategic plant layout for optimal process flow.
Emissions Management
Refineries monitor and control SOx, NOx, CO, PM, and VOCs from
various emission sources using advanced CEMS technologies and
environmental controls.
Prepare for Q&A
Production Efficiency Environmental Impact Compliance Standards Process Technology Equipment Reliability
Emission Control Monitoring Systems Future Trends
Modern oil refineries balance efficient production processes with stringent environmental controls to meet global energy demands while
minimizing environmental impact.
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