Proxanil msds

PROXANIL
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
Date of issue: 5/18/2010 Revision date: 6/15/2016 Supersedes: 3/2/2016 Version: 13.4
6/20/2016 EN (English) 1/10
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Product form : Mixture
Trade name : PROXANIL
Product code : CA701724
Synonyms : Propamocarb 400 g/L + Cymoxanil 50 g/L SC
1.2. Relevant identified uses of the substance or mixture and uses advised against
1.2.1. Relevant identified uses
Main use category : Professional use
Industrial/Professional use spec : Pesticide
Agriculture
Use of the substance/mixture : Fungicide
1.2.2. Uses advised against
No additional information available
1.3. Details of the supplier of the safety data sheet
Arysta LifeScience Benelux
Rue de Renory 26/1
B-4102 Ougrée - Belgium
T +32 (0)4 385 97 11 - F +32 (0)4 385 97 49
sdsin@arysta.com - http://www.arystalifescience.com
1.4. Emergency telephone number
Emergency number : Europe/Rest of the world (English): +44(0)1235 239670
112 (European Emergency Number)
USA: +1 215 207 0061 or 001866 928 0789
Australia: +61 2801 44558
People's Republic of China: + 86 10 5100 3039
New Zealand: +64 9929 1483
Country Organisation/Company Address Emergency number Comment
WHO http://www.who.int/gho/phe/chemical_saf
ety/poisons_centres/en/index.html
United Kingdom National Poisons Information
Service (Belfast Centre)
Royal Victoria Hospital
Grosvenor Road
BT12 6BA Belfast
0844 892 0111 (UK
only, Monday to Friday,
08.00 to 18.00 hours)
Service (Birmingham Centre)
City Hospital, Guy's & St Thomas'
Hospital Trust
Dudley Road
B18 7QH Birmingham
0844 892 0111 (UK
08.00 to 18.00 hours)
Service (Cardiff Centre)
Gwenwyn Ward, Wolfson Unit
Penarth
CF64 2XX Cardiff
0844 892 0111 (UK
08.00 to 18.00 hours)
United Kingdom NPIS Edinburgh (Scottish
Poisons Information Bureau)
Royal Infirmary of Edinburgh, Centre
Hospitalier Universitaire Bab el Oued
51 Little France Crescent
EH16 4SA Edinburgh
0844 892 0111 (UK
08.00 to 18.00 hours)
United Kingdom Guy's & St Thomas' Poisons
Unit
Medical Toxicology Unit, Centre
Hospitalier Universitaire de Constantine
Avonley Road
SE14 5ER London
0870 243 2241
Service (Newcastle Centre)
Regional Drugs and Therapeutics Centre
Claremont Place
Newcastle-upon-Tyne
NE1 4LP Newcastle
0844 892 0111 (UK
08.00 to 18.00 hours)
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]Mixture/Substance: SDS EU 2015: According to Regulation (EU) 2015/830
(REACH Annex II)
Corrosive to metals,
Category 1
H290 On basis of test data
Sensitisation — Skin,
Category 1
H317 Expert judgment

PROXANIL
Safety Data Sheet
6/20/2016 EN (English) 2/10
Reproductive toxicity,
Category 2
H361fd Expert judgment
Hazardous to the aquatic
environment — Chronic
Hazard, Category 2
H411 Calculation method
Full text of H statements : see section 16
Adverse physicochemical, human health and environmental effects
2.2. Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayExtra classification(s) to display
Hazard pictograms (CLP) :
GHS05 GHS07 GHS08 GHS09
CLP Signal word : Warning
Hazard statements (CLP) : H290 - May be corrosive to metals
H317 - May cause an allergic skin reaction
H361fd - Suspected of damaging fertility. Suspected of damaging the unborn child
H411 - Toxic to aquatic life with long lasting effects
Precautionary statements (CLP) : P201 - Obtain special instructions before use
P234 - Keep only in original container
P261 - Avoid breathing dust, fume, gas, mist, spray, vapours
P280 - Wear protective gloves, eye protection
P302+P352 - IF ON SKIN: Wash with plenty of soap and water
P308+P313 - IF exposed or concerned: Get medical advice/attention
P333+P313 - If skin irritation or rash occurs: Get medical advice/attention
P391 - Collect spillage
P501 - Dispose of contents/container to an authorised waste collection point
EUH-statements : EUH401 - To avoid risks to human health and the environment, comply with the instructions for
use
Extra phrases : SP 1 Do not contaminate water with the product or its container (Do not clean application
equipment near surface water/Avoid contamination via drains from farmyards and roads)
2.3. Other hazards
SECTION 3: Composition/information on ingredients
3.1. Substance
Not applicable
3.2. Mixture
Name Product identifier % Classification according to
Regulation (EC) No.
1272/2008 [CLP]
Propamocarb HCl (CAS No) 25606-41-1
(EC no) 247-125-9
38 - 41.1 Skin Sens. 1, H317
cymoxanil (ISO); 2-cyano-N-[(ethylamino)carbonyl]-2-
(methoxyimino)acetamide
(CAS No) 57966-95-7
(EC no) 261-043-0
(EC index no) 616-035-00-5
4 - 5 Acute Tox. 4 (Oral), H302
Skin Sens. 1, H317
Repr. 2, H361fd
STOT RE 2, H373
Aquatic Acute 1, H400
Aquatic Chronic 1, H410
CITRIC ACID (CAS No) 77-92-9
(EC no) 201-069-1
(REACH-no) 01-2119457026-42
4.98 Eye Irrit. 2, H319
PROPYLENE GLYCOL
substance with national workplace exposure limit(s) (GB, LT, LV)
(CAS No) 57-55-6
(EC no) 200-338-0
(REACH-no) 01-2119456809-23
1.11 Not classified
Full text of H-statements: see section 16

PROXANIL
Safety Data Sheet
6/20/2016 EN (English) 3/10
SECTION 4: First aid measures
4.1. Description of first aid measures
First-aid measures general : If medical advice is needed, have product container or label at hand.
First-aid measures after inhalation : IF INHALED: if breathing is difficult, remove victim to fresh air and keep at rest in a position
comfortable for breathing. If breathing is difficult, give oxygen. If breathing stops, give artificial
respiration. In all cases of doubt, or when symptoms persist, seek medical attention.
First-aid measures after skin contact : After contact with skin, take off immediately all contaminated clothing, and wash immediately
with plenty of water and soap. If skin irritation occurs: Get medical advice/attention.
First-aid measures after eye contact : Rinse immediately with plenty of water, also under the eyelids. Remove contact lenses, if
present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice and
attention.
First-aid measures after ingestion : If swallowed, rinse mouth with water (only if the person is conscious). Do not induce vomiting.
Get immediate medical advice and attention.
4.2. Most important symptoms and effects, both acute and delayed
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media : AFFF foam. dry chemical powder. Carbon dioxide (CO2). Water fog.
Unsuitable extinguishing media : High volume water jet.
5.2. Special hazards arising from the substance or mixture
Fire hazard : Non flammable.
5.3. Advice for firefighters
Precautionary measures fire : No open flames. No smoking.
Firefighting instructions : Evacuate and limit access. Use a water spray to cool exposed surfaces and to protect fire-
fighters.
Protection during firefighting : Wear suitable protective clothing. In case of inadequate ventilation wear respiratory protection.
Other information : Do not allow run-off from fire fighting to enter drains or water courses.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
General measures : Clean up even minor leaks or spills, if possible, without unnecessary risk.
6.1.1. For non-emergency personnel
Protective equipment : Wear suitable protective clothing, gloves and eye or face protection. In case of insufficient
ventilation, wear suitable respiratory equipment.
Emergency procedures : Evacuate the danger area. Provide adequate ventilation to minimize dust and/or vapour
concentrations. Consult an expert. Eliminate every possible source of ignition.
6.1.2. For emergency responders
Protective equipment : Wear self-contained breathing apparatus, rubber boots and thick rubber gloves.
6.2. Environmental precautions
Do not empty into drains, dispose of this material and its container at hazardous or special waste collection point. Notify authorities if product enters
sewers or public waters.
6.3. Methods and material for containment and cleaning up
For containment : Prevent liquid from entering sewers, watercourses, underground or low areas. Impound and
recover large spill by mixing it with inert granular solids.
Methods for cleaning up : Clean up any spills as soon as possible, using an absorbent material to collect it.
Other information : Avoid spilling the product, as this might cause falls.
6.4. Reference to other sections
Exposure controls/personal protection. Disposal considerations.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Precautions for safe handling : Handle in accordance with good industrial hygiene and safety procedures. Keep away from
heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Do not allow to
enter into surface water or drains.
Handling temperature : Store at room temperature

PROXANIL
Safety Data Sheet
6/20/2016 EN (English) 4/10
Hygiene measures : Do not eat, drink or smoke when using this product. Take off contaminated clothing and wash it
before reuse. Wash hands and other exposed areas with mild soap and water before eating,
drinking or smoking and when leaving work.
7.2. Conditions for safe storage, including any incompatibilities
Technical measures : Ground well. Use explosion-proof equipment.
Storage conditions : Keep out of direct sunlight.
Incompatible products : Strong acids. Strong bases. Strong oxidizing agents.
Storage temperature : Protect from freezing
Storage area : Keep container tightly closed and in well ventilated place. Install a retention tank.
Packaging materials : Keep only in the original container. Keep locked up and out of reach of children.
7.3. Specific end use(s)
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
PROPYLENE GLYCOL (57-55-6)
United Kingdom Local name Propane-1,2-diol
United Kingdom WEL TWA (mg/m³) 10 mg/m³ particulates
474 mg/m³ total vapour and particulates
United Kingdom WEL TWA (ppm) 150 ppm total vapour and particulates
8.2. Exposure controls
Personal protective equipment : Gloves. Gas mask. Safety glasses.
Hand protection : Wear suitable gloves resistant to chemical penetration. Nitrile rubber gloves. Wear suitable
gloves resistant to chemical penetration
Eye protection : Face shield. Chemical goggles or safety glasses
Skin and body protection : Skin protection appropriate to the conditions of use should be provided
Respiratory protection : In case of inadequate ventilation wear respiratory protection
Environmental exposure controls : Notify authorities if product enters sewers or public waters.
Other information : Emergency eye wash fountains and safety showers should be available in the immediate
vicinity of any potential exposure.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state : Liquid
Appearance : Viscous. Opaque.
Colour : Grey.
Odour : characteristic.
Odour threshold : No data available
pH : 2.27
Relative evaporation rate (butylacetate=1) : No data available
Melting point : No data available
Freezing point : No data available
Boiling point : 103 °C
Flash point : > 103 °C
Auto-ignition temperature : No data available
Decomposition temperature : > 430 °C
Flammability (solid, gas) : No data available
Vapour pressure : No data available
Relative vapour density at 20 °C : No data available

PROXANIL
Safety Data Sheet
6/20/2016 EN (English) 5/10
Relative density : No data available
Density : 1.085 g/ml (20°C)
Solubility : No data available
Log Pow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : 900 cP
Explosive properties : Product is not explosive.
Oxidising properties : No data available
Explosive limits : No data available
9.2. Other information
SECTION 10: Stability and reactivity
10.1. Reactivity
When exposed to heat, may decompose liberating hazardous gases.
10.2. Chemical stability
Stable under normal conditions of use.
10.3. Possibility of hazardous reactions
None under normal conditions. For further information, refer to section 10 : "Stability and Reactivity".
10.4. Conditions to avoid
Keep out of direct sunlight. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
10.5. Incompatible materials
Strong acids. Strong bases. Strong oxidizing agents.
10.6. Hazardous decomposition products
When heated to decomposition, emits dangerous fumes. Carbon dioxide (CO2). Carbon monoxide. Nitrogen oxides.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute toxicity : Not classified
PROXANIL
LD50 oral rat > 2000 mg/kg
LD50 dermal rat > 4000 mg/kg
LC50 inhalation rat (mg/l) > 5 mg/l/4h
LD50 dermal rabbit > 2000 mg/kg
Propamocarb HCl (25606-41-1)
LC50 inhalation rat (mg/l) > 5 mg/l/4h
CITRIC ACID (77-92-9)
LD50 oral rat 11700 mg/kg
LD50 dermal rabbit > 2000 mg/kg
cymoxanil (ISO); 2-cyano-N-[(ethylamino)carbonyl]-2-(methoxyimino)acetamide (57966-95-7)
LD50 oral rat 960 mg/kg
LC50 inhalation rat (mg/l) > 5.6 mg/l/4h
Skin corrosion/irritation : Not classified
pH: 2.27
Serious eye damage/irritation : Not classified
pH: 2.27
Respiratory or skin sensitisation : May cause an allergic skin reaction.
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
Reproductive toxicity : Suspected of damaging fertility. Suspected of damaging the unborn child.

PROXANIL
Safety Data Sheet
6/20/2016 EN (English) 6/10
Specific target organ toxicity (single exposure) : Not classified
Specific target organ toxicity (repeated
exposure)
: Not classified
Aspiration hazard : Not classified
PROXANIL
Viscosity, kinematic 829.49308756 mm²/s
SECTION 12: Ecological information
12.1. Toxicity
PROXANIL
LC50 fish 1 1000 mg/l (96h Cyprinus carpio)
EC50 Daphnia 1 590 mg/l (48h Daphnia magna)
ErC50 (algae) 190 mg/l (72h Selenastrum capricornutum)
LC50 fish 1 > 100 mg/l
EC50 Daphnia 1 > 100 mg/l
ErC50 (algae) > 100 mg/l
LC50 fish 1 > 92 mg/l (96h Lepomis macrochirus)
EC50 Daphnia 1 > 100 mg/l (48h Daphnia magna)
ErC50 (algae) > 85 mg/l (72h Pseudokirchneriella subcapitata)
NOEC chronic fish 6.3 mg/l (32d Pimephales promelas)
NOEC chronic crustacea 12.3 mg/l (21d Daphnia magna)
EbC50, Lemna gibba, Chronic > 18 mg/l (14 days)
LC50 fish 1 440 - 706 mg/l (96h)
LC50 fish 1 61 mg/l (96h Salmo gairdneri)
LC50 fish 2 29 mg/l (96h Lepomis macrochirus)
EC50 Daphnia 1 27 mg/l (48h Daphnia magna)
ErC50 (algae) 0.122 mg/l (Anabaena flos-aquae)
ErC50 (other aquatic plants) 0.7 mg/l (14d Lemna Gibba)
NOEC chronic crustacea 0.067 mg/l (21d Daphnia magna)
12.2. Persistence and degradability
Biochemical oxygen demand (BOD) 0.86 g O₂/g substance BOD5
Chemical oxygen demand (COD) 1.585 g O₂/g substance
Persistence and degradability Readily biodegradable.
Persistence and degradability Biodegradable.
Chemical oxygen demand (COD) 665 g O₂/g substance
Persistence and degradability Not readily biodegradable.
12.3. Bioaccumulative potential
Log Pow -1
BCF fish 1 3.2 - 4.7 mg/g
Log Pow -1.36
Bioaccumulative potential There is no bioaccumulation.
Log Pow 0.67 (pH=7; 20°C)

PROXANIL
Safety Data Sheet
6/20/2016 EN (English) 7/10
12.4. Mobility in soil
PROXANIL
Surface tension 28.4 mN/m (EEC A5)
Surface tension 68.7 mN/m (19°C)
12.5. Results of PBT and vPvB assessment
12.6. Other adverse effects
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Regional legislation (waste) : Disposal must be done according to official regulations.
Waste treatment methods : Do not empty into drains, dispose of this material and its container at hazardous or special
waste collection point.
Additional information : Do not contaminate water with the product or its container. Do not clean application equipment
near surface water. Notify authorities if product enters sewers or public waters.
SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN
ADR IMDG IATA ADN RID
14.1. UN number
3265 3265 3265 3265 3265
14.2. UN proper shipping name
CORROSIVE LIQUID,
ACIDIC, ORGANIC,
N.O.S. (Propamocarb HCl)
CORROSIVE LIQUID,
ACIDIC, ORGANIC,
Corrosive liquid, acidic,
organic, n.o.s.
(Propamocarb HCl)
CORROSIVE LIQUID,
ACIDIC, ORGANIC,
CORROSIVE LIQUID,
ACIDIC, ORGANIC,
Transport document description
UN 3265 CORROSIVE
LIQUID, ACIDIC,
ORGANIC, N.O.S.
(Propamocarb HCl), 8, III,
(E), ENVIRONMENTALLY
HAZARDOUS
UN 3265 CORROSIVE
LIQUID, ACIDIC,
ORGANIC, N.O.S.
MARINE
POLLUTANT/ENVIRONM
ENTALLY HAZARDOUS
UN 3265 Corrosive liquid,
acidic, organic, n.o.s.
ENVIRONMENTALLY
HAZARDOUS
UN 3265 CORROSIVE
LIQUID, ACIDIC,
ORGANIC, N.O.S.
ENVIRONMENTALLY
HAZARDOUS
UN 3265 CORROSIVE
LIQUID, ACIDIC,
ORGANIC, N.O.S.
ENVIRONMENTALLY
HAZARDOUS
14.3. Transport hazard class(es)
8 8 8 8 8
14.4. Packing group
III III III III III
14.5. Environmental hazards
Dangerous for the
environment : Yes
Dangerous for the
environment : Yes
Marine pollutant : Yes
Dangerous for the
environment : Yes
Dangerous for the
environment : Yes
Dangerous for the
environment : Yes
No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : C3
Special provisions (ADR) : 274
Limited quantities (ADR) : 5l
Excepted quantities (ADR) : E1
Packing instructions (ADR) : P001, IBC03, LP01, R001
Mixed packing provisions (ADR) : MP19
Portable tank and bulk container instructions
(ADR)
: T7
Portable tank and bulk container special
provisions (ADR)
: TP1, TP28

PROXANIL
Safety Data Sheet
6/20/2016 EN (English) 8/10
Tank code (ADR) : L4BN
Vehicle for tank carriage : AT
Transport category (ADR) : 3
Special provisions for carriage - Packages
(ADR)
: V12
Hazard identification number (Kemler No.) : 80
Orange plates :
Tunnel restriction code : E
EAC code : 2X
APP code : B
- Transport by sea
Transport regulations (IMDG) : Not subject
Special provisions (IMDG) : 223, 274
Limited quantities (IMDG) : 5 L
Excepted quantities (IMDG) : E1
Packing instructions (IMDG) : P001, LP01
IBC packing instructions (IMDG) : IBC03
Tank instructions (IMDG) : T7
Tank special provisions (IMDG) : TP1, TP28
EmS-No. (Fire) : F-A
EmS-No. (Spillage) : S-B
Stowage category (IMDG) : A
Stowage and handling (IMDG) : SW2
- Air transport
Transport regulations (IATA) : Not subject
PCA Excepted quantities (IATA) : E1
PCA Limited quantities (IATA) : Y841
PCA limited quantity max net quantity (IATA) : 1L
PCA packing instructions (IATA) : 852
PCA max net quantity (IATA) : 5L
CAO packing instructions (IATA) : 856
CAO max net quantity (IATA) : 60L
Special provisions (IATA) : A3
ERG code (IATA) : 8L
- Inland waterway transport
Classification code (ADN) : C3
Special provisions (ADN) : 274
Limited quantities (ADN) : 5 L
Excepted quantities (ADN) : E1
Carriage permitted (ADN) : T
Equipment required (ADN) : PP, EP
Number of blue cones/lights (ADN) : 0
- Rail transport
Classification code (RID) : C3
Special provisions (RID) : 274
Limited quantities (RID) : 5L
Excepted quantities (RID) : E1
Packing instructions (RID) : P001, IBC03, LP01, R001
Mixed packing provisions (RID) : MP19
Portable tank and bulk container instructions
(RID)
: T7
Portable tank and bulk container special
provisions (RID)
: TP1, TP28

PROXANIL
Safety Data Sheet
6/20/2016 EN (English) 9/10
Tank codes for RID tanks (RID) : L4BN
Transport category (RID) : 3
Special provisions for carriage – Packages
(RID)
: W12
Colis express (express parcels) (RID) : CE8
Hazard identification number (RID) : 80
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1. EU-Regulations
The following restrictions are applicable according to Annex XVII of the REACH Regulation (EC) No 1907/2006:
3. Liquid substances or mixtures which are regarded as dangerous in
accordance with Directive 1999/45/EC or are fulfilling the criteria for any
of the following hazard classes or categories set out in Annex I to
Regulation (EC) No 1272/2008
PROXANIL - cymoxanil (ISO); 2-cyano-N-[(ethylamino)carbonyl]-2-
3.b. Substances or mixtures fulfilling the criteria for any of the following
hazard classes or categories set out in Annex I to Regulation (EC) No
1272/2008: Hazard classes 3.1 to 3.6, 3.7 adverse effects on sexual
function and fertility or on development, 3.8 effects other than narcotic
effects, 3.9 and 3.10
3.c. Substances or mixtures fulfilling the criteria for any of the following
hazard classes or categories set out in Annex I to Regulation (EC) No
1272/2008: Hazard class 4.1
Contains no substance on the REACH candidate list
Contains no REACH Annex XIV substances
15.1.2. National regulations
15.2. Chemical safety assessment
SECTION 16: Other information
Indication of changes:
Revision date Modified
Supersedes Modified
7.2 Maximum storage
period
Removed
Full text of H- and EUH-statements:
Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4
Aquatic Acute 1 Hazardous to the aquatic environment — Acute Hazard, Category 1
Aquatic Chronic 1 Hazardous to the aquatic environment — Chronic Hazard, Category 1
Eye Irrit. 2 Serious eye damage/eye irritation, Category 2
Repr. 2 Reproductive toxicity, Category 2
Skin Sens. 1 Sensitisation — Skin, Category 1
STOT RE 2 Specific target organ toxicity — Repeated exposure, Category 2
H290 May be corrosive to metals
H302 Harmful if swallowed
H317 May cause an allergic skin reaction
H319 Causes serious eye irritation
H361fd Suspected of damaging fertility. Suspected of damaging the unborn child
H373 May cause damage to organs through prolonged or repeated exposure
H400 Very toxic to aquatic life
H410 Very toxic to aquatic life with long lasting effects
H411 Toxic to aquatic life with long lasting effects
EUH401 To avoid risks to human health and the environment, comply with the instructions for use
Classification and procedure used to derive the classification for mixtures according to Regulation (EC) 1272/2008 [CLP]:
Met. Corr. 1 H290 On basis of test data

PROXANIL
Safety Data Sheet
6/20/2016 EN (English) 10/10
Skin Sens. 1 H317 Expert judgment
Repr. 2 H361fd Expert judgment
Aquatic Chronic 2 H411 Calculation method
SDS EU (REACH Annex II)
This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be
construed as guaranteeing any specific property of the product

Proxanil msds

More Related Content

What's hot (9)

Viewers also liked (20)

Similar to Proxanil msds (20)

Recently uploaded (20)

Proxanil msds