SlideShare a Scribd company logo
Process Safety Management
of Highly
Hazardous Chemicals
Nancy J Bethea
Process Safety Management
(PSM)
Is the proactive identification,
evaluation and mitigation or prevention
of chemical releases that could occur
as a result of failures in processes,
procedures, or equipment.
Purpose
• Prevent Catastrophic Releases of
Highly Hazardous Chemicals
• Minimize Consequences of Such
Releases to Employees and the
Community
PSMtalk (1).ppt
Catastrophic Events
Deaths Injuries
• 1984 Mexico City 650 --
• 1984 Bhopal, India 2500 --
• 1984 Chicago area 17 17
• 1985 West Virginia -- 135
• 1988 New Orleans 5 23
• 1988 Henderson, NV 2 350
Catastrophic Events
Deaths Injuries
• 1989 Pasadena, TX 23 130
• 1990 Houston, TX 17 --
• 1990 Cincinnati, OH 2 72
• 1991 Lake Charles, LA 5 --
• 1991 Sterlington, LA 8 120
• 1991 Charleston, SC 6 33
• 1991 Seadrift, TX 1 32
Process Safety Management
Bhopal (’84): focused OSHA’s attention
Institute, WV(’85): shows disasters can
happen here
1988-1991: concern of public & Congress
increases with each event
Feb. 24, 1992: standard in Federal Register
29 CFR 1910.119
OSHA’s Process Safety
Management Standard
Anticipated Benefits
OSHA estimated that the integrated
approach of the PSM standard would reduce
the average annual number of deaths (265)
by 200 and reduce the average annual
number of serious injuries (900) by 700 in
industries involved with highly hazardous
chemicals.
Resources
• European Economic Community (EEC)
• World Bank
• International Labor Office (ILO)
• U.S. Environmental Protection Agency
• Superfund Amendments and
Reauthorization Act (SARA)
• States, Industry, & Labor Organizations
PSM Standard
Performance
NOT
Specification Standard
PSM Standard
• Process Safety Information
• Process Hazard Analysis
• Operating Procedures
• Training
• Contractors
• Pre-startup Safety Review
PSM Standard
• Mechanical Integrity
• Hot-work Permits
• Management of Change
• Incident Investigations
• Emergency Planning & Response
• Compliance Safety Audits
What’s Covered
• Listed Chemicals in Appendix A
• > 10,000 pounds of Flammable
Liquids or Gases
Examples of Covered Chemicals
Acetaldehyde Chlorine
Nitromethane Ethylamine
Perchloric Acid Phosgene
Tetramethyl Lead Ketone
HF NO
What’s Not Covered
• HC fuels used only for workplace
consumption and if not a part of a covered
hazardous process
• Flammable liquids stored or transferred
below NBP w/o chilling or refrigeration
• Retail facilities
• Oil, gas well drilling, servicing
• Normally unmanned remote facilities
Process Safety Information:
Chemicals
• Toxicity
• PEL
• Physical Data
• Reactivity and Corrosivity
• Thermal and Chemical Stability
• Effects of Mixing Chemicals
Process Safety Information:
Process
• Block flow or process flow diagram
• Process chemistry
• Maximum intended inventory
Process Safety Information:
Process
• Safe upper/lower limits for such items
as temperatures, pressures, flows or
compositions
• Consequences of deviations, e.g.
runaway reaction potential
Process Safety Information:
Equipment
• Materials of construction
• P&IDs
• Electrical Classification
• Relief system design & design
basis
Process Safety Information:
Equipment
• Ventilation system design
• Design codes and standards
• Material & energy balances
• Safety systems
Process Hazard Analysis
Organized and systematic effort to
identify and analyze the significance of
potential hazards associated with the
processing or handling of highly
hazardous chemicals
Process Hazard Analysis
• Causes/consequences of fires &
explosions
• Releases of toxic or flammable
chemicals
• Major spills of hazardous chemicals
• Methodology depends on the process
& its characteristics
PHA Focuses On
• Equipment
• Instrumentation
• Utilities
• Human Actions
• External Factors
Process Hazard Analysis
• What If?
• Checklist
• What If?/Checklist
• Hazard & Operability Study (HAZOP)
• Failure Mode & Effects Analysis (FMEA)
• Fault Tree Analysis (FTA)
PHA Must Address
• Hazards of the process
• Engineering & administrative
controls
• Consequences of failure of controls
• Facility siting
PHA Must Address
• Human factors
• Evaluate potential effects to on-site
personnel from failure of controls
• Identification of previous incidents
PHA Team
• Expertise in engineering & process
operations
• One member to have knowledge of &
experience with process being
evaluated
PHA Team
• One member knowledgeable in
specific PHA methodology used for
evaluating the process
• Other members with specific
knowledge: instrumentation,
chemistry, etc.
Employer PHA Actions
• Establish system for prompt response
• Ensure timely resolution of findings &
recommendations
• Document actions taken
Employer PHA Actions
• Develop written schedule for
completions
• Complete actions ASAP
• Communicate actions to affected
employees
Operating Procedures
• Provide clear instructions for safely
conducting activities involved in each
covered process consistent with the
process safety information
• Address at least the listed elements
Operating Procedures:
Steps for Each Operating Phase
• Initial startup, operation, shutdown
• Temporary & emergency operations,
emergency shutdown
• Startup following shutdowns
Operating Procedures:
Operating limits
• consequences of deviations
• prevention of deviations
Operating Procedures:
Safety & Health Considerations
• Chemical properties and hazards
• Precautions to prevent exposure
• Control measures if contact or
airborne exposure occurs
Operating Procedures:
Safety & Health Considerations
• Quality controls for raw materials
• Control of hazardous chemical
inventories
• Special or unique hazards
• Safety systems & their functions
Operating Procedures
• Operating procedures readily
accessible
• Reviewed as necessary to reflect
current procedures and changes
• Certified annually as current &
accurate
Operating Procedures
• Develop & implement safe work
practices to provide for the control
of hazards during operations, e.g.
lockout/tagout/ confined space
entry, opening equipment & pipes,
facility entry
• Apply to employees & contractor
employees
Training
• Process overview
• Process hazards
• Operating procedures
• Emergency procedures
• Refresher training at least every 3 yrs
• Documentation
Employer Responsibilities
• Evaluate contractor’s safety
performance & programs
• Inform contractor of potential hazards:
fire, explosion, toxic release,
applicable plant safety rules
• Develop/Implement safe work
practices
• Evaluate contractor performance
Contractor Responsibilities
• Advise employer of any unique work
hazards of contracted work
• Each employee follow all applicable
work practices & safety rules of the
facility
• Ensure each employee is trained in
necessary work practices
Contractor Responsibilities
• Ensure each employee is instructed in
known fire, explosion, or toxic release
problems related to his/her job
• Document that understanding of
training has been evaluated, verified
Pre-startup Safety Review
Done when:
• New processes
• Modified process
Pre-startup Review Verifies
• Construction: conforms to design
• Procedures: adequate, in place
• PHA recommendations resolved or
implemented
• Management of change requirements
met
• All affected workers trained
PSM Mechanical Integrity
• Pressure vessels, storage tanks
• Piping systems, components
• Relief & vent systems, devices
• Emergency shutdown systems
• Controls: monitoring devices,
sensors, alarms, interlocks
• Pumps
Mechanical Integrity
• Written procedures
• Training: process hazards, job tasks
• Inspections
• Testing
• Corrective action
• Records
Hot Work Permits
• Welding, cutting, brazing
• Control of ignition sources
• Verify safe conditions
• Authorization
Management of Change
• Establish written procedures
• Develop management support
• Evaluate safety of any changes to:
process chemicals facility
technology equipment
MOC Procedures Must Address
• Everything except “replacement in kind”
• Temporary as well as permanent
changes
• Technical basis for change
• Safety & health effects
MOC Procedures Must Address
• Modified operation procedures
• Time necessary for change
• Authorization for change
• Ways to inform & train workers before
change
Incident Investigation Goals
Identify incident causes and implement
steps to prevent reoccurence
Incident Investigation
• Every incident
• Prompt investigation
• Knowledgeable team
• Documentation & report
• Recommendations & findings
• Resolutions & corrective actions
Emergency Planning & Response
• Develop Emergency Action Plans
• Pre-plan for catastrophe
• Train & equip workers
• Drills
Compliance Safety Audits
• Certify all elements of standard
• Knowledgeable audit team
• Report & recommendations
• Address all finding & recommendations
• Conduct every three years
Appendices
A: List of chemicals
B: Sample block & flow diagrams
C: Compliance guidelines
D: References

More Related Content

PPTX
Seminar- Process Safety Management_.pptx
PDF
Process Safety Management
PPT
Process pengenalan system technology sebagai dasar engineering.ppt
DOC
ROBERT RESUME
PDF
ISO 17025 – technical requirements
PPT
QUALIFICATION-VALIDATION-_-Khadijah-Ade-Abolade.ppt
PPT
QUALIFICATION-VALIDATION-_-Khadijah-Ade-Abolade.ppt
PDF
The ISO 17025 standard: principles and management requirements
Seminar- Process Safety Management_.pptx
Process Safety Management
Process pengenalan system technology sebagai dasar engineering.ppt
ROBERT RESUME
ISO 17025 – technical requirements
QUALIFICATION-VALIDATION-_-Khadijah-Ade-Abolade.ppt
QUALIFICATION-VALIDATION-_-Khadijah-Ade-Abolade.ppt
The ISO 17025 standard: principles and management requirements

Similar to PSMtalk (1).ppt (20)

PDF
What Is Process Safety Engineering
PDF
Elements of Process Safety Management
PPTX
Qualification of analytical instruments
PDF
World Class Manufacturing:Plant Start Up and Commissioning Procedure
PPTX
Process hazard analysis 13,47
PPTX
Pharmaceutical Validation
PPTX
VALIDATION validation in pharmacy and its importance
PPTX
Different types of Lab control record
PPTX
laboratory management and their guidelines.pptx
PDF
2007-09-18-Isolation-Technology-JRickloff.pdf
PPSX
Operational Excellence in Oil and Gas Loss Prevention
PPT
Module_4_GCLP_LABORATORY_EQUIPMENT.ppt
PDF
BPS_HSE Services_2016
PPTX
modern paharmaceutics ich guidelives for .pptx
PPTX
0405process_instrumentation_and_control.pptx
PDF
IoT in Manufacturing: A Digital Transformation
PPTX
Unit 4.pptxghjyufdshulqwpvmyyjcukoifbghlonbx
PPT
Module_4_GCLP_LABORATORY_EQUIPMENT Copy 1
PPTX
Current Good Manufacturing Practices.pptx
PPTX
Technology Transfer and Scale-up in Pharmaceutical Industry
What Is Process Safety Engineering
Elements of Process Safety Management
Qualification of analytical instruments
World Class Manufacturing:Plant Start Up and Commissioning Procedure
Process hazard analysis 13,47
Pharmaceutical Validation
VALIDATION validation in pharmacy and its importance
Different types of Lab control record
laboratory management and their guidelines.pptx
2007-09-18-Isolation-Technology-JRickloff.pdf
Operational Excellence in Oil and Gas Loss Prevention
Module_4_GCLP_LABORATORY_EQUIPMENT.ppt
BPS_HSE Services_2016
modern paharmaceutics ich guidelives for .pptx
0405process_instrumentation_and_control.pptx
IoT in Manufacturing: A Digital Transformation
Unit 4.pptxghjyufdshulqwpvmyyjcukoifbghlonbx
Module_4_GCLP_LABORATORY_EQUIPMENT Copy 1
Current Good Manufacturing Practices.pptx
Technology Transfer and Scale-up in Pharmaceutical Industry
Ad

More from ssuser4f7e3f (6)

PDF
vivektraining-131212145311-phpapp01.pdf
PDF
hazardsriskandperils-141016041412-conversion-gate01.pdf
PPTX
CII Mumbai_Align F&IT_24-Sep-19.pptx
PDF
Concept of Risk.pdf
PPTX
2159_Unit III Risk Management- PART I.pptx
PDF
Manajemen _RM Padang_.pdf
vivektraining-131212145311-phpapp01.pdf
hazardsriskandperils-141016041412-conversion-gate01.pdf
CII Mumbai_Align F&IT_24-Sep-19.pptx
Concept of Risk.pdf
2159_Unit III Risk Management- PART I.pptx
Manajemen _RM Padang_.pdf
Ad

Recently uploaded (20)

PPTX
Safety Seminar civil to be ensured for safe working.
PPTX
Artificial Intelligence
PDF
BIO-INSPIRED HORMONAL MODULATION AND ADAPTIVE ORCHESTRATION IN S-AI-GPT
PPTX
Geodesy 1.pptx...............................................
PDF
PREDICTION OF DIABETES FROM ELECTRONIC HEALTH RECORDS
PPTX
Infosys Presentation by1.Riyan Bagwan 2.Samadhan Naiknavare 3.Gaurav Shinde 4...
PPT
Mechanical Engineering MATERIALS Selection
PDF
III.4.1.2_The_Space_Environment.p pdffdf
PPTX
Construction Project Organization Group 2.pptx
PDF
TFEC-4-2020-Design-Guide-for-Timber-Roof-Trusses.pdf
PDF
Evaluating the Democratization of the Turkish Armed Forces from a Normative P...
PPTX
UNIT 4 Total Quality Management .pptx
PDF
Human-AI Collaboration: Balancing Agentic AI and Autonomy in Hybrid Systems
PPTX
UNIT-1 - COAL BASED THERMAL POWER PLANTS
PDF
SM_6th-Sem__Cse_Internet-of-Things.pdf IOT
PPTX
CYBER-CRIMES AND SECURITY A guide to understanding
PDF
PPT on Performance Review to get promotions
PDF
Operating System & Kernel Study Guide-1 - converted.pdf
PDF
Unit I ESSENTIAL OF DIGITAL MARKETING.pdf
PPTX
CH1 Production IntroductoryConcepts.pptx
Safety Seminar civil to be ensured for safe working.
Artificial Intelligence
BIO-INSPIRED HORMONAL MODULATION AND ADAPTIVE ORCHESTRATION IN S-AI-GPT
Geodesy 1.pptx...............................................
PREDICTION OF DIABETES FROM ELECTRONIC HEALTH RECORDS
Infosys Presentation by1.Riyan Bagwan 2.Samadhan Naiknavare 3.Gaurav Shinde 4...
Mechanical Engineering MATERIALS Selection
III.4.1.2_The_Space_Environment.p pdffdf
Construction Project Organization Group 2.pptx
TFEC-4-2020-Design-Guide-for-Timber-Roof-Trusses.pdf
Evaluating the Democratization of the Turkish Armed Forces from a Normative P...
UNIT 4 Total Quality Management .pptx
Human-AI Collaboration: Balancing Agentic AI and Autonomy in Hybrid Systems
UNIT-1 - COAL BASED THERMAL POWER PLANTS
SM_6th-Sem__Cse_Internet-of-Things.pdf IOT
CYBER-CRIMES AND SECURITY A guide to understanding
PPT on Performance Review to get promotions
Operating System & Kernel Study Guide-1 - converted.pdf
Unit I ESSENTIAL OF DIGITAL MARKETING.pdf
CH1 Production IntroductoryConcepts.pptx

PSMtalk (1).ppt

  • 1. Process Safety Management of Highly Hazardous Chemicals Nancy J Bethea
  • 2. Process Safety Management (PSM) Is the proactive identification, evaluation and mitigation or prevention of chemical releases that could occur as a result of failures in processes, procedures, or equipment.
  • 3. Purpose • Prevent Catastrophic Releases of Highly Hazardous Chemicals • Minimize Consequences of Such Releases to Employees and the Community
  • 5. Catastrophic Events Deaths Injuries • 1984 Mexico City 650 -- • 1984 Bhopal, India 2500 -- • 1984 Chicago area 17 17 • 1985 West Virginia -- 135 • 1988 New Orleans 5 23 • 1988 Henderson, NV 2 350
  • 6. Catastrophic Events Deaths Injuries • 1989 Pasadena, TX 23 130 • 1990 Houston, TX 17 -- • 1990 Cincinnati, OH 2 72 • 1991 Lake Charles, LA 5 -- • 1991 Sterlington, LA 8 120 • 1991 Charleston, SC 6 33 • 1991 Seadrift, TX 1 32
  • 7. Process Safety Management Bhopal (’84): focused OSHA’s attention Institute, WV(’85): shows disasters can happen here 1988-1991: concern of public & Congress increases with each event Feb. 24, 1992: standard in Federal Register
  • 8. 29 CFR 1910.119 OSHA’s Process Safety Management Standard
  • 9. Anticipated Benefits OSHA estimated that the integrated approach of the PSM standard would reduce the average annual number of deaths (265) by 200 and reduce the average annual number of serious injuries (900) by 700 in industries involved with highly hazardous chemicals.
  • 10. Resources • European Economic Community (EEC) • World Bank • International Labor Office (ILO) • U.S. Environmental Protection Agency • Superfund Amendments and Reauthorization Act (SARA) • States, Industry, & Labor Organizations
  • 12. PSM Standard • Process Safety Information • Process Hazard Analysis • Operating Procedures • Training • Contractors • Pre-startup Safety Review
  • 13. PSM Standard • Mechanical Integrity • Hot-work Permits • Management of Change • Incident Investigations • Emergency Planning & Response • Compliance Safety Audits
  • 14. What’s Covered • Listed Chemicals in Appendix A • > 10,000 pounds of Flammable Liquids or Gases
  • 15. Examples of Covered Chemicals Acetaldehyde Chlorine Nitromethane Ethylamine Perchloric Acid Phosgene Tetramethyl Lead Ketone HF NO
  • 16. What’s Not Covered • HC fuels used only for workplace consumption and if not a part of a covered hazardous process • Flammable liquids stored or transferred below NBP w/o chilling or refrigeration • Retail facilities • Oil, gas well drilling, servicing • Normally unmanned remote facilities
  • 17. Process Safety Information: Chemicals • Toxicity • PEL • Physical Data • Reactivity and Corrosivity • Thermal and Chemical Stability • Effects of Mixing Chemicals
  • 18. Process Safety Information: Process • Block flow or process flow diagram • Process chemistry • Maximum intended inventory
  • 19. Process Safety Information: Process • Safe upper/lower limits for such items as temperatures, pressures, flows or compositions • Consequences of deviations, e.g. runaway reaction potential
  • 20. Process Safety Information: Equipment • Materials of construction • P&IDs • Electrical Classification • Relief system design & design basis
  • 21. Process Safety Information: Equipment • Ventilation system design • Design codes and standards • Material & energy balances • Safety systems
  • 22. Process Hazard Analysis Organized and systematic effort to identify and analyze the significance of potential hazards associated with the processing or handling of highly hazardous chemicals
  • 23. Process Hazard Analysis • Causes/consequences of fires & explosions • Releases of toxic or flammable chemicals • Major spills of hazardous chemicals • Methodology depends on the process & its characteristics
  • 24. PHA Focuses On • Equipment • Instrumentation • Utilities • Human Actions • External Factors
  • 25. Process Hazard Analysis • What If? • Checklist • What If?/Checklist • Hazard & Operability Study (HAZOP) • Failure Mode & Effects Analysis (FMEA) • Fault Tree Analysis (FTA)
  • 26. PHA Must Address • Hazards of the process • Engineering & administrative controls • Consequences of failure of controls • Facility siting
  • 27. PHA Must Address • Human factors • Evaluate potential effects to on-site personnel from failure of controls • Identification of previous incidents
  • 28. PHA Team • Expertise in engineering & process operations • One member to have knowledge of & experience with process being evaluated
  • 29. PHA Team • One member knowledgeable in specific PHA methodology used for evaluating the process • Other members with specific knowledge: instrumentation, chemistry, etc.
  • 30. Employer PHA Actions • Establish system for prompt response • Ensure timely resolution of findings & recommendations • Document actions taken
  • 31. Employer PHA Actions • Develop written schedule for completions • Complete actions ASAP • Communicate actions to affected employees
  • 32. Operating Procedures • Provide clear instructions for safely conducting activities involved in each covered process consistent with the process safety information • Address at least the listed elements
  • 33. Operating Procedures: Steps for Each Operating Phase • Initial startup, operation, shutdown • Temporary & emergency operations, emergency shutdown • Startup following shutdowns
  • 34. Operating Procedures: Operating limits • consequences of deviations • prevention of deviations
  • 35. Operating Procedures: Safety & Health Considerations • Chemical properties and hazards • Precautions to prevent exposure • Control measures if contact or airborne exposure occurs
  • 36. Operating Procedures: Safety & Health Considerations • Quality controls for raw materials • Control of hazardous chemical inventories • Special or unique hazards • Safety systems & their functions
  • 37. Operating Procedures • Operating procedures readily accessible • Reviewed as necessary to reflect current procedures and changes • Certified annually as current & accurate
  • 38. Operating Procedures • Develop & implement safe work practices to provide for the control of hazards during operations, e.g. lockout/tagout/ confined space entry, opening equipment & pipes, facility entry • Apply to employees & contractor employees
  • 39. Training • Process overview • Process hazards • Operating procedures • Emergency procedures • Refresher training at least every 3 yrs • Documentation
  • 40. Employer Responsibilities • Evaluate contractor’s safety performance & programs • Inform contractor of potential hazards: fire, explosion, toxic release, applicable plant safety rules • Develop/Implement safe work practices • Evaluate contractor performance
  • 41. Contractor Responsibilities • Advise employer of any unique work hazards of contracted work • Each employee follow all applicable work practices & safety rules of the facility • Ensure each employee is trained in necessary work practices
  • 42. Contractor Responsibilities • Ensure each employee is instructed in known fire, explosion, or toxic release problems related to his/her job • Document that understanding of training has been evaluated, verified
  • 43. Pre-startup Safety Review Done when: • New processes • Modified process
  • 44. Pre-startup Review Verifies • Construction: conforms to design • Procedures: adequate, in place • PHA recommendations resolved or implemented • Management of change requirements met • All affected workers trained
  • 45. PSM Mechanical Integrity • Pressure vessels, storage tanks • Piping systems, components • Relief & vent systems, devices • Emergency shutdown systems • Controls: monitoring devices, sensors, alarms, interlocks • Pumps
  • 46. Mechanical Integrity • Written procedures • Training: process hazards, job tasks • Inspections • Testing • Corrective action • Records
  • 47. Hot Work Permits • Welding, cutting, brazing • Control of ignition sources • Verify safe conditions • Authorization
  • 48. Management of Change • Establish written procedures • Develop management support • Evaluate safety of any changes to: process chemicals facility technology equipment
  • 49. MOC Procedures Must Address • Everything except “replacement in kind” • Temporary as well as permanent changes • Technical basis for change • Safety & health effects
  • 50. MOC Procedures Must Address • Modified operation procedures • Time necessary for change • Authorization for change • Ways to inform & train workers before change
  • 51. Incident Investigation Goals Identify incident causes and implement steps to prevent reoccurence
  • 52. Incident Investigation • Every incident • Prompt investigation • Knowledgeable team • Documentation & report • Recommendations & findings • Resolutions & corrective actions
  • 53. Emergency Planning & Response • Develop Emergency Action Plans • Pre-plan for catastrophe • Train & equip workers • Drills
  • 54. Compliance Safety Audits • Certify all elements of standard • Knowledgeable audit team • Report & recommendations • Address all finding & recommendations • Conduct every three years
  • 55. Appendices A: List of chemicals B: Sample block & flow diagrams C: Compliance guidelines D: References