BASE HYDROLYSIS AND FACTOR EFFECTING EFFECTING BASE HYDROLYSIS
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This document discusses base hydrolysis and factors that affect the rate of base hydrolysis. There are two types of hydrolysis - acidic and base hydrolysis. Base hydrolysis occurs when a reaction takes place in a basic medium, where a ligand is replaced by an OH- group. There are two mechanisms for base hydrolysis - dissociative and associative. Factors like chelating and steric hindrance increase the rate of the reaction, while increasing the electronegativity of the ligand decreases the rate due to reduced pi bonding and lability of the ligand.
![• For base hydrolysis atleast one ligand having acidic proton.
• H2O IS ENTERING GROUP .NOT OH-
• There is movement of ligand.
• In amido complex NH2- is pi donor.
• In absence of pi donor ligand T.B.P is lees stable.
• OH- abstract the H+ from NH3 group which is trans to living
group .
rate=Kb[Co(NH3)5Cl]2+
1.Whate is acid conjugate base.
2.Which is rate determining step.](https://image.slidesharecdn.com/rafiqmohammad3-190902040756/85/BASE-HYDROLYSIS-AND-FACTOR-EFFECTING-EFFECTING-BASE-HYDROLYSIS-7-320.jpg)
![Factor effecting rate hydrolysis
Chelating and Steric hindrancen increase the rate of
raction
[Co(en)2LCl]+ +OH- [Co(en)OHCl] + Cl-
L= CL- ,OH-,NO2-,CN-.
O-
H2N==Co==N
O-
Cl->CN->NO2- ;e-density provide by NH2- is removed by NO2-due to M—L
pi bonding lability of group decrise](https://image.slidesharecdn.com/rafiqmohammad3-190902040756/85/BASE-HYDROLYSIS-AND-FACTOR-EFFECTING-EFFECTING-BASE-HYDROLYSIS-9-320.jpg)
![Exception
A = [Co(py)4Cl]- B= [Co(CN)5Cl]-
trans [Co(tren)(NH3)Cl]2+ cis[Co(tren)(NH3)Cl]2+](https://image.slidesharecdn.com/rafiqmohammad3-190902040756/85/BASE-HYDROLYSIS-AND-FACTOR-EFFECTING-EFFECTING-BASE-HYDROLYSIS-10-320.jpg)
BASE HYDROLYSIS AND FACTOR EFFECTING EFFECTING BASE HYDROLYSIS
- 1. BASE HYDOLYSIS & factor effecting base hydrolysis
- 2. CONTENT 1. HYDROLYSIS 2. TYPE OF HYDROLYSIS 3. BASE HYDROLISIS 4. MECHANISM 5. QUTION ASKED IN NET AND GATE etc. 6. Factor effecting
- 3. HYDROLYSIS Addition of water is called hydrolysis or aquation IN INORGANIC CHEMISTERY The substitution reaction in which ligand is replaced by water molecule are called hydrolysis or aquation EXAMPLE
- 4. TYPE OF HYDROLYSIS There are two type of hydrolysis 1. Acidic hydrolysis If the hydrolysis is carried out in acidic pH<3 medium then it is called acidic hydrolysis. In the reaction ligand replace by H2O molecule. 2. Base hydrolyis If the reaction carried in basic medium then it is called base hydrolysis . in this reaction a ligand is replace by OH- group.
- 6. TYPE OF MECHANISM IN HYDROLYSIS There are two type of mechanism used in base hydrolysis 1. Dissociative reaction mechanism ML5---X + K1 ML5 +X It proceed first order reaction. K-1 Rate of reaction depend on ML5 + Y K2 ML5---Y concentration of one species. SN1CB 2. Associative reaction mechanism ML5X + Y K1 ML5X---Y second order reaction . rate of reaction depend on concentration two species. ML5X---Y K2 ML5Y +X SN2
- 7. • For base hydrolysis atleast one ligand having acidic proton. • H2O IS ENTERING GROUP .NOT OH- • There is movement of ligand. • In amido complex NH2- is pi donor. • In absence of pi donor ligand T.B.P is lees stable. • OH- abstract the H+ from NH3 group which is trans to living group . rate=Kb[Co(NH3)5Cl]2+ 1.Whate is acid conjugate base. 2.Which is rate determining step.
- 9. Factor effecting rate hydrolysis Chelating and Steric hindrancen increase the rate of raction [Co(en)2LCl]+ +OH- [Co(en)OHCl] + Cl- L= CL- ,OH-,NO2-,CN-. O- H2N==Co==N O- Cl->CN->NO2- ;e-density provide by NH2- is removed by NO2-due to M—L pi bonding lability of group decrise
- 10. Exception A = [Co(py)4Cl]- B= [Co(CN)5Cl]- trans [Co(tren)(NH3)Cl]2+ cis[Co(tren)(NH3)Cl]2+