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Resource Efficient
Application of Biofuels in
    British Columbia

Part 1: Fischer-Tropsch
     Drop-in Fuels
        Thomas Cheney
Bioenergy is limited
                  BCs Bioenergy
                   Resources are
                   limited

                  Efficient utilization is
                    required
Using bioenergy right
The Right Process
•   Energy Efficiency
•   Cost effective
                             The Right Fuel
•   Allows use of non-food
                             •   Compatible with the infrastructure
    feedstock
•   Scalable
                             •   Cost effective
                             •   Clean-burning
                             •   Distribution
                             •   Range




Co-Benefits: Carbon Capture, improved soil
Why Resource Efficiency Matters
                   BC Biomass
                    resources are
                    limited
                   •   Equivalent to 40% of
                       BC fossil fuel use
                   •   Mountain Pine Bettle
                       fibre supply spike
                   •   300 PJ sustainable
                       potential
Not all biofuels are created equal




• Some biofuels produce far more fuelhectare
 than others
BC Energy Use
BC Energy Use breakdown
Sector PJ                       PJ        Biomass can meet 25-
Transportation                  404       30% of Provincial
Industry                        362       energy demand
Agriculture                     18

Residential                     136

Comm., Instit. & Public Admin   105

Power Generation                35

Total                           1060

Biomass Capacity                250-300
An American Perspective
                     • Biomass is not a panacea


“If all biomass were used in CBTL-CCS systems
designed to maximize liquids output, 5.9 million
bbl/day transport fuels could be produced. ≈ U.S.
domestic crude oil production. ≈ ½ of U.S. oil
imports” This assumes that the process with driven
with coal with biomass providing the carbon atoms!
BC’s GHG
 emision

                     Of total

Marine                 3.96%

Off-Road               5.40%

Rail                   0.72%

Air                    2.52%

Passenger Vehicles    14.04%

Heavy Duty Vehicle     9.36%
BC Transportation
•   300 Petajoules of energy use
•   Assuming conversion efficiency rate of 40%, 120 PJ of fuel
    could be realized. This however leave very limited
    bioenergy resources available for sectors other than
    transportation fuel
Electric vs. Biofuel Vehicles




empr.gov.bc.ca


 • Vast electric        • Limited liquid fuel
     supplies               supplies
 •   Limited Range      •   Long range with
                            simple refuelling
We need both
                                   Apply the right
                                   technology in the
                                   right place



   The “Algaeus” biofuel plug-in




• Electricity should be seen as the dominant
  prime mover in B.C
• Biofuels hydrogen for range extension
How do we get biofuels?
• Thermochemical Pathway
  o Fischer-Troposch
  o Di-Methyl ether (DME) and Methanol
      Green Gasoline
  o Biomass Synthetic Natural Gas
  o Hydrogen


• Biochemical Pathways
  o Ethanol
  o Others based on proprietary organisms (LanzaTech)
Thermochemical Process can
produce many energy products
Thermochemical Fuel Cycles




• Gasification, Gas Cleaning, Chemical
One Option is FT-Biofuels




CHOREN Biofuels Plant in Germany
FT FUEL




• CO + H 2    CH2 + H2O
• Used for coal since 1930s
Biomass-Based FTFuels
  • Clean syngas is essential
  • Entrianed flow gasifiers are considered
      to be the most mature technology
  •   Biomass feeding is a challenge
  •   Similar technologies used in Coal to
      Liquids
FT Advantages
                                          • 40% efficiency
                                          • Drop-in fuel!
                                          • Established for coal
                                              and gas to liquids
                                          •   Biomass specific
                                              technology pre-
Coal to Liquids Plant in South Africa         commercial
http://s2.hubimg.com/u/5090925_f260.jpg
FT Compared to the Cellulosic
ethanol




http://mitei.mit.edu/system/files/kreutz-fischer-tropsch.pdf


<2.5 units of biomass are required per unit of
fuel.
Economics of FT b




         Competitive with oil at $115 per barrel gasoline withoug
         carbon price
http://www1.eere.energy.gov/hydrogenandfuelcells/pdfs/liquid_trans_tech.pdf
Biomass injection
Particular challenges to BtL
   o Use of coal based systems have energy use
     challenges
        biomass grinding to 100 um uses 8% of energy
         in biomass
   o Coal-based systems use a lock hopper
   o Biomass based systems using screw injection
     leads to greater energy efficiency
       Less pressurisation needed
       Less dilution
Piston Feeding of Biomass




• Biomass specific feeding system appear best
 rather than the systems adapted for coal.
  o Greater efficiency
  o   Van der Drift et al. 2004 covers these issues in detail
  o   “ENTRAINED FLOW GASIFICATION OF BIOMASS: Ash behaviour, feeding issues, and system analyses”
Van der Drift Syngas Preparation




Preliminary gasification (option D) offers highest
efficiency approach.
Choren




•   Low temperature gasification followed by high-
    temperature gasification to clean gas.
•   Pre-treatment low-temperature gasification to resolve
    challenges with biomass gasification of woody biomass
Solar Assisted Fuels
                                                     •   Uses solar energy to drive
                                                         endothermic reaction for
                                                         biofuels.
                                                     •   Hydrogen created from
                                                         solar energy avoiding loss
                                                         of carbon through reverse
                                                         gas shift




Hertwich, E. G. and Zhang, X (2010) “Concentrating-Solar biomass gasification process for
a 3rd generation biofuel
Solar fuels




• Solar cogeneration for electrolysis and
  gasification heat to increase process carbon
  efficiency
Cost Analysis for solar fuel
analysis
• 7.5$ per GJ of fuel produced (2001 $)
    Input costs $2.5 per GJ
•   60% Less land total
•   67% less land for biofuels
•   Assumes a $100 /tC
     Indicators                  Solar-         Bomass   Coal
                                 Biomass Fuel
     Fuel Productivity           121.0          39.9     62.2
     (kg fuel/100 kg resource)
     Cost ($2001/GJ)             $7.5           $8.9     $10.8

     Efficiency                  60.9%          42.0%    36.5%
Coal Biomass FT Fuels
                                         • Coal with carbon capture
                                             and storage can leverage
                                             the biomass

                                         1.5 units of coal + 1 unit biomass = 1
                                         unit fuel + 1.5 units sequestered
                                         CO2

                                         565 liters gasoline equivalent with
                                         coal +CCS versus 25l lge!
http://mitei.mit.edu/system/files/kreutz-fischer-tropsch.pdf
Remember This:




• Coal with CCS allows for low- mitigation cost
  very low CO2 fuels
Carbon-Neutral Coal Based biofuel
                                                           • 38% biomass +
                                                               CCS leads to
                                                               carbon neutral
                                                               biofuel.
                                                           •   Coal cheaper than
                                                               biomass, reduces
                                                               fuel production
         canindia.com
                                                               costs even with
                                                               CCS costs included
http://mitei.mit.edu/system/files/kreutz-fischer-tropsch.pdf
Economics




http://www1.eere.energy.gov/hydrogenandfuelcells/pdfs/liquid_trans_tech.pdf



 CBTL with CCS costs less than BTL without CCS!
Conclusions
• Look at combining biomass and coal or
    biomass with solar to maximize carbon
    utilization
•   Ethanol is a distraction!
•   Electrify has much as possible
•   Next SNG fuels using compressed
    biomethane and liquified biomethane
THANK YOU!




://puregreencars.com/files/SunDiesel-Choren.jpg

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Resource efficient bioenergy for BC

  • 1. Resource Efficient Application of Biofuels in British Columbia Part 1: Fischer-Tropsch Drop-in Fuels Thomas Cheney
  • 2. Bioenergy is limited BCs Bioenergy Resources are limited Efficient utilization is required
  • 3. Using bioenergy right The Right Process • Energy Efficiency • Cost effective The Right Fuel • Allows use of non-food • Compatible with the infrastructure feedstock • Scalable • Cost effective • Clean-burning • Distribution • Range Co-Benefits: Carbon Capture, improved soil
  • 4. Why Resource Efficiency Matters BC Biomass resources are limited • Equivalent to 40% of BC fossil fuel use • Mountain Pine Bettle fibre supply spike • 300 PJ sustainable potential
  • 5. Not all biofuels are created equal • Some biofuels produce far more fuelhectare than others
  • 7. BC Energy Use breakdown Sector PJ PJ Biomass can meet 25- Transportation 404 30% of Provincial Industry 362 energy demand Agriculture 18 Residential 136 Comm., Instit. & Public Admin 105 Power Generation 35 Total 1060 Biomass Capacity 250-300
  • 8. An American Perspective • Biomass is not a panacea “If all biomass were used in CBTL-CCS systems designed to maximize liquids output, 5.9 million bbl/day transport fuels could be produced. ≈ U.S. domestic crude oil production. ≈ ½ of U.S. oil imports” This assumes that the process with driven with coal with biomass providing the carbon atoms!
  • 9. BC’s GHG emision Of total Marine 3.96% Off-Road 5.40% Rail 0.72% Air 2.52% Passenger Vehicles 14.04% Heavy Duty Vehicle 9.36%
  • 10. BC Transportation • 300 Petajoules of energy use • Assuming conversion efficiency rate of 40%, 120 PJ of fuel could be realized. This however leave very limited bioenergy resources available for sectors other than transportation fuel
  • 11. Electric vs. Biofuel Vehicles empr.gov.bc.ca • Vast electric • Limited liquid fuel supplies supplies • Limited Range • Long range with simple refuelling
  • 12. We need both Apply the right technology in the right place The “Algaeus” biofuel plug-in • Electricity should be seen as the dominant prime mover in B.C • Biofuels hydrogen for range extension
  • 13. How do we get biofuels? • Thermochemical Pathway o Fischer-Troposch o Di-Methyl ether (DME) and Methanol  Green Gasoline o Biomass Synthetic Natural Gas o Hydrogen • Biochemical Pathways o Ethanol o Others based on proprietary organisms (LanzaTech)
  • 14. Thermochemical Process can produce many energy products
  • 15. Thermochemical Fuel Cycles • Gasification, Gas Cleaning, Chemical
  • 16. One Option is FT-Biofuels CHOREN Biofuels Plant in Germany
  • 17. FT FUEL • CO + H 2  CH2 + H2O • Used for coal since 1930s
  • 18. Biomass-Based FTFuels • Clean syngas is essential • Entrianed flow gasifiers are considered to be the most mature technology • Biomass feeding is a challenge • Similar technologies used in Coal to Liquids
  • 19. FT Advantages • 40% efficiency • Drop-in fuel! • Established for coal and gas to liquids • Biomass specific technology pre- Coal to Liquids Plant in South Africa commercial http://s2.hubimg.com/u/5090925_f260.jpg
  • 20. FT Compared to the Cellulosic ethanol http://mitei.mit.edu/system/files/kreutz-fischer-tropsch.pdf <2.5 units of biomass are required per unit of fuel.
  • 21. Economics of FT b Competitive with oil at $115 per barrel gasoline withoug carbon price http://www1.eere.energy.gov/hydrogenandfuelcells/pdfs/liquid_trans_tech.pdf
  • 22. Biomass injection Particular challenges to BtL o Use of coal based systems have energy use challenges  biomass grinding to 100 um uses 8% of energy in biomass o Coal-based systems use a lock hopper o Biomass based systems using screw injection leads to greater energy efficiency  Less pressurisation needed  Less dilution
  • 23. Piston Feeding of Biomass • Biomass specific feeding system appear best rather than the systems adapted for coal. o Greater efficiency o Van der Drift et al. 2004 covers these issues in detail o “ENTRAINED FLOW GASIFICATION OF BIOMASS: Ash behaviour, feeding issues, and system analyses”
  • 24. Van der Drift Syngas Preparation Preliminary gasification (option D) offers highest efficiency approach.
  • 25. Choren • Low temperature gasification followed by high- temperature gasification to clean gas. • Pre-treatment low-temperature gasification to resolve challenges with biomass gasification of woody biomass
  • 26. Solar Assisted Fuels • Uses solar energy to drive endothermic reaction for biofuels. • Hydrogen created from solar energy avoiding loss of carbon through reverse gas shift Hertwich, E. G. and Zhang, X (2010) “Concentrating-Solar biomass gasification process for a 3rd generation biofuel
  • 27. Solar fuels • Solar cogeneration for electrolysis and gasification heat to increase process carbon efficiency
  • 28. Cost Analysis for solar fuel analysis • 7.5$ per GJ of fuel produced (2001 $) Input costs $2.5 per GJ • 60% Less land total • 67% less land for biofuels • Assumes a $100 /tC Indicators Solar- Bomass Coal Biomass Fuel Fuel Productivity 121.0 39.9 62.2 (kg fuel/100 kg resource) Cost ($2001/GJ) $7.5 $8.9 $10.8 Efficiency 60.9% 42.0% 36.5%
  • 29. Coal Biomass FT Fuels • Coal with carbon capture and storage can leverage the biomass 1.5 units of coal + 1 unit biomass = 1 unit fuel + 1.5 units sequestered CO2 565 liters gasoline equivalent with coal +CCS versus 25l lge! http://mitei.mit.edu/system/files/kreutz-fischer-tropsch.pdf
  • 30. Remember This: • Coal with CCS allows for low- mitigation cost very low CO2 fuels
  • 31. Carbon-Neutral Coal Based biofuel • 38% biomass + CCS leads to carbon neutral biofuel. • Coal cheaper than biomass, reduces fuel production canindia.com costs even with CCS costs included http://mitei.mit.edu/system/files/kreutz-fischer-tropsch.pdf
  • 33. Conclusions • Look at combining biomass and coal or biomass with solar to maximize carbon utilization • Ethanol is a distraction! • Electrify has much as possible • Next SNG fuels using compressed biomethane and liquified biomethane