This document describes the development of an instrument to assess student intention to use technology and e-learning in Libyan Higher Education. Four factors were examined as independent variables that could influence intention: computer-internet experience, computer self-efficacy, technology-internet quality, and attitudes toward use. A 29-item instrument was developed and tested on a sample of 273 students. The findings provide guidelines for further statistical analysis to validate the relationships between the four factors and intention to use technology and e-learning.