This chapter discusses the key processes and controls of terrestrial decomposition. It describes the three main processes of decomposition - leaching of litter, fragmentation of litter, and chemical alteration. The chapter also addresses the temporal and spatial heterogeneity of decomposition rates. The main factors that control decomposition are the physical environment, substrate quality and quantity, and the microbial community present. Decomposition breaks down dead organic matter, releasing carbon and nutrients back into the ecosystem.