This chapter discusses Multi-Protocol Label Switching (MPLS) Virtual Private Networks (VPNs), outlining their complexities and configurations while emphasizing their popularity and advantages in ISP networks. It defines VPNs, their varying types, and the technological underpinnings of MPLS, detailing the structure and functioning of label switching as a forwarding paradigm. The chapter serves both as a high-level overview and a technical examination of MPLS VPNs, with sections dedicated to related terminology, operational mechanics, and their interplay with existing IP networks.