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PVT
    PROCESS                  RELATIONSHIP                        WNF                   WSF                   Q                 U                H                 S


  Constant Pressure
   Isobaric Process
        (P=C)
         n=0                   V1            T1          WNF =    PV                                                                                                    T2
                                        =                                                                                U = mCv(   T)    H = mCp(   T)    S = mCp ln
                                                              = mR(    T)           WSF = 0             Q=       H                                                      T1
   ILLUSTRATION:               V2            T2
     Piston Cylinder                                                                                                                                                    V2
    Assembly Spring                                                                                                                                         = mCp ln
         Loaded                                                                                                                                                         V1


                                                                                                                                                                        T2
    Constant Volume                                                                                                                                        S = mCv ln
    Isochoric Process
                               P1            T1                                                                                                                         T1
    Isometric Process
                                        =                WNF = 0                  WSF = -     Wf        Q=       U
         (V=C)
                                             T2                                                                          U = mCv(   T)    H = mCp(   T)                 P2
           n=                  P2                                                                                                                            = mCv ln
              8




                                                                                      = V(P1 - P2)                                                                      P1
   ILLUSTRATION:
    Rigid Container




  Constant Temperature
   Isothermal Process                                                   P1                                                                                           V2
                                                      WNF = c ln
         (T=C)                                                          P2                                                                                 S = mR ln
          n=1                      P1         V2                                   WSF = Q              Q = WNF                                                      V1
                                        =                                                                                  U=0            H=0
                                   P2         V1                                                                                                                     P1
   ILLUSTRATION:                                         c = PV                                                                                              = mR ln
     Piston Cylinder                                                                                                                                                 P2
   Assembly Perfectly
         Cooled



   Isentropic Process
  Reversible Adiabatic                        k-1
        Process               T2        P2        k
        (PVk=C)                     =
      (S=C, Q=0)              T1        P1             WNF = -     U              WSF = -     H             Q=0          U = mCv(    T)   H = mCp(    T)    S=0
  k=1.4 (if not given)
                                              k-1
   ILLUSTRATION:                        V1
     Piston Cylinder               =
   Assembly Perfectly                   V2
        Insulated



                                              n-1
Special Polytropic Process
        (PVn = C)             T2        P2        n
                                                                 P2V2 - P1V1                                                                                            T2
       1 < n < 1.4                  =                 WNF =                       WSF = n (WNF)       Q = mCn        T   U = mCv(   T)    H = mCp(   T)    S = mCn ln        = mCn ln
                              T1        P1                             1-n                                                                                              T1
    ILLUSTRATION:                             n-1
     Piston Cylinder                    V1                                                           Cn =   Cv k - n
   Assembly Air Cooled             =                                                                           1-n
                                        V2



                                                                      “Be ashamed to die until you have done something for humanity.”
PROCESS CURVES on Pv and Ts Planes




  P                                                                         T
                         -WNF                                                                                   Q
                          n=k         WNF = 0
                                                                                                                n=




                                                                                                                     8
                    -WNF              n=                                                                  Q=0




                                          8
                     1<n<k                                                                                n=k
                                                                                                                         Q
                -WNF                                                                                                     n=0
                 n=1
                                                                                         -Q
                                                                                      1<n<k




       -WNF                                                      WNF
                                                                                                                               Q
        n=0                                                       n=0           -Q
                                                                                n=1                                            n=1




                                                                WNF                                                            Q
                                                                 n=1
                                                                                                                               1<n<k

                                                            WNF                       -Q
                                                             1<n<k                    n=0
                                                        WNF                                 -Q
                                                         n=k
                                     WNF = 0                                                 n=




                                                                                                  8
                                     n=                                                                   Q=0
                                        8




                                                                                                          n=k



                                                                        v                                                              S




                                 “Great leaders are never satisfied with current level of performance. They
                                              constantly strive higher levels of achievement.”

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010 summary of_processes

  • 1. PVT PROCESS RELATIONSHIP WNF WSF Q U H S Constant Pressure Isobaric Process (P=C) n=0 V1 T1 WNF = PV T2 = U = mCv( T) H = mCp( T) S = mCp ln = mR( T) WSF = 0 Q= H T1 ILLUSTRATION: V2 T2 Piston Cylinder V2 Assembly Spring = mCp ln Loaded V1 T2 Constant Volume S = mCv ln Isochoric Process P1 T1 T1 Isometric Process = WNF = 0 WSF = - Wf Q= U (V=C) T2 U = mCv( T) H = mCp( T) P2 n= P2 = mCv ln 8 = V(P1 - P2) P1 ILLUSTRATION: Rigid Container Constant Temperature Isothermal Process P1 V2 WNF = c ln (T=C) P2 S = mR ln n=1 P1 V2 WSF = Q Q = WNF V1 = U=0 H=0 P2 V1 P1 ILLUSTRATION: c = PV = mR ln Piston Cylinder P2 Assembly Perfectly Cooled Isentropic Process Reversible Adiabatic k-1 Process T2 P2 k (PVk=C) = (S=C, Q=0) T1 P1 WNF = - U WSF = - H Q=0 U = mCv( T) H = mCp( T) S=0 k=1.4 (if not given) k-1 ILLUSTRATION: V1 Piston Cylinder = Assembly Perfectly V2 Insulated n-1 Special Polytropic Process (PVn = C) T2 P2 n P2V2 - P1V1 T2 1 < n < 1.4 = WNF = WSF = n (WNF) Q = mCn T U = mCv( T) H = mCp( T) S = mCn ln = mCn ln T1 P1 1-n T1 ILLUSTRATION: n-1 Piston Cylinder V1 Cn = Cv k - n Assembly Air Cooled = 1-n V2 “Be ashamed to die until you have done something for humanity.”
  • 2. PROCESS CURVES on Pv and Ts Planes P T -WNF Q n=k WNF = 0 n= 8 -WNF n= Q=0 8 1<n<k n=k Q -WNF n=0 n=1 -Q 1<n<k -WNF WNF Q n=0 n=0 -Q n=1 n=1 WNF Q n=1 1<n<k WNF -Q 1<n<k n=0 WNF -Q n=k WNF = 0 n= 8 n= Q=0 8 n=k v S “Great leaders are never satisfied with current level of performance. They constantly strive higher levels of achievement.”