Adsorption of hydrogen sulfide using palm shell

IJRET: International Journal of Research in Engineering and Technology eISSN: 2319-1163 | pISSN: 2321-7308
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Volume: 02 Issue: 08 | Aug-2013, Available @ http://www.ijret.org 302
ADSORPTION OF HYDROGEN SULFIDE USING PALM SHELL
ACTIVATED CARBON: AN OPTIMIZATION STUDY USING
STATISTICAL ANALYSIS
Lee Chung Lau1
, NorhusnaMohamadNor2
, Abdul Rahman Mohamed3
, KeatTeong Lee4
1, 2, 3
School of Chemical Engineering, UniversitiSains Malaysia, Engineering Campus, Seri Ampangan, 14300
NibongTebal, Pulau Pinang, Malaysia., Tel.: +604-5996467; Fax: +6045941013
chktlee@eng.usm.my
Abstract
Removing H2S from biogas that is produced from anaerobic digestion of palm oil mill effluent is a crucial step in order for the biogas
to be utilized as a source of energy. In this study, palm shell activated carbon (PSAC) prepared by steam activation was used to
adsorb H2S from simulated biogas. The parameters studied were H2S concentration, adsorption temperature and space velocity. The
effect of these parameters towards breakthrough adsorption capacity was studied using statistical analysis with Design Expert
Software. H2S concentration and space velocity were found to be significant in affecting the breakthrough adsorption
capacity.Adsorption temperature on its own was found not to have significant effect on the breakthrough adsorption capacity but its
interaction with other parameters was found to be significant. Characterization of fresh and spent PSAC confirmed and provided
further information on the adsorption of sulfur species on PSAC pore surface.
Keywords: Activated carbon; Biogas; Hydrogen sulfide; Adsorption
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1. INTRODUCTION
Palm oil mill effluent (POME) is the pollutant generated from
the oil palm industries in Malaysia and must be treated before
discharge. One of the possible way to treat POME is by
subjecting it to anaerobic digestion that produces biogas.
Biogas can be combusted directly as fuel. Ng et al. reported
that 1,688 million m3
of biogas is generated from palm oil mill
in 2009 [1]. Biogas concentration largely varies from 13.5–
49.0% methane (CH4) and the remaining carbon dioxide (CO2)
[2]. Typically, trace amount of hydrogen sulfide (H2S)
between 0–1%is also produced in biogasas a result from the
anaerobic digestion of POME [3].Biogas should not be
emitted directly to the atmosphere because H2S is corrosive
and CH4 is a greenhouse gas. Instead, biogas can be utilized as
a source of energy by combusting biogas in a gas engine to
generate electricity or steam. However, H2S must be removed
prior to combustion or it can cause severe corrosion [4].For
biogas scrubbing technology, H2S adsorption with activated
carbon appears to be a promising method. Activated carbon is
a cheap adsorbent that is widely utilized in air pollution
abatementtechnology due to favorable surface propertiesthat
allows it to have high adsorption capacity and fast reaction
kinetic even at ambient temperature. Activated carbon can be
produced from various lignocellulosic biomass such as
coconut shell, corncob and palm shell. The use of palm shell
to synthesize activated carbon for H2Sremoval is more
economical because both palm shell and H2S are by-products
from the oil palm industries. Thus, the use of palm shell
activated carbon (PSAC) is a sustainable process because a
waste from the oil palm industry is utilized to remove acidic
gas generated within the same industry. PSAC is
conventionally prepared using a two-step process;
carbonization and activation. During carbonization, volatile
compound in palm shell will be removed in the inert
atmosphere. Carbon is retained due to the absence of oxygen
that avoids the formation of carbon dioxide. The product after
carbonization process is palm shell char that contains mostly
carbon material with a surface area of about 100m2
/g. After
that, the char will be activated using steam or carbon dioxide.
Thermal treatment using steam or carbon dioxide will distort
the structure of char to form porous carbon that has high
surface area and good adsorption capability.
In this research, several reaction parameters;H2S
concentration, adsorption temperature and space velocity that
affect breakthrough adsorption capacity using steam activated
PSAC were studied. These parameters were studied using
statistical analysis by employing Software Design Expert 6.0.
Design of experiment is generated by the software in order to
minimize the amount of experiments required to study the
parameters thoroughly. In addition, the importance of each
parameter in affecting activated carbon adsorption capacity
can be identified. Interaction between reaction parameters can

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be also analyzed so that detailed understanding between H2S
adsorption capacity and reaction parameters can be obtained.
2. EXPERIMENTAL
2.1 Chemicals
Steam activated PSAC used in this study was obtained from
Victory Element SdnBhd, Malaysia. The mesh size of the
PSAC was 8 x 12. In the adsorption test, PSAC was used as
received without any further treatment. Three types of gases
(99.99% CH4, 99.99% CO2 and 1% H2S, balance CH4) in
cylinders supplied by WellgasSdnBhd, Malaysia were used to
simulate industrial biogas for the adsorption test.
2.2Adsorption Test
H2S adsorption test was carried out using a packed bed reactor
test rig as shown in Figure 1. The composition of simulated
biogas was adjusted by controlling the flow rate of gases
usingAalborg AFC26 mass flow controllers. CO2 and
CH4werepassed through a humidification system to give
approximately 25% relative humidity to the biogas inlet
stream. H2S/CH4was not passed through the humidification
system because H2S is soluble in water. The path of the
biogas after the humidification system to the reactor is
insulated to avoid condensation of moisture. The diameter of
the stainless steel tubular reactor used is half inch. The flow
rate of the biogas was fixed at 450 mL/min with 50% CO2,
1000–5000 ppm H2S and balance CH4. This biogas
composition was simulated to mimic the data obtained from a
collection pond located at FeldaBesout Palm Oill Mill. The
height of PSAC was adjusted corresponding to space velocity
between 3375 to 13500 h-1and placed in the middle of the
tubular reactor and supported with approximately 0.05g glass
wool. Adsorption temperature was controlled using a
Linberg/Blue M tube furnace.Concentration of H2S at the
outlet stream was analyzed using anIMR 6000 gas analyzer
via electrochemical sensor calibrated for 0–5000 ppm H2S.
The workspace of the test rig was ventilated as a safety
procedure just in case there is a leakage of hazardous H2S.
Figure1. H2S adsorption test rig.
2.3 Characterization
Several characterizations such as N2 adsorption-desorption,
scanning electron microscopy–energy dispersive X–ray
spectroscopy (SEM–EDX), thermogravimetric analysis (TGA)
and elemental analysis were performed on fresh PSAC and
spent PSAC to analyze its surface properties, functional
groups and morphologies/composition. N2 adsorption-
desorption was carried out with anMicromeritics ASAP 2020
Surface Area and Porosity Analyzer. Prior to analysis, the
samples were degassed for 5 hours. SEM–EDX analysis was
carried out by a Quanta FEG 450 at accelerating voltage of
3kV in order to obtain the sorbent surface morphologies and
determine localized chemical composition. TGA was
performed using a Perkin Elmer TGA7 with a heating rate of
100C/min until 6000C under a 100mL/min flow of purified air
[5]. Elemental analysis was performed using a Perkin Elmer
2400 CHNS Analyzer to analyze the sulfur content of the
sample.
3. RESULTS AND DISCUSSION
3.1Development and analysis of regression model
In this study, adsorption capacity of activated carbon was
determined at breakthrough point, in which theratio of the
outlet to inlet H2S concentration at 0.05. The adsorption
experimental run was conducted based on thedesign of
experiment and the complete design matrix with results are
shown in Table 1.
Table1. Design Matrix and Results for Adsorption Capacity At Different Experimental Conditions
Run Order x1: H2S concentration
(ppm)
x2: Temperature
(oC)
x3: Space velocity
(h-1)
y: Adsorption capacity
(mg/g)
R1 3000 50 3375 28.9
R2 5000 30 3375 30.3
R3 3000 50 5400 21.8
R4 3000 50 5400 21.0

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R5 1000 50 5400 93.6
R6 3000 50 5400 23.0
R7 3000 70 5400 18.4
R8 3000 50 5400 24.5
R9 3000 50 5400 23.0
R10 3000 50 5400 22.6
R11 5000 50 5400 16.6
R12 5000 70 3375 23.9
R13 1000 70 13500 5.1
R14 1000 70 3375 38.1
R15 3000 30 5400 19.1
R16 5000 30 13500 1.6
R17 1000 30 3375 116.5
R18 1000 30 13500 26.1
R19 5000 70 13500 3.2
R20 3000 50 13500 3.8
Six center points (R3, R4, R6, R8, R9, and R10) are
incorporated and spread out in the experimental matrix in
order to calculate experimental error and reduce other errors
due to unaccounted parameters. Experimental error was
calculated to be 4.8%. Using the results shown in Table 1,
adsorption parameters (x1: H2S concentration, x2: adsorption
temperature and x3: space velocity) were correlated with
breakthrough adsorption capacity (y) using Design-Expert
6.0.6 software. The model selected by this software is
Response Surface Reduced Cubic Model and the equation in
coded factors is shown inEq. (2).The graph for the predicted
versus actual breakthroughadsorption capacity is shown in
Figure2.
log10y = 1.132 – 0.423x1+ 0.005x2– 0.438x3 + 0.228x12 –
0.081x22 – 0.111x32
+ 0.174x1x2– 0.079x1x3+ 0.022x2x3 – 0.129x12x2–
0.022x12x3 + 0.147x1x22
+ 0.078 x1x2x3
(2)
Figure 2.Predicted versus actual log breakthrough adsorption
capacity.
The R2 value for Eq. (2) wasfound to be 0.9994 and the
predicted R2value of 0.9990 is in reasonable agreement with
the adjusted R2value of 0.9980. On the other hand, adequate
precision of 109.0 indicated an adequate signal to noise ratio
for the model to be used to navigate the design space. These
results verify that the developed model can be used to predict
the PSAC breakthrough adsorption capacity within the range
of adsorption parameters studied.
22
Actual
Predicted
Predicted vs. Actual
0.20
0.67
1.13
1.60
2.07
0.20 0.67 1.13 1.60 2.07

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An analysis of variance (ANOVA) that shows the significance
of the model and each adsorption parameter is shown in Table
2.Value of Prob> F less than 0.05 indicatesthat model term is
significant. Therefore, the model withProb> F value less than
0.0001implies that the model is significant.The model F-value
is 717.7 and there is only a 0.01% chance that a model F-value
this large could occur due to noise. The lack of fit F-value of
0.00 implies the lack of fit is not significant relative to the
pure error. There is a 98.70% chance that a "Lack of Fit F-
value" this large could occur due to noise. Non-significant
lack of fit indicates that the model fit the experimental result
very well. From the ANOVA result, significant terms with
high F value are x1, x3,andx1x2. Other significant terms with
lower F values are not discussed in this paper because their
effect on breakthrough adsorption capacity is less significant
as compared to those with higher F values.
Table2. Analysis of Variance of the Response Surface Reduced Cubic Model
Source Sum of
Squares
DF Mean
Square
F
Value
Prob> F
Model 3.89 13 0.2996 717.7 < 0.0001
x1 0.32 1 0.3286 787.1 < 0.0001
x2 0.00 1 0.0000 0.1 0.7707
x3 0.41 1 0.4124 987.8 < 0.0001
x12 0.11 1 0.1165 279.1 < 0.0001
x22 0.01 1 0.0169 40.5 0.0007
x32 0.01 1 0.0115 27.7 0.0019
x1x2 0.24 1 0.2427 581.3 < 0.0001
x1x3 0.04 1 0.0498 119.3 < 0.0001
x2x3 0.00 1 0.0040 9.6 0.0210
x12x2 0.02 1 0.0249 59.6 0.0002
x12x3 0.00 1 0.0008 2.0 0.2053
x1x22 0.03 1 0.0324 77.6 0.0001
x1x2x3 0.04 1 0.0492 118.0 < 0.0001
Residual 0.00 6 0.0004 – –
Lack of Fit 0.00 1 0.0000 0.0003 0.9870
Pure Error 0.0025 5 0.0005 – –
3.2 Effect of Significant Terms
Significant term with highest F valueis space velocity. Highest
F value denotes that space velocity has the greatest effect
towards breakthrough adsorption capacity among the
adsorption parameters studied.From Table 1, it can be seen
that experiments conducted withhigh space velocity (13500 h-
1) generally resulted to low breakthrough adsorption capacity.
The major reason for this observation is related with the
residence time of the biogas in the adsorption zone. At higher
space velocity, residence time of biogas in the adsorption zone
is shorter. Adsorption studies R13, R16, R19 and R20 that
utilized13500 h-1 space velocityshowed lowbreakthrough
adsorption capacity,ranging only from 1.6–5.1 mg/g. However,
although R18 was also conducted using 13500 h-1 space
velocity, but it recorded relatively highbreakthrough
adsorption capacity of 26.1 mg/g that could be mostly
attributed to the low H2S concentration used (1000 ppm).
When the space velocitywaslowered to 5400 h-1, residence
time of the gaswas increased and the PSAC breakthrough
adsorption capacity rose significantly to the range 16.6–24.5
mg/g. Again, R5 that utilized5400 h-1 space velocity
achieveda relatively high breakthrough adsorption capacity of
93.6 mg/g due to the low H2S concentration used (1000 ppm).
Further increase inbreakthrough adsorption capacity ranging
from 23.9–38.1 mg/g was obtained when usinglower space
velocity of 3375 h-1. Once again, R17 (116.5 mg/g) is an
exceptional case because of the low H2S concentration (1000
ppm). The effect of low H2S concentration will be discussed
in the next section. Higher residence time increases the
frequency of molecule collision that results to a successful
adsorption process [6]. On the contrary, low residence time

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resulted to insufficient time for all H2S molecules to adsorb
on the PSAC surface. This is especially more prominent when
more surface sites are taken up as adsorption process
progresses and the remainingH2S molecules have to diffuse
deeper into the pores of PSAC.This denotes a longer mean
free path for the H2S molecule to travel before it can be
adsorbed on the PSAC pore surface. Thus, the finding on the
significance of this term provides an insight towards the
importance of mass transfer in the adsorption process.
Another significant term with a high F value of 787.1is x1
(H2S concentration). H2S concentration has antagonistic
effect towards adsorption capacity, as indicated from a minus
sign for the term x1 in Eq. (2). From the previous discussion
onspace velocity, lower H2S concentration resulted to a
higherbreakthrough adsorption capacity. Adsorption study
using 1000 ppm H2S concentration gives adsorption capacity
in the range of 26.1-116.5 mg/g for run R13 which recorded
merely 5.1 mg/g, due to thehigh space velocity used. When
using higherH2S concentrationat 5000 ppm, breakthrough
adsorption capacity within the range of 1.6 to 30.3 mg/g was
obtained. At higher H2S concentration, the diffusion of H2S
molecules into the pores of PSAC for adsorption to occur is
not fast enough to facilitate complete removal of all H2S
molecules from the gaseous stream. Therefore, the
breakthrough occurs faster, i.e., lower adsorption capacity. At
lower H2S concentration, there will be less H2S molecules
diffusing into the PSAC pore structure per unit time. Thus on
the average, the H2S molecule will have a shorter mean free
path before reaching an active site due to lower competition
with other molecules for adsorption. However, these findings
contradict the finding reported by Xue and Liu [7].
Breakthrough capacity was found to increase with higher H2S
concentration. Nevertheless, it is worthwhile to note that the
concentration used in their study was between 210-630 ppm,
which is far lower than this study. At very low concentration
region, driving force for the H2S diffusion will increase with
higher concentration and there will be no significant
competition for active sites.Therefore, both studies is expected
to have different results. In order to have a clearer view on the
effect of H2S concentration towards breakthrough adsorption
capacity, diffusion coefficient and adsorption rate constant
should be obtainedin order todetermine the rate limiting step
of this adsorption process.
The effect of temperature (x2)was also investigated in this
study.Itwas found to have insignificant effect towards PSAC
breakthrough adsorption capacity. However, this does not
mean that temperature has no effect onbreakthrough
adsorption capacity,but merelydenotes that there is no linear
relationship between temperature and adsorption capacity.
Based on R16 and R19, increasing temperature increases
adsorption capacity. On the contrary, increasing temperature
reduces adsorption capacity asobserved from R14 and R17.
On the other hand, R7, R8 and R15 show an optimum
temperature appearing at 50oC. These three sets of
datawereconducted at different concentration and space
velocity, indicating that the effect of temperature on
breakthrough adsorption capacity is dependent on other
parameters. Temperature was found to have significant
interaction effect with H2S concentrationon breakthrough
adsorption capacity as indicated by the high F value for the
term x1x2 (581.4). This significant interaction termcould be
used to explain the three sets of data mentioned earlier which
also indicates thatthe effect of temperature toward
breakthrough adsorption capacity is dependent on the level of
H2S concentration and space velocity.This finding is again
different from those reported in the literature. Xiao et al.
studied the effect of temperature and reported that higher
temperature reduces adsorption capacity of activated carbon
[8]. They explained that physical adsorption is an exothermic
process that favors lower temperature.
The synergistic effect of x1x2 can be visualized
inFigure3.From Figure3, increasing temperature at 1000ppm
H2S and 3375 h-1 space velocityresulted to a decrease
inbreakthrough adsorption capacity. However,
whenexperiments were conducted at 5000ppm H2S and 3375
h-1 space velocity, increasing temperature would slightly
increase thebreakthrough adsorption capacity. This
phenomenon could be due to the extra kinetic energy obtained
at higher temperature. This extra kinetic energy affects the
diffusion of molecules in the pores and the bulk gas motion in
the main stream. At lower H2S concentration, the results from
the previous section shows that high adsorption capacity can
be easily achieved. If temperature is raised, H2S molecules
will gain extra kinetic energyand therefore reduces the
residence time in the adsorbent zone. Shorter residence time
does not allow all H2S molecules to diffuse deep into the
pores especially after most of theouter pores are saturated with
H2S. Thus, more H2S molecules will pass through the
adsorbent without being adsorb at higher temperature and
therefore gives a lower adsorption capacity.However, at higher
H2S concentration,breakthrough adsorption capacity is
generally lower.Therefore, the mean free path for H2S
diffusion is still considerably low. Higher temperature will
improve the diffusion of H2S molecules deeper into the pores
for adsorption to occur. Although higher temperature will also
increase the bulk motion of H2S molecules through the
adsorbent zone,the positive effect of H2S molecule diffusing
deeper into the pores of the adsorbent will be more prominent.
Thus the adsorption capacity will slightly increase at higher
temperature.

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Figure 3.Surface graph of interaction betweenx1x2 at x3 =
3375 h-1.
3.3 Optimization Study
Using Design Expert Software, optimization was performed in
order to search for the highest breakthrough adsorption
capacity within the range of parameters studied. Ten sets of
solution with predicted breakthrough adsorption capacity were
generated and tabulated in Table 3. Set Number 1was
identified as the optimum conditions for the adsorption
process because it gave the highest predicted breakthrough
adsorption capacity. The optimum operating parameters are
1006 ppm H2S, 43.60C and 3926 h-1 space velocity. Three
identical experiments were performed using thepredicted
parameters and the breakthrough adsorption capacity obtained
was 121.9-130.0mg/g, which verifies the prediction of Design
Expert Software. Comparing the result from the optimization
process with the Runs in Table 1, H2S concentration has to be
kept as low as possible in order to achieve high breakthrough
adsorption capacity. However, for practical operation, H2S
concentration is generally not consistent and fluctuates
significantly depending on the anaerobic digestion condition,
unless the digestion is performed in a bioreactor. On the other
hand, optimum temperature of 43.60C on the other hand is
beneficial to actual plant operation because trapped biogas
from POME anaerobic digestion generally range from 40–
500C due to heating by sunlight. Although in the initial part of
this paper, the breakthrough adsorption capacity was found to
increase with lower space velocity, but the optimization result
shows that there is an optimum value for space
velocity.Utilization of lower space velocity does not
necessarily guarantee higher breakthrough adsorption capacity.
Therefore, for practical application, optimized space velocity
should be used in order to obtain higher breakthrough
adsorption capacity ofPSAC.
Table3. Prediction of Optimum Adsorption Capacity at
Different Conditions
Numb
er
H2S
concentrati
on (ppm)
Tempe
rature
(0C)
Space
Velocit
y (h-1)
adsorption
capacity
(mg/g)
1 1006 43.6 3926 122.18
2 1000 37.3 5544 109.90
3 1000 43.6 5792 103.27
4 1000 30.0 5427 101.62
6 1000 44.1 6198 97.72
6 1000 41.3 6729 94.84
7 1000 57.4 3375 85.11
8 1000 30.0 8698 68.54
9 1502 30.0 3375 66.98
10 1577 30.0 3375 62.37
3.4 Characterization of Fresh and Spent PSAC
The N2 adsorption desorption of fresh PSAC enables the
derivation of adsorption and desorption isotherm. Langmuir
correlation was found to fit the adsorption capacity of nitrogen
at various pressures as shown in Figure 4. Other surface
properties analysis were tabulated in Table 4. Since the t-plot
micropore surface area is about 74.2% of BET surface area for
fresh PSAC, it can be concluded that pore structure of PSAC
is predominantly micropore (<2nm).
1.34
1.53
1.73
1.92
2.12
logy
1000
2000
3000
4000
5000 30
40
50
60
70
x1: H2S concentration
x2: Temperature

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Figure4. N2 adsorption-desorption isotherm of fresh PSAC.
Table4. Characteristic of Fresh PSAC from N2 Adsorption
Desorption
Fresh PSAC
BET surface area (m2/g) 736.8
Total pore volume (cm³/g) 0.382
t-plot micropore area (m2/g) 546.9
t-plot external surface area
(m2/g)
189.9
Average pore width (Å) 20.8
The adsorption of H2S and water molecules were determined
from the result of Thermal Gravimetric Analysis (TGA).TGA
was performed for both fresh and spent PSAC and the results
are shown in Figure 5. The derivative form of TGA is also
shown in Figure6.The weight of fresh PSAC was reduced
rapidly to 80% when temperature was increased to 1000C.
After that, the weight change of fresh PSAC was not
significant until 6000C. Spent PSAC, on the other hand, had a
weight reduction to 85% at 1000C, and the second cycle of
weight change occurred between 200-4000C. In addition, total
weight change of spent PSAC is larger than fresh PSAC
within the temperature range of the analysis, denoting spent
PSAC contained larger amount of adsorbed substances than
fresh PSAC. As shown in Figure 6, fresh PSAC only have one
peak formed. Spent PSAC shares the same peak with fresh
PSAC but possess additional peak at 200-4000C. The first
peak denotes tothe desorption of water molecules. In the H2S
adsorption operation, moisture was added to the gas stream
because it plays an important role in the adsorption process.
Therefore, spent PSAC could contain up to 15 wt% of
moisture, especially due to the long duration of the operation.
The second peak of DTG for spent PSAC denotes the release
of SO2 because oxidative atmosphere was used in the analysis
[5]. In this study, the peak that denotes to elemental sulfur was
not detected at 450-4700C [5], thereforestrengthening the
claim that the adsorption of H2S was mostly physisorption
process. Apart from that, approximately 10% weight reduction
in the 200-4000C region can be used to compare with the
adsorption capacity of PSAC (122.2 mg/g). The value of the
adsorption capacity showed that PSAC could adsorb about
12.22% H2S. Therefore, if adsorbed H2S were removed,
weight reduction of PSAC will be 12.22%, which is similar
with the results from TGA. This confirms the second peak as
H2S desorption.
170
180
190
200
210
220
230
240
250
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
cm³/gSTP
P/Po

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Figure 5.Weight % versus temperature.
Figure6. DTG curves of fresh and spent PSAC.
Figure 7 and 8 shows the SEM micrographs of fresh and spent
PSAC, respectively at various magnifications. The surface of
fresh PSAC was found to be cratered. The diameter of the
craters is in the magnitude of 30µm. Further magnification on
the crater shows a porous surface. The pores are generally
between 1-2µm. This kind of porous structure is the main
reason PSAC possesses high surface area, as determined from
N2 adsorption desorption analysis. Spent PSAC on the other
hand, possess different structure with fresh PSAC. Bone-like
structure was found and it is believed to be the product of H2S
adsorption process. EDX result shows that it contains 3.35%
sulfur, which agree well with a 2.94% sulfur detected in a
CHNS elemental analyzer. Deposit of white agglomerates was
also found in fresh and spent PSAC, as shown in Figure 9. The
deposit was identified with EDX and it contains about 4%
copper and trace amount of magnesium, potassium, calcium,
silicon and iron. This could be the inert remains that did not
burn off during the preparation of PSAC from palm shell. The
effect of these inert remains towards H2S adsorption was not
studied.
70
75
80
85
90
95
100
0 100 200 300 400 500 600
Weight%
Temperature (0C)
fresh PSAC
spent PSAC
-5
-4
-3
-2
-1
0
0 100 200 300 400 500 600
DerivativeWeight%
Temperature (0C)
fresh PSAC
spent PSAC

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Figure7. SEM of fresh PSAC at various magnifications (a) 1000X, (b) 2000X, (c) 5000X and (d) 10000X.
Figure8. SEM of spent PSAC at various magnifications, (a) 1000X, (b) 2000X, (c) 5000X, (d) 10000X.

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Figure9. Magnification of agglomerates found on the spent PSAC surface.
CONCLUSIONS
H2S adsorption has been successfully performed using palm
shell activated carbon. In this study, reaction parameters such
as H2S concentration, adsorption temperature and space
velocity were studied using a statistical analytical method via
Design Expert Software. H2S concentration and space
velocity were found to be significant in affecting the
adsorption capacity, indicated by the generated mathematical
model. Interaction terms involving temperature were also
found affecting the adsorption capacity. Characterization of
fresh and spent PSAC confirm and provide further information
on the adsorption of sulfur species on PSAC pore structure.
ACKNOWLEDGMENTS
This research is financially supported by Program My Brain
15, Knowledge Transfer Program (KTP) Grant No. 6750012
and Research University Postgraduate Research Grant Scheme
(RU-PRGS) Grant No. 8045042.
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Adsorption of hydrogen sulfide using palm shell

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Adsorption of hydrogen sulfide using palm shell