RABIA AZIZ
BS-III CHEMISTRY
5/31/2017 1RABIA AZIZ
CONTENTS
 Introduction
 Sources Of Particulate Matter
 Industrial Sources of Particulate Emissions
 Types Of Particulate Matter
 Important Terms Describing Atmospheric
Particles
 Particulate Matter And Health
 General Methods For Control Of Particulate
Emissions
 Particulate Collection Mechanism
5/31/2017 2RABIA AZIZ
Introduction
 Particulate matter is a mixture of solid, liquid or solid and liquid
particles suspended in the air.
 These suspended particles vary in size, composition and origin.
 This complex mixture includes both organic and inorganic
particles, such as dust, pollen, soot, smoke, and liquid droplets.
 Sources of particulate matter can be man-made or natural.
 They have impacts on climate and precipitation that adversely
affect human health.
 Particulate matter makes up the most visible and obvious form
of air pollution.
 Pollutant particles in the 0.001–10 mm range are commonly
suspended in the air near sources of pollution such as the urban
atmosphere, industrial plants, highways, and power plants.
5/31/2017 3RABIA AZIZ
5/31/2017 4RABIA AZIZ
Particles Differ In Their Chemical Composition
Depending On Origin. They Are Usually Made Up
Of:
 salts in the form of nitrates, sulphates, carbonates,
chlorides, etc.,
 organic carbon compounds (PAHs, oxides, condensable
organic compounds, etc.) (called "organic carbon" and
written as OC).
 trace elements such as heavy metals, etc.,
 black carbon (BC).
5/31/2017 5RABIA AZIZ
5/31/2017 6RABIA AZIZ
 Particles are distinguished by size:
 Total Suspended Particles include all particles, of
whatever size,
 PM10 are particles less than 10 µm (10 microns) in
diameter,
 PM2.5 are particles less than 2.5 µm in diameter,
 Black Carbon emissions are based on a chemical speciation of
PM2,5 emissions
 PM1.0 are particles less than 1 µm in diameter,
 Particles which are 2.5 to 10 in diameter are called
coarse particles. Particles less than 2.5 in diameter
are called fine particles and include ultra-fine
particles of less than 0.1 µm (PM0.1).
5/31/2017 7RABIA AZIZ
coarse particles
Fine particles
Ultra-fine particles
5/31/2017 8RABIA AZIZ
Sources of Particulate matter
 Particulate matter emissions are generated from different
sources:
 Mechanical: powdering, crushing, cracking, transport of non-
cohesive materials, soil erosion (by wind for example), etc.
These particles are usually a few microns to a few hundred
microns in diameter.
 Chemical or thermal: These particles form when chemical
reactions or high-temperature evaporation followed by
condensation change the state of the material. These particles
range in size from a few nanometres to under 1 .
 Biological: pollen, fungi, bacteria.
5/31/2017 9RABIA AZIZ
 Emissions of particulate matter can therefore be from natural
sources or from human activities:
 Particulate matter emissions from human activities are closely
dependent on dust removal equipment, processes and operating
conditions.
 The main sources of emissions are:
 ploughing,
 construction sites, public works and civil engineering,
 quarrying,
 combustion of solid mineral fuels, liquid fuels and biomass.
 The order of importance of emissions from these different
sources depends on the size distribution of the particles
considered.
 Particulate matter emissions from natural sources are closely
related to climate and natural conditions (wind erosion, forest
fires, volcanic eruptions, pollen, wind-blown soil and sand, sea
salt etc.)
5/31/2017 RABIA AZIZ 10
5/31/2017 RABIA AZIZ 11
5/31/2017 12RABIA AZIZ
Industrial Sources of
Particulate Emissions
 Iron & Steel Mills, the blast furnaces, steel making furnaces.
 Petroleum Refineries, the catalyst regenerators, air-blown
asphalt stills, and sludge burners.
 Portland cement industry
 Asphalt batching plants
 Production of sulfuric acid
 Production of phosphoric acid
 Soap and Synthetic detergent manufacturing
 Glass & glass fiber industry
 Instant coffee plants
5/31/2017 RABIA AZIZ 13
Types Of Particulate Matter
 The different types of particulate matter may be
divided into three categories:
 primary particulate matter: directly released into the
atmosphere by a large number of human and natural
sources (see list above).
 secondary particulate matter: formed by physical and
chemical reactions from other pollutants, called
precursors.
 re-suspended particulate matter: after it has been
deposited, particulate matter can then return into the
air through wind action or road traffic disturbance in
urban areas,
5/31/2017 14RABIA AZIZ
Important Terms Describing
Atmospheric Particles
Term Meaning
 Aerosol: Colloidal-sized atmospheric particle
 Condensation aerosol: Formed by condensation of
vapors or reactions of gases
 Dispersion aerosol: Formed by grinding of solids,
atomization of liquids, or dispersion of dusts
 Fog: Term denoting high level of water droplets
 Haze: Denotes decreased visibility due to the presence of
particles
 Mists: Liquid particles
 Smoke: Particles formed by incomplete combustion of fuel
5/31/2017 15RABIA AZIZ
5/31/2017 16RABIA AZIZ
PARTICULATE MATTER AND
HEALTH
5/31/2017 17RABIA AZIZ
5/31/2017 18RABIA AZIZ
Symptoms of exposure to particulate matter:
People with heart conditions may experience:
 Chest pain
 Irregular heartbeat
 Shortness of breath
 Fatigue
 Heart attacks
 Coronary artery disease (CAD) is the most common
heart problem related to long term exposure to PM2.5
5/31/2017 19RABIA AZIZ
 People with lung conditions may experience:
 Coughing
 Shortness of breath
 Decreased ability to breathe deeply or vigorously
 Increased susceptibility to respiratory infections
 Aggravation of existing lung conditions like asthma and
chronic bronchitis
 Healthy people may experience temporary symptoms
like:
 Eye, nose, and throat irritation
 Coughing
 Chest tightness
 Shortness of breath
5/31/2017 20RABIA AZIZ
General Methods For Control
Of Particulate Emissions
 Five Basic Types of Dust Collectors:
Gravity and Momentum collectors
 Settling chambers, louvers, baffle chambers
Centrifugal Collectors
 Cyclones
 Mechanical centrifugal collectors
Fabric Filters
 Baghouses
 Fabric collectors
5/31/2017 RABIA AZIZ 21
5/31/2017 RABIA AZIZ 22
Electrostatic Precipitators
 Tubular
 Plate
 Wet
 Dry
Wet Collectors
 Spray towers
 Impingement scrubbers
 Wet cyclones
 Peaked towers
 Mobile bed scrubbers
5/31/2017 RABIA AZIZ 23
Particulate Collection
Mechanism
 Gravity Settling
 Centrifugal Impaction
 Inertial Impaction
 Direct Interception
 Diffusion
 Electrostatic Effects
5/31/2017 RABIA AZIZ 24
5/31/2017 RABIA AZIZ 25

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Atmospheric particulate matter

  • 2. CONTENTS  Introduction  Sources Of Particulate Matter  Industrial Sources of Particulate Emissions  Types Of Particulate Matter  Important Terms Describing Atmospheric Particles  Particulate Matter And Health  General Methods For Control Of Particulate Emissions  Particulate Collection Mechanism 5/31/2017 2RABIA AZIZ
  • 3. Introduction  Particulate matter is a mixture of solid, liquid or solid and liquid particles suspended in the air.  These suspended particles vary in size, composition and origin.  This complex mixture includes both organic and inorganic particles, such as dust, pollen, soot, smoke, and liquid droplets.  Sources of particulate matter can be man-made or natural.  They have impacts on climate and precipitation that adversely affect human health.  Particulate matter makes up the most visible and obvious form of air pollution.  Pollutant particles in the 0.001–10 mm range are commonly suspended in the air near sources of pollution such as the urban atmosphere, industrial plants, highways, and power plants. 5/31/2017 3RABIA AZIZ
  • 5. Particles Differ In Their Chemical Composition Depending On Origin. They Are Usually Made Up Of:  salts in the form of nitrates, sulphates, carbonates, chlorides, etc.,  organic carbon compounds (PAHs, oxides, condensable organic compounds, etc.) (called "organic carbon" and written as OC).  trace elements such as heavy metals, etc.,  black carbon (BC). 5/31/2017 5RABIA AZIZ
  • 7.  Particles are distinguished by size:  Total Suspended Particles include all particles, of whatever size,  PM10 are particles less than 10 µm (10 microns) in diameter,  PM2.5 are particles less than 2.5 µm in diameter,  Black Carbon emissions are based on a chemical speciation of PM2,5 emissions  PM1.0 are particles less than 1 µm in diameter,  Particles which are 2.5 to 10 in diameter are called coarse particles. Particles less than 2.5 in diameter are called fine particles and include ultra-fine particles of less than 0.1 µm (PM0.1). 5/31/2017 7RABIA AZIZ
  • 8. coarse particles Fine particles Ultra-fine particles 5/31/2017 8RABIA AZIZ
  • 9. Sources of Particulate matter  Particulate matter emissions are generated from different sources:  Mechanical: powdering, crushing, cracking, transport of non- cohesive materials, soil erosion (by wind for example), etc. These particles are usually a few microns to a few hundred microns in diameter.  Chemical or thermal: These particles form when chemical reactions or high-temperature evaporation followed by condensation change the state of the material. These particles range in size from a few nanometres to under 1 .  Biological: pollen, fungi, bacteria. 5/31/2017 9RABIA AZIZ
  • 10.  Emissions of particulate matter can therefore be from natural sources or from human activities:  Particulate matter emissions from human activities are closely dependent on dust removal equipment, processes and operating conditions.  The main sources of emissions are:  ploughing,  construction sites, public works and civil engineering,  quarrying,  combustion of solid mineral fuels, liquid fuels and biomass.  The order of importance of emissions from these different sources depends on the size distribution of the particles considered.  Particulate matter emissions from natural sources are closely related to climate and natural conditions (wind erosion, forest fires, volcanic eruptions, pollen, wind-blown soil and sand, sea salt etc.) 5/31/2017 RABIA AZIZ 10
  • 13. Industrial Sources of Particulate Emissions  Iron & Steel Mills, the blast furnaces, steel making furnaces.  Petroleum Refineries, the catalyst regenerators, air-blown asphalt stills, and sludge burners.  Portland cement industry  Asphalt batching plants  Production of sulfuric acid  Production of phosphoric acid  Soap and Synthetic detergent manufacturing  Glass & glass fiber industry  Instant coffee plants 5/31/2017 RABIA AZIZ 13
  • 14. Types Of Particulate Matter  The different types of particulate matter may be divided into three categories:  primary particulate matter: directly released into the atmosphere by a large number of human and natural sources (see list above).  secondary particulate matter: formed by physical and chemical reactions from other pollutants, called precursors.  re-suspended particulate matter: after it has been deposited, particulate matter can then return into the air through wind action or road traffic disturbance in urban areas, 5/31/2017 14RABIA AZIZ
  • 15. Important Terms Describing Atmospheric Particles Term Meaning  Aerosol: Colloidal-sized atmospheric particle  Condensation aerosol: Formed by condensation of vapors or reactions of gases  Dispersion aerosol: Formed by grinding of solids, atomization of liquids, or dispersion of dusts  Fog: Term denoting high level of water droplets  Haze: Denotes decreased visibility due to the presence of particles  Mists: Liquid particles  Smoke: Particles formed by incomplete combustion of fuel 5/31/2017 15RABIA AZIZ
  • 19. Symptoms of exposure to particulate matter: People with heart conditions may experience:  Chest pain  Irregular heartbeat  Shortness of breath  Fatigue  Heart attacks  Coronary artery disease (CAD) is the most common heart problem related to long term exposure to PM2.5 5/31/2017 19RABIA AZIZ
  • 20.  People with lung conditions may experience:  Coughing  Shortness of breath  Decreased ability to breathe deeply or vigorously  Increased susceptibility to respiratory infections  Aggravation of existing lung conditions like asthma and chronic bronchitis  Healthy people may experience temporary symptoms like:  Eye, nose, and throat irritation  Coughing  Chest tightness  Shortness of breath 5/31/2017 20RABIA AZIZ
  • 21. General Methods For Control Of Particulate Emissions  Five Basic Types of Dust Collectors: Gravity and Momentum collectors  Settling chambers, louvers, baffle chambers Centrifugal Collectors  Cyclones  Mechanical centrifugal collectors Fabric Filters  Baghouses  Fabric collectors 5/31/2017 RABIA AZIZ 21
  • 23. Electrostatic Precipitators  Tubular  Plate  Wet  Dry Wet Collectors  Spray towers  Impingement scrubbers  Wet cyclones  Peaked towers  Mobile bed scrubbers 5/31/2017 RABIA AZIZ 23
  • 24. Particulate Collection Mechanism  Gravity Settling  Centrifugal Impaction  Inertial Impaction  Direct Interception  Diffusion  Electrostatic Effects 5/31/2017 RABIA AZIZ 24