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CHEMISTRY
ATOMIC SRUCTURE AND
BONDING
Short video tutorial series
 • So … what are the possible combinations of states?
 • Notation
 n L
 1 K 0 s
 2 L 1 p
 3 M 2 d
 4 N 3 f
 • We can describe an electron state as 1s or 3p or 5f
 Energy levels of the electron states
 • the energy of an electron is determined by its state
 • If there is only one electron in the atom, the
energy depends on n alone
 • If there are more electrons, they interact (repel each
other), and so different states have different energies
valence
 The electrons in the outer shell (largest n) are
called
 valence electrons
 Very important for chemical reactions and
holding matter together
 If the outer shell is filled, the atom is inert
 If not, there is a tendency for the outer shell to
become filled
 Electronegative – if it is almost full, the atom has
a tendency to gain enough electrons to fill the
shell
 Electropositive – if it is almost empty, it easily
losses the electrons in the outer shell
Valence and chemical reactivity
 Noble gases: s2p6 configuration
 Ne: 1s22s2p6
 Electronegative – if it is almost full, the atom has
a tendency to gain enough electrons to fill the
shell
 Cl: 1s22s2p63s2p5 or [Ne] 3s2p5
 Cl + 1e = Cl- negative ion (anion)
 Electropositive – if it is almost empty, it easily
losses the electrons in the outer shell (typically
metals)
 K: 1s22s2p63s2p64s1 or [Ar] 4s
 K – 1e = K+ positive ion (cation)
Types of chemical bonding
2 main types of chemical combination
 Ionic (or electrovalent combination)
 Covalent which is classed into 2
 Ordinary covalent
 Coordinate covalent
Ionic bonding
 Typically between highly electropositive
(metallic) and electronegative (nonmetallic)
elements
 NaCl
 Na 1s22s2p63s Cl 1s22s2p63s2p5
Na+ 1s22s2p6 Cl- 1s22s2p63s2p6
Atomic sructureandbonding
Covalent bonding
 Takes place between elements with small
difference in electronegativity
 - F, O, N, Cl, H, C, Si…
 s and p electrons are commonly shared to
attain noble gas electron configuration
 Multiple bonds can be formed by one atom
 Eg in H molecule
 2 H: 1s → H2 1s2
 H· + H· →H : H (electron –pair covalent
bond)
• O 2s22p4
• N 2s22p3
Other binding forces
 Metallic bond
 Van der waal’s
 Hydrogen bonds

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Atomic sructureandbonding

  • 2.  • So … what are the possible combinations of states?  • Notation  n L  1 K 0 s  2 L 1 p  3 M 2 d  4 N 3 f  • We can describe an electron state as 1s or 3p or 5f  Energy levels of the electron states  • the energy of an electron is determined by its state  • If there is only one electron in the atom, the energy depends on n alone  • If there are more electrons, they interact (repel each other), and so different states have different energies
  • 3. valence  The electrons in the outer shell (largest n) are called  valence electrons  Very important for chemical reactions and holding matter together  If the outer shell is filled, the atom is inert  If not, there is a tendency for the outer shell to become filled  Electronegative – if it is almost full, the atom has a tendency to gain enough electrons to fill the shell  Electropositive – if it is almost empty, it easily losses the electrons in the outer shell
  • 4. Valence and chemical reactivity  Noble gases: s2p6 configuration  Ne: 1s22s2p6  Electronegative – if it is almost full, the atom has a tendency to gain enough electrons to fill the shell  Cl: 1s22s2p63s2p5 or [Ne] 3s2p5  Cl + 1e = Cl- negative ion (anion)  Electropositive – if it is almost empty, it easily losses the electrons in the outer shell (typically metals)  K: 1s22s2p63s2p64s1 or [Ar] 4s  K – 1e = K+ positive ion (cation)
  • 5. Types of chemical bonding 2 main types of chemical combination  Ionic (or electrovalent combination)  Covalent which is classed into 2  Ordinary covalent  Coordinate covalent
  • 6. Ionic bonding  Typically between highly electropositive (metallic) and electronegative (nonmetallic) elements  NaCl  Na 1s22s2p63s Cl 1s22s2p63s2p5 Na+ 1s22s2p6 Cl- 1s22s2p63s2p6
  • 8. Covalent bonding  Takes place between elements with small difference in electronegativity  - F, O, N, Cl, H, C, Si…  s and p electrons are commonly shared to attain noble gas electron configuration  Multiple bonds can be formed by one atom  Eg in H molecule  2 H: 1s → H2 1s2  H· + H· →H : H (electron –pair covalent bond)
  • 9. • O 2s22p4 • N 2s22p3
  • 10. Other binding forces  Metallic bond  Van der waal’s  Hydrogen bonds