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8
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10
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1
2 < L/D < 20
UG,sup up to 50 cm/s
UG,sup >> UL,sup
Liquid
Gas
Gas Inlet
Liquid/Slurry Inlet
Gas
Liquid
Pool
Sparger
A bubble column is a liquid
pool sparged by a process
stream.
Bubble Column Reactor
Advantages
Simple construction, and
low capital cost;
No moving parts, and
minimum maintenance;
Ability to handle solids;
Ease of temperature
control.
Disadvantages
High pressure drop of the
gas due to high static head
of the liquid;
G/L area decreases if the
ratio of height to diameter
exceeds 12, because of
bubble coalescence
Bubble Column Reactors
3
Bubbly Flow
Churn-Turbulent Flow
(“Heterogeneous”)
Bubble columns: flow regimes
Bubble columns: flow regimes
Types of Bubble Columns
6
Bubble column design issues
• Design parameters:
– Gas holdup. Directly related to rise velocity. Correlations of the
form
a ~ usg
a
rl
b
sc
ml
d
are commonly used.
– Mass transfer coefficient kla. Correlations of the form
kla ~ usg
a
rl
b
sc
ml
d
mg
e
Df
Drg
are commonly used.
– Axial dispersion occurs in both the liquid and gas phase, and
correlations for each are not available.
– Mixing time. Correlations are available for a limited number of
systems.
– Volume, flow rates and residence time.
– Flow regime: homogeneous, heterogeneous, slug flow.
7
Bubble column design issues - cont’d
• Accurate knowledge of the physical properties is important,
especially the effects of coalescence and mass transfer
affecting chemicals.
• Although good correlations are available for commonly
studied air-water systems, these are limited to the ranges
studied.
• Correlations may not be available for large scale systems or
systems with vessel geometries other than cylinders without
internals.
• Furthermore, experimental correlations may not accurately
reflect changes in performance when flow regime transitions
occur.
Dynamic macroscopic flow structures :
Chen et al. (1994) and Lin et al. (1996)
Qualitative description of existing flow
regimes: Diaz et al. (2006, 2008)
Flow Structures in Bubble Column
Two Circulation
Cells (cooling
tower mode)
Aspect ratio (H/W)
Air
Superficial
Velocity
(mm/s)
0 5 10 15 20
0
5
10
15
20
20
0 5 10 15 20
0
5
10
15
20
25
x (cm)
z
(cm)
0 5 10 15 20
0
10
20
30
40
50
60
70
80
0 5 10 15 20
0
10
20
30
40
50
60
70
80
0 5 10 15 20
0
10
20
30
40
50
60
70
80
0 5 10 15 20
0
10
20
30
40
50
60
70
80
5 10 15 20
0
5
10
15
20
25
30
35
40
45
5 10 15
5
10
15
20
25
30
35
40
45
5 10 15 20
0
5
10
15
20
25
30
35
40
45
0 5 10 15 20
5
10
15
20
25
30
35
40
45
1 2.25 4
1.33
8.33
12.5
16.7
Plume
Oscillation
Single Circulation
Two
distinct
zones are
observed
No Plume
Oscillation
Air lift Reactor

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Bubble column and designing models with flow

  • 1. 1 2 < L/D < 20 UG,sup up to 50 cm/s UG,sup >> UL,sup Liquid Gas Gas Inlet Liquid/Slurry Inlet Gas Liquid Pool Sparger A bubble column is a liquid pool sparged by a process stream. Bubble Column Reactor
  • 2. Advantages Simple construction, and low capital cost; No moving parts, and minimum maintenance; Ability to handle solids; Ease of temperature control. Disadvantages High pressure drop of the gas due to high static head of the liquid; G/L area decreases if the ratio of height to diameter exceeds 12, because of bubble coalescence Bubble Column Reactors
  • 5. Types of Bubble Columns
  • 6. 6 Bubble column design issues • Design parameters: – Gas holdup. Directly related to rise velocity. Correlations of the form a ~ usg a rl b sc ml d are commonly used. – Mass transfer coefficient kla. Correlations of the form kla ~ usg a rl b sc ml d mg e Df Drg are commonly used. – Axial dispersion occurs in both the liquid and gas phase, and correlations for each are not available. – Mixing time. Correlations are available for a limited number of systems. – Volume, flow rates and residence time. – Flow regime: homogeneous, heterogeneous, slug flow.
  • 7. 7 Bubble column design issues - cont’d • Accurate knowledge of the physical properties is important, especially the effects of coalescence and mass transfer affecting chemicals. • Although good correlations are available for commonly studied air-water systems, these are limited to the ranges studied. • Correlations may not be available for large scale systems or systems with vessel geometries other than cylinders without internals. • Furthermore, experimental correlations may not accurately reflect changes in performance when flow regime transitions occur.
  • 8. Dynamic macroscopic flow structures : Chen et al. (1994) and Lin et al. (1996) Qualitative description of existing flow regimes: Diaz et al. (2006, 2008) Flow Structures in Bubble Column
  • 9. Two Circulation Cells (cooling tower mode) Aspect ratio (H/W) Air Superficial Velocity (mm/s) 0 5 10 15 20 0 5 10 15 20 20 0 5 10 15 20 0 5 10 15 20 25 x (cm) z (cm) 0 5 10 15 20 0 10 20 30 40 50 60 70 80 0 5 10 15 20 0 10 20 30 40 50 60 70 80 0 5 10 15 20 0 10 20 30 40 50 60 70 80 0 5 10 15 20 0 10 20 30 40 50 60 70 80 5 10 15 20 0 5 10 15 20 25 30 35 40 45 5 10 15 5 10 15 20 25 30 35 40 45 5 10 15 20 0 5 10 15 20 25 30 35 40 45 0 5 10 15 20 5 10 15 20 25 30 35 40 45 1 2.25 4 1.33 8.33 12.5 16.7 Plume Oscillation Single Circulation Two distinct zones are observed No Plume Oscillation