2. Chemical reactions have been a part of this
world ever since everything began. From Big
bang to the present day, everything
happening around us has something to do with
chemical reactions and chemical processes.
3. Chemical reactions are common in
our daily lives: from cooking, eating,
and cleaning to the different
chemical processes like respiration,
corrosion, and fermentation.
4. How our body lives and grows are result of
many chemical reactions that take place,
although you may not recognize them. This is
the reason we need to understand how
chemical processes take place, be they
naturally occurring or not.
5. THE COLLISIONTHEORY
All substances are comprised of millions of
tiny particles in constant motion. These
particles are colliding with each other
constantly in any substance. All collisions
between particles do not result in a reaction.
6. THERE ARE TWO FACTORS THAT DETERMINE WHETHER A
REACTION WILL OCCUR BETWEEN TWO PARTICLES THAT
ARE COLLIDING:
1. Substances or particles of reactants must
physically collide with enough energy
2. Substance or particles must come into contact
or collide in the correct orientation (facing the
correct way).
7. The collision theory states that reacting
substances must come into contact (collide)
with enough activation energy, and in the
correct orientation (facing the correct way),
so that their electron shells can rearrange
to form the products of the reaction.
8. Therefore, any factor which
changes the frequency or
energy of the collisions will
change the rate of the reaction.
10. Two atoms of Nitrogen react with two
atoms of Oxygen to yield two molecules
of Nitrogen Oxide. The shared atoms
form a bond by completing the valence
shells of both atoms.
12. A chemical reaction does not take
place if the collision between
molecules does not have sufficient
energy to break the bonds in the
reactants and if the molecules are not
properly aligned.
13. WHAT IS A CHEMICAL REACTION?
When two particles collide, sometimes a chemical
reaction can occur, which means the bonds between
two or more particles are broken and reformed,
creating one or more new substances. The
substances or particles that enter and are changed
in the chemical reaction are called reactants and
the substances that are formed are called products.
14. LET US LOOK AT THE CHEMICAL REACTION IN
PHOTOSYNTHESIS:
15. The reactants (left part of the equation)
are carbon dioxide, water, and light
while the products (right side of the
equation) are sugar and oxygen. But for
a chemical reaction to occur, several
things must happen:
16. •1. The particles must
come into contact with
one another or collide.
17. • 2. When the particles collide, the particles
must be aligned correctly so that the right
parts of the atoms or molecules are
exposed. If they are not oriented
correctly, no chemical reaction will take
place.
18. •3. The particles must collide with enough energy
to break their chemical bonds. The amount of
energy that must be available for a reaction to
occur is often referred to as the activation
energy. It is the measure of the change in the
concentration of the reactants or products.
19. The reaction rate of a chemical
reaction is a measurement of the
increase in the concentration of a
product or the decrease in the
concentration of a reactant as the
reaction proceeds over time.
20. The rate of reaction also depends on the
type of molecules that are combined. If
there are low concentrations of an
essential element or compound, the
reaction will be slower.
21. FACTORS AFFECTING THE RATE OF
REACTION
• 1. Activation Energy
• The activation energy refers to the minimum energy required for a
reaction to take place. When a collision provides energy equal to or
greater than the activation energy, a product can form. On the other
hand, if the particles have energy that is less than the activation
energy, the collision is not effective, and they just bounce off each
other unchanged.
23. The figure above shows a man trying to push a
rock over the cliff. For the man to push the
rock, he needs to have enough energy. If the
man does not have enough energy, the rock
will not move down the cliff. This energy
needed for the man to push the rock over the
cliff represents the activation energy.
24. • 2. Temperature
• Temperature refers to how hot or cold a certain substance is.
Usually, a rise in temperature of 10 0
C doubles the reaction
rate. The rate of a chemical reaction increases with increasing
temperature. As the temperature increases, a collision
between atoms and molecules becomes faster resulting in the
build-up of more energy. The increased kinetic energy will
equal to or exceed the activation energy resulting in more
collisions giving rise to a reaction.
25. • 3. Concentration
• The rate of a chemical reaction is affected by the concentration of reacting
substances. The term concentration refers to the number of particles present in a
given volume of solution. Concentration may also mean a measure of how much of of
the solute (something to be dissolved) is dissolved in a solvent (dissolving medium)
to form a homogeneous mixture. So, a higher concentration means there is more of
the solute in the solution. If the concentration of the reactant is increased, the rate
of reaction also increases. When the number of particles of the reactant is
increased, there is a great chance for particles to collide.
26. • 4. Surface Area and Particle Size
• Surface area is the measure of how much-exposed area a solid
object has, expressed in square units. In a reaction between a
solid and a liquid, the more finely divided a solid is, the faster
is the rate of reaction. Likewise, as you powder a solid, its
surface area becomes greater, thus the particles have a higher
chance of colliding, and a faster reaction happens.