Conductometry titration

CONDUCTOMETRY
DEPARTMENT OF PHARMACY,
DR. B. R. AMBEDKAR UNIVERSITY,
AGRA-282002
PREPARED BY
KRISHNA KUMAR SUBMITTED TO
B.PHARM IVSEM MR. VIJAY YADAV
krishnaworldpharma@gmail.com

CONDUCTOMETRY
 INTRODUCTION
 PRINCIPLE
 IMPORTANT DEFINITIONS & RELATIONS
 INSTRUMENTATIONS
 MEASUREMENT OF CONDUCTIVITY
 CONDUCTOMETRIC TITRATIONS
 ADVANTAGES & DISADVANTAGES OF
CONDUCTOMETRIC TITRATIONS
 APPLICATIONS OF CONDUCTOMETRY

 INTODUCTION:
 It is an electrochemical method of analysis concerned with
electrical conductance through an electrolyte solution .
( or)
 It is defined has as determination or measurement of the
electrical conductance of an electrolyte solution by means of
a conductometer .
 electric conductivity of an electrolyte solution depends on :
1. Type of ions (cations, anions, singly or doubly
charged
2. Concentration of ions
3. Temperature
4. Mobility of ions

 PRINCIPLE:
 Based on the conductance of electrical current through
electrolyte solutions similar to metallic conductors
 The electric conductance in accordance with ohms law
which states that the stength of current(i)passing
through conductor is directly porportional to potential
difference & inversely to resistance.
i =V/R

 Important definitions & relations
 Conductance
 Specific conductance
 Molar conductance
 Equivalent conductance
 Resistance
 Specific resistance

 Conductance:(G)
ease with which current flows per unit area of
conductor per unit potential applied & is reciprocal
to resistance(R)
G = I ⁄ R
o Specific conductance (K):
 conductance of the body of uniform length(l)
&uniform area cross section(A)
K =1 ⁄ R × 1 ⁄ A
• Molar conductance: (^)
Conductance of a solution containing 1 mole of
the solute in 1000 cm of the solution which
placed between two parallel electrodes which are
1 cm apart
^ = 1000 ⁄ C

 Equivalent conductance: (^eq)
 specific conductance of the solution
containing 1gm equivalent of solute in
1000cm3 of solution.
^eq =1000k ⁄ ceq
 Resistance (r):
 Is a measure of the conductors opposition to the
flow of electric charge
R =1/G
• Specific resistance:(ρ)
 Is resistance offered by a conductor of unit
length and having unit cross section
R ∞ l ⁄ A

 Instrumentation
The instrument used for measurement of
conductance are know as conductometers
It consists of :
1. Current source
• Alternating current source
2. Conductivity cells
• Wide mouthed cells
• Cell for reactions producing precipitates
• Dip type cells
3. Electrodes

CURRENT SOURCE:-
1. Mechanical high frequency AC generator by Washburn .
2. Vreeland oscillator by Taylor and Acree.
3. Vaccum tube oscillator by Hall & Adams.
 When electical potential is applied across
electrodes two process occurs.
 Ions accumulate near the electrodes.
 Transfer of charge through the interface.
 Note : DC current is not employed in conductance
measurement because
1. Electrodes becomes polarised leading to high cell
resistance.

 Conductivity cells:-
 Made of pyrex or quartz and are fitted with two platinum
electrodes.
 Should be placed in vessel containing water to maintain
constant temperature
 Types :
1. Wide mouthed cell
2. Cell for reactions producing precipitation
3. Dip type cells

 Wide mouthed cell:-
 Measurement of low conductance
 Wide mouthed fitted with an ebonite cover
which has provisions for platinum electrodes
and burettes

 Cell for reactions producing ppts:
 Mainly used for ppt reactions
 Also wide mouthed fitted with ebonite cover
which has provisions for burette ,electrode ,
stirrer
 Stirrer may be mechanical or magnetic

 Electrodes:
 Platinum sheets, each of 1 cm2 are fixed at distance
of 1 cm
 The surface is coated with platinum black to avoid
polarization effects and increase effective surface
area.
 Platinisation of electrodes is done by coating
solution of 3% chlorplatinic acid and lead acetate
on it to get uniform coating
 Electrodes usage depends on conductivity and
concentration
 If conc is low then electrodes should be largely and
closely packed

 Measurement:-
 The instrument used to measure conductance is
called conductance bridge or conductometer
 Classical circuit employed for measurement is
wheatstone bridge
 All other work on this principle
 Various types are:
1. Kohlrausch conductance bridge
2. Direct reading conductance bridge
3. Phillips conductance bridge
4. Mullard’s conductance bridge
5. Pye’s conductance bridge

 Kohlrausch conductance bridge:
 Consists of a meter bridge XY with fixed
resistors r’ & r” at both ends. One arm of
bridge consists of resistance box ‘R’ & other
arm with conductivity cell ’C’. Detector D is
head phone while inductance coil ‘J’ is AC
source which is operated by battery.
• Direct reading conductance bridge:-
• In this head phone is replaced by magic eye
which is electronic device

 The set up for Measurement :
consists of meter bridge LN attached to standard
resistance R1 & unknown resistance R2
cell is connected to standard resistance to one side ,
meter bridge LN at other. The sliding contact with galvanometer
(G) can be moved on the wire of meter bridge by means of jockey
(M) so that resistance of unknown is balanced with that of
standard. When galvanometer shows null deflection, the
resistance of unknown is measured by following equation:
ML ⁄ NL =R2 ⁄ R1
R2 =ML ⁄ NL × R1

Conductivity cell
Solution
Meter bridge

 Hence conductivity of unknown solution:
1 ⁄ R2 =NL ⁄ ML × R1
The measured conductivity (1/R1) is not always
equal to the specific conductivity of solution , because the
physical configuration of platinum electrode i.e, length and
area of electrodes varies from one another . Hence
conductivity of solution is obtained by calculating a factor
called “cell constant”.

 Cell constant:
Defined as ratio of distance between
the two electrodes(l) to the area of electrodes(A)
There fore,
θ =1 ⁄ A

 CONDUCTOMETRIC TITRATIONS:
 INTRODUCTION:
 Is process of qualitative chemical analysis in
which conc of sample is determined.Which is
done by adding areagent( titrant ) of known
conc in measured volumes to the sample
(anylate )

 TYRES OF CONDUCTOMETRIC TITRATIONS:
 Acid –base or neutral titrations
 Replacement or displacement titrations
 Redox titrations
 Precipitation titrations
 Complexometric titrations
 Non-aqueous titrations

1. ACID- BASE OR NEUTRAL TITRATIONS:
 STRONG ACID-STRONG BASE
• EG: HCL vs NaOH
 STRONG ACID-WEAK BASE
• EG: HCL vs NH4OH
 WEAK ACID-STRONG BASE
• EG: CH3COOH vs NaOH
 WEAK ACID -WEAK BASE
• EG: CH3COOH vs NH4OH

 Strong acid strong base:
 Fall in conductance due to replacement of high
conductivity Hydrogen ions by poor conductivity
sodium ions
 Rise in conductance due to increase in hydroxyl ions

 Strong acid- weak base:
 Fall in conductance due to replacement of
hydrogen by ammonium ions
 Conductance remain constant due to supression of
NH40H by NH4CL

 Weak acid –Strong base:
 Initial decrease in conductance followed by increase
due to NaOH
 Steep rise due to excess of NaOH

 Weak acid- weak base:
 Increase in conductance due to excess of
CH3COOH
 Constant conductance due to supression of NH4OH
by CH3COOH

 ADVANTAGE OF CONDUCTOMETRIC TITRATIONS:
1. Does not require indicators since change in
conductance is measured by conductometer
2. Suitable for coloured solutions
3. Since end point is determined by graphical
means accurate results are obtained with
minimum error
4. Used for analysis of turbid suspensions, weak
acids, weak bases, mix of weak & strong acids

 Dis advantages of conductometric titration:
1. Increased level of salts in solution masks the
conductivity changes , in such cases it does not
give accurate results
2. Application of conductometric titrations to redox
systems is limited because, high concentrations of
hydronium ions in the solution tends to mask the
changes in conductance

 Applications :
1. Check water pollution in rivers and lakes
2. Alkalinity of fresh water
3. Salinity of sea water (oceanography)
4. Deuterium ion concentration in water- deuterium
mixture
5. Food microbiology- for tracing micro organisms
6. Tracing antibiotics
7. Estimate ash content in sugar juices
8. Purity of distilled and de - ionised water can
determined
9. Solubility of sparingly soluble salts like
AgCl,BaSo4 can be detected
10. Determination of atmospheric so2,etimation of
vanillin in vanilla flavour

References
 Instrumental analysis by A. Skoog, F. James Holler
and Stanly R. Crouch.
 Text book of pharmaceutical analysis, third edition by
Dr.S.Ravi sankar.

Presented by
KRISHNA KUMAR
THE END

Conductometry titration

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Conductometry titration