In the 1920s, Louis de Broglie, Erwin Schrödinger, and Werner Heisenberg developed the electron cloud model of the atom. De Broglie proposed that electrons have wave-like properties, while Heisenberg established that the exact location and momentum of a particle cannot be known simultaneously. Schrödinger then created mathematical equations to predict the probability of finding electrons in certain regions or orbitals, rather than fixed orbits. This led to the concept of an electron cloud showing the probable locations of electrons around the nucleus.