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Electron
Configuration
Is the representation of the arrangement of electrons
distributed among the orbital shells and subshells within an
atom.
www.naturalbornscientist.com
Remember the quantum numbers?
www.naturalbornscientist.com
www.naturalbornscientist.com
Quantum Numbers in the Periodic Table
www.naturalbornscientist.com
www.naturalbornscientist.com
The electron configuration is given by
the following rules:
Aufbau Principle
Aufbau comes from the German word "Aufbauen"
which means "to build". In essence when writing
electron configurations we are building up electron
orbitals as we proceed from atom to atom. As we
write the electron configuration for an atom, we will
fill the orbitals in order of increasing atomic number.
www.naturalbornscientist.com
Pauli Exclusion Principle
In an atom, no two electrons can have the same
four electronic quantum numbers. We are aware
that in one orbital a maximum of two electrons can
be found and the two electrons must have
opposing spins. That means one would spin up
(+1/2) and the other would spin down (-1/2).
www.naturalbornscientist.com
Hund's rule
Every orbital in a sublevel is singly occupied before
any orbital is doubly occupied. All of the electrons
in singly occupied orbitals have the same spin (to
maximize total spin). When assigning electrons to
orbitals, an electron first seeks to fill all the orbitals
with similar energy before pairing with another
electron in a half-filled orbital.
www.naturalbornscientist.com
There are three ways of writing the
electron configuration:
Orbital diagrams:
According to the
Aufbau and Hund’s
rule, each level will fill
one electron at a time
until all the orbitals are
full. In this diagram,
you can also see the
exclusion principle as
you represent the
electrons as vertical
arrows pointing on
opposite directions.
www.naturalbornscientist.com
Using the periodic table:
The periodic table is
arranged according to the
energy levels and sublevels.
As you go through the
periods in the periodic table,
you will notice how the
atomic number increases
and how each level is filled.
www.naturalbornscientist.com
Möeller Diagram:
It is a structure that guides
you through the sublevels
and indicates the energy
levels and numbers of
electrons on each one. By
guiding yourself with the
atomic number, you just
follow the arrows counting
the superscripts until you
reach the value of the
atomic number of the given
atom.
www.naturalbornscientist.com
REFERENCES:
• http://chemwiki.ucdavis.edu/Inorganic_Chemistry/Electronic_Configurations
• http://kaffee.50webs.com/Science/images/electronic_config2.JPG
• http://www.gobiernodecanarias.org/educacion/3/usrn/lentiscal/1-cdquimica-tic/applets/configuracionelectronica-
1/imagenes/DiagramaMoller.gif
• BURNS, Ralph A. Fundamentos de Química. Pearson Educación, 2003.
www.naturalbornscientist.com

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Electron configuration

  • 1. Electron Configuration Is the representation of the arrangement of electrons distributed among the orbital shells and subshells within an atom. www.naturalbornscientist.com
  • 2. Remember the quantum numbers? www.naturalbornscientist.com
  • 6. The electron configuration is given by the following rules: Aufbau Principle Aufbau comes from the German word "Aufbauen" which means "to build". In essence when writing electron configurations we are building up electron orbitals as we proceed from atom to atom. As we write the electron configuration for an atom, we will fill the orbitals in order of increasing atomic number. www.naturalbornscientist.com
  • 7. Pauli Exclusion Principle In an atom, no two electrons can have the same four electronic quantum numbers. We are aware that in one orbital a maximum of two electrons can be found and the two electrons must have opposing spins. That means one would spin up (+1/2) and the other would spin down (-1/2). www.naturalbornscientist.com
  • 8. Hund's rule Every orbital in a sublevel is singly occupied before any orbital is doubly occupied. All of the electrons in singly occupied orbitals have the same spin (to maximize total spin). When assigning electrons to orbitals, an electron first seeks to fill all the orbitals with similar energy before pairing with another electron in a half-filled orbital. www.naturalbornscientist.com
  • 9. There are three ways of writing the electron configuration: Orbital diagrams: According to the Aufbau and Hund’s rule, each level will fill one electron at a time until all the orbitals are full. In this diagram, you can also see the exclusion principle as you represent the electrons as vertical arrows pointing on opposite directions. www.naturalbornscientist.com
  • 10. Using the periodic table: The periodic table is arranged according to the energy levels and sublevels. As you go through the periods in the periodic table, you will notice how the atomic number increases and how each level is filled. www.naturalbornscientist.com
  • 11. Möeller Diagram: It is a structure that guides you through the sublevels and indicates the energy levels and numbers of electrons on each one. By guiding yourself with the atomic number, you just follow the arrows counting the superscripts until you reach the value of the atomic number of the given atom. www.naturalbornscientist.com
  • 12. REFERENCES: • http://chemwiki.ucdavis.edu/Inorganic_Chemistry/Electronic_Configurations • http://kaffee.50webs.com/Science/images/electronic_config2.JPG • http://www.gobiernodecanarias.org/educacion/3/usrn/lentiscal/1-cdquimica-tic/applets/configuracionelectronica- 1/imagenes/DiagramaMoller.gif • BURNS, Ralph A. Fundamentos de Química. Pearson Educación, 2003. www.naturalbornscientist.com