J.J. Thomson discovered electrons through his experiments with cathode ray tubes in 1897. He observed that something was moving from the cathode to the anode, even through a vacuum. To determine if these particles carried an electrical charge, Thomson passed cathode rays through an electric field. He found that the particles were deflected towards the positive plate, indicating they were negatively charged particles. This led Thomson to conclude that the particles, which he named "corpuscles," were subatomic constituents within atoms that could be broken off, contradicting prevailing theories that atoms were indivisible. His discovery of electrons and their negative charge was a major breakthrough in understanding atomic structure.