International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 06 Issue: 06 | June 2019 www.irjet.net p-ISSN: 2395-0072
© 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 3828
EFFECT OF DIFFERENT CURING ON STRENGTH OF CONCRETE
RAM PRATAP YADAV1, KUNDAN KULBUSHAN2
1M.Tech, Department of Civil Engineering, Maharishi University of Information Technology, Lucknow, U.P.
2Assistant Professor, Department of Civil Engineering, Maharishi University of Information Technology,
Lucknow, U.P.
---------------------------------------------------------------------***----------------------------------------------------------------------
Abstract - Normal concrete was prepared with a water-cement ratio of 0.50. cube specimens were cast for testing the
compressive strength at 7 and 28 days of curing respectively using three curing methodsnamelyimmersion, sprinkling andPlastic
sheeting, curing to cure the cube specimens until the day of testing. Test results indicates that water curing (WAC) as well as
sprinkling (spraying) curing provided much better results than membrane (Plastic Sheeting) method of curing. Therateofdrying
was significant when the specimens were subjected to membrane (Plastic sheeting) method of curing. This thus hampered the
hydration process and thus affected the compressive strength property of the hardened concrete. The overall finding of this study
suggests that concrete should be cured by water curing to achieve a better compressive strength.
Key Words: concrete, course aggregate, cement, curing, compressive strength test.
1. INTRODUCTION
Concrete in general is the most commonly used structural material and it consists essentially from mixing water, cement,
aggregate and if necessary special additives withselectedconcreteproportionsoftheingredientstoproduceconcretemixwith
specific properties. The concrete has to be satisfactory in its hardened state and also in its fresh state while being transported
from the mixer and placed in the form work. The requirements in the fresh state are that the consistenceofthe mixis suchthat
it can be compacted by the means desired without excessive effort, and also that the mix be cohesive enough forthe methodof
placing used, not to produce segregation with consequent lack ofthefinishedproduct.Theusual primaryrequirementsofgood
concrete in its hardened state are satisfactory compressive strength, density, durability, tensile strength, etc., are considered.
The selection of more suitable and economical mix can be made, using mix design to give concrete with specified conditions
and any defect in the mix ingredient may cause some problems in the concrete mix, such as segregation, bleeding and may
cause shrinkage and creep after hardening. In warm to hot weathers, in-site concrete quality will vary for many reasons other
than selection of materials and design characteristics. Concrete changes in volume when it loses or gains water. Surface
cracking of fresh concrete occurs due to drying shrinkage caused by rapid loss of water in hot and dry climates. The rate at
which concrete will dry depends on air temperature, concrete temperature, relative humidity and wind velocity. The lack of
proper curing affects the quality of concrete in both fresh and hardened states.Concretehardensandgainsstrength becauseof
A chemical reaction between Portland cement and water. If concrete driesprematurely,therewill beinsufficientwaterforthat
reaction, i.e. .no water, no hydration, no strength gain. According to the standards, ponding is the most through method of
water curing but it is seldom used in the field because it is difficult and cumbersome. Fog spring or sprinkling with nozzles
provides excellent curing, but it requires constant vigilance. Burlap, wet sand and saw dust, usually providegoodcuringwhen
fully saturated. Sealing materials are sheets or membranes placed on the Concrete to reduce the loss of mixing water. Use of
plastic films is one way to protect the fresh concrete and can be applied as soonasfree waterhasdisappearedfrom thesurface.
Liquid membrane curing compounds are one of the practical methods of curing concrete.
2. MATERIALS AND METHODS
Materials:
Cement -
Portland Pozzolana Cement (fly ash based) brand name Birla Gold confirming to IS 1489 (Part 1) -1991wasusedinthisstudy.
Fine Aggregate -
River sand available in Allahabad confirming to IS 383-1970, zone II used in the study. It was completely passedby 4.75mmIS
sieve. Fineness modulus and specific gravity was 2.76 and 2.3 respectively.
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 06 Issue: 06 | June 2019 www.irjet.net p-ISSN: 2395-0072
© 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 3829
Coarse Aggregate -
Locally available coarse aggregate having two fraction 20mm and 10mm sizes individually sieved was used in the present
study. One fraction completely passed through 20 mm sieve and another 10 mm sieve. For mix the ratio of these aggregates
was 60:40 respectively.
Methods
All the building material which was required for the present study such as course aggregate, fine aggregate and cement is
purchased from market and then bring to the concrete technology laboratory as the all the work has to done there only.About
50 kg of cement were bought and 15 kg of course aggregate as well as fine aggregate were bought. After Bringing all the
construction material to the concrete technology laboratory, sample will be prepare for making M20 grade concrete and the
ratio of M20 is 1:1.5:3 so all the construction material are mixed in the specified ratio by volume and water is mixed in the
mixture of building material and the paste is thoroughly mix by the help of trowel. After the preparation of concrete, about 50
cubes of concrete in the size of 15 cm X 15 cm was casted and tempting rod is used for removingairvoids.Thecubecastingwas
done by the help of cube mould of standard size which is easily available in themarket. Thiscastedcubeswereleftin themould
for about 12 hours in order to archive the setting time of cement then it is taken out of the mould by removing nut and bolt
which was used to attached the plates of mould together and then kept in water for curing. After Casting of cubes they were
allow to settle down first and for achieving this the concrete was left in the mould for about 12 hours andwhenthey getset the
cubes were taken out of the mould by removing nut and bolt and then the cubes were directly subjected to different types of
curing. Here three types of curing was used in the current study namely Ponding, Spreying, Covering hold water. After the
curing Compressive strength test will be performed on the casted and cured cube on the 3, 7, 14, 21 & 28 days. The days that
were selected for compressive testing ofconcretecubewereaccordingtoIndianStandard(IS456:2000)andthetestprocedure
that were followed were according to Indian Standard codes.
3. RESULTS
The sample preparation as well as analysis of the cured concrete cubes were done according to the IS 456:2000.
Result for the analysis on the concrete cubes are as follows:-
Types of curing Cover Hold Water Ponding Spraying
Testing days
3 day 7.89 N/mm2 6.54 N/mm2 5.82 N/mm2
7 day 12.43 N/mm2 11.29 N/mm2 10.84 N/mm2
14 day 18.00 N/mm2 17.15 N/mm2 16.00 N/mm2
21 day 18.69 N/mm2 17.71 N/mm2 15.73 N/mm2
28 day 19.82 N/mm2 17.93 N/mm2 16.58 N/mm2
4. CONCLUSIONS
The conclusion for the present investigation is:-
 After casting and curing of concrete cube for 3, 7, 14, 21 & 28 days. The cubes are subjected for compressive test and
the result is tabulated above.
 Curing with water is very effective method. It balance the heat of hydration and helpsingainingcompressivestrength
in concrete. This all happens due to the pore structure and low porosity cause due to heat of hydration which cause
loss of moisture in concrete.
 Covering hold water method of curing provide good compressive strength than the ponding and sprayingmethod.As
we can see in the table above the ponding provide its maximum strength on 14 dayand sprayingprovideat21daybut
covering hold water provide at 14 and 28 days.
 When spraying and ponding are considered, the ponding performance is better than spraying as it provide good
compressive strength. This is because the moisture movement from the concrete specimen is higher in spraying
method, which did not provide and any protection against early drying out of concrete. Hence hydration of cement
reaction was abated.
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 06 Issue: 06 | June 2019 www.irjet.net p-ISSN: 2395-0072
© 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 3830
 The extent of moisture movement was greatly dependent of the methodofcuring.Greatermoisturemovementoccurs
under spraying method, and it significantly affected the strength property of the concrete.
 Normal concrete should be cured by water curing method in order toachievegoodhardenedproperties.Watercuring
produces no loss of moisture, and thereforeenhancescementhydrationreaction.Incaseofwatershortage,incovering
hold water immediate sprinkling can be adopted instead.
REFERENCES
 Ahmed. A.A. and. Fadi .A. I. ‘‘Strength of Concrete as Effected by Curing Conditions in Hot and Dry climate’’The first
MINIA International conference for Advanced Trends in Engineering, Egypt, March, 1999.
 Neville, A.M., ‘‘Properties of Concrete’’ John Wiley and sons, New York, 1973.
 A.C.I committee 308‘‘Standard Practice for Curing Concrete (ACI 308-92)’’AmericanConcreteInstitute,Detroit,1992.
 Mindess, Sidney and Young, J. Francis‘‘Concrete Prentice-Hall Inc ’’ 1981.
 Transportation Research Committee on Batching, Mixing, Placing and Curing of concrete‘‘Curing of Concrete
Pavements’’Transportation Research Circular No.208, Transportation Research Board, Washington, June 1979.
 ‘‘2000 Annual Book of ASTM Standards’’ Vol .4.02, American Society for Testing and Materials, Philadelphia, PA.
 Neil Jackson&Ravindra K.Dhir (1997) ‘‘Civil Engineering Materials’’ 5th Edition ISBN: 033363683X Macmillan.
 B.S.1881 Part (2), (3), (4) and (5) ‘‘Method of Testing concrete’’.
 A.C.I. committee 224‘‘Control of Cracking in Concrete Structures’’Concrete International: Design and Construction,
Vol.2, No.10, October1980.
 A.C.I Committee 315‘‘Hot Weather Concreting’’A.C.I.Journal, proc., Vol.74, No.8, August1977.
 Adams, D.L. ‘‘The Measurement of Very Early Hydration Reactions of Portland Cement Clinker by a Thermoelectric
Conduction Calorimeter ’’Cement and Concrete Research, vol.6, NO.2, pp. 293- 308, March 1976.
 Ish-Shalom, M., and Bentur, A. ‘‘ Some Observations On the Effect of the Initial Temperature on the Hydration and
Strength of Portland Cement with Different Aluminates Contents’’Concrete and ReinforcedConcreteinHotcountries,
Vol.11, proceedings of International Rilem SYMPOSIM, Haifa, August 1971.
 Idorn, G.M‘‘Hydration of Portland Cement Paste at HighTemperatureunderAtmosphericPressure’’proceedingsofthe
Fifth International Symposium on the Chemistry of Cement, part (ІІІ), Tokyo, December 1969.
 Taylor, H.F.W. ‘‘The Calcium Silicate Hydrates’’Proceedings of the Fifth International Symposium on the Chemistry,
part (ІІ), Hydration of Cements’’ pp. 1-35. Tokyo, December 1968.
 Popovics, S. ‘‘ Concrete Making Materials’’MC Graw-Hill Book company, New YORK etc., and Hemisphere Publishing
Corporation, Washington, 1979.
 Venuat, M. ‘‘Effect of Elevated Temperatures and Pressure on the Hydration and Hardening of Cement’ ’A principal
paper, the VI International Congress on the Chemistry of Cement, Moscow, September 1974.
 Lea, F.M. ‘‘the Chemistry of Cement and Concrete’’Third Edition, Chemical Publishing Company Inc., New York, 1971.
 Meyer, L.M., and Perenchio, W.F‘‘Theory of Concrete Slump Loss as Related to the Use of Chemical
Admixtures’’Concrete International: Design and Construction, Vol.1, No.1, January 1979.
 Bogue, R.H. ‘‘the Chemistry of Portland cement’’ Second Edition, Rheinhold Publishing Co., New York 1955.
 Klieger, P. ‘‘Effect of Mixing and Curing Temperature on Concrete Strength’’A.C.I. Journal, Proc., Vol. 54, June 1958.
 Previte, R.W. ‘‘Concrete Slump Loss’’ A.C.I. Journal, Vol. 74, No. 8, August 1977.
 Ramakrishnan, V., Coyle, W.V., and Pande, S.S‘‘Workability and Strength of Retempered Super Plasticzed
Concretes’’Transportation Research Record 720, Super Politicizes in Concrete, 1979.
 Mufid A.Samarai‘‘Hot Weather Concreting’’, Irbid – Jordan, October 1983.
 Popovics, S. ‘‘Phenomenological Approach to the Role of C3A in the Hardening of PortlandcementPastes’’Cementand
Concrete Research, Vol.6, No.3, May 1976.
 Verbeck, G.J., and Helmuth, R.H. ‘‘Structures and Physical Properties of Cement Pastes’’Proceedings of the Fifth
International Symposium on the Chemistry of Cement, part (ΙΙΙ), Tokyo, December 1969.

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IRJET- Effect of Different Curing on Strength of Concrete

  • 1. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 06 Issue: 06 | June 2019 www.irjet.net p-ISSN: 2395-0072 © 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 3828 EFFECT OF DIFFERENT CURING ON STRENGTH OF CONCRETE RAM PRATAP YADAV1, KUNDAN KULBUSHAN2 1M.Tech, Department of Civil Engineering, Maharishi University of Information Technology, Lucknow, U.P. 2Assistant Professor, Department of Civil Engineering, Maharishi University of Information Technology, Lucknow, U.P. ---------------------------------------------------------------------***---------------------------------------------------------------------- Abstract - Normal concrete was prepared with a water-cement ratio of 0.50. cube specimens were cast for testing the compressive strength at 7 and 28 days of curing respectively using three curing methodsnamelyimmersion, sprinkling andPlastic sheeting, curing to cure the cube specimens until the day of testing. Test results indicates that water curing (WAC) as well as sprinkling (spraying) curing provided much better results than membrane (Plastic Sheeting) method of curing. Therateofdrying was significant when the specimens were subjected to membrane (Plastic sheeting) method of curing. This thus hampered the hydration process and thus affected the compressive strength property of the hardened concrete. The overall finding of this study suggests that concrete should be cured by water curing to achieve a better compressive strength. Key Words: concrete, course aggregate, cement, curing, compressive strength test. 1. INTRODUCTION Concrete in general is the most commonly used structural material and it consists essentially from mixing water, cement, aggregate and if necessary special additives withselectedconcreteproportionsoftheingredientstoproduceconcretemixwith specific properties. The concrete has to be satisfactory in its hardened state and also in its fresh state while being transported from the mixer and placed in the form work. The requirements in the fresh state are that the consistenceofthe mixis suchthat it can be compacted by the means desired without excessive effort, and also that the mix be cohesive enough forthe methodof placing used, not to produce segregation with consequent lack ofthefinishedproduct.Theusual primaryrequirementsofgood concrete in its hardened state are satisfactory compressive strength, density, durability, tensile strength, etc., are considered. The selection of more suitable and economical mix can be made, using mix design to give concrete with specified conditions and any defect in the mix ingredient may cause some problems in the concrete mix, such as segregation, bleeding and may cause shrinkage and creep after hardening. In warm to hot weathers, in-site concrete quality will vary for many reasons other than selection of materials and design characteristics. Concrete changes in volume when it loses or gains water. Surface cracking of fresh concrete occurs due to drying shrinkage caused by rapid loss of water in hot and dry climates. The rate at which concrete will dry depends on air temperature, concrete temperature, relative humidity and wind velocity. The lack of proper curing affects the quality of concrete in both fresh and hardened states.Concretehardensandgainsstrength becauseof A chemical reaction between Portland cement and water. If concrete driesprematurely,therewill beinsufficientwaterforthat reaction, i.e. .no water, no hydration, no strength gain. According to the standards, ponding is the most through method of water curing but it is seldom used in the field because it is difficult and cumbersome. Fog spring or sprinkling with nozzles provides excellent curing, but it requires constant vigilance. Burlap, wet sand and saw dust, usually providegoodcuringwhen fully saturated. Sealing materials are sheets or membranes placed on the Concrete to reduce the loss of mixing water. Use of plastic films is one way to protect the fresh concrete and can be applied as soonasfree waterhasdisappearedfrom thesurface. Liquid membrane curing compounds are one of the practical methods of curing concrete. 2. MATERIALS AND METHODS Materials: Cement - Portland Pozzolana Cement (fly ash based) brand name Birla Gold confirming to IS 1489 (Part 1) -1991wasusedinthisstudy. Fine Aggregate - River sand available in Allahabad confirming to IS 383-1970, zone II used in the study. It was completely passedby 4.75mmIS sieve. Fineness modulus and specific gravity was 2.76 and 2.3 respectively.
  • 2. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 06 Issue: 06 | June 2019 www.irjet.net p-ISSN: 2395-0072 © 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 3829 Coarse Aggregate - Locally available coarse aggregate having two fraction 20mm and 10mm sizes individually sieved was used in the present study. One fraction completely passed through 20 mm sieve and another 10 mm sieve. For mix the ratio of these aggregates was 60:40 respectively. Methods All the building material which was required for the present study such as course aggregate, fine aggregate and cement is purchased from market and then bring to the concrete technology laboratory as the all the work has to done there only.About 50 kg of cement were bought and 15 kg of course aggregate as well as fine aggregate were bought. After Bringing all the construction material to the concrete technology laboratory, sample will be prepare for making M20 grade concrete and the ratio of M20 is 1:1.5:3 so all the construction material are mixed in the specified ratio by volume and water is mixed in the mixture of building material and the paste is thoroughly mix by the help of trowel. After the preparation of concrete, about 50 cubes of concrete in the size of 15 cm X 15 cm was casted and tempting rod is used for removingairvoids.Thecubecastingwas done by the help of cube mould of standard size which is easily available in themarket. Thiscastedcubeswereleftin themould for about 12 hours in order to archive the setting time of cement then it is taken out of the mould by removing nut and bolt which was used to attached the plates of mould together and then kept in water for curing. After Casting of cubes they were allow to settle down first and for achieving this the concrete was left in the mould for about 12 hours andwhenthey getset the cubes were taken out of the mould by removing nut and bolt and then the cubes were directly subjected to different types of curing. Here three types of curing was used in the current study namely Ponding, Spreying, Covering hold water. After the curing Compressive strength test will be performed on the casted and cured cube on the 3, 7, 14, 21 & 28 days. The days that were selected for compressive testing ofconcretecubewereaccordingtoIndianStandard(IS456:2000)andthetestprocedure that were followed were according to Indian Standard codes. 3. RESULTS The sample preparation as well as analysis of the cured concrete cubes were done according to the IS 456:2000. Result for the analysis on the concrete cubes are as follows:- Types of curing Cover Hold Water Ponding Spraying Testing days 3 day 7.89 N/mm2 6.54 N/mm2 5.82 N/mm2 7 day 12.43 N/mm2 11.29 N/mm2 10.84 N/mm2 14 day 18.00 N/mm2 17.15 N/mm2 16.00 N/mm2 21 day 18.69 N/mm2 17.71 N/mm2 15.73 N/mm2 28 day 19.82 N/mm2 17.93 N/mm2 16.58 N/mm2 4. CONCLUSIONS The conclusion for the present investigation is:-  After casting and curing of concrete cube for 3, 7, 14, 21 & 28 days. The cubes are subjected for compressive test and the result is tabulated above.  Curing with water is very effective method. It balance the heat of hydration and helpsingainingcompressivestrength in concrete. This all happens due to the pore structure and low porosity cause due to heat of hydration which cause loss of moisture in concrete.  Covering hold water method of curing provide good compressive strength than the ponding and sprayingmethod.As we can see in the table above the ponding provide its maximum strength on 14 dayand sprayingprovideat21daybut covering hold water provide at 14 and 28 days.  When spraying and ponding are considered, the ponding performance is better than spraying as it provide good compressive strength. This is because the moisture movement from the concrete specimen is higher in spraying method, which did not provide and any protection against early drying out of concrete. Hence hydration of cement reaction was abated.
  • 3. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 06 Issue: 06 | June 2019 www.irjet.net p-ISSN: 2395-0072 © 2019, IRJET | Impact Factor value: 7.211 | ISO 9001:2008 Certified Journal | Page 3830  The extent of moisture movement was greatly dependent of the methodofcuring.Greatermoisturemovementoccurs under spraying method, and it significantly affected the strength property of the concrete.  Normal concrete should be cured by water curing method in order toachievegoodhardenedproperties.Watercuring produces no loss of moisture, and thereforeenhancescementhydrationreaction.Incaseofwatershortage,incovering hold water immediate sprinkling can be adopted instead. REFERENCES  Ahmed. A.A. and. Fadi .A. I. ‘‘Strength of Concrete as Effected by Curing Conditions in Hot and Dry climate’’The first MINIA International conference for Advanced Trends in Engineering, Egypt, March, 1999.  Neville, A.M., ‘‘Properties of Concrete’’ John Wiley and sons, New York, 1973.  A.C.I committee 308‘‘Standard Practice for Curing Concrete (ACI 308-92)’’AmericanConcreteInstitute,Detroit,1992.  Mindess, Sidney and Young, J. Francis‘‘Concrete Prentice-Hall Inc ’’ 1981.  Transportation Research Committee on Batching, Mixing, Placing and Curing of concrete‘‘Curing of Concrete Pavements’’Transportation Research Circular No.208, Transportation Research Board, Washington, June 1979.  ‘‘2000 Annual Book of ASTM Standards’’ Vol .4.02, American Society for Testing and Materials, Philadelphia, PA.  Neil Jackson&Ravindra K.Dhir (1997) ‘‘Civil Engineering Materials’’ 5th Edition ISBN: 033363683X Macmillan.  B.S.1881 Part (2), (3), (4) and (5) ‘‘Method of Testing concrete’’.  A.C.I. committee 224‘‘Control of Cracking in Concrete Structures’’Concrete International: Design and Construction, Vol.2, No.10, October1980.  A.C.I Committee 315‘‘Hot Weather Concreting’’A.C.I.Journal, proc., Vol.74, No.8, August1977.  Adams, D.L. ‘‘The Measurement of Very Early Hydration Reactions of Portland Cement Clinker by a Thermoelectric Conduction Calorimeter ’’Cement and Concrete Research, vol.6, NO.2, pp. 293- 308, March 1976.  Ish-Shalom, M., and Bentur, A. ‘‘ Some Observations On the Effect of the Initial Temperature on the Hydration and Strength of Portland Cement with Different Aluminates Contents’’Concrete and ReinforcedConcreteinHotcountries, Vol.11, proceedings of International Rilem SYMPOSIM, Haifa, August 1971.  Idorn, G.M‘‘Hydration of Portland Cement Paste at HighTemperatureunderAtmosphericPressure’’proceedingsofthe Fifth International Symposium on the Chemistry of Cement, part (ІІІ), Tokyo, December 1969.  Taylor, H.F.W. ‘‘The Calcium Silicate Hydrates’’Proceedings of the Fifth International Symposium on the Chemistry, part (ІІ), Hydration of Cements’’ pp. 1-35. Tokyo, December 1968.  Popovics, S. ‘‘ Concrete Making Materials’’MC Graw-Hill Book company, New YORK etc., and Hemisphere Publishing Corporation, Washington, 1979.  Venuat, M. ‘‘Effect of Elevated Temperatures and Pressure on the Hydration and Hardening of Cement’ ’A principal paper, the VI International Congress on the Chemistry of Cement, Moscow, September 1974.  Lea, F.M. ‘‘the Chemistry of Cement and Concrete’’Third Edition, Chemical Publishing Company Inc., New York, 1971.  Meyer, L.M., and Perenchio, W.F‘‘Theory of Concrete Slump Loss as Related to the Use of Chemical Admixtures’’Concrete International: Design and Construction, Vol.1, No.1, January 1979.  Bogue, R.H. ‘‘the Chemistry of Portland cement’’ Second Edition, Rheinhold Publishing Co., New York 1955.  Klieger, P. ‘‘Effect of Mixing and Curing Temperature on Concrete Strength’’A.C.I. Journal, Proc., Vol. 54, June 1958.  Previte, R.W. ‘‘Concrete Slump Loss’’ A.C.I. Journal, Vol. 74, No. 8, August 1977.  Ramakrishnan, V., Coyle, W.V., and Pande, S.S‘‘Workability and Strength of Retempered Super Plasticzed Concretes’’Transportation Research Record 720, Super Politicizes in Concrete, 1979.  Mufid A.Samarai‘‘Hot Weather Concreting’’, Irbid – Jordan, October 1983.  Popovics, S. ‘‘Phenomenological Approach to the Role of C3A in the Hardening of PortlandcementPastes’’Cementand Concrete Research, Vol.6, No.3, May 1976.  Verbeck, G.J., and Helmuth, R.H. ‘‘Structures and Physical Properties of Cement Pastes’’Proceedings of the Fifth International Symposium on the Chemistry of Cement, part (ΙΙΙ), Tokyo, December 1969.