The document compares MPLS and IPSec VPN for connecting multiple business sites over a WAN. MPLS creates a private network without encryption that provides built-in any-to-any connectivity between sites, improving reliability. It allows for quality of service prioritization of traffic. While IPSec VPN provides encryption and thus more security, it has overhead from encryption that can increase latency. Reliability is also generally better with MPLS than IPSec VPN due to fewer configuration complexities. The document provides a detailed comparison chart of MPLS and IPSec VPN features.