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Polymers
Polymers: What are they?
Different Types
Uses and Applications
Chemical Make-up
Polymers - What are they?
Polymers are a special kind of
macromolecule
The word polymer comes from the Greek
words “poly,” meaning “many”, and
“meres,” meaning “parts” or “repeating
units”
A Polymer consists of a large chain of
repeating molecules (monomers) that are
attached in an end to end fashion
Description of Polymers
Imagine a string of beads
Each bead is identical (for example, red
sphere)
• Represents the “mer”
The string can contain 100’s of beads
• Represents the “poly” characteristic
The string in between the beads represents
the chemical bond between monomers
Length of Polymers
Polymer chains are HUGE!
Polymers typically consist of between
20,000 and 40,000 individual monomers
If each bead on the string of beads were one
inch apart, one polymer molecule could be as
long as 10 football fields!!!
This chain length is what gives the
polymer most of its desirable
characteristics
Description of Polymers
Polymer chains are flexible, and usually
“clump” together into a smaller shape
This enables the individual chains to
interact and become entangled
This helps to give a polymer its strength
and flexibility
Types of Polymers
There are two main types of polymers
Natural
• (cotton, silk, wood, leather…)
Synthetic
• (plastics, nylon, latex…)
Synthetic Polymers
There are two basic types of synthetic
polymers
Thermoplastics (plastics, Styrofoam)
• These can be softened by heating and hardened by
cooling - easily recycled
• Can easily be cast into various shapes
Thermosets (epoxy’s, adhesives)
• These harden after being heated
• Can easily be cast into different shapes
• Cannot be reformed
Types of Polymers -
Copolymers
Most polymer chains are made up of one
type of monomer (for example, red
beads)
However, some polymers are made up of
different types of monomers (for example,
blue and red beads) - these are called
copolymers
Copolymers
There are four main types of copolymers
The different monomers can be arranged
either in an alternating or random fashion
Alternating
...-red-blue-red-blue-red-blue-red-blue-red-…
Random
…-blue-red-red-blue-red-blue-blue-red-blue-…
Copolymers
There are also block copolymers and graft
co-polymers
Block
…-R-R-R-R-R-R-B-B-B-B-B-B-R-R-R-R-R-R-…
Graft
…-R-R-R-R-R-R-R-R-R-R-R-R-R-R-R-R-R-…
|
B-B-B-B-B-B-B-B-B-…
Polymers - Pros and Cons
A polymer has many very advantageous
properties. Polymers are:
Lightweight
Strong and durable
Cheap
Easy to manufacture
Unfortunately, polymers do not easily
biodegrade and end up producing large
amounts of waste
Uses of Polymers
Polymers are incorporated into nearly
every aspect of daily life
Entertainment
Sports
Clothes
Hobbies/Toys
Household products
Automotive
Polymer Chemistry
A polymer chain is built on a Carbon
backbone
A monomer unit consists of a small
carbon chain attached to a specific type of
functional group
The functional group is what gives each
polymer chain its individual characteristics
Polymer Chemistry
As previously stated, polymer chains
interact with one another, becoming
entangled
Polymer chains also form cross-links with
adjacent chains, which allows the polymer
to hold its shape and gives added
strength
Summary
Polymers are made up of large chains of
repeating units, called monomers
Individual chains interact to form a
stronger overall substance through
entanglements and cross-links
Polymers are incorporated into almost
every aspect of daily life
Polymers are lightweight, strong, and
inexpensive

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PolymerIntro.ppt

  • 1. Polymers Polymers: What are they? Different Types Uses and Applications Chemical Make-up
  • 2. Polymers - What are they? Polymers are a special kind of macromolecule The word polymer comes from the Greek words “poly,” meaning “many”, and “meres,” meaning “parts” or “repeating units” A Polymer consists of a large chain of repeating molecules (monomers) that are attached in an end to end fashion
  • 3. Description of Polymers Imagine a string of beads Each bead is identical (for example, red sphere) • Represents the “mer” The string can contain 100’s of beads • Represents the “poly” characteristic The string in between the beads represents the chemical bond between monomers
  • 4. Length of Polymers Polymer chains are HUGE! Polymers typically consist of between 20,000 and 40,000 individual monomers If each bead on the string of beads were one inch apart, one polymer molecule could be as long as 10 football fields!!! This chain length is what gives the polymer most of its desirable characteristics
  • 5. Description of Polymers Polymer chains are flexible, and usually “clump” together into a smaller shape This enables the individual chains to interact and become entangled This helps to give a polymer its strength and flexibility
  • 6. Types of Polymers There are two main types of polymers Natural • (cotton, silk, wood, leather…) Synthetic • (plastics, nylon, latex…)
  • 7. Synthetic Polymers There are two basic types of synthetic polymers Thermoplastics (plastics, Styrofoam) • These can be softened by heating and hardened by cooling - easily recycled • Can easily be cast into various shapes Thermosets (epoxy’s, adhesives) • These harden after being heated • Can easily be cast into different shapes • Cannot be reformed
  • 8. Types of Polymers - Copolymers Most polymer chains are made up of one type of monomer (for example, red beads) However, some polymers are made up of different types of monomers (for example, blue and red beads) - these are called copolymers
  • 9. Copolymers There are four main types of copolymers The different monomers can be arranged either in an alternating or random fashion Alternating ...-red-blue-red-blue-red-blue-red-blue-red-… Random …-blue-red-red-blue-red-blue-blue-red-blue-…
  • 10. Copolymers There are also block copolymers and graft co-polymers Block …-R-R-R-R-R-R-B-B-B-B-B-B-R-R-R-R-R-R-… Graft …-R-R-R-R-R-R-R-R-R-R-R-R-R-R-R-R-R-… | B-B-B-B-B-B-B-B-B-…
  • 11. Polymers - Pros and Cons A polymer has many very advantageous properties. Polymers are: Lightweight Strong and durable Cheap Easy to manufacture Unfortunately, polymers do not easily biodegrade and end up producing large amounts of waste
  • 12. Uses of Polymers Polymers are incorporated into nearly every aspect of daily life Entertainment Sports Clothes Hobbies/Toys Household products Automotive
  • 13. Polymer Chemistry A polymer chain is built on a Carbon backbone A monomer unit consists of a small carbon chain attached to a specific type of functional group The functional group is what gives each polymer chain its individual characteristics
  • 14. Polymer Chemistry As previously stated, polymer chains interact with one another, becoming entangled Polymer chains also form cross-links with adjacent chains, which allows the polymer to hold its shape and gives added strength
  • 15. Summary Polymers are made up of large chains of repeating units, called monomers Individual chains interact to form a stronger overall substance through entanglements and cross-links Polymers are incorporated into almost every aspect of daily life Polymers are lightweight, strong, and inexpensive