PowerShell 101 provides an overview of PowerShell, including what it is, how it works, and why it is important for Windows administrators. PowerShell is a task automation platform and scripting language that makes Windows administration easier. It uses cmdlets, objects, and the pipeline model where cmdlets produce and consume objects that can be piped between commands. PowerShell is built into Windows and provides discoverability through commands like Get-Help and Get-Member. It offers advantages over traditional shells like being faster, more repeatable, and reducing errors.