Rp b401 cathodic protection design-2005

RECOMMENDED PRACTICE
DET NORSKE VERITAS
DNV-RP-B401
CATHODIC PROTECTION DESIGN
JANUARY 2005
Since issued in print (January 2005), this booklet has been amended, latest in October 2005.
See the reference to “Amendments and Corrections” on the next page.

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DET NORSKE VERITAS
Amended October 2005, Recommended Practice DNV-RP-B401, January 2005
see note on front cover Changes – Page 3
Main Changes January 2005
• Sec.1 Introduction
— Impressed current cathodic protection (CP) has been re-
moved from the scope. As a consequence of this, the RP
does not actually cover CP of mobile installations for oil
and gas production, but can be applied if a galvanic anode
system has been selected.
— The revisions made to the 1993 issue are addressed in gen-
eral terms in 1.2.5.
— Sec.1 has been amended to give detailed guidelines to the
use of the RP as a contractual document. A check-list for
information to Contractor and specification of optional re-
quirements associated with CP design, anode manufacture
and anode installation are further given in 7.1.2, 8.1.2 and
9.1.3 respectively.
• Sec.2 References
— There are a few amendments, e.g. a reference to
NORSOK M-501.
• Sec.3 Terminology and Definitions
— Some references to paragraphs in the text for definition of
CP design terms are included.
• Sec.5 General CP Design Considerations (Informative)
— Some informative text on CP design parameters/calcula-
tions has been moved to this section. The text on HISC by
CP has been amended to include experience after 1993,
primarily related to martensitic and ferritic-austenitic (du-
plex) stainless steels.
• Sec.6 CP Design Parameters
— Revisions to the 1993 issue are addressed in 6.1.6. The pri-
mary ones are the revision of coating categories which
have been reduced from 4 to 3 and made 'wider' to include
commonly applied systems.. Reference is also made to
NORSOK M-501 Systems 3B and 7. The constants for
calculation of time dependant coating breakdown is slight-
ly reduced for Category III. However, as to the required
anode capacity, this is largely compensated for by higher
design current densities at depths exceeding 100 m where
coated components are mostly used. For design current
densities, two further depth zones have been defined. The
effect of this is most significant in tropical waters.
• Sec.7 CP Calculation and Design Procedures
— As stated in 7.1.4, the only major revision made is the in-
troduction of a paragraph (7.8.6) that advises against the
use of anodes with large differences in size.
• Sec.8 Anode Manufacture
— Compared to the 1993 revision, this section has been made
more comprehensive. It has been revised to include e.g.
ISO 15589-2 requirements for anode chemical composi-
tion, extended requirements for quality control and ac-
ceptance criteria for electrochemical testing. The basis for
this section is NACE RP0387 and no requirements in this
standard are repeated.
• Sec.9 Anode Installation
— This section has been extended compared to the 1993 re-
vision. However, most of the additional requirements for
documentation of quality control are optional.
• Annex A Figures and Tables
— See comments to Sec.6 and Sec.8 above.
• Annex B Laboratory testing of galvanic anode materials for
quality control
— Only minor revisions, see 11.1.4
• Annex C Laboratory testing of galvanic anode materials for
qualification of electrochemical performance
— Only minor revisions, see 12.1.4.

DET NORSKE VERITAS
Recommended Practice DNV-RP-B401, January 2005 Amended October 2005,
Page 4 – Changes see note on front cover

DET NORSKE VERITAS
see note on front cover Page 5
CONTENTS
1. GENERAL............................................................. 7
1.1 Introduction............................................................7
1.2 Scope .......................................................................7
1.3 Objectives and Use.................................................7
1.4 Document Structure ..............................................7
1.5 Relation to Other DNV Documents......................7
2. REFERENCES ..................................................... 8
2.1 General....................................................................8
2.2 ASTM (American Society for Testing and
Materials)................................................................8
2.3 DNV (Det Norske Veritas) ....................................8
2.4 EN (European Standards).....................................8
2.5 NORSOK................................................................8
2.6 ISO (International Organization for
Standardisation).....................................................8
2.7 NACE International ..............................................8
3. TERMINOLOGY AND DEFINITIONS............ 8
3.1 Terminology ...........................................................8
3.2 Definitions...............................................................8
4. ABBREVIATIONS AND SYMBOLS................. 9
4.1 Abbreviations .........................................................9
4.2 Symbols...................................................................9
5. GENERAL CP DESIGN CONSIDERATIONS
(INFORMATIVE) ................................................ 9
5.1 General....................................................................9
5.2 Limitations of CP...................................................9
5.3 Environmental Parameters Affecting CP............9
5.4 Protective Potentials ............................................10
5.5 Detrimental effects of CP ....................................10
5.6 Galvanic Anode Materials ..................................11
5.7 Anode Geometry and Fastening Devices ...........11
5.8 Use of Coatings in Combination with CP..........11
5.9 Electrical Continuity and Current Drain..........12
6. CP DESIGN PARAMETERS............................ 12
6.1 General..................................................................12
6.2 Design Life............................................................12
6.3 Design Current Densities ....................................12
6.4 Coating Breakdown Factors for CP Design ......13
6.5 Galvanic Anode Material Design Parameters...14
6.6 Anode Resistance Formulas................................15
6.7 Seawater and Sediment Resistivity ....................15
6.8 Anode Utilization Factor.....................................15
6.9 Current Drain Design Parameters.....................15
7. CP CALCULATION AND DESIGN
PROCEDURES................................................... 15
7.1 General..................................................................15
7.2 Subdivision of CP Object ....................................16
7.3 Surface Area Calculations..................................16
7.4 Current Demand Calculations ...........................16
7.5 Current Drain Calculations................................16
7.6 Selection of Anode Type......................................16
7.7 Anode Mass Calculations....................................17
7.8 Calculation of Number of Anodes......................17
7.9 Calculation of Anode Resistance........................17
7.10 Anode Design .......................................................18
7.11 Distribution of Anodes........................................18
7.12 Provisions for Electrical Continuity ..................18
7.13 Documentation.....................................................18
8. ANODE MANUFACTURE............................... 19
8.1 General .................................................................19
8.2 Manufacturing Procedure Specification ...........19
8.3 Pre-Production Qualification Testing ...............19
8.4 Quality Control of Production ...........................20
8.5 Materials, Fabrication of Anode Inserts and
Casting of Anodes................................................20
8.6 Inspection and Testing of Anodes......................20
8.7 Documentation and Marking .............................21
8.8 Handling, Storage and Shipping of Anodes......21
9. INSTALLATION OF ANODES....................... 21
9.1 General .................................................................21
9.2 Installation Procedure Specification..................22
9.3 Qualification of installation................................22
9.4 Receipt and Handling of Anodes........................22
9.5 Anode Installation and Provisions for Electrical
Continuity.............................................................22
9.6 Inspection of Anode Installation ........................22
9.7 Documentation.....................................................22
10. ANNEX A – TABLES AND FIGURES............ 23
10.1 Tables and Figures ..............................................23
11. ANNEX B – LABORATORY TESTING OF
GALVANIC ANODE MATERIALS FOR
QUALITY CONTROL...................................... 25
11.1 General .................................................................25
11.2 Sampling and Preparation of Test Specimens..25
11.3 Equipment and Experimental Procedure .........25
11.4 Acceptance Criteria and Re-Testing..................26
11.5 Documentation.....................................................26
12. ANNEX C – LABORATORY TESTING OF
GALVANIC ANODE MATERIALS FOR
QUALIFICATION OF ELECTROCHEMICAL
PERFORMANCE .............................................. 28
12.1 General .................................................................28
12.2 Sampling and Preparation of Test Specimens..28
12.3 Equipment and Experimental Procedure .........28
12.4 Documentation.....................................................29

DET NORSKE VERITAS
Page 6 see note on front cover

DET NORSKE VERITAS
1. General
1.1 Introduction
1.1.1 ‘Cathodic protection’ (CP) can be defined as e.g. “elec-
trochemical protection by decreasing the corrosion potential to
a level at which the corrosion rate of the metal is significantly
reduced” (ISO 8044) or “a technique to reduce corrosion of a
metal surface by making that surface the cathode of an electro-
chemical cell” (NACE RP0176). The process of suppressing
the corrosion potential to a more negative potential is referred
to as ‘cathodic polarization’.
1.1.2 For galvanic anode CP systems, the anode of the electro-
chemical cell is a casting of an electrochemically active alloy
(normally aluminium, zinc or magnesium based). This anode
is also the current source for the CP system and will be con-
sumed. Accordingly, it is often referred to as a ‘sacrificial an-
ode’, as alternative to the term ‘galvanic anode’ consistently
used in this Recommended Practice (RP). For ‘impressed cur-
rent’ CP, an inert (non-consuming) anode is used and the cur-
rent is supplied by a rectifier. In this RP, the cathode of the
electrochemical cell (i.e. the structure, sub-system or compo-
nent to receive CP) is referred to as the ‘protection object’.
1.1.3 For permanently installed offshore structures, galvanic
anodes are usually preferred. The design is simple, the system
is mechanically robust and no external current source is need-
ed. In addition, inspection and maintenance during operation
can largely be limited to periodic visual inspection of anode
consumption and absence of visual corrosive degradation.
However, due to weight and drag forces caused by galvanic an-
odes, impressed current CP systems are sometimes chosen for
permanently installed floating structures.
1.1.4 Cathodic protection is applicable for all types of metals
and alloys commonly used for subsea applications. It prevents
localised forms of corrosion as well as uniform corrosion at-
tack, and eliminates the possibility for galvanic corrosion
when metallic materials with different electrochemical charac-
teristics are combined. However, CP may have certain detri-
mental effects, for example hydrogen related cracking of
certain high-strength alloys and coating disbondment as de-
scribed in 5.5.
1.1.5 Cathodic protection is primarily intended for metal sur-
faces permanently exposed to seawater or marine sediments.
Still, CP is often fully effective in preventing any severe cor-
rosion in a tidal zone and has a corrosion reducing effect on
surfaces intermittently wetted by seawater.
1.2 Scope
1.2.1 This Recommended Practice (RP) has been prepared to
facilitate the execution of conceptual and detailed CP design
using aluminium or zinc based galvanic anodes, and specifica-
tion of manufacture and installation of such anodes. Whilst the
requirements and recommendations are general, this document
contains advice on how amendments can be made to include
project specific requirements. The RP can also easily be
amended to include requirements or guidelines by a regulating
authority, or to reflect Owner’s general philosophy on corro-
sion control by CP.
1.2.2 Some of the design recommendations and methods in
Sections 5, 6 and 7 are also valid for CP systems using other
current sources such as magnesium anodes and rectifiers (i.e.
impressed current).
1.2.3 This RP is primarily intended for CP of permanently in-
stalled offshore structures associated with the production of oil
and gas. Mobile installations for oil and gas production like
semi-submersibles, jack-ups and mono-hull vessels are not in-
cluded in the scope of this document. However, to the discre-
tion of the user, relevant parts of this RP may be used for
galvanic anode CP of such structures as well.
1.2.4 Detailed design of anode fastening devices for structural
integrity is not included in the scope of this RP. Considerations
related to safety and environmental hazards associated with
galvanic anode manufacture and installation are also beyond
its scope.
1.2.5 Compared to the 1993 edition of DNV-RP-B401, design
considerations for impressed current CP have been deleted
from the scope of the 2004 revision whilst the sections on an-
ode manufacture and installation are made more comprehen-
sive. CP of submarine pipelines is further excluded from the
scope (see 1.5).
In this revision, guidance and explanatory notes are contained
in a ‘Guidance note’ to the applicable paragraph in Sections
6, 7, 8 and in Annex B and C. (Most of the Guidance notes are
based on queries on the 1993 revision of DNV-RP-B401 and
other experience from its use. Furthermore, some informative
text in the old revision has been contained in such notes).
All tables and figures associated with Sec.6 are contained in
Annex A. The document has further been revised to facilitate
specification of Purchaser information to Contractor, and op-
tional requirements associated with CP design, manufacture
and installation of anodes (see 1.3). Additional comments on
revisions in this 2004 issue are made in the Introduction (last
paragraph) of Sections 6, 7, 8 and Annex B and C.
1.3 Objectives and Use
1.3.1 This RP has two major objectives. It may be used as a
guideline to Owner’s or their contractors’ execution of concep-
tual or detailed CP design, and to the specification of galvanic
anode manufacture and installation. It may also be used as an
attachment to an inquiry or purchase order specification for
such work. If Purchaser has chosen to refer to this RP in a pur-
chase document, then Contractor shall consider all require-
ments in Sections 6-9 of this document as mandatory, unless
superseded by amendments and deviations in the specific con-
tract. Referring to this document in a purchase document, ref-
erence shall also be made to the activities for which DNV-RP-
B401 shall apply, i.e. CP design in Sections 6 and 7, anode
manufacture in Sec.8 and/or anode installation in Sec.9.
1.3.2 CP design, anode manufacture and anode installation are
typically carried out by three different parties (all referred to as
‘Contractor’). Different parties issuing a contract (i.e. ‘Pur-
chaser’) may also apply. The latter includes ‘Owner’, e.g. for
CP design and qualification of galvanic anode materials. For
definition of contracting parties and associated terminology,
see Sec.3.
1.3.3 Specification of project specific information and option-
al requirements for CP detailed design, anode manufacture and
anode installation are described in 7.1.2, 8.1.2 and 9.1.3, re-
spectively.
1.4 Document Structure
1.4.1 Guidelines and requirements associated with conceptual
and detailed CP design are contained in Sections 5, 6 and 7,
whilst galvanic anode manufacture and installation are covered
in Sec.8 and Sec.9, respectively. Tabulated data for CP design
are compiled in Annex A. Annex B and C contain recommend-
ed procedures for laboratory testing of anode materials for pro-
duction quality control and for documentation of long-term
electrochemical performance, respectively.
1.5 Relation to Other DNV Documents
1.5.1 Cathodic protection of submarine pipelines is covered in
DNV-RP-F103.

DET NORSKE VERITAS
2. References
2.1 General
The following standards (2.2-2.7) are referred to in this RP.
The latest editions apply.
2.2 ASTM (American Society for Testing and
Materials)
2.3 DNV (Det Norske Veritas)
2.4 EN (European Standards)
2.5 NORSOK
2.6 ISO (International Organization for
Standardisation)
2.7 NACE International
3. Terminology and Definitions
3.1 Terminology
3.2 Definitions
For the following technical items below, definitions in the text
apply:
cathodic protection (1.1.1), galvanic anode (1.1.2), protection
object (1.1.2), polarization (1.1.1), calcareous scale/layer
(5.5.13), cathodic disbondment (5.5.1).
References within parentheses refer to the applicable para-
graph.
For items applicable to quality control and CP design parame-
ters, reference to the applicable paragraph is made in the list of
abbreviations (4.1) and symbols (4.2).
ASTM G8 Test Method for Cathodic Disbonding of
Pipeline Coating
ASTM D1141 Specification for Substitute Ocean
Seawater
DNV-RP-F103 Cathodic Protection of Submarine
Pipelines by Galvanic Anodes
EN 10204 Metallic Products – Types of Inspection
Documents
NORSOK M-501 Standard for Surface Preparation and
Protective Coating
ISO 3506 Mechanical Properties of
Corrosion-Resistant Stainless Steel
Fasteners
ISO 8044 Corrosion of Metals and Alloys; Basic
Terms and Definitions
ISO 8501-1 Preparation of Steel Substrates for
Application of Paint and Related
Products – Visual Assessment of Surface
Cleanliness.
Part 1: Rust Grades and Preparation
Grades of Uncoated Steel Substrates.
ISO 10005 Quality Management- Guidelines for
Quality Plans
ISO 10474 Steel and Steel Products – Inspection
Documents
NACE RP0176 Corrosion Control of Steel Fixed Off-
shore Structures Associated with Petrole-
um Production
NACE RP0387 Metallurgical and Inspection Require-
ments for Cast Sacrificial Anodes for
Offshore Applications
Owner Party legally responsible for design, con-
struction and operation of the object to
receive CP.
Purchaser Party (Owner or main contractor) issuing
inquiry or contract for CP design, anode
manufacture or anode installation work,
or nominated representative.
Contractor Party to whom the work (i.e. CP design,
anode manufacture or anode installation)
has been contracted.
shall indicates a mandatory requirement.
should indicates a preferred course of action.
may indicates a permissible course of action.
agreed/agreement refers to a written arrangement between
Purchaser and Contractor (e.g. as stated
in a contract).
report and notify refers to an action by Contractor in writ-
ing.
accepted
acceptance
refers to a confirmation by Purchaser in
writing.
certificate
certified
refers to the confirmation of specified
properties issued by Contractor or sup-
plier of metallic materials according to
EN 10204:3.1.B, ISO 10474:5.1-B or
equivalent.
purchase
document(s)
refers to an inquiry/tender or purchase/
contract specification, as relevant.

DET NORSKE VERITAS
4. Abbreviations and Symbols
4.1 Abbreviations
4.2 Symbols
5. General CP Design Considerations
(Informative)
5.1 General
5.1.1 This section addresses aspects of cathodic protection
which are primarily relevant to CP conceptual design, includ-
ing the compatibility of CP with metallic materials and coat-
ings. The content of this section is informative in nature and
intended as guidelines for Owners and their contractors prepar-
ing for conceptual or detailed CP design. Nothing in this sec-
tion shall be considered as mandatory if this RP has been
referred to in a purchase document.
5.1.2 Compared to the 1993 revision of this RP, the major re-
visions of this 2004 revision are contained in 5.5.
5.2 Limitations of CP
5.2.1 For carbon and low-alloy steels, cathodic protection
should be considered as a technique for corrosion control, rath-
er than to provide immunity (1.1.1). It follows that cathodic
protection is not an alternative to corrosion resistant alloys for
components with very high dimensional tolerances, e.g. seal-
ing assemblies associated with subsea production systems.
5.3 Environmental Parameters Affecting CP
5.3.1 The major seawater parameters affecting CP in-situ are:
— dissolved oxygen content
— sea currents
— temperature
— marine growth
— salinity
In addition, variations in seawater pH and carbonate content
are considered factors which affect the formation of calcareous
layers associated with CP and thus the current needed to
achieve and to maintain CP of bare metal surfaces. In seabed
CP cathodic protection
CR concession request (8.5.6)
CRA corrosion resistant alloy
CTOD crack tip opening displacement
DC direct current
DFT dry film thickness
HAZ heat affected zone
HISC hydrogen induced stress cracking (5.5.3)
HV Vicker’s hardness
ITP inspection and testing plan (8.4.2)
IPS installation procedure specification (9.2)
MIP manufacture and inspection plan (8.4.2)
MPS manufacture procedure specification (8.2)
NDT non-destructive testing
PQT production qualification test (8.3)
PWHT post weld heat treatment (5.5.7)
ROV remotely operated vehicle
RP recommended practice
SCE standard calomel electrode (6.1.5)
SMYS specified minimum yield strength
UNS unified numbering system
WPS welding procedure specification
WPQT welding procedure qualification test
YS yield strength
A (m²) anode surface area (Table 10-7)
Ac (m²) cathode surface area (7.4.1)
a constant in coating breakdown factor (6.4.2)
b constant in coating breakdown factor (6.4.2)
C (Ah) current charge associated with quality control
testing of anode materials (11.3.10)
c (m) anode cross sectional periphery (Table 10-7)
Ca (Ah) (individual) anode current capacity (7.8.2)
Ca tot (Ah) total anode current capacity (7.8.2)
Ea
º (V) design closed circuit anode potential (6.5.1)
Ec
º (V) design protective potential (7.8.2)
E'c (V) global protection potential (6.3.4)
E'a (V) (actual) anode closed circuit potential (6.3.4)
∆Eº (V) design driving voltage (7.8.2)
ε (Ah/kg) anode electrochemical capacity (6.5.1)
fc coating breakdown factor (6.4.1)
fci initial coating breakdown factor (6.4.4)
fcm mean coating breakdown factor (6.4.4)
fcf final coating breakdown factor (6.4.4)
Ia(A) (individual) anode current output (7.8.2)
Iai (A) (individual) initial anode current output (7.8.2)
Iaf (A) (individual) final anode current output (7.8.2)
Ia tot (A) total anode current output (6.3.4)
Ia tot i (A) total initial current output (7.8.4)
Ia tot f (A) total final current output (7.8.4)
Ic (A) current demand (7.4.2)
Ici (A) initial current demand (7.4.2, 6.3.1)
Icm (A) mean current demand (7.4.2)
Icf (A) final current demand (7.4.2)
ic (A/m²) design current density (6.3.1)
ici (A/m²) design initial current density (6.3.1)
icm (A/m²) design mean current density (6.3.5)
icf (A/m²) design final current density (6.3.1)
L (m) anode length (Table 10-7)
Ma (kg) total net anode mass (7.7.1)
ma (kg) (individual) net anode mass (7.8.3)
mai (kg) (individual) initial net anode mass (7.9.3)
maf (kg) (individual) final net anode mass (7.9.3)
N number of anodes (7.8.1)
r (m) anode radius (Table 10-7)
Ra (ohm) (individual) anode resistance (6.6.1)
Rai (ohm) (individual) anode initial resistance (7.9.2)
Raf (ohm) (individual) anode final resistance (7.9.2)
Ra tot (ohm) total anode resistance (6.3.4)
S (m) arithmetic mean of anode length and width
(Table 10-7)
ρ (ohm·m) seawater/sediment resistivity (6.7.1)
tf (years) design life (6.4.4)
u anode utilisation factor (6.8)
∆w (g) weight loss associated with quality control test-
ing of anode materials (11.3.10)

DET NORSKE VERITAS
sediments, the major parameters are: temperature, bacterial
growth, salinity and sediment coarseness.
5.3.2 The above parameters are interrelated and vary with ge-
ographical location, depth and season. It is not feasible to give
an exact relation between the seawater environmental parame-
ters indicated above and cathodic current demands to achieve
and to maintain CP. To rationalise CP design for marine appli-
cations, default design current densities, ic (A/m2), are defined
in this document based on 1) climatic regions (related to mean
seawater surface temperature) and 2) depth. The ambient sea-
water temperature and salinity determine the specific seawater
resistivity, ρ (ohm·m), which is used to calculate the anode re-
sistance, Ra (ohm), a controlling factor for the current output
from an anode.
5.4 Protective Potentials
5.4.1 A potential of - 0.80 V relative to the Ag/AgCl/seawater
reference electrode is generally accepted as the design protec-
tive potential Ec
º (V) for carbon and low-alloy steels. It has
been argued that a design protective potential of - 0.90 V
should apply in anaerobic environments, including typical sea-
water sediments. However, in the design procedure advised in
this RP, the protective potential is not a variable.
5.4.2 For a correctly designed galvanic anode CP system, the
protection potential will for the main part of the design life be
in the range - 0.90 to - 1.05 (V). Towards the end of the service
life, the potential increases rapidly towards - 0.80 (V), and
eventually to even less negative values, referred to as ‘under-
protection’. The term ‘over-protection’ is only applicable to
protection potentials more negative than - 1.15 (V). Such po-
tentials will not apply for CP by galvanic anodes based on Al
or Zn.
5.5 Detrimental effects of CP
5.5.1 Cathodic protection will be accompanied by the forma-
tion of hydroxyl ions and hydrogen at the surface of the pro-
tected object. These products may cause disbonding of non-
metallic coatings by mechanisms including chemical dissolu-
tion and electrochemical reduction processes at the metal/coat-
ing interface, possibly including build-up of hydrogen pressure
at this interface. This process of coating deterioration is re-
ferred to as ‘cathodic disbonding’. On components containing
hot fluids, the process is accelerated by heat flow to the metal/
coating interface.
5.5.2 Coatings applied to machined or as-delivered surfaces of
corrosion resistant alloys (CRAs) are particularly prone to ca-
thodic disbonding. However, with surface preparation to
achieve an optimum surface roughness, some coating systems
(e.g. those based on epoxy or polyurethane) have shown good
resistance to cathodic disbonding by galvanic anode CP, when
applied to CRAs as well as to carbon and low-alloy steel. For
coating systems whose compatibility with galvanic anode CP
is not well documented, Owner should consider carrying out
qualification testing, including laboratory testing of resistance
to cathodic disbondment. Testing of marine coatings’ resist-
ance to cathodic disbondment has been standardised, e.g. in
ASTM G8.
5.5.3 Cathodic protection will cause formation of atomic hy-
drogen at the metal surface. Within the potential range for CP
by aluminium or zinc based anodes (i.e. - 0.80 to - 1.10 V Ag/
AgCl/seawater), the production of hydrogen increases expo-
nentially towards the negative potential limit. The hydrogen at-
oms can either combine forming hydrogen molecules or
become absorbed in the metal matrix. In the latter case, they
may interact with the microstructure of components subject to
high stresses causing initiation and growth of hydrogen-related
cracks, here referred to as ‘hydrogen induced stress cracking’
(HISC).
5.5.4 For all practical applications, austenitic stainless steels
and nickel based alloys are generally considered immune to
HISC in the solution annealed condition. With the exceptions
of UNS S30200 (AISI 302) and UNS S30400 (AISI 304) stain-
less steel, moderate cold work does not induce HISC sensitiv-
ity of these materials. The same applies for welding or hot
forming according to an appropriate procedure. Bolts in AISI
316 stainless steel manufactured according to ISO 3506, part
1, grade A4, property class 80 and lower (up to SMYS 640
MPa) have proven compatibility with galvanic anode CP.
5.5.5 For certain nickel based alloys (i.e. austenitic alloys in-
cluding e.g. UNS N05500 and N07750), precipitation harden-
ing may induce high sensitivity to HISC. For precipitation
hardened austenitic stainless steels, the susceptibility is lower
and a hardness of max. 300 HV may be considered a reasona-
bly safe limit, whilst materials with hardness higher than 350
HV should generally be avoided for any components to receive
CP. In the intermediate hardness range (i.e. 300 to 350 HV),
precautions should be applied during design to avoid local
yielding and/or to specify a qualified coating system as a bar-
rier to hydrogen absorption by CP. The qualification of coat-
ings for this purpose should include documentation of
resistance to disbonding in service by environmental effects,
including CP and any internal heating.
5.5.6 Based on practical experience, ferritic and ferritic-pear-
litic structural steels with specified minimum yield strength
(SMYS) up to at least 500 MPa have proven compatibility with
marine CP systems. (However, laboratory testing has demon-
strated susceptibility to HISC during extreme conditions of
yielding). It is recommended that all welding is carried out ac-
cording to a qualified procedure with 350 HV as an absolute
upper limit. With a qualified maximum hardness in the range
300 to 350 HV, design measures should be implemented to
avoid local yielding and to apply a reliable coating system as a
barrier to CP induced hydrogen absorption.
5.5.7 For martensitic carbon, low-alloy and stainless steels,
failures by CP induced HISC have been encountered involving
materials with an actual YS and hardness of about 700 MPa
and 350 HV, respectively. It is widely recognised that untem-
pered martensite is especially prone to HISC. Welding of ma-
terials susceptible to martensite formation should be followed
by post weld heat treatment (PWHT) to reduce heat-affected
zone (HAZ) hardness and residual stresses from welding. The
same recommendations for hardness limits and design meas-
ures as for ferritic steels (5.5.6) apply. Bolts in martensitic steel
heat treated to SMYS up to 720 MPa (e.g. ASTM A182 grade
B7 and ASTM A320 grade L7) have well documented compat-
ibility with CP. However, failures due to inadequate heat treat-
ment have occurred and for critical applications, batch wise
testing is recommended to verify a maximum hardness of 350
HV.
5.5.8 Ferritic-austenitic (’duplex’) stainless steels should be
regarded as potentially susceptible to HISC, independent of
SMYS (typically 400 to 550 MPa) or specified maximum
hardness. Welding may cause increased HISC susceptibility in
the weld metal and in the HAZ adjacent to the fusion line. This
is related to an increased ferrite content rather than hardness.
Qualification of welding should therefore prove that the maxi-
mum ferrite content in the weld metal and the inner HAZ
(about 0.1 mm wide) can be efficiently controlled; contents of
maximum 60 to 70% are typically specified. Forgings are more
prone to HISC than wrought materials due to the course micro-
structure allowing HISC to propagate preferentially in the fer-
rite phase. Cold bent pipes of small diameter (uncoated and
with mechanical connections, i.e. no welding) have proven
records for CP compatibility when used as production control
piping for subsea installations. Design precautions should in-
clude 1) measures to avoid local plastic yielding and 2) use of

DET NORSKE VERITAS
coating systems qualified for e.g. resistance to disbondment by
mechanical and physical/chemical effects.
5.5.9 Copper and aluminium based alloys are generally con-
sidered immune to HISC, regardless of fabrication modes. For
high-strength titanium alloys, documentation is limited and
special considerations (including e.g. qualification testing, see
5.5.10) should apply.
5.5.10 There is no generally accepted test method to verify CP
compatibility of different metallic materials. Constant exten-
sion rate testing (also referred to as “slow strain rate testing”)
is applicable to compare HISC susceptibility of materials of
the same type (e.g. relative susceptibility of martensitic steels),
but a comparison of different types of materials is less straight-
forward. For more quantitative testing, uni-axially loaded ten-
sile specimens (with constant load), 4-point bend specimens
(with constant displacement), crack tip opening displacement
(CTOD) and other testing configurations have been applied at
controlled CP conditions. Such testing is, however, beyond the
scope of this document.
5.5.11 Special techniques have been applied to control the CP
protective potential to a less negative range (e.g. - 0.80 to - 0.90
V), including the use of diodes and special anode alloys, but
practical experience is limited. A major disadvantage of this
approach is that the individual component or system needs to
be electrically insulated from adjacent “normal” CP systems.
5.5.12 Cathodic protection in closed compartments without
ventilation may cause development of hydrogen gas to an ex-
tent that an explosive gas mixture (i.e. hydrogen/oxygen) may
eventually develop. The risk is moderate with Al and Zn-base
galvanic anodes but at least one explosion during external
welding on a water flooded platform leg containing such an-
odes has been related to this phenomenon. (Closed water
flooded compartments will not normally require CP, see
6.3.7).
5.5.13 A consequence of CP application is that a calcareous
layer (consisting primarily of calcium carbonate) will form on
bare metal surfaces. The thickness is typically of the order of a
tenth of a millimetre, but thicker deposits may occur. The cal-
careous layer reduces the current demand for maintenance of
CP and is therefore beneficial. A calcareous layer may, how-
ever, obstruct mating of subsea electrical and hydraulic cou-
plers with small tolerances. This may be prevented by applying
an insulating layer of a thin film coating (e.g. baked epoxy res-
in). An alternative measure is to electrically insulate the con-
nectors from the CP system and use seawater resistant
materials for all wetted parts. High-alloyed stainless steels,
nickel-chromium-molybdenum alloys, titanium and certain
copper based alloys (e.g. nickel-aluminium bronze) have been
used for this purpose.
5.5.14 Galvanic anodes may interfere with subsea operations
and increase drag forces by flowing seawater (see 5.7.3).
5.5.15 CP eliminates the anti-fouling properties of copper
based alloys in seawater.
5.6 Galvanic Anode Materials
5.6.1 Galvanic anodes for offshore applications are generally
based on either aluminium or zinc. The generic type of anode
material (i.e. aluminium or zinc base) is typically selected by
Owner and specified in the conceptual CP design report and/or
in the design premises for detailed CP design.
5.6.2 Aluminium based anodes are normally preferred due to
their higher electrochemical capacity, ε (A·h/kg). However,
zinc based anodes have sometimes been considered more reli-
able (i.e. with respect to electrochemical performance) for ap-
plications in marine sediments or internal compartments with
high bacterial activity, both environments representing anaer-
obic conditions.
5.6.3 Some manufacturers offer proprietary anode alloys. Pur-
chaser may require that the anode manufacturer shall docu-
ment the electrochemical performance of their products by
operational experience or by long term testing in natural sea-
water. (A recommended testing procedure is contained in An-
nex C).
5.7 Anode Geometry and Fastening Devices
5.7.1 There are three major types of anodes for offshore struc-
tures:
— slender stand-off
— elongated, flush mounted
— bracelet
Stand-off and flush-mounted anodes may further be divided
into “short” and “long”, based on the length to width ratio. The
anode type determines the anode resistance formula (6.6) and
anode utilisation factor (6.8) to be applied.
5.7.2 The slender stand-off type is typically cast on a tubular
insert and used for relatively large anodes on e.g. platform sub-
structures and subsea templates. The current output, Ia (A), in
relation to net anode mass, Ma (kg), is high, as is the utilisation
factor u.
Stand-off anodes are manufactured up to a net anode mass of
several hundred kilograms. In surface waters, drag forces ex-
erted by sea currents are significant.
Bracelet anodes are used primarily for pipelines but have also
found some use on platform legs in the upper zone, combining
high current output to weight ratio with low drag. All flush
mounted anodes should have a suitable coating system applied
on the surface facing the protection object. This is to avoid
build-up of anode corrosion products that could cause distor-
tion and eventually fracture of anode fastening devices.
5.7.3 Type of anodes and any special requirements to anode
fastening should be defined during conceptual CP design, tak-
ing into account forces exerted during installation (e.g. piling
operations) and operation (e.g. wave forces). For stand-off
type anodes, special precautions may be necessary during an-
ode design and distribution of anodes to avoid impeding sub-
sea operations (7.10.2).
5.8 Use of Coatings in Combination with CP
5.8.1 The use of non-metallic coatings drastically reduces the
CP current demand of the protection object and hence, the re-
quired anode weight. For weight-sensitive structures with a
long design life, the combination of a coating and CP is likely
to give the most cost-effective corrosion control. For some sys-
tems with very long design lives, CP may be impractical unless
combined with coatings.
5.8.2 The use of coatings should be considered for applica-
tions where the demand for CP of bare metal surfaces is known
or expected to be high. This includes deep water applications
for which the formation of calcareous deposits may be slow
(see 6.3.2). It should further be considered for surfaces that are
partly shielded from CP by geometrical effects.
5.8.3 For large and complex structures like e.g. multi-well
subsea production units, extensive use of coating is required to
limit the overall current demand and to ensure adequate current
distribution. The CP design procedure in this document does
not account for a voltage drop in the seawater remotely from
anodes.
To compensate for this, the design coating breakdown factors
to be used for CP design are deliberately selected in a conserv-
ative manner to ensure that a sufficient total final current out-

DET NORSKE VERITAS
put capacity is installed. As a consequence, any calculations of
the electrolytic voltage drop away from the anodes (e.g. by
means of finite or boundary element analyses) and using these
coating breakdown factors may result in excessively high elec-
trolytic voltage drops, indicating marginal or even insufficient
cathodic protection in terms of the estimated protection poten-
tial.
This will primarily apply to relatively long design lives when
the calculated coating breakdown, and hence current demands
and electrolytic voltage drop increase exponentially.
5.8.4 The application of coatings may not be suitable for parts
of submerged structures requiring frequent inspection for fa-
tigue cracks, e.g. critical welded nodes of jacket structures.
5.8.5 Metallic coatings on zinc or aluminium basis are com-
patible with galvanic anode CP. However, compared to organ-
ic coatings, they have not been concidered to afford any
advantage in decreasing the current demand for CP. Zinc rich
primers have been considered unsuitable for application with
CP due to either susceptibility to cathodic disbondment (5.5.1)
or low electrical resistivity, leading to high CP current de-
mand.
5.8.6 For components in materials sensitive to HISC by CP, a
non-metallic coating system should always be considered as a
barrier to hydrogen adsorption (5.5.6-5.5.7).
5.9 Electrical Continuity and Current Drain
5.9.1 Provisions for electrical insulation are only necessary if
certain components or sub-systems are to be electrically insu-
lated to avoid CP or to control the CP potential by special
means (see 5.5.11 and 5.5.12).
5.9.2 CP current drain to components that are electrically con-
nected to the protection object will have to be considered dur-
ing the design. This may include e.g. components in alloys that
are regarded as fully resistant to corrosion in seawater and
components that do not need corrosion protection for structural
purposes due to high wall thickness relative to expected corro-
sion rates (e.g. piles and casings installed in sea bed).
6. CP Design Parameters
6.1 General
6.1.1 This section describes design parameters to be used for
conceptual and detailed design of galvanic anode CP systems
and gives guidance on the selection of such parameters. With
the exception of the design life (see 6.2) and possible also coat-
ing breakdown factors (see 6.4.3), the actual design values to
be applied for a specific project are normally selected by Con-
tractor, based on environmental and other parameters identi-
fied in the project design basis. However, sometimes certain or
all CP design parameters have already been defined by Pur-
chaser in a project document.
6.1.2 If reference is given to this RP in a purchase document,
and unless otherwise agreed, the default design values referred
to in this section shall apply.
6.1.3 The design values recommended in this section are con-
sistently selected using a conservative approach. Adherence to
these values is therefore likely to provide a service life that ex-
ceeds the design life of the CP system.
6.1.4 Owners of offshore structures may specify a less, or in
certain cases a more conservative design data, based on their
own experience or other special considerations. Contractor
(i.e. other than Owner) may further propose use of alternative
design data, however, any such data shall then be accepted by
Owner, preferably before the CP design work has started.
6.1.5 All electrochemical potentials associated with CP in this
section refer to the Ag/AgCl/seawater reference electrode. The
potential of this reference electrode is virtually equivalent to
that of the standard calomel electrode (SCE)
6.1.6 Compared to the 1993 revision of this RP, the major re-
visions of this 2004 revision are that the number of depth zones
for design current densities have been extended from 2 to 4 (3
only for CP of concrete reinforcing steel) whilst the number of
‘coating categories’ are reduced from 4 to 3. Revisions of the
actual design parameters (contained in Annex A in this revi-
sion) are otherwise marginal.
6.2 Design Life
6.2.1 The design life of a CP system is normally specified by
Owner, taking into account the likelihood of the design life of
the protection object being extended. The design life shall fur-
ther take into account any period of time when the CP system
will be active prior to operation of the protection object.
Guidance note:
Maintenance and repair of CP systems for fixed offshore struc-
tures are generally very costly and sometimes impractical. It is
therefore normal practice to apply at least the same anode design
life as for the protection object. However, in certain circumstanc-
es planned retrofitting of sacrificial anodes may be an economi-
cally viable alternative to the installation of very large anodes
initially. This alternative should then be planned such that neces-
sary provisions for retrofitting are made during the initial design
and fabrication.
---e-n-d---of---G-u-i-d-a-n-c-e---n-o-t-e---
6.3 Design Current Densities
6.3.1 In this document ‘current density’, ic , refers to cathodic
protection current per unit surface area (in A/m2). The ‘initial’
and ‘final’ design current densities, ici (initial) and icf (final),
respectively, give a measure of the anticipated cathodic current
density demand to achieve cathodic protection of a bare metal
surface within a reasonably short period of time. They are used
to calculate the initial and final current demands which deter-
mine the number and sizing of anodes. The effect of any coat-
ing on current demand is taken into account by application of
a ‘coating breakdown factor’, see 6.4.
6.3.2 The initial design current density refers to the cathodic
current density that is required to effect polarization of an ini-
tially bare metal surface, typically for structural steel surfaces
with some rusting and/or mill scale.
Guidance note:
The initial design cathodic current density is necessarily higher
than the final design current density because the calcareous scale
(see 5.5.13) and possibly marine fouling layer developed during
this initial phase reduce the subsequent current demand (i.e. the
‘polarization resistance’ is reduced). A sufficient initial design
current density enables rapid formation of protective calcareous
scale and hence efficient polarization.
6.3.3 The final design current density refers to metal surfaces
with established calcareous scale and marine growth. It takes
into account the current density required to re-polarize a struc-
ture if such layers are partly damaged, e.g. by periodic removal
of marine growth.
Guidance note:
An appropriate final design current density (and hence CP polar-
izing capacity) will further ensure that the protection object re-
mains polarized to a potential of - 0.95 to - 1.05 V throughout the
design life. In this potential range, the current density demand for

DET NORSKE VERITAS
maintenance of CP is lowest.
6.3.4 The initial and final current densities are used to calcu-
late the required number of anodes of a specific type (7.7) to
achieve a sufficient polarizing capacity by use of Ohm’s law
and assuming that
1) the anode potential is in accordance with the design closed
circuit potential (6.5.3) and
2) the potential of the protection object (i.e. cathode) is at the
design protective potential for C-steel and low-alloy steel,
i.e. - 0.80 V.
Guidance note:
It follows from the above relationship that the anode current and
hence the cathodic current density decreases linearly when the
cathode is polarised towards the closed circuit anode potential,
reducing the driving voltage for the galvanic cell. According to
7.8.3, the total CP current for a CP unit, Itot (A), becomes:
Where Ra tot (ohm) is the total anode resistance, E'c (V) is the
global protection potential and E'a (V) is the actual anode (closed
circuit) potential.
6.3.5 The mean (or ‘maintenance’) design current density, icm
(A/m2), is a measure of the anticipated cathodic current density
once the CP system has attained its steady-state protection po-
tential; this is typically 0.15 to 0.20 V more negative than the
design protective potential.
Guidance note:
The decrease in cathode potential (i.e. ‘cathodic polarization’)
reduces the anode current as stated in the Guidance note to 6.3.4
so that the average design current density becomes about 50% of
the initial/final design current density. As the initial polarization
period proceeding steady-state condition is normally short com-
pared to the design life, the time-weighted cathodic current den-
sity becomes very close to the steady-state cathodic current
density.
6.3.6 Cathodic current densities to achieve and maintain CP
are dependent on factors that vary with geographical location
and operational depth. Recommendations for initial/final and
average design current densities are given in Tables 10-1 and
10-2 of Annex A, respectively, based on climatic regions and
depth. These design current densities have been selected in a
conservative manner to account for harsh weather conditions,
including waves and sea currents, but not erosive effects on
calcareous layers by silt or ice. They further assume that the
seawater at the surface is saturated with air (i.e. at 0.2 bar ox-
ygen partial pressure).
Guidance note:
The data in Tables 10-1 and 10-2 reflect the expected influence
of seawater temperature and depth on the properties of a calcar-
eous scale formed by cathodic protection and of the content of
dissolved oxygen content. The properties of such layers are de-
pendant on the seawater ambient temperature and moreover, on
certain depth dependant parameters other than temperature (see
5.3.1). Oxygen is dissolved in the surface layer (by dissolution
from air and photo synthesis) such that the oxygen content at a
large depth in a tropical region is likely to be substantially lower
than in temperate or arctic surface waters of the same ambient
seawater temperature. The higher design current densities in the
uppermost zone are a result of wave forces and marine growth on
degradation of calcareous scales and convective mass transfer of
oxygen. In certain areas, decomposition of organic material may
reduce and ultimately consume all oxygen in the seawater. No
such reduction in oxygen content is accounted for in Tables
10-1 and 10-2.
6.3.7 For freely flooded compartments and for closed com-
partments with free access to air, design current densities for
30-100 m given in Tables 10-1 and 10-2 are recommended.
Closed and sealed flooded compartments do not normally need
CP.
6.3.8 For bare steel surfaces buried in sediments, a design cur-
rent density (initial/final and average) of 0.020 A/m2 is recom-
mended irrespective of geographical location and depth.
Guidance note:
In the uppermost layer of seabed sediments, bacterial activity
may be the primary factor determining the CP current demand.
Further down into sediments, the current will be related to hydro-
gen evolution.
6.3.9 For piping and other components heated by an internal
fluid, the design current densities as specified in Tables 10-1
and 10-2 shall be increased by 0.001 A/m2 for each °C that the
metal/environment interface is assumed to exceed 25°C. For
single wall conduits this temperature shall be assumed to be
equal to the temperature of the internal fluid.
Guidance note:
The additional CP current density is to account for increased con-
vective and diffusive mass transfer of oxygen induced by heat
transfer.
6.3.10 The design current densities in Tables 10-1 and 10-2
shall also apply for surfaces of any stainless steel or non-fer-
rous components of a CP-system which includes components
in C-steel or low-alloy steel. For calculation of anode current
output according to 7.8.2, a protective potential of -0.80 V
shall then also apply for these materials.
6.3.11 For aluminium components, or those coated with either
aluminium or zinc, a design current density of 0.010 A/m2 is
recommended for initial/final as well as mean values. For in-
ternally heated components, the design current density shall be
increased by 0.002 A/m2 for each °C that the metal /seawater
is assumed to exceed 25°C.
6.3.12 For cathodic protection of concrete reinforcing steel
and other concrete embedded steel components associated
with offshore structures, the design current densities in
Table 10-3 of Annex A are recommended. For seawater filled
concrete shafts, cathodic protection should be provided from
both sides. For external protection of shafts that are normally
empty, the design current densities in Table 10-3 shall be mul-
tiplied with a factor of 1.5.
Guidance note:
The cathodic current density of steel embedded in concrete is
mainly controlled by reduction of oxygen. In the splash zone and
in internal dry compartments, oxygen is transported by capillary
action of pore water, driven by evaporation at the atmospheric
surface. Hence, the cathodic current density will be dependent on
the exposure conditions (i.e. distance to atmospheric exposure of
concrete) and ambient temperature.
6.3.13 When the actual reinforcing steel surface area (in m2)
to reinforced concrete volume (in m3) ratio B exceeds 5, an ad-
justment factor 5/B may be applied to the design current den-
sities in Table 10-3
6.4 Coating Breakdown Factors for CP Design
6.4.1 The coating breakdown factor, fc , describes the antici-
atot
ac
tot
R
)'E'E(
I
−
=

DET NORSKE VERITAS
pated reduction in cathodic current density due to the applica-
tion of an electrically insulating coating. When fc = 0, the
coating is 100% electrically insulating, thus decreasing the ca-
thodic current density to zero. fc = 1 means that the coating has
no current reducing properties.
Guidance note:
The coating breakdown factor should not be confused with coat-
ing degradation as apparent by visual examination. A coating
showing extensive blistering may still retain good electrically in-
sulating properties. Conversely, an apparently perfect coated sur-
face may allow a significant passage of current.
6.4.2 The coating breakdown factor is a function of coating
properties, operational parameters and time. As a simple engi-
neering approach, fc can be expressed as:
fc = a + b · t
where t (years) is the coating lifetime and a and b are constants
that are dependent on coating properties and the environment.
Guidance note:
The effect of marine growth is highest in the upper 30 meters
where wave forces may further contribute to coating degradation.
Another factor is periodic cleaning of marine growth in this zone.
6.4.3 Owner should preferably specify constants a and b for
calculation of coating breakdown factors based on his own
practical experience of specific coating systems in a particular
environment. When Owner has not specified any such data, the
default values in Table 10-4 of Annex A shall be used. The
coating breakdown factors as established in Annex A are based
on considerations addressed in 5.8.3.
6.4.4 Once a and b are defined, mean and final coating break-
down factors, fcm and fcf, respectively, to be used for CP de-
sign purposes are to be calculated by introducing the CP design
life, tf (yrs):
fcf = a + b · tf
For certain protection objects, with large uncoated surfaces,
the initial coating breakdown factor, fci = a, may be applied to
calculate the initial current demand to include coated surfaces.
6.4.5 If the calculated value according to 6.4.4 exceeds 1,
fc = 1 shall be applied in the design. When the design life of the
CP system exceeds the actual calculated life of the coating sys-
tem according to (6.4.2), fcm may be calculated as:
6.4.6 To account for the effect of a coating system on coating
breakdown factors, three ‘coating categories’ have been de-
fined for inclusion in Table 10-4:
Category I One layer of epoxy paint coating, min. 20
µm nominal DFT
Category II One or more layers of marine paint coating
(epoxy, polyurethane or vinyl based), total
nominal DFT min. 250 µm.
Category III Two or more layers of marine paint coating
(epoxy, polyurethane or vinyl based), total
nominal DFT min. 350 µm.
Category I includes shop primer type of coatings. It is assumed
for Categories II and III that the supplier-specific coating ma-
terials to be applied have been qualified by documented per-
formance in service, or by relevant testing. It is further
assumed for all three categories that all coating work has been
carried out according to manufacturer’s recommendations and
that surface preparation has included blast cleaning to mini-
mum SA 2.5 in accordance with ISO 8501. The surface rough-
ness shall be controlled according to manufacturer’s
recommendation. For any coatings applied without blast clean-
ing (including machined, ground, brushed and as-rolled surfac-
es), a coating break-down factor of fcm = fcf = 1 shall be
applied, while the initial current demand may be calculated as
for Category I.
Guidance note:
Published data on the performance of coatings on cathodically
protected structures are scarce, in particular for long service
lives. The data in Table 10-4 should therefore be regarded as
rather course but conservative engineering judgements. For any
coating system not covered by the three coating categories above
and with major potential effect on the overall current demand,
Owner should specify or accept the applicable constants a and b.
6.4.7 NORSOK M-501 Systems no. 3B and 7 meet the re-
quirements of Category III.
6.4.8 a and b values for a depth 30-100 m in Table 10-4 are ap-
plicable to calculations of current demands of flooded com-
partments and of closed compartments with free access to air.
6.4.9 The constants in Table 10-4 do not account for signifi-
cant damage to paint coatings during fabrication and installa-
tion. If such damage is anticipated, the affected surface area is
to be estimated and included in the design calculations as bare
metal surface.
6.5 Galvanic Anode Material Design Parameters
6.5.1 Unless otherwise specified or accepted by Owner, the
compositional limits for alloying and impurity elements for Al
and Zn-based anodes in Table 10-5 shall apply. The CP design
parameters related to anode material performance are:
— design electrochemical capacity, ε (Ah /kg)
— design closed circuit anode potential, Eo
a (V)
The design electrochemical capacity, ε (Ah /kg), and design
closed circuit anode potential, Eo
a (V) are used to calculate
1) the design anode current output and
2) the required net anode mass using Ohm’s and Faraday’s
laws, respectively.
6.5.2 The design values for electrochemical capacity, ε (Ah /
kg), in Table 10-6 of Annex A shall be used for design unless
otherwise specified or accepted by Owner. The data are appli-
cable for ambient temperature seawater (i.e. up to 30°C as a
yearly mean value).
Guidance note:
Data on anode electrochemical efficiency from short-term labo-
ratory examinations of galvanic anode materials will typically re-
sult in values close to the theoretical limit (e.g. ≥ 2,500 Ah/kg for
Al-Zn-In material). This is due to the relatively high anodic cur-
rent densities that are utilized for testing. Such data shall not re-
place the recommended design values for electrochemical
capacity. The use of electrochemical capacity greater than the de-
fault values in Table 10-6 should be justified by long term testing
according to Annex C. Even such testing will tend to result in
slightly non-conservative values as the testing time is still rela-
tively short and the anodic current density relatively high com-
pared to the working conditions for real anodes. When using
anode manufacturer’s testing data for design, it should further be
ensured that the composition of alloying and impurity elements
of the material tested and the casting conditions are representa-
tive for normal, and preferably also “worst case” production (see
12.2.2 of Annex C).
2
t
baf f
cm ⋅+=
( )
f
2
cm
tb2
a1
1f
⋅⋅
−
−=

DET NORSKE VERITAS
6.5.3 The design values for closed circuit anode potential, Eo
a
(V), in Table 10-6 of Annex A shall be used for design. The
data are applicable for all ambient seawater temperatures (i.e.
max 30°C yearly average).
Guidance note:
Higher anode temperatures may apply if anodes are heated by an
internal medium and buried in seabed sediments and the data in
Table 10-6 are then not applicable. However, such conditions are
only relevant for CP of pipelines which is not covered by this
document.
6.6 Anode Resistance Formulas
6.6.1 Unless otherwise agreed, the anode resistance, Ra
(ohm), shall be calculated using the formula in Table 10-7 of
Annex A that is applicable to the actual anode shape. Calcula-
tions shall be performed for the initial anode dimensions and
for the estimated dimensions when the anode has been con-
sumed to its utilisation factor (7.8).
6.7 Seawater and Sediment Resistivity
6.7.1 The seawater resistivity, ρ (ohm·m), is a function of the
seawater salinity and temperature. In the open sea, the salinity
does not vary significantly and temperature is the main factor.
The relationship between resistivity and temperature at a salin-
ity of 30 to 40 ‰ (parts per thousand) is shown in Fig. 10-1 of
Annex A.
6.7.2 In shore areas, particularly at river outlets and in en-
closed bays, the salinity will vary significantly. It is recom-
mended that the design of CP systems in such locations is
based on resistivity measurements reflecting the annual mean
value and the variation of resistivity with depth.
6.7.3 Compared to seawater, the resistivity of marine sedi-
ments is higher by a factor ranging from about 2 for very soft
clays to approximately 5 for sand. Unless sediment data for the
location are available, the highest factor shall be assumed for
calculation of the resistance of any buried anodes.
6.7.4 In temperate regions (annual average surface water tem-
perature 7 to 12°C), resistivities of 0.30 and 1.3 ohm·m are rec-
ommended as reasonably conservative estimates for the
calculation of anode resistance in seawater and marine sedi-
ments, respectively, and independent of depth. Lower values
are to be documented by actual measurements, taking into ac-
count any seasonal variations in temperature.
6.8 Anode Utilization Factor
6.8.1 The anode utilisation factor, u, is the fraction of anode
material of an anode with a specific design that may be utilised
for calculation of the net anode mass required to sustain pro-
tection throughout the design life of a CP system (see 7.7.1).
When an anode is consumed to its utilisation factor, the polar-
izing capacity (as determined by the anode current output) be-
comes unpredictable due to loss of support of anode material,
or rapid increase of anode resistance due to other factors (see
7.9)
6.8.2 The utilisation factor is dependant on the anode design,
particularly its dimensions and the location of anode cores
(7.10.4). Unless otherwise agreed, the anode utilisation factors
in Table 10-8 of Annex A shall be used for design calculations.
6.9 Current Drain Design Parameters
6.9.1 The design current densities and coating breakdown fac-
tors in 6.3 and 6.4, respectively, are applicable for calculation
of current drains to components that are not considered to need
CP, but will be (or may possibly become) electrically connect-
ed to the CP system being designed.
6.9.2 For buried surfaces of mud mats, skirts and piles, a cur-
rent drain (i.e. 0.020 A/m2 in accordance with 6.3.8) shall be
accounted for, based on the outer (sediment exposed) external
surface area. For open pile ends, the top internal surface shall
be included for a distance of 5 times the diameter and shall be
regarded as seawater exposed. Internal surfaces of piles filled
with sediments do not have to be included.
6.9.3 Unless otherwise specified or accepted by Owner, a cur-
rent drain of 5 A per well casing shall be included in current
drain calculations.
Guidance note:
Casings for subsea wells are typically cemented which reduces
the current drain compared to platform wells which are normally
not cemented. However, subsea wells may become exposed to
significant current drain by e.g. installation and work-over equip-
ment during subsea installations and interventions.
6.9.4 Current drain to anchor chains shall be accounted for by
30 m for systems with mooring point topside only. For systems
with mooring point below the water level, the seawater ex-
posed section above this point shall also be included. A current
drain of 30 m shall also be included for CP of anchoring ar-
rangements using chains.
7. CP Calculation and Design Procedures
7.1 General
7.1.1 For large protection objects such as platform sub-struc-
tures, the detailed design of a CP system is normally preceded
by a conceptual design activity. During this conceptual design,
the type of anodes and fastening devices should be selected,
taking into account forces exerted on anodes during installa-
tion and operation. Moreover, any coating systems to be ap-
plied to specific areas or components would also normally be
specified, allowing for a preliminary calculation of current de-
mands for cathodic protection and the associated total net mass
of anode material required. If no CP conceptual report has been
prepared, then the premises and basic concepts for detailed CP
design shall be defined by Purchaser in some other reference
document(s) to be included in an inquiry for CP detailed de-
sign.
7.1.2 Besides any reference to this RP in a ‘purchase docu-
ment’ (see 1.3), the following information and any optional re-
quirements (intended as a check-list) shall be provided by
Purchaser:
Information:
— conceptual CP design report, if completed (7.1.1)
— design life of CP system to be installed (6.2)
— relevant information from the project design basis (7.1.1);
e.g. salinity and temperature as a function of depth for cal-
culation of anode resistance, location of seawater level and
mud line for platform substructures, environmental and in-
stallation parameters affecting forces exerted on anodes
— structural drawings and information of coating systems as
required for calculation of surface areas to be protected,
including components which may exert temporary or per-
manent current drain (7.1.3)
— identification of any interfaces to electrically connected
components/systems with self-sufficient CP systems, e.g.
pipelines.
Requirements (optional):
— requirements to documentation and 3rd party verification,
including schedule for supply (7.13)
— any specific requirement to CP design parameters to be ap-

DET NORSKE VERITAS
plied, e.g. coating breakdown factors (6.4.3) and current
drain to wells (6.9.3)
— any specific requirements to anode material (6.5) and an-
ode design (7.6)
— any further amendments and deviations to this RP applica-
ble to CP design.
7.1.3 Purchaser shall ensure that valid revisions of drawings
and specifications affecting calculation of current demand for
CP and location of anodes are available to Contractor during
the design work. It shall be ensured that all necessary informa-
tion is provided for Contractor to calculate the overall current
demand, e.g. conductors for production platform sub-struc-
tures and production control system for subsea valve trees.
7.1.4 The CP calculation procedure in this 2004 revision is the
same as in the 1993 issue of this RP and revisions in the text
are primarily for clarification. However, a note on the use of
anodes with large difference in size has been added in 7.8.6.
7.2 Subdivision of CP Object
7.2.1 In the design of CP systems for large and/or complex ob-
jects, it is always convenient to divide the protection object
into units to be protected.
7.2.2 The division into units may be based on e.g. depth zones
or physical interfaces of the protection object such as retrieva-
ble units within a subsea production system.
7.3 Surface Area Calculations
7.3.1 For each CP unit (7.2), surface areas to receive CP shall
be calculated separately for surfaces with and without a coat-
ing system (see Coating Categories in 6.4.6) and for surfaces
affected by other parameters (e.g. surface temperature) which
influence the CP current demand.
7.3.2 It is practical to apply some simplification when calcu-
lating surface areas for objects with complex geometries.
However, it shall be ensured that the overall result of any such
simplification is conservative.
Guidance note:
For major surface areas, an accuracy of -5/+10 % is adequate. For
smaller components, the required accuracy may be lower de-
pending on whether or not a coating will be applied to such items
and to the major surfaces.
7.3.3 Surface area calculations for each unit shall be docu-
mented in the CP design report. Reference shall be made to
drawings, including revision numbers.
7.3.4 Contractor shall make sure that all items affecting CP
current demand are included in the surface area calculations.
This may include various types of outfitting to be installed by
different contractors.
Guidance note:
For subsea production systems, production control equipment is
typically manufactured from uncoated stainless steel (piping
components, couplings, connectors, cable trays, etc.) which con-
stitutes a significant current demand. ROV override components
are also often manufactured from stainless steel without a coat-
ing. Moreover, some components like valve blocks and hydraulic
cylinders may have coating applied directly to machined surfac-
es, increasing the coating breakdown factor to be used for design
(6.4.6).
7.4 Current Demand Calculations
7.4.1 To calculate the current demand, Ic (A), to provide ade-
quate polarizing capacity (6.3.1-6.3.4) and to maintain cathod-
ic protection during the design life (6.3.5), the individual
surface areas, Ac (m2), of each CP unit shall be calculated ac-
cording to (7.2) and multiplied by the relevant design current
density, ic (A/m2), and the coating breakdown factor, fc , if ap-
plicable:
ic and fc are then to be selected according to (6.3) and (6.4), re-
spectively.
7.4.2 For items with major surfaces of uncoated metal, the CP
current demands for both initial polarization and for polariza-
tion at the end of the design life, Ici (A) and Icf (A), respective-
ly, shall be calculated, together with the mean current demand
required to maintain cathodic protection throughout the design
period, Icm (A). For protection objects with current demand
primarily associated with coated surfaces, the initial current
demand can be deleted in the design calculations. For future
reference, all calculated data shall be documented in the design
report.
7.5 Current Drain Calculations
7.5.1 All items which are expected to (or may) become elec-
trically connected to a CP system shall be considered in current
drain calculations.
Guidance note:
Complex offshore structures often include temporary or perma-
nent components which are not considered to require CP but will
drain current from the CP system (e.g. mooring systems for float-
ing installations) or secondary structural components (e.g. piles
and skirts) which can readily tolerate some corrosive wear. Also,
metallic materials with intrinsic resistance to corrosion in seawa-
ter will still drain current from a CP system.
7.5.2 Calculations of current drain shall use the design current
densities (6.3) and coating breakdown factors (6.4) for items
requiring CP. Calculations of surface areas and current de-
mands shall be carried out according to (7.3) and (7.4), respec-
tively.
7.5.3 For calculation of current drain to mud mats, skirts,
piles, well casings and steel anchor chains, see 6.9.2, 6.9.3 and
6.9.4.
7.6 Selection of Anode Type
7.6.1 For certain structures, anode types (i.e. stand-off, flush
mounted or bracelet anodes) may be specified by Owner/Pur-
chaser, taking into account effects of e.g. sea current drag and
interference with subsea interventions (7.1).
7.6.2 If anode type has not been specified by Owner/Purchas-
er, then Contractor shall select anode type taking into account
e.g. net anode mass to be installed and available space for lo-
cation of anodes. Selection of anode type is primarily deter-
mined by the size and geometrical configuration of the
protection object, in addition to forces exerted on anodes dur-
ing installation and operation. The anode type further affects
the anode utilisation factor and the anode current output in re-
lation to weight. (For general considerations of anode type se-
lection, see 5.7).
Guidance note:
Long stand-off type anodes are usually preferred for relatively
large anodes (about 100 kg and more) to be installed on platform
substructures and subsea templates. A flush-mounted anode with
the same net anode mass will have a lower anode current output
and lower utilisation factor.
Ic = Ac · ic · fc (1)

DET NORSKE VERITAS
7.7 Anode Mass Calculations
7.7.1 The total net anode mass, Ma (kg), required to maintain
cathodic protection throughout the design life, tf (yrs), is to be
calculated from Icm (A) for each unit of the protection object
(including any current drain):
In (2), 8760 refers to hours per year. u and ε (Ah /kg) are to be
selected based on (6.8) and (6.5), respectively.
7.8 Calculation of Number of Anodes
7.8.1 From the anode type selected (7.6), the number of an-
odes, (N), anode dimensions and anode net mass, ma (kg), shall
be defined to meet the requirements for:
1) initial/final current output, Ici/ Icf (A), and
2) anode current capacity Ca (Ah)
which relate to the CP current demand, Ic (A), of the protection
object.
Guidance note:
The preliminary sizing of anodes should be based on commer-
cially available products, requiring liaison with potential anode
vendors.
7.8.2 The individual anode current output, Ia (A), required to
meet the current demand, Ic (A), is calculated from Ohm’s law:
where Eo
a (V) is the design closed circuit potential of the anode
material (6.5) and Ra (ohm) is the anode resistance (6.6). The
initial and final current output, Iai and Iaf, are to be calculated
using the initial and final anode resistance, Rai and Raf, respec-
tively. For calculation of anode resistance, see 7.9. Ec
o (V) is
the design protective potential which is - 0.80 V (5.4). ∆ Eo (V)
is termed the design driving voltage.
Guidance note:
As the design driving voltage in (3) is defined using the design
protective potential for C-steel, the initial/final design current
densities that define the anode current output capacity, and hence
the driving voltage, refer to the required anode current output at
this potential. Hence, the initial/final design current densities
given in Table 10-3 are based on a protection potential of -
0.80 V. This means that they shall always be used for calcula-
tions according to (3) in combination with this potential, also if a
more negative protection potential (e.g. ≤ - 0.90 V) is aimed for,
see 6.3.
7.8.3 The individual anode current capacity, Ca (A·h), is given
by:
where ma (kg) is the net mass per anode. The total current ca-
pacity for a CP unit with N anodes thus becomes N · Ca (A·h)
7.8.4 Calculations shall be carried out to demonstrate that the
following requirements are met:
Ca tot in (5) is the total anode current capcity. Icm/ Ici/ Icf in (5,
6, 7) are the current demands of a CP unit, including any cur-
rent drain. 8760 is the number of hours per year. Iai and Iaf in
(6) and (7) are the initial and final current output for the indi-
vidual anodes.
Guidance note:
If anodes with different size and hence, anode current capacity ,
Ca (Ah), and current output, Ia (A), are utilised for a CP unit,
N · Ca and N · Iai / N · Iaf will have to be calculated for each in-
dividual size and then added for calculation of the total anode
current capacity (Ca tot) and total anode current output
(Ia tot i / Ia tot f ).
7.8.5 If the above criteria cannot be fulfilled for the anode di-
mensions and net mass initially selected, another anode size
shall be selected and the calculations repeated until the criteria
are fulfilled.
Guidance note:
Optimising the requirements in (5), (6) and (7) is an iterative
process where a simple computer spreadsheet may be helpful. In
general, if (5) is fulfilled, but not (6) and/or (7), a higher number
of smaller anodes, or the same number of more elongated anodes
are to be used. On the other hand, if N·Ia in (6, 7) is much larger
than Ici and Icf, fewer and/or more compact anodes may be ap-
plied.
7.8.6 Unless a high initial current capacity is deliberately
aimed for (e.g. in the case of protection objects consisting pri-
marily of uncoated metal surfaces), the anodes to be installed
should have a similar anode current output (Ia) to net anode
mass (ma) ratio. Small anodes with high anode current output
to net mass ratio will be more rapidly consumed than large an-
odes with a higher ratio, which could result in an insufficient
total anode current capacity towards the end of the design life.
Guidance note:
For anodes with the same anode resistance and hence, same an-
ode current output, but a major difference in net anode mass (i.e.
due to different anode geometry), the anode with the lowest net
anode mass will be consumed first. Similarly, for anodes with the
same net anode mass but with major difference in anode resist-
ance and hence, anode current output, the anode with the lowest
anode resistance will be consumed first.
7.9 Calculation of Anode Resistance
7.9.1 The anode resistance, Ra (ohm), to be used in (3) shall
be based on the applicable formulas in Table 10-7 of Annex A,
using the actual anode dimensions and specific resistivity of
the surrounding environment. Specific resistivities of the sur-
rounding environment shall be selected according to (6.7).
7.9.2 To calculate the initial anode resistance, Rai (ohm), the
initial anode dimensions are inserted in the relevant anode re-
sistance formula in Table 10-7. The final anode resistance, Raf
(ohm), is calculated based on the expected dimensions when
the anode has been consumed to its utilisation factor, u, (see
6.8) as explained below.
7.9.3 When the anode has been consumed to its utilisation fac-
tor, u, at the end of the design life, tf (years), the remaining net
anode mass, maf (kg), is given by:
The final volume of the anode to be used for calculation of Raf
can be calculated from the remaining net anode mass, maf (kg),
specific density of anode material and the volume of insert ma-
terials. When details of anode inserts are not available, their
volume should either be neglected or estimated to give a con-
(2)
(3)
Ca = ma · ε · u (4)
Ca tot = N · Ca ≥ Icm · tf · 8760 (5)
Ia tot i = N · Iai ≥ Ici (6)
Ia tot f = N · Iaf ≥ Icf (7)
ε⋅
⋅⋅
=
u
8760tI
M fcm
a
Ic N Ia⋅
N Ec° Ea°–( )
Ra
--------------------------------- N ∆E°⋅
Ra
-------------------= = =
maf = mai · (1 – u) (8)

DET NORSKE VERITAS
servative approach.
7.9.4 For long and short slender stand-off anodes consumed to
their utilisation factor, a length reduction of 10% shall be as-
sumed. Furthermore, assuming that the final anode shape is cy-
lindrical, the final radius shall be calculated based on this
length reduction, and the final anode mass/volume as ex-
plained in (7.9.3)
7.9.5 For long and flush mounted anodes, the final shape shall
be assumed to be a semi-cylinder and the final length and radi-
us shall be calculated as above.
7.9.6 For short flush-mounted anodes, bracelet anodes and
other shapes mounted flush with the protection object, the final
exposed area shall be assumed to be equivalent to the initial
area facing the surface to be protected.
7.10 Anode Design
7.10.1 Contractor shall specify in CP design report tentative
dimensions and/or net mass for anodes to be used.
7.10.2 For anodes that may become subject to significant forc-
es during installation and operation, the design of anode fas-
tening devices shall be addressed in the design report. Special
considerations apply for large anodes to be installed on struc-
tural members subject to fatigue loads during pile driving op-
erations. Doubler and/or gusset plates may be required for
large anodes.
7.10.3 For use of the anode resistance formula in Table 10-7
for stand-off type anodes, the minimum distance from anode to
protection object shall be minimum 300 mm. However, for dis-
tances down to 150 mm, the formula can still be used by mul-
tiplying the anode resistance with a factor of 1.3.
7.10.4 The detailed anode design shall ensure that the utilisa-
tion factor assumed during calculations of required anode net
mass according to 7.7 is met. Hence, it shall be ensured that the
anode inserts are still likely to support the remaining anode
material when the anode has been consumed to its design uti-
lisation factor. Unless otherwise agreed, anode cores of stand-
off type anodes shall protrude through the end faces.
7.10.5 With the exception of stand-off type anodes, a marine
grade paint coating (min. 100 µm DFT) shall be specified for
anode surfaces facing the protection object.
7.11 Distribution of Anodes
7.11.1 The calculated number of anodes, N, for a CP unit shall
be distributed to provide a uniform current distribution, taking
into account the current demand of individual members due to
different surface areas and any coatings used. On platform sub-
structures, special areas to be considered when distributing an-
odes are e.g. nodes, pile guides and conductor bundles. The
location of all individual anodes shall be shown on drawings.
7.11.2 Whenever practical, anodes dedicated to CP of surfaces
buried in sediments shall be located freely exposed to the sea.
7.11.3 Anodes shall be located with sufficient spacing be-
tween each other to avoid interaction effects that reduce the
useful current output. As far as practical, anodes shall be locat-
ed so that those of its surfaces intended for current output are
not in close proximity to structural members, reducing the cur-
rent output.
Guidance note:
With the exception of very large anodes, shielding and interfer-
ence effects become insignificant at a distance of about 0.5 meter
or less. If anodes are suspected to interfere, a conservative ap-
proach may be to consider two adjacent anodes as one long an-
ode, or as one wide anode, depending on their location in relation
to each other.
7.11.4 No anodes shall be located for welding to pressure con-
taining components or areas with high fatigue loads. For main
structural components the minimum distance from anode fas-
tening welds to structural welds shall be 150 mm. On jacket
structures, no anodes shall be located closer than 600 mm to
nodes.
7.11.5 The location of anodes shall take into account restric-
tions imposed by fabrication, installation and operation. For
large and/or complicated objects, early liaison with other engi-
neering disciplines, as well as with fabrication and installation
contractors is advised.
7.12 Provisions for Electrical Continuity
7.12.1 Besides welded connections, full electrical continuity
may be assumed for cold forged connections, metallic seals
and threaded connections (i.e. across the mated threads) with-
out coating.
7.12.2 For anodes attached to the protection object by other
means than welding, and for components of a CP unit without
a reliable electrical connection as defined above, electrical
continuity shall be ensured by a stranded cable (typically cop-
per). Cables for electrical continuity shall have a minimum
cross section of 16 mm2 and are to be attached by brazing, fric-
tion or explosion welding, or by a mechanical connection us-
ing e.g. serrated washers to provide a reliable electrical
connection at bolt heads or washers. Any cable shoes shall
have a brazed connection to the cable. Use of cable connec-
tions apply both for any anodes attached to the protection ob-
ject by means other than welding and to individual components
to receive CP, but without a reliable electrical connection to
the CP unit as defined in (7.12.1).
7.12.3 If the CP design includes use of cables for electrical
continuity, requirements to verification of electrical continuity
shall be specified in the CP design report. It is recommended
that the product of the connection resistance and the current de-
mand (or current output for a non-welded anode) does not ex-
ceed 10% of the design driving voltage. In no case shall the
resistance across a continuity cable exceed 0.1 ohm.
7.12.4 For anodes intended for cathodic protection of concrete
rebar, special provisions are required to ensure electrical con-
tinuity.
7.13 Documentation
7.13.1 The detailed engineering documentation (‘CP detailed
design report’) shall contain the following items:
— Design premises
(incl. reference to all relevant project specifications, codes
and standards)
— Surface area calculations
(incl. reference to all relevant drawings, incl. revision
numbers)
— Current demand calculations
(initial/final and mean)
— Current drain calculations (if applicable),
(initial/final and mean)
— Calculations of minimum required net anode mass
— Anode resistance calculations
(initial and/or final, as relevant)
— Calculations of minimum number of anodes required
(incl. anode current output and anode capacity for initial
and final life of system)
— Calculation of net anode mass based on required number
of anodes (if higher than required net anode mass)
— Calculation of total current output based on number and

DET NORSKE VERITAS
type/size of anodes to be installed
— Tentative anode design (incl. any special provisions for
structural integrity and electrical continuity. Any require-
ment for utilisation factors higher than the default values
in Table 10-8 shall be highlighted)
— Anode distribution drawings
— Provisions for electrical continuity, including verification
by testing (if applicable).
7.13.2 For a conceptual CP design report, the scope shall be
agreed.
7.13.3 The documentation shall be sufficiently well organised
and detailed to allow third party verification and possible fu-
ture calculations for life extension or retrofit.
8. Anode Manufacture
8.1 General
8.1.1 This section covers the manufacture of galvanic anodes,
including preparation of anode cores prior to casting. The re-
quirements in this section comply with those in NACE
RP0387, giving some amendments, primary related to quality
control.
ment’ (see 1.3.1), the following information and any optional
requirements (intended as a check-list) shall be enclosed by
Purchaser:
Information:
— anode material type (i.e. aluminium or zinc-base) and any
special requirements to chemical composition (i.e. other
than specified in 6.5.1) and to qualification of anode mate-
rial (5.6.3)
— tentative anode dimensions and net anode mass for each
anode type and any special requirements to anode fasten-
ing devices (7.10)
— any special requirements for anode utilisation factor (6.8)
— any special requirements for pre-production qualification
testing (PQT), including schedule for notification and sup-
ply of documentation (8.3.2-8.3.4)
— any special requirements for ‘manufacturing procedure
specification’ (MPS) (8.2) or ‘inspection and testing plan’
(ITP) (8.4.2), including schedule for supply of documen-
tation.
— any special requirements for frequency of dimensional
testing (8.6.2), destructive testing (8.6.5) and electrochem-
ical testing (8.6.6) during production
— any specific requirements for Contractor’s management of
non-conformities (8.6.10) and concession requests (8.5.6)
— any reduced requirements for traceability (8.5.1, 8.5.10)
— any requirements for retaining of anode material speci-
mens (8.6.1)
— any special requirements for marking of anodes (8.7.1)
— any special requirements for handling, storage and ship-
ping of anodes (8.8.1)
— any special requirements for final documentation, includ-
ing schedule for supply (8.7.4)
— any further amendments and deviations to this RP.
8.1.3 Unless otherwise agreed, electrochemical testing of gal-
vanic anode materials for quality control shall be carried out
according to Annex B. The testing procedure for documenta-
tion of long-term performance in Annex C is, however, non-
mandatory and shall be specified by Purchaser in the purchase
document, if applicable.
8.1.4 Compared to the 1993 revision of this RP, the require-
ments to quality control associated with anode manufacture,
both mandatory and optional to Purchaser, have been extend-
ed.
8.2 Manufacturing Procedure Specification
8.2.1 Unless otherwise agreed, a ‘manufacturing procedure
specification’ (MPS) shall be prepared for purchase orders of
15,000 kg net alloy or more. However, Purchaser may also
specify an MPS for smaller orders. The MPS shall include as a
minimum:
— specification of anode core materials
— receipt, handling and storage of materials
— maximum and/or minimum contents of anode material al-
loying elements and maximum contents of impurity ele-
ments
— detailed anode drawing, with anode inserts, including
gross/net weight and dimensional/weight tolerances (see
comment below in this paragraph)
— welding procedure specification and reference to qualifi-
cation test (WPQT) for any welding of anode cores, and
qualification requirements for welders
— preparation of anode cores prior to casting
— anode casting, including control of temperature and addi-
tion of alloying elements
— inspection and testing of anodes
— coating of surfaces facing protection object (not stand-off
type anodes)
— handling, storage and shipping of anodes
— marking, traceability and documentation.
The detailed anode design shall ensure that anode internal
cores are not significantly exposed and support the remaining
anode mass when the anode is consumed to the utilisation fac-
tor as specified in Table 10-8, or any less conservative (i.e.
higher) factor specified by Purchaser.
8.2.2 Purchaser may specify that detailed procedures for test-
ing/inspection and other information relevant to quality control
are also included in the MPS, e.g. detailed procedures for in-
spection and testing, handling of non-conformances and con-
cession requests. Purchaser may further specify that the MPS
shall be submitted for review and acceptance prior to com-
mencement of anode manufacture.
8.3 Pre-Production Qualification Testing
8.3.1 The primary objective of ‘pre-production qualification
testing’ (PQT) is to verify that the MPS is adequate to achieve
the specified anode properties. Of particular interest are those
aspects that require destructive testing and hence cannot be fre-
quently verified during regular production. The PQT shall use
the same specific materials and equipment as for regular pro-
duction.
8.3.2 Unless otherwise agreed, a PQT shall be prepared for a
purchase order of 15,000 kg net alloy or more. However, Pur-
chaser may also specify a PQT for smaller orders.
8.3.3 Specific requirements to the PQT, including e.g. number
of anodes to be inspected for each mould (including those for
destructive examination), schedule for notification and report-
ing, shall be specified in the purchase documents.
8.3.4 An MPS and an ‘inspection and test plan’ (ITP, see
8.4.2) specific for the PQT, together with a detailed schedule
for anode casting, inspection and/or testing, and reporting shall
be submitted to Purchaser in a timely manner (as per the pur-
chase document) prior to start-up of the qualification activities.
8.3.5 Data sheets and calibration certificates for instruments
essential to quality control (e.g. temperature sensors) shall be
available for Purchaser’s review during the PQT.

DET NORSKE VERITAS
8.3.6 Results from all inspection, testing and calibrations dur-
ing qualification, recordings of essential operational parame-
ters for casting and material certificates shall be compiled in a
PQT report. Unless otherwise agreed, the report shall be ac-
cepted by Purchaser prior to start of production.
8.4 Quality Control of Production
8.4.1 Prior to start-up of regular production (i.e. for purchase
orders of 15,000 kg net alloy or more, or for higher/lower
quantities as agreed on, see 8.2.1), Contractor shall submit the
following documents to Purchaser for acceptance:
— a project specific MPS, updated to reflect the process pa-
rameters used during the completed and accepted PQT
(8.3)
— a project specific ‘inspection and testing plan’ (ITP) up-
dated to reflect the process parameters used during the
completed and accepted PQT
— a ‘daily log’ format (see 8.6.11)
— a description of responsibilities of personnel involved in
quality control.
8.4.2 The ITP shall meet the general requirements of ISO
10005, Sec.5.10. It shall be in tabular form, defining all quality
control activities associated with receipt of materials, prepara-
tion of anode cores, casting, inspection, testing and marking of
anodes. The activities shall be listed in consecutive order, with
each activity assigned a unique number and with reference to
the applicable codes, standards and Contractor’s procedures or
work instructions, applicable to the specific project. Further-
more, frequency and/or extent of inspection and testing, ac-
ceptance criteria and actions in the case of non-conformances
shall be defined in the plan. The ITP shall further contain a col-
umn for inspection codes, (e.g. inspection, witnessing and hold
points) indicating the involvement of Contractor, Purchaser
and any 3rd party. It is good practice to include a reference to
the applicable reporting form or document, and to refer to the
specific equipment or tools to be used for verification.
8.4.3 The MPS, ITP, and ‘daily log’ shall be in English, unless
otherwise agreed.
8.4.4 Procedures and work instructions referenced in the ITP,
and applicable acceptance criteria, shall be available to all per-
sons concerned with the associated work in their native lan-
guage.
8.4.5 Purchaser shall have the right to inspect any activity as-
sociated with the work throughout production and to carry out
audits of Contractor’s QA / QC system. Purchaser shall identi-
fy any hold points for witnessing in the ITP and inform Con-
tractor accordingly.
8.5 Materials, Fabrication of Anode Inserts and
Casting of Anodes
8.5.1 Anode insert materials shall meet all requirements in
NACE RP0387 and unless otherwise agreed, inserts for weld-
ing to the protection object shall be traceable to a certificate ac-
cording to EN 10204, 3.1.B or ISO 10474, 5.1.B.
8.5.2 Contractor shall verify that all materials received for an-
ode manufacture are in accordance with the specified require-
ments. The verification may include actual testing or review of
supplier’s certificates. Review of certificates and any verifica-
tion testing to be performed by Contractor shall be included in
the ITP. Any materials checked and found non-conforming
shall be marked and quarantined.
8.5.3 Materials to be used for surface preparation and coating
shall be contained in their original packing until use and shall
be adequately marked, including:
— manufacturer’s name and location of manufacture
— material type and product designation
— batch/lot number
— date of manufacturing (and shelf life, if applicable)
— manufacture standard (if applicable)
— instruction for storage and handling (including health and
safety notes).
8.5.4 Contractor shall ensure that any materials for coating
and surface preparation are stored and handled so as to avoid
damage by the environment or other effects. Supplier’s recom-
mendations for storage and use shall be readily available for
Purchaser’s review.
8.5.5 All fabrication welding of steel inserts and surface prep-
aration before casting shall meet the requirements in NACE
RP0387 and shall be subject to visual inspection just prior to
casting.
8.5.6 All work associated with preparation of anode cores and
casting of anodes shall be carried out according to the qualified
MPS (if applicable), describing equipment and procedures to
be used. Once the MPS has been qualified, any changes shall
be formally accepted by Purchaser through a ‘concession re-
quest’ (CR).
8.5.7 Equipment for monitoring of process parameters critical
to quality (e.g. temperature sensors) shall be calibrated at
scheduled intervals as specified in the ITP.
8.5.8 No heat treatment is allowed for galvanic anodes of zinc
or aluminium-zinc-indium type.
8.5.9 Coating of flush mounted type anodes shall be applied
according to a coating procedure and after visual inspection for
surface defects has been completed.
8.5.10 Unless otherwise agreed, all anodes produced shall be
traceable to certificates for anode core materials and to coating
materials, if applicable.
8.6 Inspection and Testing of Anodes
8.6.1 Sampling for chemical analyses shall be carried out ac-
cording to NACE RP0387 and for each ‘anode heat’ (i.e. after
all alloying and homogenisation is completed), except for alu-
minium based anodes, for which samples shall be collected for
all heats exceeding 500 kg (unless otherwise agreed). For spec-
trometric analyses of anode chemical composition, reference
standards with a known chemical composition (i.e. for the
specified contents of all alloying and impurity elements) certi-
fied by an independent party shall be used. Purchaser shall
have the right to require anode sample material for verification
testing in an independent laboratory, or to present samples for
testing by Purchaser. Purchaser may further specify that Con-
tractor shall retain sample material for any additional chemical
analyses and/or electrochemical testing. All anodes produced
from a testing lot not meeting the specified composition shall
be rejected.
8.6.2 Verification of anode weight and dimensions shall be
carried out with the frequency and acceptance criteria speci-
fied in NACE RP0387. Positions of protruding inserts shall
comply with tolerances in manufacturer’s drawing and shall be
checked for a minimum of 10% of the anodes of a specific de-
sign. Purchaser may specify extended inspection of anode di-
mensional tolerances.
8.6.3 Inspection for cracks and other surface irregularities
shall be carried out on all anodes with the acceptance criteria
as specified in NACE RP0387, with the following amend-
ments:
— for zinc based anodes, no cracks visible to the naked eye
are acceptable
— cracks that are seen to penetrate to anode inserts are not ac-

DET NORSKE VERITAS
cepted
— within the section fully supported by anode inserts, cracks
of a width greater than 2 mm are only accepted if the
length is maximum 100 mm.
8.6.4 Any coating applied shall be visually inspected on all
anodes concerned. Spill of coating on surfaces not intended for
coating shall be removed.
8.6.5 Unless otherwise agreed, a minimum of two anodes of
each size shall be subject to destructive testing to verify ab-
sence of internal defects and adequate location of anode in-
serts. The cutting procedure and acceptance criteria in NACE
RP0387 shall apply. Such testing shall be carried out as a part
of the PQT, if applicable. If no PQT is to be performed, testing
should be carried out during the first day of production. Own-
er/purchaser shall have the right to select anodes for testing.
Any batchwise destructive testing of anodes during production
shall be specified in the purchase order.
8.6.6 As a minimum, electrochemical testing shall be per-
formed as a part of a PQT or first day production test for pur-
chase orders exceeding 15,000 kg of net anode material and for
each further 15,000 kg of production. Owner/purchaser may
specify extended testing and/or 3rd party testing.
8.6.7 When electrochemical testing applies, sampling for test-
ing shall be carried out for each heat produced, ref. 11.2.1, An-
nex B. (For definition of heat, see 8.6.1). Unless otherwise
agreed, the testing shall be carried out according to the proce-
dure in Annex B and the following acceptance criteria shall ap-
ply:
Aluminium based anodes:
electrochemical capacity: minimum 2,500 Ah/kg,
closed circuit potential: ≤ 1.05 V at end of the 4th testing peri-
od.
Zinc based anodes:
electrochemical capacity: minimum 780 Ah/kg,
closed circuit potential: ≤ 1.00 V at end of the 4th testing peri-
od.
In the case of failure to meet specified electrochemical proper-
ties, Contractor shall immediately issue a non-conformance re-
port.
8.6.8 Failures during testing which are obviously due to de-
fective sampling or operational errors of testing equipment
may be disregarded and testing repeated on the same anode
(sample).
8.6.9 In case of failure during fractional testing of other prop-
erties than electrochemical performance (e.g. destructive test-
ing of one per 50 anodes), the preceding and following anodes
shall be tested individually until at least 3 successive anodes
are acceptable.
8.6.10 In case of repeated failures to meet specified properties
(i.e. other than electrochemical performance), production shall
be discontinued and Contractor shall issue a ‘non-conformance
report’ and the cause of the failure shall be determined. Non-
conforming anodes (individual or lots) shall be marked and
quarantined. For failures during electrochemical testing, see
11.4.3, Annex B.
8.6.11 All data from inspection and testing of anodes and cal-
ibration of testing and monitoring equipment shall be noted in
the ‘daily log’. For anode specific data, reference shall be made
to the unique anode number or heat (8.7.2). The log shall be
updated on a daily basis and shall be available for Purchaser’s
review at any time during manufacture.
8.7 Documentation and Marking
8.7.1 As a minimum, each anode shall be marked with manu-
facturer’s name or symbol, anode material (e.g. ‘A’ for alu-
minium, ‘Z’ for zinc), heat number and serial number. Any
further requirements for marking shall be specified in the pur-
chase document.
8.7.2 All results from inspection and testing during PQT (if
applicable) and production shall be documented and shall be
traceable to a unique anode number (or batch of anodes, as ap-
plicable), certificates for anode core materials and coating ma-
terials, if applicable. For specific requirements to a ‘daily log’,
see 8.6.11.
8.7.3 Contractor shall issue an inspection document according
to EN 10204 or ISO 10474, inspection certificate 3.1.B.
8.7.4 Purchaser may specify requirements to final documenta-
tion, additional to those in NACE RP0387; e.g. documentation
to be supplied to Purchaser (including format and schedule)
and Contractor’s retaining of documentation exceeding 2 years
(minimum requirement in NACE RP0387).
8.8 Handling, Storage and Shipping of Anodes
8.8.1 Any additional requirements to those in NACE RP0387
shall be specified in the purchase document.
9. Installation of Anodes
9.1 General
9.1.1 Installation of galvanic anodes on offshore structures
will normally involve welding and sometimes also clamping of
anode supports to structural steel components. In the latter
case, electrical continuity is typically provided by a copper ca-
ble, attached to the anode support and the protection object by
brazing, or by some special mechanical connection designed to
ensure a reliable electrical continuity. Electrical continuity ca-
bles may also be installed to provide electrical continuity to
components of a CP unit without reliable electrical connection
to anodes by welds, metallic seals or threaded couplings. The
design requirements for such connections in 7.12 shall apply.
9.1.2 Considerations of the mechanical integrity of anode fas-
tening devices during installation and operation of the applica-
ble structures and any special requirements shall be included in
the CP detailed design report. For large anodes, the design may
include use of doubler and/or gusset plates. No welding or
brazing to pressure containing components shall be performed.
Thermite welding is not recommended for CRAs. Alternative
methods like pin brazing or soft soldering may be considered.
ment’ (see 1.3.1), the following information and any optional
requirements (intended as a check-list) shall be enclosed by
Purchaser:
Information:
— anode drawings from detailed CP design, or by manufac-
turer if completed
— drawings from detailed CP design showing location of in-
dividual anodes.
— any requirement for preparation of an IPS (9.2)
— any special requirements for documentation (9.7.2)
— any further amendments to and deviations from this RP.

DET NORSKE VERITAS
9.2 Installation Procedure Specification
9.2.1 Contractor may specify that all work related to anode in-
stallation shall be described in an ‘installation procedure spec-
ification’ (IPS). If applicable, this document shall include, as a
minimum:
— specification of materials and equipment to be used, in-
cluding certificates and material data sheets
— receipt, handling and storage of anodes and materials for
anode installation
— reference to welding and/or brazing procedure specifica-
tions and qualification of personnel carrying out welding/
brazing
— inspection and testing of anode fastening
— documentation of materials and inspection records.
9.3 Qualification of installation
9.3.1 All welding associated with anode installation shall be
qualified according to a recognised standard. Only qualified
welders and/or operators of brazing equipment shall be used.
9.4 Receipt and Handling of Anodes
9.4.1 All anodes supplied by Purchaser shall be inspected by
Contractor to confirm compliance with anode drawings and to
confirm no significant damage or other adverse effects. Non-
conforming anodes and other materials shall be quarantined.
9.4.2 Contractor shall ensure that anodes and other materials
for anode installation are stored and handled so as to avoid
damage by environment or other effects.
9.5 Anode Installation and Provisions for Electrical
Continuity
9.5.1 Installation of anodes shall be carried out according to
drawings approved for construction, showing locations of in-
dividual anodes and any other relevant specifications for fabri-
cation of the protection object. All welding associated with
anode installation shall be carried out according to the quali-
fied WPS and by qualified welders.
9.5.2 Any significant changes of anode installation from ap-
proved drawings shall be approved by Purchaser. However, for
ease of installation, stand-off anodes to be mounted on struc-
tural components may be displaced laterally not more than one
anode length and circumferentially max. 30°.
9.5.3 For welding of anodes to components subject to high ex-
ternal loads, welded connections shall be placed at least 150
mm away from other welds, and minimum 600 mm away from
structural nodes of jacket structures.
9.5.4 Installed anodes shall be adequately protected during
any subsequent coating work. Any spill of coating on anodes
shall be removed. For coated objects, exposed anode cores
shall be coated to the same standard.
9.6 Inspection of Anode Installation
9.6.1 Inspection of anode installation shall, as a minimum, in-
clude visual examination of welds and any brazed connections.
For welding to structural components, further NDT may apply
in accordance with the applicable fabrication specification.
9.6.2 Subsequent to completed anode installation, compliance
with drawings for anode installation shall be confirmed.
9.6.3 For brazed and mechanical connections for electrical
continuity, measurements shall be carried out according to a
documented procedure and with an instrument capable of ver-
ifying an electrical resistance of 0.1 ohm maximum.
9.7 Documentation
9.7.1 The final location of anodes shall be documented on as-
built drawings.
9.7.2 Measurements for verification of electrical continuity
shall be documented.
9.7.3 Purchaser may specify further requirements to the anode
installation documentation.

DET NORSKE VERITAS
10. Annex A – Tables and Figures
10.1 Tables and Figures
Table 10-1 Recommended initial and final design current densities (A/m2) for seawater exposed bare metal surfaces, as a function of
depth and ‘climatic region’ based on surface water temperature (ref. 6.3).
Depth
(m)
‘Tropical’
(> 20 °C)
‘Sub-Tropical’
(12- 20 °C)
‘Temperate’
(7-11 °C)
‘Arctic’
(< 7 °C)
initial final initial final initial final initial final
0-30 0.150 0.100 0.170 0.110 0.200 0.130 0.250 0.170
>30-100 0.120 0.080 0.140 0.090 0.170 0.110 0.200 0.130
>100-300 0.140 0.090 0.160 0.110 0.190 0.140 0.220 0.170
>300 0.180 0.130 0.200 0.150 0.220 0.170 0.220 0.170
Table 10-2 Recommended mean design current densities (A/m2) for seawater exposed bare metal surfaces, as a function of depth
and ‘climatic region’ based on surface water temperature (ref. 6.3).
Depth
(m)
‘Tropical’
(> 20 °C)
‘Sub-Tropical’
(12- 20 °C)
‘Temperate’
(7-12 °C)
‘Arctic’
(< 7 °C)
0-30 0.070 0.080 0.100 0.120
>30-100 0.060 0.070 0.080 0.100
>100-300 0.070 0.080 0.090 0.110
>300 0.090 0.100 0.110 0.110
Table 10-3 Recommended mean design current densities for protection of reinforcing steel (i.e. in concrete structures) as a function
of depth and ‘climatic region’ based on surface water temperature (ref. 6.3.12). The current densities in A/m2 refer to the steel
reinforcement surface area, not surface area of concrete.
Depth
(m)
‘Tropical’
(> 20 °C)
‘Sub-Tropical’
(12- 20 °C)
‘Temperate’
(7-12 °C)
‘Arctic’
(< 7 °C)
0-30 0.0025 0.0015 0.0010 0.0008
>30-100 0.0020 0.0010 0.0008 0.0006
>100 0.0010 0.0008 0.0006 0.0006
Table 10-4 Recommended constants a and b for calculation of
paint coating breakdown factors.
(Coating Categories are defined in 6.4.6).
Depth
(m)
Recommended a and b values for
Coating Categories I, II and III (see 6.4.7)
I
(a = 0.10)
II
(a = 0.05)
III
(a = 0.02)
0-30 b = 0.10 b = 0.025 b = 0.012
>30 b = 0.05 b = 0.015 b = 0.008
Table 10-5 Recommended compositional limits for Al-based
and Zn-based anode materials (ref. 6.5).
Alloying/Impurity
Element
Zn-base Al-base
Zn rem. 2.5-5.75
Al 0.10-0.50 rem.
In na 0.015-0.040
Cd ≤ 0.07 ≤ 0.002
Si na ≤ 0.12
Fe ≤ 0.005 ≤ 0.09
Cu ≤ 0.005 ≤ 0.003
Pb ≤ 0.006 na
Table 10-6 Recommended design electrochemical capacity and
design closed circuit potential for anode materials at seawater
ambient temperatures (ref. 6.5).
Anode Material
Type
Environment Electrochem-
ical Capacity
(Ah/kg)
Closed Circuit
Potential
(V)
Al-based
seawater 2,000 -1.05
sediments 1,500 -0.95
Zn-based
seawater 780 -1.00
sediments 700 -0.95

DET NORSKE VERITAS
Figure 10-1
Seawater resistivity as a function of temperature for salinity 30 to
40 ‰.
Table 10-7 Recommended Anode Resistance Formulae for CP Design Calculations.
Anode Type Resistance Formula
Long slender stand-off 1)
L ≥ 4r
Short slender stand-off 1)
L< 4r
Long flush mounted 2)
L ≥ width
L ≥ thickness
Short flush-mounted, bracelet and
other types
1) The equation is valid for anodes with minimum distance 0.30 m from protection object. For anode-to-object distance less than 0.30 m but
minimum 0.15 m the same equation may be applied with a correction factor of 1.3
2) For non-cylindrical anodes: r = c/ 2 π where c (m) is the anode cross sectional periphery
⎜⎜
⎝
⎛
⎟
⎠
⎞
−
⋅
⋅π⋅
ρ
= 1
r
L4
ln
L2
Ra
⎥
⎥
⎥
⎦
⎤
⎢
⎢
⎢
⎣
⎡
⎟
⎠
⎞
⎜
⎝
⎛
+−+
⎪
⎭
⎪
⎬
⎫
⎪
⎩
⎪
⎨
⎧
⎟
⎟
⎟
⎠
⎞
⎜
⎜
⎜
⎝
⎛
⎟
⎠
⎞
⎜
⎝
⎛
++
⋅π⋅
ρ
=
22
a
L2
r
1
L2
r
L2
r
11
r
L2
ln
L2
R
S2
Ra
⋅
ρ
=
A
315.0
Ra
ρ⋅
=
Table 10-8 Recommended Anode Utilisation Factors for CP
Design Calculations.
Anode Type Anode Utilisation Factor
Long slender stand-off
L ≥ 4r
0.90
Short slender stand-off
L < 4r
0.85
Long flush mounted
L ≥ width and
L ≥ thickness
0.85
Short flush-mounted, bracelet
and other types
0.80

DET NORSKE VERITAS
11. Annex B – Laboratory Testing of Galvanic Anode Materials for Quality Control
11.1 General
11.1.1 This laboratory test procedure is intended for quality
control of Al-base and Zn-base anode materials during manu-
facture of galvanic anodes. In this Annex, the definitions of
Owner, Purchaser and Contractor (i.e. anode manufacturer) in
3.1 apply.
Guidance note:
The results from testing according to this procedure are not ap-
plicable to cathodic protection design because electrochemical
data from short-term testing, typically using high anodic current
densities will tend to be non-conservative with respect to the ac-
tual long-term performance in the field.
11.1.2 The testing shall be performed according to a detailed
procedure describing all relevant steps. For testing at the
premises of Contractor, Owner/Purchaser shall have the right
to witness the testing.
11.1.3 All requirements of this procedure shall be considered
as mandatory, unless deviations have been agreed, see 8.1.3.
Owner/Purchaser may, however, choose to specify an alterna-
tive test procedure.
11.1.4 Compared to the 1993 revision of this document, some
amendments have been made, primarily regarding sampling of
testing material. Moreover, a detailed testing procedure is re-
quired for quality control purposes. Use of 3 % NaCl solution
as alternative to natural or synthetic seawater is not allowed in
the 2004 revision. Acceptance criteria have further been in-
cluded in 8.6.6. Other revisions are for clarification or simpli-
fication only.
11.2 Sampling and Preparation of Test Specimens.
11.2.1 Unless otherwise specified, quality control of electro-
chemical properties (i.e. electrochemical efficiency and
closed-circuit anode potential) shall be carried out for each
15,000 kg of anodes produced. Sampling for potential testing
(by separate mini-castings) shall, however, be performed for
each heat of anode material produced. All samples for testing
shall have adequate marking. For retainment of samples, see
8.6.1. Owner/Purchaser shall have the right to select sample
for testing, e.g. based on a review of chemical composition of
the individual heats.
Guidance note:
The individual heats are sometimes much smaller than 15,000 kg
and it is then essential that the testing is performed on a heat that
is representative for all those produced. Hence, the heat selected
should have contents of alloying and/or impurity elements in the
lower and upper ranges, respectively.
11.2.2 Cylindrical test specimens with a diameter of 10 mm
± 1 mm and a length of 50 mm ± 5 mm shall be prepared by
machining of samples. A hole of about 2 mm diameter shall be
drilled and tapped on one end for connection of a titanium sup-
port rod. The specimen shall subsequently be rinsed in tap wa-
ter followed by ethanol, dried and weighed to an accuracy of
± 0.1 mg
11.2.3 The specimens shall be adequately marked throughout
all stages of preparation, storage and testing.
11.3 Equipment and Experimental Procedure
11.3.1 After mounting of the support rod, the specimen ends
and the part of the rod exposed to the test solution shall be coat-
ed with a suitable sealing compound such as polychloroprene
glue or silicon rubber.
11.3.2 The testing solution shall be natural seawater (of ade-
quate purity and a salinity of minimum 30 ‰) or synthetic sea-
water according to ASTM D1141.
Guidance note:
Seawater constituents other than chloride, sulphate, bicarbonate/
carbonate, sodium, calcium and magnesium ions have no effect
on the electrochemical performance of galvanic anodes and may
be omitted when preparing synthetic seawater. Tap water is ac-
ceptable for preparation of the solution.
11.3.3 A minimum of 10 litres per test specimen shall be used.
The solution shall be continuously purged with air and shall
not be exchanged during the test period. The temperature shall
be maintained at 20 ± 3 °C.
11.3.4 Each specimen shall be suspended in the centre of an
uncoated cylindrical steel container (e.g. made of a pipe sec-
tion), the wetted surface area of which shall be minimum 20
times the exposed anode specimen area, i.e. minimum 400
cm2, approximately. The general arrangement is shown in Fig.
11-1
11.3.5 Galvanostatic control shall be affected by means of a
DC constant current source, capable of controlling the current
according to 11.3.7 below. The specimen and the cathode shall
be coupled to the positive and negative rectifier terminals, re-
spectively. Multiple testing cells may be connected in series to
one DC source.
11.3.6 A current integrator, e.g. a copper coulometer or an
electronic device capable of determining the total discharged
current to an accuracy of ± 2%, shall be inserted into the circuit
containing one or more test cells in circuit.
11.3.7 The current through the cell(s) shall be adjusted to pro-
vide anodic current densities, based on the initially exposed
surface area, in accordance with the following scheme:
Day 1: 1.5 mA/cm2
Day 2: 0.4 mA/cm2
Day 3: 4.0 mA/cm2
Day 4: 1.5 mA/cm2
The current density shall be controlled to an accuracy of 0.1
mA/cm2 and shall be maintained for a period of 24 hours ± 1
hour. The total testing time shall be 96 hours ± 4 hours.
11.3.8 At the end of each testing period, the anode potential
shall be measured at three positions per specimen. A standard
reference electrode (silver /silver chloride or calomel) with an
electrolyte bridge (e.g. a Luggin capillary) shall be used. The
tip of the bridge shall be positioned within 1 mm from the spec-
imen surface, however, without disturbing any corrosion prod-
ucts formed on the anode specimen. Reference electrodes shall
be calibrated at intervals not exceeding one week. Potential re-
cordings using a reference electrode other than ‘Ag/AgCl/sea-
water’ (e.g. a SCE) shall be converted to this reference.
11.3.9 After completion of the full test period, the support rod
and sealing compound shall be removed and the specimen
cleaned of corrosion products. Aluminium-based specimens
shall be cleaned for 10 min at 80°C in a solution of 20 g chro-
mium trioxide and 30 ml phosphoric acid per litre water. Zinc-
based specimens shall be immersed for 2 hours in a saturated

DET NORSKE VERITAS
ammonium chloride solution at ambient temperature. Speci-
mens shall subsequently be rinsed in tap water, thereafter in
ethanol and weighed to an accuracy of ± 0.1 mg.
11.3.10 The electrochemical efficiency, ε (Ah/kg), shall be
calculated from
ε = (C·1000)/ ∆w
where C is the total current charge in Ah and ∆w is the weight
loss in grams.
11.4 Acceptance Criteria and Re-Testing
11.4.1 The acceptance criteria in 8.6.7 apply.
11.4.2 Failures during testing which are obviously due to op-
erational errors may be disregarded and testing repeated on a
new specimen of the same sample (ref. 8.6.8) or a specimen cut
from an anode of the same heat.
11.4.3 In the case of failure to meet the specified require-
ments, re-tests may be carried out on 3 specimens from each
heat of the testing lot (normally representing up to 15,000 kg
of anode material). Failure of any specimen of a heat shall lead
to rejection of all anodes from that heat.
11.5 Documentation
11.5.1 The test report shall contain relevant data for the anode
material(s) tested, including heat number, chemical composi-
tion and casting date. Specimen preparation, test equipment
and testing procedure shall be outlined.
11.5.2 All recorded potentials (i.e. 3 per specimen) shall be
presented in tabular form, as-recorded and converted to Ag/
AgCl/seawater, if applicable. Specimen weight loss and total
current charge shall be given in addition to the calculated elec-
trochemical efficiency. A photograph of the cleaned specimen
shall be included in the report.
Figure 11-1
General arrangement for quality control testing of galvanic an-
ode materials

DET NORSKE VERITAS

DET NORSKE VERITAS
12. Annex C – Laboratory Testing of Galvanic Anode Materials for
Qualification of Electrochemical Performance
12.1 General
12.1.1 This Annex gives a recommended procedure for docu-
mentation of the electrochemical performance of galvanic an-
ode materials in natural seawater of ambient temperature. (The
procedure can be modified to include testing in hot or cold sea-
water).
Guidance note:
The performance of anodes is best documented by field testing of
full size anodes. However, such testing is elaborate and often not
practical.
12.1.2 Qualification testing should preferably be performed
by, or at least witnessed by a party independent of the anode
manufacturer.
12.1.3 Testing according to this procedure is non-mandatory
and shall be specified by Purchaser, see 8.1.3. Modifications of
the test parameters may be agreed.
12.1.4 Compared to the 1993 revision of this document, some
amendments have been made, primarily regarding sampling of
testing material. The recommended size of the testing speci-
men has further been increased as experience has shown that
the specimen may become consumed before a test period of 12
months has been completed. Some further amendments are
made in 12.2.3 and 12.3.5. Other revisions are for clarification
or simplification only.
12.2 Sampling and Preparation of Test Specimens.
12.2.1 Specimens for testing shall be cut from full scale an-
odes using the same type of raw materials, smelting and cast-
ing practices as for normal production. The net mass of the
anode shall be minimum 30% of the maximum anode net mass
of anodes for which the documentation shall apply.
Guidance note:
The performance of an anode material may be affected by solid-
ification and cooling such that specimens from smaller anodes,
or separately cast specimens, may not be fully representative for
larger anodes.
12.2.2 The chemical composition of the anode(s) to be used
for documentation shall reflect the compositional limits that
shall apply during manufacturer’s normal production (see
6.5.2). This will normally require preparation of a special heat,
combining maximum specified contents of impurity elements
and minimum contents of the actual alloying elements. No heat
treatment of the casting is allowed for Zn and Al-Zn-In anode
materials.
Guidance note:
To justify the compositional limits specified by the manufactur-
er, testing of more than one heat may be required.
12.2.3 Minimum 5 specimens of each heat to be documented
shall be tested. Cylindrical specimens with a diameter of min-
imum 25 mm and a length of 100 mm shall be prepared. A hole
of about 2 mm diameter shall be drilled and tapped on one end
for connection of a titanium support rod. The specimen shall
subsequently be rinsed in tap water followed by ethanol, dried
and weighed to an accuracy of ± 0.1 mg
12.2.4 The specimens shall be adequately marked throughout
all stages of preparation, storage and testing. Anode material
from the anode casting should be retained for any additional
testing later on.
12.3 Equipment and Experimental Procedure
12.3.1 After mounting of the support rod, the specimen ends
and the part of the rod exposed to the test solution shall be coat-
ed with a suitable sealing compound such as polychloroprene
glue or silicon rubber.
12.3.2 The testing environment shall be clean natural seawater
with salinity ≥ 30 ‰. Temperature may be allowed to vary in
the range + 7°C to + 20°C. Temperature and salinity of seawa-
ter shall be recorded at least once per week.
The test shall be configured as outlined in Annex B, however,
there shall be a continuous exchange of seawater in the cell
(minimum 1 l/min). The seawater shall be continuously purged
with air.
Guidance note:
Variations in seawater temperature in the range above are not
considered to affect the electrochemical performance of anode
materials significantly. However, lower temperatures are some-
times believed to reduce the performance and purchasers of an-
odes may require documentation of anode materials’
performance at such temperatures.
12.3.3 Testing may be performed either with galvanostatic
control or as a ‘free-running test’. The testing time shall be
minimum 12 months.
Guidance note:
‘Free-running’, implies that the anode/cathode assembly is al-
lowed to polarize spontaneously during the test. The driving volt-
age and hence the anodic current density will thus vary during the
test. For a ‘galvanostatic’ test, the anode potential is controlled
throughout the testing period.
12.3.4 With galvanostatic control, the anodic current density
shall be maximum 1 mA/cm2 based on the initial exposed an-
ode surface area. The integrated current (i.e. for minimum 12
months) may be determined as for 11.3.6 in Annex B but man-
ual readings minimum once per day and 5 days per week for
the first two weeks, thereafter once per week, will suffice. Re-
cordings of anode potential (see 11.3.8, Annex B) shall be per-
formed with a minimum frequency as for manual current
readings.
12.3.5 For a free-running test, the anode and cathode shall be
connected over a 10 ohm ± 1 ohm precision resistance (Actual
resistance to be recorded with an accuracy of ± 0.2 ohm).The
inner uncoated cathode surface area shall be approximately 30
times the exposed anode surface area. The outer surface shall
be coated to achieve a defined surface area of about 1:30.
The current shall be calculated from measurements of the volt-
age drop across the precision resistance using a high imped-
ance (≥ 107 ohm) voltmeter. Measurements of anode potential,
cathode potential and cell current shall be carried out at maxi-
mum intervals as specified above.
12.3.6 Reference electrodes used for recordings of anode po-
tential shall be calibrated at regular intervals (minimum once
per month). After completed test, the specimens shall be

DET NORSKE VERITAS
cleaned and the electrochemical efficiency calculated as in
11.3.9 and 11.3.10, Annex B.
12.4 Documentation
12.4.1 The test report shall contain relevant data on smelting
and casting of anodes and location of test specimens. Contents
of alloying and impurity elements shall be specified with nom-
inal and guaranteed contents as a reference.
12.4.2 Average, and maximum/minimum salinity and temper-
ature of seawater shall be reported.
12.4.3 Sampling, specimen preparation, marking, testing
equipment, calibrations and recordings of data shall be de-
scribed in the report. Anode potentials (versus Ag/AgCl/sea-
water) shall be displayed graphically as a function of time. For
free running tests, the calculated anodic current density (based
on original exposed surface area) and the cathode potential
shall also be given in graphical form.
12.4.4 Data from measurements of anode weight loss shall be
included in the report in addition to the calculated electro-
chemical efficiency (in Ah/kg). Mean value and standard devi-
ation shall be reported. Photographs of anode specimens prior
to, and after cleaning, shall be included.

DET NORSKE VERITAS

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