Ficha de seguridad pilas Kodak MAX C LR14
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The document is a Material Safety Data Sheet (MSDS) for Kodak alkaline batteries, detailing their identification, hazards, composition, first aid measures, fire-fighting procedures, and handling/storage guidelines. It identifies potential risks from battery contents like manganese dioxide and potassium hydroxide, emphasizes the importance of safety in handling, and outlines disposal and transportation regulations. First aid instructions are provided for various exposure scenarios, and it notes that these batteries are typically not classified as hazardous when shipped.
Ficha de seguridad pilas Kodak MAX C LR14
- 1. Material Safety Data Sheet M-01-101/102/103/104/105/207/213 Page 1 of 8 Version: 1.2 Date: 16 Apr 2014 KODAK ALKALINE BATTERIES 1. Identification of the substance/preparation and of the company/undertaking Product names: KODAK ALKALINE BATTERY TYPES; ULTRA PREMIUM – AAA, AA, C, D and 9V MAX - AAA, AA, C, D and 9V XTRALIFE - AAA, AA, C, D and 9V ULTRA Photoelectronic – 357 (LR44/KA76), K23A, KN-LR1, K28A- 4LR44 Supplier: Strand Europe Ltd., Strand House, Galway Road, Yateley, Hampshire, GU46 6GE, United Kingdom Emergency telephone number: +44 (0) 1252 864533 For other information or to request an MSDS, contact; Kodak Batteries - Technology Department Tel. +44 (0) 1252 864520 Email: kodakbatteries@strandeurope.com Synonyms: None. Product Use: Battery, for consumer and industrial use. 2. Hazards identification CONTAINS: Manganese dioxide (1313-13-9), Zinc (7440-66-6), Potassium hydroxide (1310-58-3), Graphite (7782-42-5) WARNING! HARMFUL IF SWALLOWED MAY FLAME OR LEAK IF OPENED, SHORT CIRCUITED, RECHARGED, CONNECTED IMPROPERLY, OR EXPOSED TO FIRE OR HIGH TEMPERATURES. VAPORS/FUMES FROM DAMAGED BATTERIES MAY CAUSE RESPIRATORY TRACT IRRITATION DAMAGED BATTERIES MAY CAUSE SKIN AND EYE BURNS 3. Composition/information on ingredients Weight % Components - (CAS-No.) 20 - 40 Manganese dioxide (1313-13-9) 10 - 20 Zinc (7440-66-6) 1 - 10 Potassium hydroxide (1310-58-3) 1 - 5 Graphite (7782-42-5) Weight per cent listed is based on approximate per cent of the average weight of the battery. The components in this section may only represent a hazard if the integrity of the battery is compromised.
- 2. Material Safety Data Sheet M-01-101/102/103/104/105/207/213 Page 2 of 8 Version: 1.2 Date: 16 Apr 2014 KODAK ALKALINE BATTERIES 4. First aid measures The routine handling and use of intact, non-damaged batteries is not expected to result in situations that require first-aid measures. If battery is damaged due to opening, cutting, crushing, overheating, improper installation, exposure to fire or high temperatures, or recharging, battery contents may be released. Inhalation: If vapours or fumes from vented or leaking battery are irritating to respiratory tract, move to fresh air. Get medical attention if symptoms occur. Eyes: In case of contact with battery contents (liquid or metal), immediately flush with plenty of water for at least 15 minutes. Get medical attention immediately. Skin: In case of contact with battery contents (liquid or metal), immediately remove metal fragments and flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention immediately. Wash contaminated clothing before re-use. Destroy or thoroughly clean contaminated shoes. Ingestion: All batteries may be harmful if swallowed. Call a physician or poison control centre immediately for any actual or suspected ingestion. If swallowed, DO NOT induce vomiting. Batteries may lodge in the throat or digestive tract and fragment. If battery was leaking or was chewed, rinse mouth thoroughly with water. Notes to physician: Hazards: Battery ingestions should not be managed in the same way as other small metallic object ingestions, e.g., coins. The position and integrity of the battery in the gastrointestinal tract should be assessed and monitored by x-ray. Leaking batteries may cause necrosis and tissue damage. Larger batteries or batteries that lodge in the gastrointestinal tract may have to be removed endoscopically or surgically. 5. Fire-fighting measures Extinguishing Media: Use appropriate agent for adjacent fire. Special Fire-Fighting Procedures: Wear self-contained breathing apparatus and protective clothing. Fire or excessive heat may produce hazardous decomposition products. Hazardous Combustion Products: Carbon oxides, oxides of manganese, oxides of zinc, (see also Hazardous Decomposition Products sections.) Unusual Fire and Explosion Hazards: Fire or high temperatures may cause battery to flame or leak flammable and hazardous vapours. Damaged or opened batteries can result in rapid heating and the release of flammable and hazardous vapours. 6. Accidental release measures Dispose of in accordance with local regulations (see Section 13. Disposal considerations). For Large Spills: None should be needed.
- 3. Material Safety Data Sheet M-01-101/102/103/104/105/207/213 Page 3 of 8 Version: 1.2 Date: 16 Apr 2014 KODAK ALKALINE BATTERIES 7. Handling and storage Personal precautions: If battery has been damaged, do not breathe fumes or vapours. Do not get battery contents in eyes, on skin, on clothing. Wash thoroughly after handling. Prevention of Fire and Explosion: DO NOT DISASSEMBLE. Keep away from heat and flame. Do not short circuit. Avoid the use of old and new batteries or batteries of varying sizes and types in the same battery assembly. The batteries electrical characteristics and capabilities may vary and damage may result to the batteries or electrical equipment. DO NOT RECHARGE. Charging may result in electrolyte leakage, explosion and/or cause the battery to flame. Avoid reversing polarity within a device or a battery assembly. To do so may cause leakage, explosion, and/or flame. Storage: Do not store in a manner that allows terminals to short circuit. Keep in a dry, cool place. Keep away from direct sunlight. Storage above 21°C (70°F) may affect product quality. Do not freeze. Keep away from water. Short circuiting may reduce battery service life. Extended short circuiting creates high temperatures in the battery. High temperatures can cause leakage, explosion, and/or flame. Keep away from incompatible substances (see Incompatibility section.) 8. Exposure controls/personal protection Occupational exposure controls Chemical Name Regulatory List Value Type Value Manganese dioxide ACGIH time weighted average 0.2 mg/m3 Expressed Mn OSHA Ceiling Limit Value 5 mg/m3 Expressed Mn Potassium hydroxide ACGIH Ceiling Limit Value 2 mg/m3 Graphite time weighted average 2 mg/m3 Form of exposure: respirable fraction Remarks: all forms except graphite fibres OSHA TWA 15 mppcf Ventilation: Supplemental ventilation may be needed in special circumstances to control fumes/vapours to an acceptable level. Respiratory protection: None should be needed. Eye protection: When handling a damaged battery, wear safety glasses with side shields (or goggles). Hand protection: When handling a damaged battery, wear impervious gloves.
- 4. Material Safety Data Sheet M-01-101/102/103/104/105/207/213 Page 4 of 8 Version: 1.2 Date: 16 Apr 2014 KODAK ALKALINE BATTERIES 9. Physical and chemical properties Physical form: solid Colour: not applicable Odour: odourless Specific gravity: not applicable Vapour pressure: negligible Vapour density: not applicable Volatile fraction by weight: not applicable Melting point/range: not applicable Water solubility: insoluble pH: not applicable Flash point: not applicable 10. Stability and reactivity Stability: Stable under normal conditions. Incompatibility: no data available. Hazardous decomposition products: None under normal conditions of use. Hazardous Polymerization: Hazardous polymerisation does not occur. 11. Toxicological information Effects of Exposure General advice: Since the materials in this battery are sealed in the battery case, the potential for exposure to the components of the battery is negligible when the battery is used as directed. However, technical or electrical abuse of the battery may result in the release of battery contents. Contains: Manganese dioxide. Can cause nervous system damage. Inhalation: Intact battery: Expected to be a low hazard for recommended handling. Damaged battery: Harmful if inhaled. May cause irritation to the mucous membranes and upper respiratory tract. Eyes: Intact battery: Expected to be a low hazard for recommended handling. Damaged battery: Contact with electrolyte (liquid) causes burns. Airborne dust/mist/vapor irritating. Contact with metal fragments may cause burns or mechanical injury. Skin: Intact battery: Expected to be a low hazard for recommended handling. Damaged battery:
- 5. Material Safety Data Sheet M-01-101/102/103/104/105/207/213 Page 5 of 8 Version: 1.2 Date: 16 Apr 2014 KODAK ALKALINE BATTERIES Contact with electrolyte (liquid) causes burns. Contact with metal fragments may cause burns or mechanical injury. Harmful if absorbed through skin. Vapours or fumes may cause irritation. Ingestion: All batteries may be harmful if swallowed. May cause burns of the gastrointestinal tract if swallowed. Data for Manganese dioxide (CAS 1313-13-9): Acute Toxicity Data: Oral LD50 (rat): > 3,478 mg/kg Data for Potassium hydroxide (CAS 1310-58-3): Acute Toxicity Data: Oral LD50 (rat): 273 mg/kg • Skin irritation: severe 12. Ecological information This material is not expected to be harmful to aquatic life. 13. Disposal considerations DO NOT INCINERATE or expose to fire. Discharge, treatment, or disposal may be subject to national, federal, state, commonwealth, provincial, or local laws. 14. Transport information These batteries are not regulated by international agencies as hazardous materials or dangerous goods when shipped. A shipping name of “Alkaline Batteries – Non-hazardous” may be used on all domestic and international bills of lading. Kodak batteries follow the regulatory concerns on batteries from all agencies for safe packaging which require that batteries be packaged in a manner that prevents short circuits and be contained in “strong outer packaging” that prevents spillage of contents.
- 6. Material Safety Data Sheet M-01-101/102/103/104/105/207/213 Page 6 of 8 Version: 1.2 Date: 16 Apr 2014 KODAK ALKALINE BATTERIES 15. Regulatory information Notification status Regulatory List Notification status TSCA All listed DSL All listed NDSL None listed EINECS All listed ELINCS None listed NLP None listed AICS All listed IECS All listed ENCS Not all listed ECI All listed NZIoC All listed PICCS All listed "Not all listed" indicates one or more component is either not on the public Inventory or is subject to exemption requirements. If additional information is needed contact Strand Europe. Other regulations American Conference of Governmental Industrial Hygienists (ACGIH): No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH International Agency for Research on Cancer (IARC): No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. U.S. National Toxicology Program (NTP): No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. U.S. Occupational Safety and Health Administration (OSHA): No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. California Prop. 65 This product does not contain any chemicals known to State of California to cause cancer, birth, or any other reproductive defects. U.S. - CERCLA/SARA (40 CFR § 302.4 Designation of hazardous substances): Potassium hydroxide, Zinc
- 7. Material Safety Data Sheet M-01-101/102/103/104/105/207/213 Page 7 of 8 Version: 1.2 Date: 16 Apr 2014 KODAK ALKALINE BATTERIES U.S. - CERCLA/SARA - Section 302 (40 CFR § 355 Appendices A and B - The List of Extremely Hazardous Substances and Their Threshold Planning Quantities): No components of this product are subject to the SARA Section 302 (40 CFR 355) reporting requirements. U.S. - CERCLA/SARA - Section 313 (40 CFR § 372.65 Toxic Chemical Release Reporting): Manganese dioxide, Zinc U.S. - California - 8 CCR Section 339 - Director's List of Hazardous Substances: Potassium hydroxide, Manganese dioxide, Zinc, Graphite U.S. - California - 8 CCR Section 5200-5220 - Specifically Regulated Carcinogens: No components found on the California Specifically Regulated Carcinogens List. U.S. - California - 8 CCR Section 5203 Carcinogens: No components found on the California Section 5203 Carcinogens List. U.S. - California - 8 CCR Section 5209 Carcinogens: No components found on the California Section 5209 Carcinogens List. U.S. - Massachusetts - General Law Chapter 111F (MGL c 111F) - Hazardous Substances Disclosure by Employers (a.k.a. Right to Know Law): Potassium hydroxide, Zinc, Graphite U.S. - Minnesota Employee Right-to-Know (5206.0400, Subpart 5. List of Hazardous Substances): Potassium hydroxide, Manganese dioxide, Graphite U.S. - New Jersey - Worker and Community Right to Know Act (N.J.S.A. 34:5A-1): Potassium hydroxide, Manganese dioxide, Zinc, Graphite U.S. - Pennsylvania - Part XIII. Worker and Community Right-to-Know Act (Chapter 323 Hazardous Substance List, Appendix A): Potassium hydroxide, Manganese dioxide, Zinc, Water, Graphite List, Appendix A): U.S. - Rhode Island - Title 28 Labour and Labour Relations (Chapters 28-21 Hazardous Substance Right-to-Know Act): Potassium hydroxide, Zinc, Graphite
- 8. Material Safety Data Sheet M-01-101/102/103/104/105/207/213 Page 8 of 8 Version: 1.2 Date: 16 Apr 2014 KODAK ALKALINE BATTERIES 16. Other information The data below reflects current legislative requirements whereas the product in your possession may carry a different version of the label depending on the date of manufacture. US/Canadian Label Statements: CONTAINS: Manganese dioxide (1313-13-9), Zinc (7440-66-6), Potassium hydroxide (1310- 58-3), Graphite (7782-42-5) WARNING! HARMFUL IF SWALLOWED MAY FLAME OR LEAK IF OPENED, SHORT CIRCUITED, RECHARGED, CONNECTED IMPROPERLY, OR EXPOSED TO FIRE OR HIGH TEMPERATURES. VAPORS/FUMES FROM DAMAGED BATTERIES MAY CAUSE RESPIRATORY TRACT IRRITATION DAMAGED BATTERIES MAY CAUSE SKIN AND EYE BURNS FIRST AID: If vapours or fumes from vented or leaking battery are irritating to respiratory tract, move to fresh air. Get medical attention if symptoms occur. In case of contact with battery contents (liquid or metal), immediately flush with plenty of water for at least 15 minutes. Get medical attention immediately. In case of contact with battery contents (liquid or metal), immediately remove metal fragments and flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention immediately. Wash contaminated clothing before re-use. Destroy or thoroughly clean contaminated shoes. All batteries may be harmful if swallowed. Call a physician or poison control centre immediately for any actual or suspected ingestion. If swallowed, DO NOT induce vomiting. Batteries may lodge in the throat or digestive tract and fragment. If battery was leaking or was chewed, rinse mouth thoroughly with water. Keep out of reach of children. Do not handle or use until safety precautions in Material Safety Data Sheet (MSDS) have been read and understood. Since emptied containers retain product residue, follow label warnings even after container is emptied. IN CASE OF FIRE: Use appropriate agent for adjacent fire. IN CASE OF SPILL: Dispose of in accordance with local regulations (see Section 13. Disposal considerations). For Large Spills: None should be needed. The information contained herein is furnished without warranty of any kind. Users should consider these data only as a supplement to other information gathered by them and must make independent determinations of suitability and completeness of information from all sources to assure proper use and disposal of these materials and the safety and health of employees and customers and the protection of the environment. The information relating to the working solution is for guidance purposes only, and is based on correct mixing and use of the product according to instructions.