Sample paper xi chem 2

XI
CHEMISTRY
SAMPLE PAPER 3
Time: Three Hours Max. Marks: 70
General Instructions
1. All questions are compulsory.
2. Question nos. 1 to 8 are very short answer questions and carry 1 mark
each.
3. Question nos. 9 to 18 are short answer questions and carry 2 marks
each.
4. Question nos. 19 to 27 are also short answer questions and carry 3
marks each
5. Question nos. 28 to 30 are long answer questions and carry 5 marks
each
6. Use log tables if necessary, use of calculators is not allowed.
Q1: Which of these contain the largest number of atoms – 1.0 g Li(s) and
1g Na(s)?
Q2: HI is put in a sealed glass bulb and is then heated to decompose HI
into H2 and I2? What type of system does the reaction mixture represent?
Q3: What is the difference between a vapour and a gas?
Q4: Calculate the maximum number of electrons in f subshell with same
spin.
Q5: What is the direction of flow of electrons and of conventional current
in the following cell?
2+ +
Zn(s)|Zn (aq)||Ag (aq)|Ag(s)
Q6: Give IUPAC name of allyl alcohol.
Q7: Calculate the pH of 0.001M NaOH.
Q8: Why is Ga smaller in size than Al?
Q9: Convert
(a)C and H2 to benzene
(b) Calcium carbide to oxalic acid
Q10: Give reason for the following
(a) F has lower electron gain enthalpy than Cl.
(b) Ionization enthalpy of N is higher than O

Q11: Arrange the following in increasing order of size. Give reason for
your answer.
Mg2+
O2-
Na+
F-
Al3+
Q12: The density of 3M solution of NaCl is 1.25g/mL. Calculate the
molality of the solution.
Q13:
Which of the two is steam volatile and why? o-nitrophenol or p-
nitrophenol
OR
Q13:
Which of the two as higher dipole moment and why? NF3 or NH3
Q14: Calculate the enthalpy change when 2.38g of CO vaporizes at its
normal boiling point? Enthalpy of vaporization of CO is 6.04 kJ/mol.
Q15: Balance the following equation in acidic medium by half reaction
method.
2- 3+
2 7 2 4 2 4 2
Cr O + C H O C H O + Cr
Q 16 Explain
(a) LiCl is more covalent than KCl
(b) In aqueous solution Li+
has lowest mobility.
Q17: In the estimation of sulphur by Carius method, 0.468 g of an organic
sulphur compound afforded 0.668 g of barium sulphate. Find out the
percentage of sulphur in the given compound.
Q18: How many neutrons and protons are there in following nuclei?
(a)
56
26
Fe
(b)
88
38
Sr
Q19:
(i) Which of the two is more stable and why? H2
+
or H2
-
(ii) All bonds in PCl5 are not equal. Explain.
(iii) Which of the two is more ionic and why? NaCl or NaI
Q20: Give reasons:
(i) Evaporation causes cooling
(ii) Falling liquids drops are spherical.
(iii) Vapour pressure of acetone is less than that of ether at same
temperature.
Q21: The combustion of one mole of methanol takes place at 298 K and 1
atm. After combustion CO2 (g) and H2O(l) are produced and 726 kJ of
heat is liberated. Calculate the standard enthalpy of formation of one mole

of CH3OH(l). Standard enthalpies of formation of CO2(g) and H2O(l) are -
393 kJ mol-1
and -286 kJ mol-1
respectively.
Q22:
(a) Name the class of hydrides to which H2O and NaH belong.
(b) What is understood by hydride gap ?
(c) What do you mean by 15 volume H2O2 solution ?
Q23:
Comment on each of the following observations:
(a) Lithium forms a nitride directly like magnesium. Give equation
involved.
(b) BaO is soluble but BaSO4 is insoluble in water.
Q24:Explain:
(i) Boron is unable to form BF6
3-
ion.
(ii) [SiF6]2-
is known whereas [SiCl6]2-
not known.
(iii) Conc. HNO3 can be stored in aluminium container.
Q25: How much energy is required to ionize a H – atom if the electron
occupies n = 5 orbit? Compare your answer with the ionization enthalpy of
H – atom (energy required to remove the electron from n = 1 orbit).
OR
(a) Lifetimes of the molecules in the excited states are often
measured by using pulsed radiation source of duration nearly in
the nano second range. If the radiation source has the duration
of 2 ns and the number of photons emitted during the pulse
source is 2.5 x 1015
, calculate the energy of the source.
(b) Calculate the wavenumber for the longest wavelength transition
in the Balmer series of atomic hydrogen
Q26: Write balance equation for:
(i) BF3 is reacted with ammonia.
(ii) Al is treated with dilute NaOH
(iii) Sodium hydride is reacted with diborane
Q.27:
(a) What is photochemical smog and what are its harmful effects?
(b) What are the reactions involved for ozone layer depletion in the
stratosphere?
Q.28

(a) The species H2O, HCO3, HSO4
-
and NH3 can act both as Bronsted acids
and bases. For each case give the corresponding conjugate acid and base.
(b) Consider the following endothermic reaction:
CH4(g) + H2O (g) CO(g) + 3H2 (g)
(i) Write expression for Kp for the above reaction.
(ii) How will the equilibrium be affected by 1. Increasing the
pressure 2. Using a catalyst?
OR
(a)Predict the acidic, basic or neutral nature of the following salt :
NaCN, KBr, NaNO2, NH4NO3
(b)How many grams of KBr be added to 1 L of 0.05 M solution of silver
nitrate just to start the precipitation of AgBr? Ksp of AgBr = 5.0 x
10-13
Q 29.
(a) In which C-C bond of CH3CH2CH2Br, the inductive effect is expected to
be least?
(b)Which of the following compound shows geometrical isomerism?
(i) Pent-1-ene
(ii) Pent-2-ene
(iii) 2-Methylbut-2-ene
(c) What type of isomerism is present in the following pairs?
(i)
(ii) CH3CH2COCH2CH3 and CH3COCH2CH2CH3
(iii) CH3CH2OH and CH3OCH3
OR
(a)Identify the functional groups in the following:
(b)Draw the bondline formula of heptan-4-one
(c) How many isomers are possible for mono substituted and di
substituted benzene?

Q 30:
(a) Do the following conversions:
(i) Benzene to p-nitrobromobenzene
(ii) Ethyl chloride to ethene
(b) Give mechanism of addition of HBr to propene.
(c) Write a note on Friedel-Crafts alkylation.
OR
(a)Out of n-hexane and ethyne which will be more acidic. Also give
reason for this behaviour.
(b)Explain with example
(i) Wurtz reaction
(ii) Acidic dehydration
(c) Convert propyne to propanone
SOLUTIONS TO SAMPLE PAPER 3
Ans1: 1 g Li(s) (1 mark)
Ans2: Closed system (1mark)
Ans3: Gas below its critical temperature is called a vapour. Vapour is
unstable and becomes a liquid while gas is stable and can be liquefied at
low temperature and high pressure. (1 mark)
Ans4: Total number of electrons in f subshell is 14 but half of them will
have the same spin i.e. 7 electrons will have same spin. (1 mark)
Ans5:
(a)Direction of flow of electrons: From Zn to Ag
1
mark
2
(b)Conventional current: from Ag to Zn
1
mark
2
Ans6: Prop-2-en-1-ol

Ans7:
[NaOH]= [OH-
] = 0.001M
[H3O+
][OH-
]=1.0x10-14
[H3O+
] = 1.0x10-14
/0.001 = 10-11
pH= -log[H3O+
]= -log 10-11
=11 (1 mark)
Ans8: Due to poor screening effect of 10 d electrons, effective nuclear
charge in Ga increases leading to decrease in size. (1 mark)
Ans9:
Ans10:
(a)Less negative electron gain enthalpy value of F is due to very small size
of F atom. As a consequence of small size there are strong interelectronic
repulsions in relatively compact 2p-subshell of fluorine and thus electron
does not feel much attraction. Cl is comparatively bigger in size than F
and can accommodate electron easily. (1 mark)
(b) Due to exactly half filled configuration of N (
2 2 1 1 1
x y z
1s 2s 2p 2p 2p ), it
more stable than O (electronic configuration for which
is
2 2 2 1 1
x y z
1s 2s 2p 2p 2p ), ionization enthalpy of N is higher than O.
(1 mark)
Ans11:
Increasing order of size: Al3+
< Mg2+
< Na+
< F-
< O2-
(1 mark)
This is an isoelectronic series i.e. the number electrons are the same in all
the elements. Thus, as the effective nuclear charge decreases, electrons
are held away from the nucleus and thus size increases.
(1mark)
Ans12:

Molarity = 3M
Density = 1.25g/mL
Mass of NaCl in 1L solution
= Molarity x molar mass
= 3x58.5
1
= 175.5g mark
2
M
Density =
ass
Volume
Mass of 1L NaCl solution
= 1.25 x 1000
1
= 1250g mark
2
Mass of water in solution
= 1250-175.5
= 1074.5g
1
= 1.0745 kg mark
2
Molality
Number of moles of solute
=
Mass of water in solution in kg
3
=
1.0745
1
= 2.79 m mark
2
Ans13:
o-nitrophenol is steam volatile.
1
mark
2
o-nitrophenol has intramolecular hydrogen bonding and results in
cyclisation of molecule .p-nitrophenol has intermolecular hydrogen
bonding and results in association of molecules. Molecules which are
associated require larger energy to separate them before they melt or
boil. Thus p-nitrophenol has higher boiling point and o-nitrophenol has
lower boiling point. Consequently o-nitrophenol is more volatile than p-
nitrophenol.
1
1 mark
2

OR
Ans13:
NH3 has a higher dipole moment than NF3.
1
mark
2
In case of NH3 orbital dipole due to lone pair is in same direction as
resultant dipole due to three N-H bonds. Therefore lone pair moment adds
on the resultant dipole of N-H bonds.
1
mark
2
In case of NF3 orbital dipole due to lone pair is in opposite direction as
resultant dipole due to three N-F bonds. Therefore lone pair moment
cancels the resultant dipole of N-F bonds.
1
mark
2
1
mark
2
Ans14.
-1
-1
Enthalpy of vaporization of CO = 6.04 kJ mol
1
Molar mass of CO = 28 g mol mark
2
Enthalpy change for vaporization of 28 g of
CO at boiling point = 6.04 kJ
Enthalpy change for vaporization of 2.38 g
of CO at boling point
6.04 2.38 1
= mark
28 2
= 0.5134 kJ
= 513.4 J 1mark

Ans15:
2- 3+
2 7 2 4 2 4 2
a) Write down the oxidation number of each atom
Cr O + C H O C H O + Cr
6 1 0 3
b) Write separately oxidation & reduction half reactions
2 4 2 4 2
2- 3+
2 7
Oxidation half reaction:
C H O C H O
1 0
Reduction half reaction:
Cr O Cr
6 3
1
mark
2
2- 3+
2 7
+
2 4 2 2 4 2
2- + 3+
2 7 2
c)Balance Cr atoms in reduction half reaction
Cr O 2Cr
d) Balance O atoms and H atoms
C H O +H O C H O +2H
Cr O 14H 2Cr 7H O
+ -
2 4 2 2 4 2
2- + - 3+
2 7 2
1
mark
2
e) Balance charges :
C H O +H O C H O +2H +2e
Cr O 14H 6e 2Cr 7H O
1
mark
2

+ -
2 4 2 2 4 2
2 4
f) Equalise the electrons lost and gained by multiplying the oxidation half
reaction with 3.
3C H O +3H O 3C H O +6H +6e
Adding the oxidation half reaction and reduction half reaction we get
3C H O
+ -
2 2 4 2
2- + - 3+
2 7 2
+3H O 3C H O +6H +6e
Cr O 14H 6e 2Cr 7H O
__________________________________________
2- + 3+
2 4 2 7 2 4 2 2
_______
3C H O+Cr O 8H 3C H O 2Cr 4H O
1
mark
2
Ans16:
(a) According to Fajan’s rule smaller the size of cation and larger the size
of anion greater is the covalent character of ionic bond. Li is small in size
than K, thus Li+
has a high charge density. Thus polarizing power of Li+
is
higher than K+
, hence LiCl is more covalent than KCl. (1 mark)
(b) Smaller the size of ion greater is the degree of hydration. In aqueous
medium Li+
gets heavily hydrated.Thus mobility of hydrated Li+
is low.
(1 mark)
Ans17:
Ans18:
4
4
4
Mass of organic compound = 0.468 g
Mass of BaSO formed = 0.668 g
1
233 g of BaSO contains S = 32 g mark
2
32 .668
0.668 of BaSO contains S =
233
1
= 0.917 g mark
2
% of sulphur =
0.0917 1
100 mark
0.468 2
1
= 19.59 % mark
2

No. Nuclei No. of protons No. of neutrons
1 56
26
Fe 26
1
mark
2
30
1
mark
2
2 88
38
Sr 38
1
mark
2
50
1
mark
2
Ans19:
(i) H2
+
is more stable than H2
-
as it contains no electron in antibonding MO
while latter contains an electron in antibonding MO making it less stable.
(1 mark)
(ii) PCl5 contains axial and equatorial bonds. Axial bonds are longer than
equatorial bonds as they face more repulsion from equatorial bonds.
Hence axial bonds are weaker than equatorial bonds. (1 mark)
(iii) NaI is more covalent due to high polarizability of iodide ion due to its
bigger size than chloride ion. (1 mark)
Ans20:
(i) This is due to the reason that the molecules which undergo evaporation
are high energy molecules and therefore, the kinetic energy of the
remaining molecules becomes less. Since the remaining molecules have
lower average kinetic energy, their temperature becomes low. (1 mark)
(ii) This is due to surface tension of liquids. Due to surface tension, the
molecules of a liquid, try to make surface area to be minimum and for a
given volume, sphere has the minimum surface area. Therefore the falling
liquid drops are spherical. (1 mark)
(iii) Intermolecular forces are stronger in acetone than in ether. Thus the
vapour pressure of acetone is less than ether. (1 mark)
Ans 21:

3 2 2 2
2
2 2
i) Combustion of methanol
3 1
CH OH (l) + O (g) CO (g) + 2 H O(l) ; H= -726 kJ/mol (Eq-1) mark
2 2
(ii) Enthalpy of formation of CO
C (graphite) + O (g) CO (g) ; H= -393 kJ/mol (Eq-2)
2
2 2 2
2 2 3
1
mark
2
(iii) Enthalpy of formation of H O
1 1
H (g) + O (g) H O (l) ; H= -286 kJ/mol (Eq-3) mark
2 2
Required reaction :
1
C(graphite) + 2H (g) + O CH OH(l) ; H= ? (Eq-4)
2
-1
1
mark
2
1
(Eq-2) + (2 x Eq-3) - (Eq-1) gives the required enthalpy mark
2
for formation of methanol
H = (-572-393)-726
1
= -239 kJ mol mark
2
Ans 22:
(a) H2O is covalent hydride whereas NaH is ionic or saline hydride.
(1 mark)
(b) Group 7 to group 9 elements do not form hydrides. This region of
periodic table from group 7 to 9 is called as hydride gap. (1 mark)
(c) 1 L of H2O2 gives 15 L of O2 at NTP. (1 mark)
Ans 23:
(a) Lithium and magnesium follow diagonal relationship and so lithium like
magnesium forms nitride while other alkali metals do not.
(1 mark)
Heat
2 3
6Li(s) + N (g) 2Li N(s) 1 mark (1)
(b) Size of O 2-
ion is smaller than SO4
2-
. Since a bigger anions stabilizes
bigger cation more than a smaller cation stabilizes a bigger anion, lattice
enthalpy of BaO is smaller than BaSO4. BaO is soluble as hydration energy
is more than lattice energy but BaSO4 (as hydration energy is less than
lattice energy) is insoluble in water. (1mark)

Ans 24:
(i) Due to non-availability of d orbitals, boron is unable to expand its
octet. Therefore, the maximum covalence of boron cannot exceed 4 and it
cannot form BF6
3–
ion. (1 mark)
(ii) [SiF6]2-
is known whereas [SiCl6] 2-
is not known since six large size
atoms i.e. six chlorine atoms cannot be accommodated around Si but six
small size atoms (F atoms) can be comfortably accommodated. (1 mark)
(iii) Conc. HNO3 can be stored in aluminium container because of the
formation of protective layer of oxide which prevents subsequent layers
from undergoing reaction with nitric acid. (1 mark)
Ans 25:
19
1
2n
1 2
19
2 22 1
2 1
19
2
19
20
21.8 10 1
E J atom mark
2n
For ionization from 5th orbit, n 5, n
1 1 1
E E E 21.8 10 mark
2n n
1 1
21.8 10
5
1
21.8 10
25
1
8.72 10 J mark
2
1 2
19
2
19
19
20
For ionization from Ist orbit, n 1, n
1 1 1
E' 21.8 10 mark
21
1
21.8 10 J mark
2
E' 21.8 10 J 1
mark
E 28.72 10
25
OR
Ans 25:
(a)

9
9 1
15 34 9 1
10
1 1
Frequency(v) mark
22 10
1
0.5 10 s mark
2
1
Energy Nhv mark
2
(2.5 10 ) (6.62 10 Js) (0.5 10 s )
1
8.275 10 J mark
2
(b)
2 2
1 2
1
2
7 1
2 2
7
6 1
1 1 1
v R mark
2n n
For Balmer series n 2, for longest wavelenght,
v should be minimumso that n 3
1 1
v (1.097 10 m )
2 3
5
1.097 10
36
1
1.523 10 m mark
2
Ans 26
(i) 3 3 3 3
BF + :NH H N BF 1mark
(ii) 2 4 2
2Al + 2NaOH + 6H O 2Na[Al(OH) ] + 3H 1mark
(iii) 2 6 4
2NaH + B H 2NaBH 1mark
Ans 27:
(a) On burning fossil fuel, a large amount of unburnt hydrocarbons and
nitric oxide is emitted and in the presence of sunlight they form smog
called photochemical smog.
1
mark
2
Harmful effect of photochemical smog:

(i) All these compounds produced during photochemical smog are
eye and lung irritants.
1
mark
2
(ii) Reduces visibility leading to accidents
1
mark
2
(b) Reactions involved for Ozone layer depletion in the stratosphere:
CFC’s (chlorofluorocarbons) that are released in the atmosphere mix with
the other atmospheric gases and when eventually reach the stratosphere,
gets broken down by UV radiations as:
Ans 28:
(a)
Conjugate acid Conjugate base Marks
H2O H3O+
OH-
1
mark
2
HCO3
-
H2CO3 CO3
2-
1
mark
2
HSO4
-
H2SO4 SO4
2-
1
mark
2
NH3 NH4
+
NH2
-
1
mark
2
(b) For the reaction CH4(g) +H2O(g) CO(g) + 3H2 (g)
(i) 2
4 2
3
CO H
p
CH H O
(p )(p )
K =
(p )(p )
(1mark)
(ii)
1. On increasing pressure, the reaction equilibrium will shift in the
backward direction. (1mark)

2. There is no effect of catalyst in equilibrium composition; however the
equilibrium will be attained faster. (1mark)
OR
Ans 28:
(a)
1) NaCN , NaNO2 – Solution are basic as they are salts of strong base and
weak acid. (HCN and HNO2 are weak acids and NaOH is strong base).
(1mark)
2) KBr- This solution is neutral as it salt of strong acid HBr and strong
base KOH.
1
mark
2
3)NH4NO3- Its solution is acidic as it is salt of strong acid (HNO3) and
weak base (NH4OH).
1
mark
2
(b)For AgBr, Ksp = 5.0 x 10-13
Precipitation of AgBr will occur when ionic product [Ag+
] [Br-
] becomes
larger than Ksp. (1 mark)
+ -
3 3
+
-
-13
sp- -11
+
- -11
AgNO Ag + NO
[Ag ]=0.05M
The concentration of Br requiredto start precipitation.
K 5.0 x10
[Br ]= = =1.0 x10 (1 mark)
0.05[Ag ]
Now, [Br ] = [KBr]=1.0 x10
Molar mass of KBr=120
Therefore, the amount of KBr req -11
-9
uired=1.0 x10 x120
= 1.20 x10 g (1 mark)
Ans29:
(a) The inductive effect is least in C2-C3 bond because the magnitude of
inductive effect decreases as the number of intervening bonds increases.
(1 mark)
(b)Pent-2- ene will show geometrical isomerism. (1 mark)

(c)
(i) Position isomerism (1 mark)
(ii) Metamerism(1 mark)
(iii)Functional group isomerism (1 mark)
OR
Ans29:
(a)
The principal functional group is aldehydic group (-CHO)
The secondary functional groups are alcoholic (-OH) and methoxy
(-OMe) group.
(1 mark)
(b) Bondline structure of heptan-4-one:
(1 mark)
(c) There is one isomer for monosubstituted benzene
(1 mark)
There are three isomers for disubstituted benzene

(2 marks)
Ans 30:
(a)
(i) Benzene to p-Nitrobromobenzene

(1 mark)
(iii) Ethyl chloride to ethene
(1 mark)
(b)Mechanism of addition of HBr to propene

(2 marks)
(c ) Friedel- Crafts alkylation- It is the reaction of benzene with alkyl
halide in presence of anhydrous aluminium chloride. The reaction results
in the formation of alkyl benzene.
(1 mark)
OR
Ans 30:
3 2 2 2 2 3
3
CH -CH -CH -CH -CH -CH CH CH
n-hexane Ethyne
sp hybridised sp hybridized
carbon carbon
s-character 25% s-character 50%
Since s-orbital are closer to the nucleus, hence due to more s character in
ethyne (sp hybridized) the hybridized orbital is nearest to this carbon

atom in comparision to sp2
hybridised carbon. This leads to the movement
of C-H
bond pair more towards sp hybridized carbon, leading to the development
of partial positive charge on the hydrogen attached to sp hydridised
carbon and eventually helps in release of proton (H+
). Thus ethyne is
more acidic than n-hexane.
(1
mark)
( b)
(i)Wurtz reaction: Alkyl halides on treatment with sodium metal in dry
ether medium give higher alkanes. This is called Wurtz reaction and is
used for the preparation of alkanes with even number of carbon
atoms.
1
mark
2
Ether
3 3 3 3
1
CH Br + 2Na + BrCH CH -CH + 2NaBr mark
2
Bromomethane Ethane
(ii)Acidic dehydration: Alcohols on heating with conc. H2SO4 at 443 K form
alkenes with elimination of one water molecule. Since a water molecule is
lost in the presence of acid, the reaction is called acidic dehydration of
alcohols.
1
mark
2
2 4
conc. H SO
3 2 2 2 2
1
CH -CH OH CH =CH + H O mark
2
(c)
(2 marks)

Sample paper xi chem 2

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