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Lecture No 1 07-01-2013
Course Title: MY-301: Steel Making Processes
Course Teacher: Muhammad Ali Siddiqui, Lecturer
Academic Session: Spring Semester (2013) Batch: 2010-11
Course Plan
TOPICS
NO. OF
PERIODS
Introduction, Difference between iron and steel making processes.
An outline of various methods of steelmaking - Physical chemistry of
steel making process
Raw materials for steel making Process;Acid open hearth and basic
open hearth processes. Oxygen Enrichment of fuel Operation, control
of composition and different slag practices.
Principles of operation under different slag practices for steelmaking
by Electric Arc furnace and Induction furnace. Rapid steel making,
Basic oxygen furnaces.
Acid Bessemer. Basic Bessemer. Side blown convertor. L.D.
convertor, Kaldo Rotor- Bottom blown and combined blown
processes ofsteel making
Mid Test
Deoxidation by Si. Al- Mn etc., Comparison of deoxidising effects of
various deoxidisers. Deoxidation by complex deoxidisers. Vacuum
degassing of steels. Ladle Metallurgy. Conceptof clean steel.
Lecture No 1 07-01-2013
Introduction to secondary steel making. Some modern developments
in steel making like ESR VOD and AOD process Pre-treatment of
steels.
Ingot solidification. Killed, semi killed. Rimmed and capped steels.
Ingot defects, their identification and remedial actions
Continuous casting of steel.
Low, medium and high carbonsteels.
Alloy Steels
Toolsteels and stainless steels.
Applications of Computers in steel making processes
Manganese steels
Free cutting steel
Basis of designing of Steels.
Final Test
Total 45
Lecture No 1 07-01-2013
Sessional Marks Distribution
Activity in Spring Semester Marks Distribution
Attendance No Marks
Total Test = 02
(Each test of 5 No’s)
10 No's.
Problems Assignment
Assign During lectures
5 No’s.
Working on EAF,BOS,CC
Simulation (Minimum Practice =
30 times per simulation),
False HEAT does not included
(www.steeluniversity.org)
5 + 5 + 5 = 15 No’s.
Total 30
Total Marks = 100 No’s.
Sessional Marks = 40 No's.
Final Exams Marks = 60 No's.
Lecture No 1 07-01-2013
List of Text Books
1. Introduction to Modern Steel Making by R. H. Tupkary and V. R. Tupkary (2008)
2. The Making, Shaping and Treating of Steel (Steel Making and Refining)
by Richard J. Fruehan, United States Steel Co., American Society for Metals
ISBN-10: 0930767039, ISBN-13: 978-0930767037
3. Modeling of Steelmaking Processesby Dipak Mazumdar, James W. Evans
ISBN-10: 1420062433 | ISBN-13: 978-1420062434
4. SecondarySteelmaking: Principles and Applications Ahindra Ghosh ISBN-10:
0849302641 | ISBN-13: 978-0849302640
5. Ironmaking and Steelmaking: Theory and Practice Ahindra Ghosh (Author), Amit
Chatterjee
6. Physical Chemistry of Steel Making by John. F Elliott, ISBN-10: 0-262-55046-6, ISBN-
13: 978-0-262-55046-8
7. A Text Book Of Metallurgical Analysis Author: B C Agarwal P Jain and S C Sharma
ISBN: 8174091351
Useful Link
www.steeluniversity.org
Make your own Notes it will be easy to understand any subject/topic
Lecture No 1 07-01-2013
MY-301: STEEL MAKING PROCESSES
INTRODUCTION:
 Whatis steel?
 Differencebetween iron and steel making processes?
Engineering practice of the reductionof Iron oxide
1) Reduction of Iron Oxide in Blast furnace by (Indirect Method):
2) Reduction of Iron Oxide in Shaft or Rotary Furnace by (Direct
Method) or MIDREX® Process
Lecture No 1 07-01-2013
1)BLAST FURNACEby (indirect method)
Iron is extracted from the ore haematite (Fe2O3) by reduction CO is
a reducing agent because it is more reactive than iron
Processor steps or (how iron is extractedfrom their ore)
Lecture No 1 07-01-2013
Hot air is blasted into the furnace causing coke (carbon)to burn
rapidly and raise the temperatureto 2000 °C. (Exothermic
reaction)
C(s) + O2 (g)  CO2 (g) + Heat
 The carbon dioxide then reacts with hot carbon to form carbon
monoxide.
CO2 (g) + C(s)  2CO (g)
 Carbon monoxide then reduces iron in the ore to iron metal.
3CO (g) + Fe2O3(s)  3CO2 (g) + 2Fe (l)
The main impurity is silica (sand or rock) which is SiO2
SiO2 is solid at the furnace temperature and the furnace would
become blocked if it was not removed
Limestone is calcium carbonate(CaCO3) and it is added to the
blast furnace to remove the impurities in the iron ore.
Calcium carbonateis decomposed by heat in the furnace to give
calcium oxide (lime) and carbon dioxide.
This is called thermal decomposition.
CaCO3(s)  CaO(s) + CO2 (g)
Silicon dioxide reacts with calcium oxide to form calcium
silicate (called slag) which is liquid in the furnace.
Slag flows to the bottomof the furnace where it floats on the
liquid iron and is easily removed.
CaO(s) + SiO2(s)  CaSiO3 (l)
The slag (CaSiO3) is allowed to cool until it becomes a solid
and is used for road construction.
Lecture No 1 07-01-2013
2) Shaft or Rotary Furnaceby (Direct Method) or MIDREX®
Lecture No 1 07-01-2013
Lecture No 1 07-01-2013
Reduction:
 Iron oxide, in pellet or lump form, is introduced through a
proportioning hopper at the top of the shaft furnace.
 As the ore descends through the furnace by gravity flow, it is
heated and the oxygen is removed from the iron (reduced) by
counter flowing gases which have a high H2 and CO content.
 These gases react with the Fe2O3 in the iron ore and convert it
to metallic iron, leaving H2O and CO2.
 For production of cold DRI, the reduced iron is cooled and
carburized by counter flowing cooling gases in the lower
portion of the shaft furnace.
 The DRI can also be discharged hot and fed to a briquetting
machine for production of HBI, or fed hot, as HDRI, directly
to an EAF.
Reaction in Reformer:
CH4 + CO2  2CO + 2H2
CH4 + H2O  CO + 3H2
Reaction in shaft Furnace:
Fe3O4 + CO  3FeO + CO2
Fe3O4 + H2  3FeO + H2O
FeO + CO  Fe + CO2
FeO + H2  Fe + H2O

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Steel Making: Lecture 1 Introduction to the subject and review of Iron Making

  • 1. Lecture No 1 07-01-2013 Course Title: MY-301: Steel Making Processes Course Teacher: Muhammad Ali Siddiqui, Lecturer Academic Session: Spring Semester (2013) Batch: 2010-11 Course Plan TOPICS NO. OF PERIODS Introduction, Difference between iron and steel making processes. An outline of various methods of steelmaking - Physical chemistry of steel making process Raw materials for steel making Process;Acid open hearth and basic open hearth processes. Oxygen Enrichment of fuel Operation, control of composition and different slag practices. Principles of operation under different slag practices for steelmaking by Electric Arc furnace and Induction furnace. Rapid steel making, Basic oxygen furnaces. Acid Bessemer. Basic Bessemer. Side blown convertor. L.D. convertor, Kaldo Rotor- Bottom blown and combined blown processes ofsteel making Mid Test Deoxidation by Si. Al- Mn etc., Comparison of deoxidising effects of various deoxidisers. Deoxidation by complex deoxidisers. Vacuum degassing of steels. Ladle Metallurgy. Conceptof clean steel.
  • 2. Lecture No 1 07-01-2013 Introduction to secondary steel making. Some modern developments in steel making like ESR VOD and AOD process Pre-treatment of steels. Ingot solidification. Killed, semi killed. Rimmed and capped steels. Ingot defects, their identification and remedial actions Continuous casting of steel. Low, medium and high carbonsteels. Alloy Steels Toolsteels and stainless steels. Applications of Computers in steel making processes Manganese steels Free cutting steel Basis of designing of Steels. Final Test Total 45
  • 3. Lecture No 1 07-01-2013 Sessional Marks Distribution Activity in Spring Semester Marks Distribution Attendance No Marks Total Test = 02 (Each test of 5 No’s) 10 No's. Problems Assignment Assign During lectures 5 No’s. Working on EAF,BOS,CC Simulation (Minimum Practice = 30 times per simulation), False HEAT does not included (www.steeluniversity.org) 5 + 5 + 5 = 15 No’s. Total 30 Total Marks = 100 No’s. Sessional Marks = 40 No's. Final Exams Marks = 60 No's.
  • 4. Lecture No 1 07-01-2013 List of Text Books 1. Introduction to Modern Steel Making by R. H. Tupkary and V. R. Tupkary (2008) 2. The Making, Shaping and Treating of Steel (Steel Making and Refining) by Richard J. Fruehan, United States Steel Co., American Society for Metals ISBN-10: 0930767039, ISBN-13: 978-0930767037 3. Modeling of Steelmaking Processesby Dipak Mazumdar, James W. Evans ISBN-10: 1420062433 | ISBN-13: 978-1420062434 4. SecondarySteelmaking: Principles and Applications Ahindra Ghosh ISBN-10: 0849302641 | ISBN-13: 978-0849302640 5. Ironmaking and Steelmaking: Theory and Practice Ahindra Ghosh (Author), Amit Chatterjee 6. Physical Chemistry of Steel Making by John. F Elliott, ISBN-10: 0-262-55046-6, ISBN- 13: 978-0-262-55046-8 7. A Text Book Of Metallurgical Analysis Author: B C Agarwal P Jain and S C Sharma ISBN: 8174091351 Useful Link www.steeluniversity.org Make your own Notes it will be easy to understand any subject/topic
  • 5. Lecture No 1 07-01-2013 MY-301: STEEL MAKING PROCESSES INTRODUCTION:  Whatis steel?  Differencebetween iron and steel making processes? Engineering practice of the reductionof Iron oxide 1) Reduction of Iron Oxide in Blast furnace by (Indirect Method): 2) Reduction of Iron Oxide in Shaft or Rotary Furnace by (Direct Method) or MIDREX® Process
  • 6. Lecture No 1 07-01-2013 1)BLAST FURNACEby (indirect method) Iron is extracted from the ore haematite (Fe2O3) by reduction CO is a reducing agent because it is more reactive than iron Processor steps or (how iron is extractedfrom their ore)
  • 7. Lecture No 1 07-01-2013 Hot air is blasted into the furnace causing coke (carbon)to burn rapidly and raise the temperatureto 2000 °C. (Exothermic reaction) C(s) + O2 (g)  CO2 (g) + Heat  The carbon dioxide then reacts with hot carbon to form carbon monoxide. CO2 (g) + C(s)  2CO (g)  Carbon monoxide then reduces iron in the ore to iron metal. 3CO (g) + Fe2O3(s)  3CO2 (g) + 2Fe (l) The main impurity is silica (sand or rock) which is SiO2 SiO2 is solid at the furnace temperature and the furnace would become blocked if it was not removed Limestone is calcium carbonate(CaCO3) and it is added to the blast furnace to remove the impurities in the iron ore. Calcium carbonateis decomposed by heat in the furnace to give calcium oxide (lime) and carbon dioxide. This is called thermal decomposition. CaCO3(s)  CaO(s) + CO2 (g) Silicon dioxide reacts with calcium oxide to form calcium silicate (called slag) which is liquid in the furnace. Slag flows to the bottomof the furnace where it floats on the liquid iron and is easily removed. CaO(s) + SiO2(s)  CaSiO3 (l) The slag (CaSiO3) is allowed to cool until it becomes a solid and is used for road construction.
  • 8. Lecture No 1 07-01-2013 2) Shaft or Rotary Furnaceby (Direct Method) or MIDREX®
  • 9. Lecture No 1 07-01-2013
  • 10. Lecture No 1 07-01-2013 Reduction:  Iron oxide, in pellet or lump form, is introduced through a proportioning hopper at the top of the shaft furnace.  As the ore descends through the furnace by gravity flow, it is heated and the oxygen is removed from the iron (reduced) by counter flowing gases which have a high H2 and CO content.  These gases react with the Fe2O3 in the iron ore and convert it to metallic iron, leaving H2O and CO2.  For production of cold DRI, the reduced iron is cooled and carburized by counter flowing cooling gases in the lower portion of the shaft furnace.  The DRI can also be discharged hot and fed to a briquetting machine for production of HBI, or fed hot, as HDRI, directly to an EAF. Reaction in Reformer: CH4 + CO2  2CO + 2H2 CH4 + H2O  CO + 3H2 Reaction in shaft Furnace: Fe3O4 + CO  3FeO + CO2 Fe3O4 + H2  3FeO + H2O FeO + CO  Fe + CO2 FeO + H2  Fe + H2O