Structure Of The Atom.pdf notes important
- 5. Introduction to the Structure of an Atom Atoms ❑Atoms are the building blocks of matter. It is the smallest unit of matter that is composed of three sub- atomic particles: the proton, the neutron and the electron.
- 6. Cathode Ray Experiment J. J. Thomson discovered the existence of electrons. He did this using a cathode ray tube, which is a vacuum-sealed tube with a cathode and anode on one end that created a beam of electrons travelling towards the other end of the tube. The air inside the chamber is subjected to high voltage, and electricity flows through the air from the negative electrode to the positive electrode. The characteristics of cathode rays (electrons) do not depend upon the material of electrodes and the nature of the gas present in the cathode ray tube. The experiment showed that the atom was not a simple, indivisible particle and contained at least one subatomic particle – the electron.
- 9. Electrons Electrons are the negatively charged sub-atomic particles of an atom. The mass of an electron is considered to be negligible, and its charge is -1. The symbol for an electron is e– Electrons are extremely small. They are found outside the nucleus.
- 10. Thomson’s Model of an Atom According to Thomson,(i) An atom consists of a positively charged sphere and the electrons are embedded in it. (ii) The negative and positive charges are equal in magnitude. So, the atom as a whole is electrically neutral The first model of an atom to be put forward and taken into consideration. He proposed a model of the atom be similar to that of a Christmas pudding/watermelon. The red edible part of the watermelon is compared with the positive charge in the atom. The black seeds in the watermelon are compared with the electrons which are embedded on it.
- 12. Radioactivity Radioactivity Radioactivity is the term for the process by which an unstable nucleus of an atom loses energy by giving out particles. It does so by giving out particles such as alpha and beta particles. This process is spontaneous. An atom is unstable if the nucleus has an imbalance, meaning a difference in the protons and neutrons.
- 14. Rutherford Model Rutherford’s Experiment and Observations In this experiment, fast-moving alpha (α)-particles were made to fall on a thin gold foil. His observations were: A major fraction of the α-particles bombarded towards the gold sheet passed through it without any deflection, and hence most of the space in an atom is empty. Some of the α-particles were deflected by the gold sheet by very small angles, and hence the positive charge in an atom is not uniformly distributed. The positive charge in an atom is concentrated in a very small volume. Very few of the α-particles were deflected back; that is, only a few α- particles had nearly 180o angle of deflection. So the volume occupied by the positively charged particles in an atom is very small as compared to the total volume of an atom.
- 15. Rutherford’s Model of an Atom Rutherford concluded the model of the atom from the α-particle scattering experiment as follows: (i) There is a positively charged centre in an atom called the nucleus. Nearly all the mass of an atom resides in the nucleus. (ii) The electrons revolve around the nucleus in well- defined orbits. (iii) The size of the nucleus is very small compared to the size of the atom.
- 18. Drawbacks of Rutherford’s Model He explained that the electrons in an atom revolve around the nucleus in well-defined orbits. Particles in a circular orbit would experience acceleration. Thus, the revolving electron would lose energy and finally fall into the nucleus. But this cannot take place as the atom would be unstable, and the matter would not exist in the form we know.
- 19. Be More Curious!!! The Millikan’s Oil Drop Experiment was an experiment performed by Robert A. Millikan and Harvey Fletcher in 1909 to measure the charge of an electron. In the experiment, Millikan allowed charged tiny oil droplets to pass through a hole into an electric field. By varying the strength of the electric field, the charge over an oil droplet was calculated, which always came as an integral value of ‘e.’ The conclusion of this is that the charge is said to be quantized, i.e. the charge on any particle will always be an integral multiple of e which is 1.6*10-19
- 20. Neil Bohr Model
- 21. Bohr’s Model of an Atom Bohr came up with the following postulates to overcome the objections raised against Rutherford’s model. Electrons revolve around the nucleus in stable orbits without the emission of radiant energy. Each orbit has a definite energy and is called an energy shell or energy level. An orbit or energy level is designated as K, L, M, and N shells. When the electron is in the lowest energy level, it is said to be in the ground state. An electron emits or absorbs energy when it jumps from one orbit or energy level to another. When it jumps from a higher energy level to a lower energy level, it emits energy, while it absorbs energy when it jumps from a lower energy level to a higher energy level.
- 23. Electron Distribution in Different Orbits The distribution was suggested by Bohr and Bury. The maximum number of electrons present in a shell is given by the formula 2n2, where ‘n’ is the orbit number or energy level index, 1,2,3,…. The maximum number of electrons in different shells are as follows: the first orbit will have 2*12=2, the second orbit will have 2*2Msup>2=8, the third orbit will have 2*32=18, the fourth orbit 2*42=32 and so on. The shells are always filled in a step-wise manner from the lower to higher energy levels. Electrons are not filled in the next shell unless previous shells are filled.
- 25. Valency The electrons present in the outermost shell of an atom are known as the valence electrons. The combining capacity of the atoms or their tendency to react and form molecules with atoms of the same or different elements is known as the valency of the atom. Atoms of elements, having a completely filled outermost shell, show little chemical activity. Their combining capacity or valency is zero. For example, we know that the number of electrons in the outermost shell of hydrogen is 1, and in magnesium, it is 2. Therefore, the valency of hydrogen is 1 as it can easily lose 1 electron and become stable. On the other hand, that of magnesium is 2 as it can lose 2 electrons easily and also attain stability.
- 26. Atomic Number The number of protons found in the nucleus of an atom is termed the atomic number. It is denoted by the letter ‘Z’.
- 27. Mass Number and Representation of an Atom Protons and neutrons are present in the nucleus, so the mass number is the total of these protons and neutrons.
- 30. Isotopes and Isobars Isotopes are defined as the atoms of the same element, having the same atomic number ( number of protons ) but different mass numbers ( number of protons+neutrons ). For example: In the case of Hydrogen we have:
- 31. Atoms of different elements with different atomic numbers, which have the same mass number, are known as isobars. For example, Calcium and Argon: both have the same mass number – 40 20Ca40 and 18Ar40 To know more about Isotopes and Isobars
- 32. Calculation of Mass Number for Isotopic Elements
- 33. Extra question :- Q1What are the features of ‘Thomas’ atomic model’? J.J. Thomson’s experiments with cathode ray tubes showed that all atoms contain tiny negatively charged subatomic particles or electrons. Thomson proposed the plum pudding model of the atom.
- 34. Q2Who was ‘Ernest Rutherford’? Ernest Rutherford was a New Zealand physicist who came to be known as the father of nuclear physics.
- 35. Q3What did ‘Neils Bohr’ discover? Niels Bohr proposed a theory for the hydrogen atom, based on quantum theory, that some physical quantities only take discrete values.
- 38. TEXTBOOK QUESTION :- 1. Compare the properties of electrons, protons and neutrons 2. What are the limitations of J.J. Thomson’s model of the atom? 3. What are the limitations of Rutherford’s model of the atom? 4. Explain with examples (i) Atomic number, (ii) (ii) Mass number, (iii) (iii) Isotopes and (iv) iv) Isobars. (v) Give any two uses of isotopes 5. Write the electronic configuration of any one pair of isotopes and isobars
- 39. Extra Questions 1. Which subatomic particle is absent in an ordinary hydrogen atom? 2. Write the electronic configuration of an element whose atomic number is 12. 3. Give two important applications of radioactive isotopes. 4. How do you know that nucleus is very small as compared to the size of atom? 5. Write two characteristics of the canal rays.
- 40. 1. Helium atom has 2 electrons in its valence shell but its valency is not 2. Explain. 2. Why do isotopes show similar chemical properties?