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THE RETURN OF H2 –
CHALLENGES OF MODELLING H2
IN TIMES
ETSAP WORKSHOP, Zurich, 13.12.2017
Sofia Simoes, Juliana Barbosa, Luís
Fazendeiro
CO2
ENERGY &
CLIMATE
New
Technologies
& Low
Carbon
Practices
Climate
Mitigation/
Adaptation
Consumers
Profiles &
Energy
Efficiency
Policy
Support
Energy
Transitions
Integrative
Energy City
Planning
ASSESSING THE H2 POTENTIAL IN THE PT ENERGY SYSTEM
[2]
(a) Analysis of current and emerging H2 chains (focus on mobility and storage of variable intermittent
RES power)
(b) Review and update H2 tehnologies in TIMES
(c) Simulation, using the TIMES_PT model on the cost-effectiveness of H2 deployment in Portugal in
several scenarios, including very high share and variable CO2 mitigation targets
(d) Develop a Road map for the development of H2 technologies in the Portuguese energy system till
2050
18 months - first results April 2018
H2 HOLISTIC ANALYSIS
[3]
ERP (2016) | http://erpuk.org/wp-
content/uploads/2016/10/ERP-
Hydrogen-report-Oct-2016.pdf
“Hydrogen has often been criticised for being an inefficient way of using
energy, but a system approach should be taken, when comparing it with
other options, that takes into account the flexibility of hydrogen and how it
can supply multiple markets. Hydrogen should therefore be evaluated on
the cost effectiveness of the overall system and its potential
environmental impacts, primarily carbon reduction“
H2 IN TIMES_PT
Older version of TIMES_PT includes approx. 90 H2 technologies (last update 2010)
› 15 options for H2 production (gaseification, electrolysis, partial oxidation, thermochemical cycles);
› 15 options for H2 conversion and distribution;
› 60 options for end-use consumption of H2 for power generation and heat production in buildings,
industry and for transport (bus, cars and heavy duty trucks)
• Cascade-Mints D1.1 Fuel cell technologies and Hydrogen production/Distribution options, DLR, September 2005; E3 Spain
Electrolysis
Large
Electricity Small
Gaseification
with CCS
Coal
w/o CCS
Steam
Steam reforming
Solar
Biomass
Gaseification
Natural Gas
Pyrolisis
Large
Small
with CCS
Process Kvaerner
Partial oxidationHeavy fuel oil
SMR CH4
Thermochemical cycles
H2 END-USES IN TIMES_PT
Residential
Space Heating
Space cooling
Water heating
Lighting
Cooking
Refrigeration
Dishwashers
Washing machines
Clothes dryers
Other electric uses
Other energy uses
Rural houses
Urban houses
Appartments
Services
Space Heating
Space cooling
Water heating
Cooking
Other electric uses
Other energy uses
Lighting
Refrigeration
Public lighting
Large
services
buildings
Small
services
buildings
Agriculture
Generic use
Blending with natural gas
H2 END-USES IN TIMES_PT (II)
Transport
Iron & Steel
Outros metais não ferrosos
Ammonia
Chlorine
Other chemical
Cement
Lime
Glass
Other non-metallic
minerals
Pulp and paper
Nitric Acid
Other industry
Graphic
Packaging
Hollow
Flat
Industry
Passengers
Freight
BUS urban
BUS
interurban
Cars
Motos
Road
Rail
Metro
Trains
Passenger
Freight
Heavy duty
Light duty
Generic Aviation
Generic navigation
Aluminium
Copper
Other non-
ferrous metals
Blending with
natural gas
UPDATE H2 IN TIMES_PT
Older version of TIMES_PT included approx. 90 H2 technologies
› 15 options for H2 production (gaseification, electrolysis, parcial oxidation, thermochemical cycles);
› 15 options for H2 conversion and distribution;
› 60 options for end-use consumption of H2 for power generation and heat production in buildings,
industry and for transport (bus, cars and heavy duty trucks)
• Cascade-Mints D1.1 Fuel cell technologies and Hydrogen production/Distribution options, DLR, September 2005
• E3 Spain
2016 paper using JRC-EU-TIMES model which includes:
› 23 options for generation of H2 (…+PEM);
› 24 options for conversion and distribution of H2 / 3 storage and 21 distribution (3 liquid H2);
› ?? options for end-use consumption for electricity generation, heat production in buildings, for
industry and transport (freight heavy and light duty, buses) + blending with natural gas
• Bolat, P., Thiel, C. (2014). Hydrogen supply chain architecture for bottom-up energy systems models. Part 1: Developing pathways.
International Journal of Hydrogen Energy (39) 17, pp. 8881-8897. http://www.sciencedirect.com/science/article/pii/S0360319914008684
• Bolat, P., Thiel, C. (2014). Hydrogen supply chain architecture for bottom-up energy systems models. Part 2: Techno-economic inputs for
hydrogen production pathways. International Journal of Hydrogen Energy (39) 17, pp. 8898-8925.
• Gaseification
• Steam reforming
• Electrolysis
GENERATION
• Centralized -
underground
• Centralized - tank
• Decentralized
STORAGE •Road: short/long distance;
liquified or compressed;
refueling stations: LL, LG, GG
•Ships (liquified)
•Final delivery: road, pipelines or
blended with natural gas (6-
15%)
DISTRIBUTION
•Transport: road for cars and
passengers and freight (light/heavy)
and rail (?)
•Industry: 1st gen biofuels
• Buildings (services and residential)
• Electricity generation
•Agriculture (in gas)
END-USE
H2 IN TIMES_PT: 1ST APPROACH
Slide [8]
Main area to improve
Main area to improve
Gaseificaçãode
biomassa
Processo
Kvaener
SteamreformingEletrólise
Gaseificaçãodo
carvão
SCOAH2G101
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IPPPUPC
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IPPPUPC
HE05
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SELCH2G
TRA01
T
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TCARG
H2FCEL
C110TCARG
H2IC110
TFHGH2
FC110
TFLGH2
FC110
TFLGH2
FCELC1
10TFLGH2
IC110
TBISGH
2FC110TBUSG
H2FC11
0TCARG
H2FC11
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RSDHH2R0
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RSDHH2U0
1
SH2GH2L10
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SH2GH2L13
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SH2GH2L20
1
TRAGH230
1
COMHH201
ELCHH20
1
INDHH20
1
TRAGH240
1
SYNH2L
TRAGH2101
TRAGH2201
TRALH2101
TRALH2201
SGASCH2
CCS110
SGASH2G
101
SGASH2G
2101
Óleo
Combustíve
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301
SHFOH2G
101
SSOLH2G
130
SSOLH2G
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Energiasolar
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A
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2
TCARLH
2IC110
TFLLH2I
C110
COMHH
2
CHLEFCHH2610
CHLEFCHH2510
CHLEFCHH2310
CHLEFCHH2410
CSLEFCHH2510
CSLEFCHH2410
CHPCOMFCHH2
110
CHSEFCHH2310
CSLEFCHH2610
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CHLEFC
110
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H100
CHLELT
H199
CHLELT
H100
CHLELT
H101
CWLELT
H199
CWLELT
H100
CHSELT
H101
CHSELT
H199
CWSEL
TH100
CWSEL
TH199
DUMAF
SCOM
C
W
L
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EUFCHH201
PUFCHH210
H
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CHPICHFCHH21
10
CHPIGHFCHH21
10
CHPIISFCHH211
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CHPILMFCHH21
10
CHPINDFCHH21
10
CHPINMFCHH21
10
CHPIOIFCHH211
0
CHPIPPFCHH21
10
CHPREFFCHH21
10
I
A
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HTH00
ICHSTM
HTH01
ICHSTM
HTH99
ICHOTH
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PRD02
ICMDRY
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ICMDRY
PRD10
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ICMFINP
RO01
ICMFINP
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HTH00
INMSTM
HTH01
INMOTH
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HTH00
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2R
CHPRSDFCHH2
310
CHPRSDFCHH2
410
CHPRSDFCHH2
510
CHPRSDFCHH2
610
RHMEFCHH2310
RHMEFCHH2410
RHMEFCHH2510
RHMEFCHH2610
RHMNFCHH2310
RHMNFCHH2410
RHMNFCHH2510
RHMNFCHH2610
RHREFCHH2310
RHREFCHH2410
RHREFCHH2510
RHREFCHH2610
RHRNFCHH2310
RHRNFCHH2410
RHRNFCHH2510
RHRNFCHH2610
RHUEFCHH2310
RHUEFCHH2410
RHUEFCHH2510
RHUEFCHH2610
RHUNFCHH2310
RHUNFCHH2410
RHUNFCHH2510
RHUNFCHH2610
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C110
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C110
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RHMEF
C110
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RHMEFCHH2710
RHMEFCHH2810
RHMEFCHH2910
RHMNFCHH2710
RHMNFCHH2810
RHMNFCHH2910
RSDHH
2U
TRANSPORTS
RESIDENTIAL
INDUSTRY
ServicesSYNH2
CU
SYNH2
CT
THE RETURN OF H2?
• Bolat, P., Thiel, C. (2014). Hydrogen supply chain architecture for bottom-up energy systems models. Part 1: Developing
pathways. International Journal of Hydrogen Energy (39) 17, pp. 8881-8897.
http://www.sciencedirect.com/science/article/pii/S0360319914008684
• Bolat, P., Thiel, C. (2014). Hydrogen supply chain architecture for bottom-up energy systems models. Part 2: Techno-
economic inputs for hydrogen production pathways. International Journal of Hydrogen Energy (39) 17, pp. 8898-8925.
https://doi.org/10.1016/j.ijhydene.2014.03.170
• Sgobbi, A. et al (2016). How far away is hydrogen? Its role in the medium and long-term decarbonisation of the European
energy system. Int. Journal of Hydrogen Energy (41) 1, pp 19-35.
http://www.sciencedirect.com/science/article/pii/S0360319915301889
• IEA (2015) Technology Roadmap, Hydrogen and Fuel Cells. Paris.
• Fuel Cell and Hydrogen Joint Undertaking. (2015) Study on H2 from RES in the EU (Final Report)
• Fuel Cells and Hydrogen Joint Undertaking Fuel Cell Electric Buses (2015) Potential for Sustainable Public
Transport in Europe
• Hydrogenics. (2016) Power to Gas Roadmap for Flanders
• Hydrogen Council (2017) How hydrogen empowers the energy transition. http://hydrogeneurope.eu/wp-
content/uploads/2017/01/20170109-HYDROGEN-COUNCIL-Vision-document-FINAL-HR.pdf
• The Energy Research Partnership. (2016) Potential Role of Hydrogen in the UK Energy System
• DOE/NREL (2017) Comparison of conventional vs. modular hydrogen refueling stations, and on-site
production vs. delivery.
H2FIRST: HYDROGEN FUELING INFRASTRUCTURE RESEARCH AND STATION TECHNOLOGY
[11]
Fuel stations
built on site
Modular pre-
fabricated fuel
stations
(1-1.5 M USD)
H2 delivered as compressed
gas from centralised
production plant
H2 produced locally via SMR
H2 produced locally via
eletrolysis
100 kg/day
(12 GJ/day*)
200 kg/day
(24 GJ/day*)
300 kg/day
(36 GJ/day*)
H2 produced locally via
eletrolysis
H2 produced locally via
eletrolysis
* Condered NCV 120 MJ/kg of http://www.h2data.de/
DOE USA
Exclude liquid H2 and underground storage
UPDATE SUBRES H2 IN TIMES_PT
Electrolysis
Alkaline (6)
Electricity PEM
Gaseification
with CCS
Coal
w/o CCS
Offgrid (2)
Steam reforming
Solar
Biomass
Gaseification
Natural Gas
Pyrolisis
Central CCS
Central
Decentral.
Process Kvaerner
Partial oxidationHeavy fuel oil
SMR Natural gas
Thermochemical cycles
Central CCS
Central
Decentral.
electricity
SR
electricity
Natural gas
Steam reformingBioethanol
electricity
BLENDING H2 IN NATURAL GAS?
[13]
Reference Model/Organisation Year Blending?
Sgobbi et al., Int. J. Hydrogen E., 41, 19-35,
2016
JRC-EU-TIMES 2016 Yes, 15%
Bolat and Thiel, Part I, Int. J. Hydrogen E.,
39, 8898-8925, 2014
JRC, literature review 2014 Yes, 10% (pathway 16)
NRC- The Hydrogen Economy
US National Research
Council – review
2004
No - discussion dedicated gas H2
pipelines
IEA – Technology Roadmap, Hydrogen and
Fuel Cells
IEA 2016 Yes, 5-10%
Hydrogen Council - How hydrogen
empowers the energy transition
H2 Council 2017 Yes, but no value given
Klaus Altfeld and Dave Pinchbeck -
Admissible hydrogen concentrations in
natural gas systems, ISSN 2192-158X
DIV Deutscher
Industrieverlag GmbH
2013
Looks at this issue in great detail,
suggests a likely upper limit of 10% for
most cases
Potential Role of Hydrogen in the UK Energy
System
Energy Research
Partnership
2016
Up to 20% appears possible without
modifications
LIQUID H2?
[14]
Reference Model/Team Year Consider liquid H2?
NRC- The Hydrogen Economy
US National Research
Council – review
2004
yes, but mainly storage and
distribution
Bolat and Thiel, Part I, Int. J. Hydrogen E.,
39, 8898-8925, 2014
JRC, literature review 2014 yes
Sgobbi et al., Int. J. Hydrogen E., 41, 19-35,
2016
JRC-EU-TIMES 2016 yes
IEA – Technology Roadmap, Hydrogen and
Fuel Cells
IEA 2016
yes, but mainly storage and
distribution
Hydrogen Council - How hydrogen
empowers the energy transition
H2 Council 2017 yes, briefly
Potential Role of Hydrogen in the UK Energy
System
Energy Research
Partnership
2016 yes, for distribution
Ethan S. Hecht, Joseph Pratt, Comparison of
conventional vs. modular hydrogen refueling
stations, and on-site production vs. delivery
Sandia National
Laboratories, study for
DOE, USA
2017 yes, for distribution
Dodd-Ekins, powertrains for the UK, Int. J.
Hydr. E. , 39, 13941-13952, 2014
UK-MARKAL/ UCL 2014 no
Ballard – Hydro rail presentation Ballard 2017 no
TECHNOLOGY ROADMAP – H2 AND FUEL CELLS
[15]
IEA
> Ortions for Generation (8): alkaline electrolysis , PEM electrolysis, gas SMR, gas SRM with CCS, coal gaseification, biomass gaseification, FC
alkaline, FC PEM
> Options for Storage (13): PEM alkaline, PEM fixed, PEM FC mobile, FC solid oxides, FC phosporic acid, molten carbonates, compressor at 18
MPa, compressor at 70 Mpa, Liquidifier, FCEV on-board storage tank at 70 Mpa, pressurized tank, liquid storage, pipeline
Power to gas
Electrolysis PEM
Methanation
Natural gas
grid
OCGT
Power to power
Electrolysis PEM Storag. Und. PEMFC
Electrolysis Alkaline
Electrolysis PEM OCGTStorag. Und.
Storage in pumped hydro CAES
H2 IN TIMES_PT: 2ND APPROACH
Slide [16]
Storage
Distribution
ConversionEnd-use
Generation
End-use
Generation
ConversionEnd-use
Generation
MODELLING H2 IN TIMES_PT
We have been modelling H2 as
separate puzzle pieces and may
the most cost-effective win
It should instead be modelled
as pathways
PATHWAYS - CENTRALIZED
Centralized
generation
Compression (gas)
Dedicated
pipelines
Dedicated
distribution
Fuel stations
Residential sector with FC for electricity generation
Services sector with FC for electricity generation
Transport in
trucks
Fuel
stations
Undergroun
d storage
Storage in
tanks
Conversion
Synthetic fuels
Electricity
generation (VRES)
Methanation & blending in
natural gas grid
Blending
1
2
34
PATHWAYS - DECENTRALIZED
.
Decentralized production
In fuel stations
Storage in
tanks
Storage in
trucks
At the fuel
station
Industry Electricity generation
Storage in
tanks
Ammonia
production
Diesel
desulfurization
Other industry
uses
4
SOME TOUGHTS
› communicating with the H2 world
› e.g. costs units in ton H2 or m3 H2 not €/kW; lifetime in operation hours not years
› H2 feedstocks are very varied and fundamental to explain why some feedstock are in and some
are not
› simplify your model – update SubRES based on scenarios to explore
› less effort on fossil based generation options
› modular H2 supply for transport instead of very detailed representation of all possible
distribution options
› ignore liquid H2 possibilities for transport
› specify format of operation for some technologies considering the specific
pathway: lifetime of PEM might not be 3 years depending how it is operated
[20]
Sofia Simões
sgcs@fct.unl.pt
Juliana Barbosa
jpa.barbosa@campus.fct.unl.pt
Luís Fazendeiro
l.fazendeiro@campus.fct.unl.pt
Júlia Seixas
mjs@fct.unl.pt
CO2
ENERGY &
CLIMATE
New
Technologies
& Low
Carbon
Practices
Climate
Mitigation/
Adaptation
Consumers
Profiles &
Energy
Efficiency
Policy
Support
Energy
Transitions
Integrative
Energy City
Planning

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The Return of H2 – Challenges of Modelling H2 in TIMES

  • 1. THE RETURN OF H2 – CHALLENGES OF MODELLING H2 IN TIMES ETSAP WORKSHOP, Zurich, 13.12.2017 Sofia Simoes, Juliana Barbosa, Luís Fazendeiro CO2 ENERGY & CLIMATE New Technologies & Low Carbon Practices Climate Mitigation/ Adaptation Consumers Profiles & Energy Efficiency Policy Support Energy Transitions Integrative Energy City Planning
  • 2. ASSESSING THE H2 POTENTIAL IN THE PT ENERGY SYSTEM [2] (a) Analysis of current and emerging H2 chains (focus on mobility and storage of variable intermittent RES power) (b) Review and update H2 tehnologies in TIMES (c) Simulation, using the TIMES_PT model on the cost-effectiveness of H2 deployment in Portugal in several scenarios, including very high share and variable CO2 mitigation targets (d) Develop a Road map for the development of H2 technologies in the Portuguese energy system till 2050 18 months - first results April 2018
  • 3. H2 HOLISTIC ANALYSIS [3] ERP (2016) | http://erpuk.org/wp- content/uploads/2016/10/ERP- Hydrogen-report-Oct-2016.pdf “Hydrogen has often been criticised for being an inefficient way of using energy, but a system approach should be taken, when comparing it with other options, that takes into account the flexibility of hydrogen and how it can supply multiple markets. Hydrogen should therefore be evaluated on the cost effectiveness of the overall system and its potential environmental impacts, primarily carbon reduction“
  • 4. H2 IN TIMES_PT Older version of TIMES_PT includes approx. 90 H2 technologies (last update 2010) › 15 options for H2 production (gaseification, electrolysis, partial oxidation, thermochemical cycles); › 15 options for H2 conversion and distribution; › 60 options for end-use consumption of H2 for power generation and heat production in buildings, industry and for transport (bus, cars and heavy duty trucks) • Cascade-Mints D1.1 Fuel cell technologies and Hydrogen production/Distribution options, DLR, September 2005; E3 Spain Electrolysis Large Electricity Small Gaseification with CCS Coal w/o CCS Steam Steam reforming Solar Biomass Gaseification Natural Gas Pyrolisis Large Small with CCS Process Kvaerner Partial oxidationHeavy fuel oil SMR CH4 Thermochemical cycles
  • 5. H2 END-USES IN TIMES_PT Residential Space Heating Space cooling Water heating Lighting Cooking Refrigeration Dishwashers Washing machines Clothes dryers Other electric uses Other energy uses Rural houses Urban houses Appartments Services Space Heating Space cooling Water heating Cooking Other electric uses Other energy uses Lighting Refrigeration Public lighting Large services buildings Small services buildings Agriculture Generic use Blending with natural gas
  • 6. H2 END-USES IN TIMES_PT (II) Transport Iron & Steel Outros metais não ferrosos Ammonia Chlorine Other chemical Cement Lime Glass Other non-metallic minerals Pulp and paper Nitric Acid Other industry Graphic Packaging Hollow Flat Industry Passengers Freight BUS urban BUS interurban Cars Motos Road Rail Metro Trains Passenger Freight Heavy duty Light duty Generic Aviation Generic navigation Aluminium Copper Other non- ferrous metals Blending with natural gas
  • 7. UPDATE H2 IN TIMES_PT Older version of TIMES_PT included approx. 90 H2 technologies › 15 options for H2 production (gaseification, electrolysis, parcial oxidation, thermochemical cycles); › 15 options for H2 conversion and distribution; › 60 options for end-use consumption of H2 for power generation and heat production in buildings, industry and for transport (bus, cars and heavy duty trucks) • Cascade-Mints D1.1 Fuel cell technologies and Hydrogen production/Distribution options, DLR, September 2005 • E3 Spain 2016 paper using JRC-EU-TIMES model which includes: › 23 options for generation of H2 (…+PEM); › 24 options for conversion and distribution of H2 / 3 storage and 21 distribution (3 liquid H2); › ?? options for end-use consumption for electricity generation, heat production in buildings, for industry and transport (freight heavy and light duty, buses) + blending with natural gas • Bolat, P., Thiel, C. (2014). Hydrogen supply chain architecture for bottom-up energy systems models. Part 1: Developing pathways. International Journal of Hydrogen Energy (39) 17, pp. 8881-8897. http://www.sciencedirect.com/science/article/pii/S0360319914008684 • Bolat, P., Thiel, C. (2014). Hydrogen supply chain architecture for bottom-up energy systems models. Part 2: Techno-economic inputs for hydrogen production pathways. International Journal of Hydrogen Energy (39) 17, pp. 8898-8925.
  • 8. • Gaseification • Steam reforming • Electrolysis GENERATION • Centralized - underground • Centralized - tank • Decentralized STORAGE •Road: short/long distance; liquified or compressed; refueling stations: LL, LG, GG •Ships (liquified) •Final delivery: road, pipelines or blended with natural gas (6- 15%) DISTRIBUTION •Transport: road for cars and passengers and freight (light/heavy) and rail (?) •Industry: 1st gen biofuels • Buildings (services and residential) • Electricity generation •Agriculture (in gas) END-USE H2 IN TIMES_PT: 1ST APPROACH Slide [8] Main area to improve Main area to improve
  • 9. Gaseificaçãode biomassa Processo Kvaener SteamreformingEletrólise Gaseificaçãodo carvão SCOAH2G101 G A S B F G C O A L I G G A S C O G C O A H A R C O A C O K C O A B R O SUP COA 00 S U P C O A SCOAH2G110 BBLQH2G110 BWOOH2G101 BWOOH2G130 SELCH2G 120 SELCH2G L201 SELCH2G S101 I N D B L Q IPPPUPC HE00 IPPPUPC HE01 IPPPUPC HE05 IPPPUPC HE99 I N D E L C I P P H T H I P P P R C S Y N H 2 G S U P H T H SELCH2G TRA01 T R A G H 2 TCARG H2FCEL C110TCARG H2IC110 TFHGH2 FC110 TFLGH2 FC110 TFLGH2 FCELC1 10TFLGH2 IC110 TBISGH 2FC110TBUSG H2FC11 0TCARG H2FC11 0 T B IT B U T C L T C S T F H T F L RSDHH2R0 1 RSDHH2U0 1 SH2GH2L10 1 SH2GH2L13 0 SH2GH2L20 1 TRAGH230 1 COMHH201 ELCHH20 1 INDHH20 1 TRAGH240 1 SYNH2L TRAGH2101 TRAGH2201 TRALH2101 TRALH2201 SGASCH2 CCS110 SGASH2G 101 SGASH2G 2101 Óleo Combustíve l SGASH2G 301 SHFOH2G 101 SSOLH2G 130 SSOLH2G 20120 Energiasolar S U P G A S S U P E L C S U P H F O R E N S O L T R A L H 2 TCARLH 2IC110 TFLLH2I C110 COMHH 2 CHLEFCHH2610 CHLEFCHH2510 CHLEFCHH2310 CHLEFCHH2410 CSLEFCHH2510 CSLEFCHH2410 CHPCOMFCHH2 110 CHSEFCHH2310 CSLEFCHH2610 C O M H L E CHLEFC 110 C H L E C O M L T H CHSELT H100 CHLELT H199 CHLELT H100 CHLELT H101 CWLELT H199 CWLELT H100 CHSELT H101 CHSELT H199 CWSEL TH100 CWSEL TH199 DUMAF SCOM C W L E C H S E C W S E ELCHH2 EUFCHH201 PUFCHH210 H E T H T H INDHH2 CHPICHFCHH21 10 CHPIGHFCHH21 10 CHPIISFCHH211 0 CHPILMFCHH21 10 CHPINDFCHH21 10 CHPINMFCHH21 10 CHPIOIFCHH211 0 CHPIPPFCHH21 10 CHPREFFCHH21 10 I A L H T H I A M H T H I C U H T H I C H H T H I C L H T H I G F H T H I G H H T H I I S H T H I N F H T H I L M H T H I C M H T H I N M H T H I O I H T H I P P H T H I N D H T H IALFINP R00 I A L i l m IALFINP R01 ICHSTM HTH00 ICHSTM HTH01 ICHSTM HTH99 ICHOTH TH01 I C H S T M ICHDEM AND00 I C H I C H O T HICUORE PRD00 ICUREC PRD00 ICUREC PRD01 ICUSCD PRD01 M C U S C U ICUFINP R00 I C U IISFINP RO01 IISFECR FR00 IISFECR FR01 I I S G A S B F G INFSTM HTH01 I N F S T M INFDEM AND00 I N F ILMQLM PRO00 ILMQLM PRO01 I L M ICMDRY PRD00 ICMDRY PRD01 ICMDRY PRD02 ICMDRY PRD99 ICMDRY PRD10 M C M C L K ICMFINP RO00 ICMFINP RO01 ICMFINP RO05 ICMFINP RO99 I C M INMSTM HTH00 INMSTM HTH01 INMOTH HTH01 INMSTM HTH99 I N M S T M INMDEM AND00 I N M I N M O T H IOIOTH HTH01 I O I O T H IOIDEM AND00 I O I IPPHIG QUA00 IPPHIG QUA01 IPPHIG QUA05 IPPHIG QUA99 IPPLOW QUA00 IPPLOW QUA01 IPPLOW QUA05 IPPLOW QUA99 IPPPUP CHE00 IPPPUP CHE01 IPPPUP CHE05 IPPPUP CHE99 IPPPUP RYC00 IPPPUP RYC01 IPPPUP RYC99 I P H I P L I N D B I O I N D B L Q M P P P U P IOIOTH HTH00 INMOTH HTH00 ICHOTH TH00 INFSTM HTH00 RSDHH 2R CHPRSDFCHH2 310 CHPRSDFCHH2 410 CHPRSDFCHH2 510 CHPRSDFCHH2 610 RHMEFCHH2310 RHMEFCHH2410 RHMEFCHH2510 RHMEFCHH2610 RHMNFCHH2310 RHMNFCHH2410 RHMNFCHH2510 RHMNFCHH2610 RHREFCHH2310 RHREFCHH2410 RHREFCHH2510 RHREFCHH2610 RHRNFCHH2310 RHRNFCHH2410 RHRNFCHH2510 RHRNFCHH2610 RHUEFCHH2310 RHUEFCHH2410 RHUEFCHH2510 RHUEFCHH2610 RHUNFCHH2310 RHUNFCHH2410 RHUNFCHH2510 RHUNFCHH2610 E L C L O W R S D H R E RHREF C110 R H R E R S D H R NR S D H U E R S D H U NR S D H M E R S D H M N RHMNF C110 R H M N RHRNF C110 R H R N RHUEF C110 R H U E RHUNF C110 R H U N RHMEF C110 R H M E RHMEFCHH2710 RHMEFCHH2810 RHMEFCHH2910 RHMNFCHH2710 RHMNFCHH2810 RHMNFCHH2910 RSDHH 2U TRANSPORTS RESIDENTIAL INDUSTRY ServicesSYNH2 CU SYNH2 CT
  • 10. THE RETURN OF H2? • Bolat, P., Thiel, C. (2014). Hydrogen supply chain architecture for bottom-up energy systems models. Part 1: Developing pathways. International Journal of Hydrogen Energy (39) 17, pp. 8881-8897. http://www.sciencedirect.com/science/article/pii/S0360319914008684 • Bolat, P., Thiel, C. (2014). Hydrogen supply chain architecture for bottom-up energy systems models. Part 2: Techno- economic inputs for hydrogen production pathways. International Journal of Hydrogen Energy (39) 17, pp. 8898-8925. https://doi.org/10.1016/j.ijhydene.2014.03.170 • Sgobbi, A. et al (2016). How far away is hydrogen? Its role in the medium and long-term decarbonisation of the European energy system. Int. Journal of Hydrogen Energy (41) 1, pp 19-35. http://www.sciencedirect.com/science/article/pii/S0360319915301889 • IEA (2015) Technology Roadmap, Hydrogen and Fuel Cells. Paris. • Fuel Cell and Hydrogen Joint Undertaking. (2015) Study on H2 from RES in the EU (Final Report) • Fuel Cells and Hydrogen Joint Undertaking Fuel Cell Electric Buses (2015) Potential for Sustainable Public Transport in Europe • Hydrogenics. (2016) Power to Gas Roadmap for Flanders • Hydrogen Council (2017) How hydrogen empowers the energy transition. http://hydrogeneurope.eu/wp- content/uploads/2017/01/20170109-HYDROGEN-COUNCIL-Vision-document-FINAL-HR.pdf • The Energy Research Partnership. (2016) Potential Role of Hydrogen in the UK Energy System • DOE/NREL (2017) Comparison of conventional vs. modular hydrogen refueling stations, and on-site production vs. delivery.
  • 11. H2FIRST: HYDROGEN FUELING INFRASTRUCTURE RESEARCH AND STATION TECHNOLOGY [11] Fuel stations built on site Modular pre- fabricated fuel stations (1-1.5 M USD) H2 delivered as compressed gas from centralised production plant H2 produced locally via SMR H2 produced locally via eletrolysis 100 kg/day (12 GJ/day*) 200 kg/day (24 GJ/day*) 300 kg/day (36 GJ/day*) H2 produced locally via eletrolysis H2 produced locally via eletrolysis * Condered NCV 120 MJ/kg of http://www.h2data.de/ DOE USA Exclude liquid H2 and underground storage
  • 12. UPDATE SUBRES H2 IN TIMES_PT Electrolysis Alkaline (6) Electricity PEM Gaseification with CCS Coal w/o CCS Offgrid (2) Steam reforming Solar Biomass Gaseification Natural Gas Pyrolisis Central CCS Central Decentral. Process Kvaerner Partial oxidationHeavy fuel oil SMR Natural gas Thermochemical cycles Central CCS Central Decentral. electricity SR electricity Natural gas Steam reformingBioethanol electricity
  • 13. BLENDING H2 IN NATURAL GAS? [13] Reference Model/Organisation Year Blending? Sgobbi et al., Int. J. Hydrogen E., 41, 19-35, 2016 JRC-EU-TIMES 2016 Yes, 15% Bolat and Thiel, Part I, Int. J. Hydrogen E., 39, 8898-8925, 2014 JRC, literature review 2014 Yes, 10% (pathway 16) NRC- The Hydrogen Economy US National Research Council – review 2004 No - discussion dedicated gas H2 pipelines IEA – Technology Roadmap, Hydrogen and Fuel Cells IEA 2016 Yes, 5-10% Hydrogen Council - How hydrogen empowers the energy transition H2 Council 2017 Yes, but no value given Klaus Altfeld and Dave Pinchbeck - Admissible hydrogen concentrations in natural gas systems, ISSN 2192-158X DIV Deutscher Industrieverlag GmbH 2013 Looks at this issue in great detail, suggests a likely upper limit of 10% for most cases Potential Role of Hydrogen in the UK Energy System Energy Research Partnership 2016 Up to 20% appears possible without modifications
  • 14. LIQUID H2? [14] Reference Model/Team Year Consider liquid H2? NRC- The Hydrogen Economy US National Research Council – review 2004 yes, but mainly storage and distribution Bolat and Thiel, Part I, Int. J. Hydrogen E., 39, 8898-8925, 2014 JRC, literature review 2014 yes Sgobbi et al., Int. J. Hydrogen E., 41, 19-35, 2016 JRC-EU-TIMES 2016 yes IEA – Technology Roadmap, Hydrogen and Fuel Cells IEA 2016 yes, but mainly storage and distribution Hydrogen Council - How hydrogen empowers the energy transition H2 Council 2017 yes, briefly Potential Role of Hydrogen in the UK Energy System Energy Research Partnership 2016 yes, for distribution Ethan S. Hecht, Joseph Pratt, Comparison of conventional vs. modular hydrogen refueling stations, and on-site production vs. delivery Sandia National Laboratories, study for DOE, USA 2017 yes, for distribution Dodd-Ekins, powertrains for the UK, Int. J. Hydr. E. , 39, 13941-13952, 2014 UK-MARKAL/ UCL 2014 no Ballard – Hydro rail presentation Ballard 2017 no
  • 15. TECHNOLOGY ROADMAP – H2 AND FUEL CELLS [15] IEA > Ortions for Generation (8): alkaline electrolysis , PEM electrolysis, gas SMR, gas SRM with CCS, coal gaseification, biomass gaseification, FC alkaline, FC PEM > Options for Storage (13): PEM alkaline, PEM fixed, PEM FC mobile, FC solid oxides, FC phosporic acid, molten carbonates, compressor at 18 MPa, compressor at 70 Mpa, Liquidifier, FCEV on-board storage tank at 70 Mpa, pressurized tank, liquid storage, pipeline Power to gas Electrolysis PEM Methanation Natural gas grid OCGT Power to power Electrolysis PEM Storag. Und. PEMFC Electrolysis Alkaline Electrolysis PEM OCGTStorag. Und. Storage in pumped hydro CAES
  • 16. H2 IN TIMES_PT: 2ND APPROACH Slide [16] Storage Distribution ConversionEnd-use Generation End-use Generation ConversionEnd-use Generation
  • 17. MODELLING H2 IN TIMES_PT We have been modelling H2 as separate puzzle pieces and may the most cost-effective win It should instead be modelled as pathways
  • 18. PATHWAYS - CENTRALIZED Centralized generation Compression (gas) Dedicated pipelines Dedicated distribution Fuel stations Residential sector with FC for electricity generation Services sector with FC for electricity generation Transport in trucks Fuel stations Undergroun d storage Storage in tanks Conversion Synthetic fuels Electricity generation (VRES) Methanation & blending in natural gas grid Blending 1 2 34
  • 19. PATHWAYS - DECENTRALIZED . Decentralized production In fuel stations Storage in tanks Storage in trucks At the fuel station Industry Electricity generation Storage in tanks Ammonia production Diesel desulfurization Other industry uses 4
  • 20. SOME TOUGHTS › communicating with the H2 world › e.g. costs units in ton H2 or m3 H2 not €/kW; lifetime in operation hours not years › H2 feedstocks are very varied and fundamental to explain why some feedstock are in and some are not › simplify your model – update SubRES based on scenarios to explore › less effort on fossil based generation options › modular H2 supply for transport instead of very detailed representation of all possible distribution options › ignore liquid H2 possibilities for transport › specify format of operation for some technologies considering the specific pathway: lifetime of PEM might not be 3 years depending how it is operated [20]
  • 21. Sofia Simões sgcs@fct.unl.pt Juliana Barbosa jpa.barbosa@campus.fct.unl.pt Luís Fazendeiro l.fazendeiro@campus.fct.unl.pt Júlia Seixas mjs@fct.unl.pt CO2 ENERGY & CLIMATE New Technologies & Low Carbon Practices Climate Mitigation/ Adaptation Consumers Profiles & Energy Efficiency Policy Support Energy Transitions Integrative Energy City Planning