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Unit 2 Synthesis Approaches
of nanomaterial
Introduction
 What are Nanomaterials?
 Materials with at least one dimension between 1–100 nm.
 Size comparison: ~5 silicon atoms or ~10 hydrogen atoms = 1 nanometer.
 Historical Context
 4500 years ago: Asbestos nanofibers reinforced ceramics.
 4000 years ago: Ancient Egyptians used PbS nanoparticles for hair dye.
 4th Century A.D.: Romans crafted the Lycurgus Cup, showcasing color
changes due to Ag and Au nanoparticles.
 Modern Origin
 1914: Term “nanometer” introduced by Richard Adolf Zsigmondy.
 1959: Richard Feynman’s visionary talk "There’s Plenty of Room at the Bottom"
proposed atomic/molecular-level engineering.
A schematic representation of nanomaterials and
their applications.
https://pubs.rsc.org/en/content/articlehtml/2021/ma/d0ma00807a
Approaches for the synthesis of
nanomaterials
DOI: 10.1039/D0MA00807A (Review Article) Mater. Adv., 2021, 2, 1821-1871
Top-down approaches
 In top-down approaches, bulk materials are divided to
produce nanostructured materials.
 Top-down methods include mechanical milling, laser
ablation, etching, sputtering, and electro-explosion.
Mechanical milling
 Mechanical milling is a cost-effective
method for producing materials at the
nanoscale level from bulk materials.
 Mechanical milling is an effective
method for producing blends of
different phases, and it is helpful in the
production of nanocomposites.
Unit 2 Synthesis Approaches of nanomaterial.ppt
Mechanical milling
 Mechanical milling is used to produce oxide- and carbide-
strengthened aluminum alloys, wear-resistant spray coatings,
aluminum/nickel/magnesium/copper-based nanoalloys, and
many other nanocomposite materials.26
 Ball-milled carbon nanomaterials are considered a novel class
of nanomaterial, providing the opportunity to satisfy
environmental remediation, energy storage, and energy
conversion demands.
Electrospinning
 Electrospinning is one of the simplest top-down methods for the
development of nanostructured materials.
 It is generally used to produce nanofibers from a wide variety
of materials, typically polymers.28
 One of the important breakthroughs in electrospinning was
coaxial electrospinning.
 In coaxial electrospinning, the spinneret comprises two coaxial
capillaries.
Electrospinning
 In these capillaries, two viscous liquids, or a viscous liquid as the
shell and a non-viscous liquid as the core, can be used to form
core–shell nanoarchitectures in an electric field.
 Coaxial electrospinning is an effective and simple top-down
approach for achieving core–shell ultrathin fibers on a large
scale.
 The lengths of these ultrathin nanomaterials can be extended
to several centimeters.
 This method has been used for the development of core–shell
and hollow polymer, inorganic, organic, and hybrid materials.

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Unit 2 Synthesis Approaches of nanomaterial.ppt

  • 1. Unit 2 Synthesis Approaches of nanomaterial
  • 2. Introduction  What are Nanomaterials?  Materials with at least one dimension between 1–100 nm.  Size comparison: ~5 silicon atoms or ~10 hydrogen atoms = 1 nanometer.  Historical Context  4500 years ago: Asbestos nanofibers reinforced ceramics.  4000 years ago: Ancient Egyptians used PbS nanoparticles for hair dye.  4th Century A.D.: Romans crafted the Lycurgus Cup, showcasing color changes due to Ag and Au nanoparticles.  Modern Origin  1914: Term “nanometer” introduced by Richard Adolf Zsigmondy.  1959: Richard Feynman’s visionary talk "There’s Plenty of Room at the Bottom" proposed atomic/molecular-level engineering.
  • 3. A schematic representation of nanomaterials and their applications. https://pubs.rsc.org/en/content/articlehtml/2021/ma/d0ma00807a
  • 4. Approaches for the synthesis of nanomaterials DOI: 10.1039/D0MA00807A (Review Article) Mater. Adv., 2021, 2, 1821-1871
  • 5. Top-down approaches  In top-down approaches, bulk materials are divided to produce nanostructured materials.  Top-down methods include mechanical milling, laser ablation, etching, sputtering, and electro-explosion.
  • 6. Mechanical milling  Mechanical milling is a cost-effective method for producing materials at the nanoscale level from bulk materials.  Mechanical milling is an effective method for producing blends of different phases, and it is helpful in the production of nanocomposites.
  • 8. Mechanical milling  Mechanical milling is used to produce oxide- and carbide- strengthened aluminum alloys, wear-resistant spray coatings, aluminum/nickel/magnesium/copper-based nanoalloys, and many other nanocomposite materials.26  Ball-milled carbon nanomaterials are considered a novel class of nanomaterial, providing the opportunity to satisfy environmental remediation, energy storage, and energy conversion demands.
  • 9. Electrospinning  Electrospinning is one of the simplest top-down methods for the development of nanostructured materials.  It is generally used to produce nanofibers from a wide variety of materials, typically polymers.28  One of the important breakthroughs in electrospinning was coaxial electrospinning.  In coaxial electrospinning, the spinneret comprises two coaxial capillaries.
  • 10. Electrospinning  In these capillaries, two viscous liquids, or a viscous liquid as the shell and a non-viscous liquid as the core, can be used to form core–shell nanoarchitectures in an electric field.  Coaxial electrospinning is an effective and simple top-down approach for achieving core–shell ultrathin fibers on a large scale.  The lengths of these ultrathin nanomaterials can be extended to several centimeters.  This method has been used for the development of core–shell and hollow polymer, inorganic, organic, and hybrid materials.