2. Newtonian vs. Non-Newtonian
Fluids
Newtonian fluid: shear stress is
proportional to shear strain
– Slope of line is dynamic
viscosity
Shear thinning: ratio of shear stress
to shear strain decreases as shear
strain increases (toothpaste,
catsup, paint, etc.)
Shear thickening: viscosity increases
with shear rate (glass particles in
water, gypsum-water mixtures).
3. Surface tension
What’s happening here?
– Bug is walking on water
Why is this possible?
– It doesn’t weigh much
– It’s spreading its weight
out
– The downward forces are
less than the effects of
surface tension
4. Surface Tension
• A molecules in the interior of a liquid is under
attractive force in all direction.
• However, a molecule at the surface of a liquid is
acted on by a net inward cohesive force that is
perpendicular to the surface.
• Hence it requires work to move molecules to
the surface against this opposing force and
surface molecules have more energy than
interior ones
• Higher forces of attraction at surface
• Creates a “stretched membrane effect”
5. Surface Tension
Surface tension, σs: the force resulting from molecular
attraction at liquid surface [N/m]
surface tension varies with temperature
Fs= σs L (check your book, pg.21)
Fs= surface tension force [N]
σs = surface tension [N/m]
L = length over which the surface tension acts [m]
6. Capillarity
Rise and fall of liquid in a capillary tube is caused by surface tension.
Capillarity depends on the relative magnitudes of the cohesion of the liquid
to walls of the containing vessel.
When the adhesive forces between liquid and solid are larger than the
liquid's cohesive forces, the meniscus in a small diameter tube will tend to
be concave
If adhesive forces are smaller than cohesive forces the meniscus will tend
to be convex, for example mercury in glass.
water
mercury
concave convex
7. Differences between adhesive &
Cohesive
A distinction is usually made between an adhesive force,
which acts to hold two separate bodies together (or to stick
one body to another)
and
a cohesive force, which acts to hold together the like or
unlike atoms, ions, or molecules of a single body.
8. Vapor Pressure
Vapor pressure: the pressure at which
a liquid will boil.
Vapor pressure ↑ when
temperature increases
At atmospheric pressure,
water at 100 °C will boil
Water can boil at lower
temperatures if the
pressure is lower
When vapor pressure > the
liquid’s actual pressure