SlideShare a Scribd company logo
1
They’re JUST capacitors?
James Lewis
Marketing Director
jameslewis@kemet.com
@baldengineer
2
Different materials make different capacitors
Electrode Plates Dielectric
Basic Capacitor
C = ε0KA(n−1)
d
3
Topic List
• Ceramics
– Why they lose capacitance
• Aluminum
– Why they don’t last forever
• Tantalum
– Why are they are safe to use
• Supercapacitors
– Why they are called super
We need a context…
4
Capacitors should be
voltage derated 50%
True Or False
It Depends…
5
Ceramics
6
Multilayer Ceramic Capacitor (MLCC)
Typical Construction
Ceramic Dielectric
Electrode
(Ni for BME, Ag/Pd for PME)
Termination
(Cu for BME, Ag for PME)
Finish
(Plated Sn)
Barrier Layer
(Plated Ni)
+
-
Capacitances in parallel are additive
CT=C1+C2+C3+….Cn
C = ε0KA(n−1)
d
Max Capacitance is limited by “larger” layers
7
Relative Capacitance vs. Temperature
Temperature Coefficients
C0G (NP0)
Temperature
‘K’Magnitude
X7R
X5R
Z5U
Y5V
‘Room’ Ambient
U2J
8
Voltage Coefficient (Class II and III)
1210 vs 0805, X7R, 10uF, 6.3V
-60%
-50%
-40%
-30%
-20%
-10%
0%
10%
0 1 2 3 4 5 6
CapacitanceChange
Applied DC Bias (VDC)
Capacitance Change vs. DC Bias
Rated 6.3V
How much capacitance do you really get?
1206
0805
9
K-SIM: ESR, Z, SPICE Model, VCC, and S-Parameters
ksim.kemet.com
10
X7R Aging Rate
1.5% per Decade Hour (Limit)
-14
-12
-10
-8
-6
-4
-2
0
2
4
6
8
10
12
14
1 10 100 1,000 10,000 100,000
Time Post Heat
PercentageNominal
Reference
8,777Hr=1Yr
87,770Hr=10Yr
https://ec.kemet.com/aging-calculator-for-ceramics
11
Aluminum Electrolytic
12
Aluminum Electrolytic
Form Factors
Axial/Radial Screw Terminal Snap-In
Single Ended SMD Motor Start
Same construction different form factors
13
Cathode
Plate
Electrolyte
Aluminum Untreated Surface Area
Anode
Plate
C1 C2
If C2 >> C1,
then Ct ~ C1
d
A
C r 0εε
=
0ε
( ) 932 =OAlrε
14
d
A
C r 0εε
=
Electrolyte
Anode
Plate
Aluminum Acid-Etched Surface Area
C1 C2
C2 must remain >> C1
Cathode
Plate
0ε
15
Anode Foil
Etched Surface
16
Aluminum
Anode
VFormation > VRating > Vapplication
Wet
Electrolyte
Reformed dielectric region Dielectric
Depletion
O-2
O-2
Reform
Reforming / Self-Healing Wet Aluminum
Electrolyte
“Cathode”
Dielectric
Voltage contributes to operational lifetime
17
Tantalum
18
All Tantalums explode… or do they?
MnO2 MnO2 MnO2 MnO2 MnO2
Poly Poly Poly Poly Poly
2x Rated Voltage,
applied with reverse polarity and
>20 amps of current.
18
Every capacitor on this board failed as “short”
19
• Stable C (No Temp or Bias Effects), DCL (t)
• Reliable (Decreasing FR)
• Long Life (Exceeds Expected Life of All Hardware)
• Most Volumetrically Efficient (CV/cc, E/cc)
Military
Space
Medical
Automotive
Computers
Telecom
Ta
Ta2O5
SEM of a Sintered Ta Anode
Ta
Why use Tantalum?
Ta Oxide Dielectric
20
Polymer Electrolytic:
A “new” kind of capacitor
22
Difference in Self-Healing
“Traditional”
MnO2
New
Polymer
Current through fault
generates enough heat
and oxygen for ignition.
Conductive polymer
consumes oxygen
preventing ignition.
Tantalum Crack
Impurity
Ta Polymer
Polymer
oxidized
Ta2O5
Crack
Impurity
Ta MnO2
Mn2O3
Ta2O5
If a polymer fails, it fails safely.
23
Tantalum Voltage Derating
Depend on cathode material
• Typical derating guidelines:
• Tantalum MnO2: 50%
• Tantalum Polymer: 20%(>10V), 10% (≤10V)
• Aluminum Polymer: 0%!
35
12
4
0
126%
Ta-Poly KO
VR>10VDC
6,310
@100% VRated
FR(PPM)
1,700
@90% VRated
FR(PPM)
458
@80% VRated
FR(PPM)
9
@50% VRated
FR(PPM)
0
0
0
0
235%
8
2
1
0
197%68%
100 PPM FR
% VRated
Alum-Poly AO
Ta-Poly KO
VR≤10VDC
Ta-MnO2
24
Supercapacitors
25
What Is A “Super” Capacitor?
APowerCap
BestCap
BoostCap
CAP-XX
DLCAP
EneCapTen
EVerCAP
DynaCap
Faradcap
GreenCap
Goldcap
HY-CAP
Super capacitor
SuperCap
AS Capacitor
PowerStor
PseudoCap
Ultracapacitor
Electrostatic Double-Layer Capacitor (EDLC)
26
(Electrical) Double Layers
1. IHP Inner Helmholtz Layer
2. OHP Outer Helmholtz Layer
3. Diffuse layer
4. Solvated ions
5. Specifically adsorptive ions
6. Solvent molecule
27
Traditional and EDLC
Comparison
Aluminium Reference
+
+
+
+
+
+
+
-
-
-
-
-
-
-
AlAl2O3
Dielectric
Al
+
+
+
+
+
+
+
-
-
-
-
-
-
-
C =
Q
V
-
-
-
-
-
-
-
+
+
+
+
+
+
+
Battery
Electrode
Solvent
Molecule
(~0.3 to 2 nm)
C
Symmetric
“Supercapacitor”
+
+
+
+
+
+
+
-
-
-
-
-
-
-
C
Separator
+
+
+
+
+
+
+
-
-
-
-
-
-
-
Asymmetric
“Hybrid Capacitor”
C
Separator
C =
ε0KA
d
Surface area of carbon
Inner Helmholtz Layer
28
Electrolytes
Acetonitrile
– CH3CN
– Common for SC
– Dielectric constant:
37
– Burns to HCN
– BP: ~80°C
Propylene
Carbonate (PC)
– C4H6O3
– Dielectric constant:
64
– Destructive effect
on graphite
– BP: ~240°C
Sulfuric Acid
– H2SO4
– Used in lead-acid
batteries
– Dielectric constant:
~100
– BP: 337°C
29
Tools
30
Mobile Catalog Apps
Access to over 350 catalogs and 4.8MM data
sheets
www.kemet.com/mobileapps
31
ksim.kemet.com
32
www.engineeringcenter.com
33
james@baldengineer.com
email | www | twitter
www.baldengineer.com & www.addohms.com
34
Capacitors should be
voltage derated 50%
True Or False
It Depends…
35
Summary
• Ceramic
– More capacitance
• Aluminum Electrolytic
– Longer operational life
• Tantalum
– Power-On Reliability
• Supercapacitors
– Operational Life
Why do you voltage de-rate a capacitor?
Slides: www.baldengineer.com/hddg11
36
Thank You!

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Hardware Developers Didactic Galactic 0xb: Capacitors

  • 1. 1 They’re JUST capacitors? James Lewis Marketing Director jameslewis@kemet.com @baldengineer
  • 2. 2 Different materials make different capacitors Electrode Plates Dielectric Basic Capacitor C = ε0KA(n−1) d
  • 3. 3 Topic List • Ceramics – Why they lose capacitance • Aluminum – Why they don’t last forever • Tantalum – Why are they are safe to use • Supercapacitors – Why they are called super We need a context…
  • 4. 4 Capacitors should be voltage derated 50% True Or False It Depends…
  • 6. 6 Multilayer Ceramic Capacitor (MLCC) Typical Construction Ceramic Dielectric Electrode (Ni for BME, Ag/Pd for PME) Termination (Cu for BME, Ag for PME) Finish (Plated Sn) Barrier Layer (Plated Ni) + - Capacitances in parallel are additive CT=C1+C2+C3+….Cn C = ε0KA(n−1) d Max Capacitance is limited by “larger” layers
  • 7. 7 Relative Capacitance vs. Temperature Temperature Coefficients C0G (NP0) Temperature ‘K’Magnitude X7R X5R Z5U Y5V ‘Room’ Ambient U2J
  • 8. 8 Voltage Coefficient (Class II and III) 1210 vs 0805, X7R, 10uF, 6.3V -60% -50% -40% -30% -20% -10% 0% 10% 0 1 2 3 4 5 6 CapacitanceChange Applied DC Bias (VDC) Capacitance Change vs. DC Bias Rated 6.3V How much capacitance do you really get? 1206 0805
  • 9. 9 K-SIM: ESR, Z, SPICE Model, VCC, and S-Parameters ksim.kemet.com
  • 10. 10 X7R Aging Rate 1.5% per Decade Hour (Limit) -14 -12 -10 -8 -6 -4 -2 0 2 4 6 8 10 12 14 1 10 100 1,000 10,000 100,000 Time Post Heat PercentageNominal Reference 8,777Hr=1Yr 87,770Hr=10Yr https://ec.kemet.com/aging-calculator-for-ceramics
  • 12. 12 Aluminum Electrolytic Form Factors Axial/Radial Screw Terminal Snap-In Single Ended SMD Motor Start Same construction different form factors
  • 13. 13 Cathode Plate Electrolyte Aluminum Untreated Surface Area Anode Plate C1 C2 If C2 >> C1, then Ct ~ C1 d A C r 0εε = 0ε ( ) 932 =OAlrε
  • 14. 14 d A C r 0εε = Electrolyte Anode Plate Aluminum Acid-Etched Surface Area C1 C2 C2 must remain >> C1 Cathode Plate 0ε
  • 16. 16 Aluminum Anode VFormation > VRating > Vapplication Wet Electrolyte Reformed dielectric region Dielectric Depletion O-2 O-2 Reform Reforming / Self-Healing Wet Aluminum Electrolyte “Cathode” Dielectric Voltage contributes to operational lifetime
  • 18. 18 All Tantalums explode… or do they? MnO2 MnO2 MnO2 MnO2 MnO2 Poly Poly Poly Poly Poly 2x Rated Voltage, applied with reverse polarity and >20 amps of current. 18 Every capacitor on this board failed as “short”
  • 19. 19 • Stable C (No Temp or Bias Effects), DCL (t) • Reliable (Decreasing FR) • Long Life (Exceeds Expected Life of All Hardware) • Most Volumetrically Efficient (CV/cc, E/cc) Military Space Medical Automotive Computers Telecom Ta Ta2O5 SEM of a Sintered Ta Anode Ta Why use Tantalum? Ta Oxide Dielectric
  • 21. 22 Difference in Self-Healing “Traditional” MnO2 New Polymer Current through fault generates enough heat and oxygen for ignition. Conductive polymer consumes oxygen preventing ignition. Tantalum Crack Impurity Ta Polymer Polymer oxidized Ta2O5 Crack Impurity Ta MnO2 Mn2O3 Ta2O5 If a polymer fails, it fails safely.
  • 22. 23 Tantalum Voltage Derating Depend on cathode material • Typical derating guidelines: • Tantalum MnO2: 50% • Tantalum Polymer: 20%(>10V), 10% (≤10V) • Aluminum Polymer: 0%! 35 12 4 0 126% Ta-Poly KO VR>10VDC 6,310 @100% VRated FR(PPM) 1,700 @90% VRated FR(PPM) 458 @80% VRated FR(PPM) 9 @50% VRated FR(PPM) 0 0 0 0 235% 8 2 1 0 197%68% 100 PPM FR % VRated Alum-Poly AO Ta-Poly KO VR≤10VDC Ta-MnO2
  • 24. 25 What Is A “Super” Capacitor? APowerCap BestCap BoostCap CAP-XX DLCAP EneCapTen EVerCAP DynaCap Faradcap GreenCap Goldcap HY-CAP Super capacitor SuperCap AS Capacitor PowerStor PseudoCap Ultracapacitor Electrostatic Double-Layer Capacitor (EDLC)
  • 25. 26 (Electrical) Double Layers 1. IHP Inner Helmholtz Layer 2. OHP Outer Helmholtz Layer 3. Diffuse layer 4. Solvated ions 5. Specifically adsorptive ions 6. Solvent molecule
  • 26. 27 Traditional and EDLC Comparison Aluminium Reference + + + + + + + - - - - - - - AlAl2O3 Dielectric Al + + + + + + + - - - - - - - C = Q V - - - - - - - + + + + + + + Battery Electrode Solvent Molecule (~0.3 to 2 nm) C Symmetric “Supercapacitor” + + + + + + + - - - - - - - C Separator + + + + + + + - - - - - - - Asymmetric “Hybrid Capacitor” C Separator C = ε0KA d Surface area of carbon Inner Helmholtz Layer
  • 27. 28 Electrolytes Acetonitrile – CH3CN – Common for SC – Dielectric constant: 37 – Burns to HCN – BP: ~80°C Propylene Carbonate (PC) – C4H6O3 – Dielectric constant: 64 – Destructive effect on graphite – BP: ~240°C Sulfuric Acid – H2SO4 – Used in lead-acid batteries – Dielectric constant: ~100 – BP: 337°C
  • 29. 30 Mobile Catalog Apps Access to over 350 catalogs and 4.8MM data sheets www.kemet.com/mobileapps
  • 32. 33 james@baldengineer.com email | www | twitter www.baldengineer.com & www.addohms.com
  • 33. 34 Capacitors should be voltage derated 50% True Or False It Depends…
  • 34. 35 Summary • Ceramic – More capacitance • Aluminum Electrolytic – Longer operational life • Tantalum – Power-On Reliability • Supercapacitors – Operational Life Why do you voltage de-rate a capacitor? Slides: www.baldengineer.com/hddg11