IRJET-Polyaniline-TIO2 Nanocomposite Formation and Characterization

International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 04 Issue: 06 | June -2017 www.irjet.net p-ISSN: 2395-0072
© 2017, IRJET | Impact Factor value: 5.181 | ISO 9001:2008 Certified Journal | Page 3271
POLYANILINE-TiO2 NANOCOMPOSITE FORMATION AND
CHARACTERIZATION
Varsha Bhatkhande 1, Madhuri Samel2, Smita A.Bhatavadekar3
1 Former Lecturer FC Rodrigues Polytechnics Vashi -Maharashtra, India.
2 Assistant Professor Lokmanya Tilak College of Engineering Koparkhairane- Maharashtra, India
3 Assistant Professor Lokmanya Tilak college of Engineering,Koparkhairane-Maharashtra,India.
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Abstract -Aniline and Titanium dioxide (TiO2) were polymerized into textiles by inverted emulsion polymerization method.
Aqueous mixture of Aniline, a free radical oxidant and TiO2 nanoparticles are utilized to synthesize the hybrid
nanocomposites.FTIR and XRD analysis were used to confirm the formation of nanocomposites.
Key Words: Aniline, TiO2 nanoparticles;
1. INTRODUCTION
The emerging field of electro textiles can be viewed as an integration of technologies of materials, electronics and textiles in
order to create a new generation of flexible/ comfortable small or large multifunctional textile structure with electronics
capabilities. The reason is that apart from exhibiting properties like anti flammability, antistatic,creaseresistantandhygienic,
these materials also act as ‘smart’ or ‘intelligent’ textiles.[1-3]
Thiscan be the first step towards development of flexiblebattery construction usingconductingpolymerTiO2Nanocomposite.
In the present investigation an attempt has been made to incorporate organic conducting polymer such as PANi along with
inorganic TiO2 nanoparticlesinto textile matrix suchas that of cotton.[4,5]Organicpolymerssuchasconductingpolymershave
been shown to be excellent hosts for trapping nano particles of metals and semiconductors because of their ability to act as
stabilizers or surface capping agents.[6-7]
2. Material and Methods:
Aniline, Conc. HCl, Ammonium per sulphate (APS) all of A.R. Grade were obtained from S.D. fine chemicals ltd. India.
Titania nanopwder, Cetyl Trimethyl Ammonium Bromide (CTAB), Chloroform were obtained from Aldrich as Reagent
grade. Aniline was distilled twice before use. Cotton was obtained from piyush syndicate, India. The IR, ATR absorption
spectra of various samples were recorded in the range 500- 4000 cm-1 using a Perkin –Elmer FTIR spectrometer model
paragon 500.
HAV
Result and Discussion:
FTIR:
Since the samples were dark green in color Attenuated Total Reflection (ATR)
Fourier transform IR were recorded instead of FTIR.. In the PANi spectrum it is in correlation with previouslyreportedresults
[8]. The bands at 1496 cm-1 shows the characteristic C=C stretching of the quinoid and benzoid rings.Thepeak atstretchingof
the secondary aromatic amine and a C-H out of plane bending vibrations respectively. The above observations indicate the
formation of PANi in our sample i.e. inside the textile matrix. Fig.1 indicates that all characteristic bands of PANi are present
between 750-1500 cm-1 and these are all found in PANi-TiO2 nanocomposites. The relative intensity of some bands has
changed due to the presence of TiO2 nanoparticles. The presence of TiO2 nanoparticles led to the shift of some peaks in the
PANi macromolecules for e.g., the peaks at 1496, 890, 815 cm-1 shift to 1489.46, 880.70 and 812 cm-1 respectively. Because
Titanium is a transition meal, it has intense tendency to form co-ordination compound with nitrogen atom in PANi
Macromolecule. This interaction may weaken the bond strength of C=N, C=C & C-N in PANi
Macromolecule. This result confirm the presence of PANi and TiO2 in nanocomposites

Fig.1 Cotton +PANi Fig.2 Cotton+PANi+TiO2 Fig.3 Pure Cotton
In the PANi spectrum it is in correlation with previously reported results [8]. The bands at 1496 cm-1 showsthecharacteristic
C=C stretching of the quinoid and benzoid rings.The peak at stretching of the secondary aromatic amine anda C-Houtofplane
bending vibrations respectively. The above observations indicate the formation of PANi in our sample i.e. inside the textile
matrix. Fig.1 indicates that all characteristic bandsofPANiarepresent between750-1500cm-1andtheseareall foundinPANi-
TiO2 nanocomposites. The relative intensity of some bands has changed due to the presence of TiO2 nanoparticles. The
presence of TiO2 nanoparticles led to the shift of some peaks in the PANi macromolecules for e.g., the peaks at 1496, 890, 815
cm-1 shift to 1489.46, 880.70 and 812 cm-1 respectively. Because Titanium isa transitionmeal,ithasintensetendencytoform
co-ordination compound with nitrogen atom in PANi macromolecule. This interaction may weaken the bond strength of C=N,
C=C & C-N in PANi macromolecule. This result confirm the presence of PANi and TiO2 in nanocomposites.
XRD Analysis:
The peaks of cotton appearing at 2è=15º,23º slightly shifts in position at 15º and 18º respectively. The corresponding26º and
28º in pure TiO2 spectra in fig.5 they shift to 25.8º and 2è=28 remains at the same position with decrease in intensity and few
other peaks of TiO2 2è= 48º,55º are also appeared in the samples with diminished intensity. However the calculation of %
crystallinity showed that decrease of about 5%. The presence of PANi has only added to the general
Fig.5 Cotton+PANi+TiO2 Fig4: Pure TiO2

Fig.6 XRD of Pure cotton
Scattering backgrounds. The shifts with diminished intensity may beattributedto thepresenceofTiO2inthecotton matrix.As
per the nucleation and growth theory it is known that the TiO2 nanoparticles are intrinsically produced in the initial stage of
polymerization of PANi [7,12]. As a result the formation of PANi -TiO2 nanocomposites should be the effect of free aniline
cation radicals adsorb on the surface of TiO2 nanoparticlesgrowingtogether bytheinverted emulsionpolymerizationmethod.
Thus PANi and TiO2 together get impregnated in to the matrix of cotton.
REFERENCES
1. Malhotra BD(2002) Handbook of Polymers in Electronics Rapra Technology Ltd, UKa
2. Nalwa, H.S.,; ed. Handbook of Organic and conductive Molecules and Polymers, Vol-1-4; John wiley: New York, 1997
3. Bajaj, P. Indian J. Fibre Text Res 2001, 26, 162
4. Scrosati B(1993) Application of electroactive polymers, Chapman and Hall London.
5. Gupta, S., Ed. Smart Textiles- Their production and markeing strategies; NIFT: New Delhi,2000
6.X.W.Li,etal Appl. Surf. Sci., 217,16(2003)
7. Desai, etalIn Proc. Of the International conf. on High Performance Textiles and Apparels, Kumarguru college of Technology,
Coimbatore, India, July 2004; P. 475
8. E. M. Genies, etal , Polyaniline: a historical survey, synth. Met. 36(2), P.139 ,1990
9. F.Trinidad, etal J. Electrochem. Soc. 138,1991, P 31863
10. M. Malta, etal electrochem, Commun., 5, 1011 (2003) .
11. L.J.Zang, M.X.wang, J. Phys. Chem. 107( 2003), 6748
12. E. M. Genies, etal , Polyaniline: a historical survey, synth. Met. 36(2), P.139 ,1990

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