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Lecture 6 biogeochemical cycles
Lecture 6 biogeochemical cycles
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Lecture 6 biogeochemical cycles
Ecosystem Pool                   Turnover Time
                        =                                 =
                   Coffee Cup                      Time it takes
                                                   for all coffee
                                                  molecules in
                 Residence Time                      cup to be
                         =                        replaced with
                 Average time that                  new coffee
                   one coffee
                 molecule spends
                    inside cup


                                      “sink”
Steady State                  Non-Steady State         Non-Steady State
input = output                   input > output                input < output
Lecture 6 biogeochemical cycles
%, percent of Earth’s water
y, years
d, days
Video Everglades, coral reef, restoration, agriculture, irrigation:
http://video.nationalgeographic.com/video/player/environment/going-green-
environment/conservation-in-action/everglades.html
photosynthesis
                           produces O2
•


•        Oxidation of Earth’s Minerals
    e.g., oxidation of iron (rust) –
    transfer of electrons from Fe2+ to O2
•   4 Fe2+ + O2     4 Fe3+ + 2 O2




•
3.7 x 107



                              8400


                                                                8384



                                                    2.4 x 105

                                  16                    16


Units are                                            16 x 108
1012 moles O2 / year

By far the largest reservoir of Earth's oxygen is within the silicate and oxide minerals
of the Earth’s crust and mantle (99.5%). Only a small portion has been released as
free molecular O2 to the biosphere (0.01%) and atmosphere (0.5%).
Walker, J. C. G. (1980) The oxygen cycle in the natural environment and the biogeochemical cycles,
Springer-Verlag, Berlin.




             16,000,000,000,000,000 Biosphere
          1,400,000,000,000,000,000 Atmosphere
        290,000,000,000,000,000,000 Lithosphere (Geosphere)
Annual gains and losses of atmospheric oxygen (1010 kg O2 per year)

  Gains
  Photosynthesis (land)               16,500
  Photosynthesis (ocean)              13,500
  Photolysis of N2O                        1.3
  Photolysis of H2O                        0.03
                                                  Total Gains    ~ 30,000

  Losses - Respiration and Decay
  Aerobic Respiration            23,000
  Microbial Oxidation                  5,100
  Combustion of Fossil Fuel            1,200
  Photochemical Oxidation           600
  Fixation of N2 by Lightning              12
  Fixation of N2 by Industry          10
  Oxidation of Volcanic Gases               5

  Losses - Weathering
  Chemical Weathering                     50
  Surface Reaction of O3                  12
                                                  Total Losses   ~ 30,000
Video, Antarctica ecosystems (research on seals and whales):
http://www.pbs.org/wnet/nature/episodes/under-antarctic-ice/video-full-
episode/1430/
Lecture 6 biogeochemical cycles
Lecture 6 biogeochemical cycles
Lecture 6 biogeochemical cycles
Lecture 6 biogeochemical cycles
Cutting Cows’ Greenhouse Gas Emissions:
http://video.nationalgeographic.com/video/player/news/environment-
news/uk-cowgas-apvin.html
Lecture 6 biogeochemical cycles
Lecture 6 biogeochemical cycles
Lecture 6 biogeochemical cycles

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Lecture 6 biogeochemical cycles

  • 3. • • • • • • • • • •
  • 5. Ecosystem Pool Turnover Time = = Coffee Cup Time it takes for all coffee molecules in Residence Time cup to be = replaced with Average time that new coffee one coffee molecule spends inside cup “sink” Steady State Non-Steady State Non-Steady State input = output input > output input < output
  • 7. %, percent of Earth’s water y, years d, days
  • 8. Video Everglades, coral reef, restoration, agriculture, irrigation: http://video.nationalgeographic.com/video/player/environment/going-green- environment/conservation-in-action/everglades.html
  • 9. photosynthesis produces O2 • • Oxidation of Earth’s Minerals e.g., oxidation of iron (rust) – transfer of electrons from Fe2+ to O2 • 4 Fe2+ + O2 4 Fe3+ + 2 O2 •
  • 10. 3.7 x 107 8400 8384 2.4 x 105 16 16 Units are 16 x 108 1012 moles O2 / year By far the largest reservoir of Earth's oxygen is within the silicate and oxide minerals of the Earth’s crust and mantle (99.5%). Only a small portion has been released as free molecular O2 to the biosphere (0.01%) and atmosphere (0.5%).
  • 11. Walker, J. C. G. (1980) The oxygen cycle in the natural environment and the biogeochemical cycles, Springer-Verlag, Berlin. 16,000,000,000,000,000 Biosphere 1,400,000,000,000,000,000 Atmosphere 290,000,000,000,000,000,000 Lithosphere (Geosphere)
  • 12. Annual gains and losses of atmospheric oxygen (1010 kg O2 per year) Gains Photosynthesis (land) 16,500 Photosynthesis (ocean) 13,500 Photolysis of N2O 1.3 Photolysis of H2O 0.03 Total Gains ~ 30,000 Losses - Respiration and Decay Aerobic Respiration 23,000 Microbial Oxidation 5,100 Combustion of Fossil Fuel 1,200 Photochemical Oxidation 600 Fixation of N2 by Lightning 12 Fixation of N2 by Industry 10 Oxidation of Volcanic Gases 5 Losses - Weathering Chemical Weathering 50 Surface Reaction of O3 12 Total Losses ~ 30,000
  • 13. Video, Antarctica ecosystems (research on seals and whales): http://www.pbs.org/wnet/nature/episodes/under-antarctic-ice/video-full- episode/1430/
  • 18. Cutting Cows’ Greenhouse Gas Emissions: http://video.nationalgeographic.com/video/player/news/environment- news/uk-cowgas-apvin.html