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Lesson electron
Lesson electron
Lesson electron
Lesson electron
Lesson electron
Lesson electron
Lesson electron
• Principal Quantum Number, n
• Azimuthal Quantum Number, l
• Magnetic Quantum Number, ml
Exercise
• What are the similarities and differences
between the hydrogen atom 1s and 2s
orbitals?
• For n=4 what are the possible values of l and
m?
• give the values for n, l, m for
a. 2p
b. 5d
c. 5f
Main
Energy
Level
No. of
Sublevel
Identity of
Sublevels
No. of
Orbitals
(n2)
Max. No. of
Electrons
(2n2)
1 1 1s 1 2
2 2
2s
2p
1
3
2
6
3 3
3s
3p
3d
1
3
5
2
6
10
4 4
4s
4p
4d
4f
1
3
5
7
2
6
10
14
Lesson electron
Lesson electron
Electron Spin Quantum Number, m
• Two possible values are allowed
+ ½ and - ½
• Opposite directions
Can two electrons in an atom have the
same set of quantum numbers?
Pauli Exclusion Principle
• No two electrons in an atom can have the
same set of four quantum numbers, n, l, ml,
and ms.
• An orbital can hold a maximum of two
electrons and they must have opposite spins.
Electron Configuration
• The way in which electrons are distributed
among the various orbitals of an atom
Aufbau Principle
• Electrons occupy orbitals of lower energy first.
Lesson electron
The relation between orbital filling and the periodic
table
The relation between orbital filling and the periodic
table
Lesson electron
Hund’s Rule
• For degenerate orbitals, the lowest energy is
attained when the number of electrons with
the same spin is maximized.
Orbital Diagram
Lesson electron
Lesson electron
Lesson electron
Anomalous Electron Configuration
Example:
Chromium
Copper
• Consequence of the closeness of the 3d and
4s orbital energies.
• Minor departures from the expected
• Not of great chemical significance
Seat work
Write the electron configuration and the
electron orbital diagram for the following
elements.
1. Cl
2. Os
3. Cs

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Lesson electron