The paper reviews advanced digital modulation and multiplexing techniques used in optical fiber communication to achieve data rates exceeding 400 Gb/s, focusing on maximizing spectral efficiency. It presents a comparative analysis of various digital modulation formats, multiplexing techniques, and their performance metrics through tabular and 3D graphical representations. The analysis includes techniques such as Wavelength Division Multiplexing (WDM), Orthogonal Frequency Division Multiplexing (OFDM), and several digital modulation formats, highlighting their suitability concerning parameters like Bit Error Rate and spectral efficiency.