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Polysaccharides
Mrs. R.Subha, M.Sc., M.Phil., D.C.T.,
Assistant Professor of Home Science
Introduction
• Polysaccharides also play important roles in our
lives.
• Starch is the most common type of complex
carbohydrate which is present in the food we
consume.
• They are complex carbohydrates formed with a
chain of monosaccharides.
• The bonds that keep the chain together are
glycosidic.
• Some common Polysaccharides examples are
starch, glycogen, and cellulose.
• Polysaccharides can also be defined as the
long polymers of carbohydrates that are made
up of repeating mono- or di-saccharide units
joined by glycosidic connections (e.g., glucose,
fructose, galactose).
• They might be linear or very branching in
structure.
• Storage Polysaccharides like starch and
glycogen, as well as structural Polysaccharides
like cellulose and chitin, are just a few
examples.
• More than 10 monosaccharide units make up
a Polysaccharide.
Characteristics of Polysaccharides
• They are not sweet in taste.
• Many are insoluble in water.
• They are hydrophobic in nature.
• They do not form crystals on desiccation.
• Can be extracted to form a white powder.
• They are high molecular weight carbohydrates.
• Inside the cells, they are compact and osmotically
inactive.
• They consist of hydrogen, carbon, and oxygen.
• The hydrogen to oxygen ratio being 2:1.
Important Polysaccharides
1.Starch
• It occurs in cereal grains, pulses, tubers, fruits etc.
• It is the major source of energy in diet of man.
• Starch is a polymer of glucose.
• Starch is a mixture of two substances, about 25%
amylose (straight-chain polymer) and 75%
amylopectin (branched chain polymer). Because of
the structural differences between amylose and
amylopectin, they exhibit different properties.
• Amylose contributes to gel-formation while
Amylopectin is responsible for thickness properties
of foods containing starch.
• Amylose & Amylopectin chains in granules – semi-
crystalline structure – retards their digestion by
pancreatic amylase
Starch classification
• Starch has been classified as
• rapidly digestible starch
• slowly digestible starch
• resistant starch
( depending upon its digestion profile)
Rapidly Digestible Starch
Slowly Digestible Starch
Resistant starch
• Starch and Starch degradation products escapes digestion
in small intestine & available for fermentation by
microflora in large intestine.
• The body cannot easily digest this form of starch, and it
can pass through the digestive system untouched, similar
to dietary fiber.
• It may support healthy intestinal microflora.
RS1 - physically inaccessible starch exists in grains, seeds, and
beans & in processed starchy foods ex. Pasta.
RS2 - Starch that escapes digestion in Small Intestine because of
ungelatinised granules in raw potatoes and unripe bananas
highly resistant to hydrolysis by pancreatic amylase.
RS3 - retrograded amylose formed during cooling of gelatinized
starch (foods that undergo cooking then cooling)such as rice
and cornflakes.
RS4 – produced by modifying the starch to introduce chemical
bonds that leave starch not readily digested - chemically
modified starches is bread.
2. Dextrins
• Degradation products of starch in which
polymers broken down to smaller units by
partial hydrolysis
• Main source of CHO in proprietary preparation
– used as oral supplements for tube feeding.
• Liquid glucose – mixture of dextrins, maltose,
glucose and water – used in products easily
assimilated form to patients who are seriously
ill.
• They are larger molecules than
sucrose/glucose & have less osmotic effect.
Nonstarch polysaccharides (NSPs)
• occur naturally in many foods.
• The physiochemical and biological properties
of these compounds correspond to dietary
fiber.
• Ex. Arabinose, Xylose, Mannose, Galactose,
Glucose and Uronic acids
Reference
• Srilakshmi B.(2022). Nutrition Science. 7th
Edition. New Age International (P) Ltd.,
• http://ecoursesonline.iasri.res.in/mod/page/vi
ew.php?id=90238
• https://byjus.com/biology/polysaccharides/
• https://www.vedantu.com/chemistry/polysac
charides

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Polysaccharides.ppt

  • 1. Polysaccharides Mrs. R.Subha, M.Sc., M.Phil., D.C.T., Assistant Professor of Home Science
  • 2. Introduction • Polysaccharides also play important roles in our lives. • Starch is the most common type of complex carbohydrate which is present in the food we consume. • They are complex carbohydrates formed with a chain of monosaccharides. • The bonds that keep the chain together are glycosidic. • Some common Polysaccharides examples are starch, glycogen, and cellulose.
  • 3. • Polysaccharides can also be defined as the long polymers of carbohydrates that are made up of repeating mono- or di-saccharide units joined by glycosidic connections (e.g., glucose, fructose, galactose). • They might be linear or very branching in structure. • Storage Polysaccharides like starch and glycogen, as well as structural Polysaccharides like cellulose and chitin, are just a few examples. • More than 10 monosaccharide units make up a Polysaccharide.
  • 4. Characteristics of Polysaccharides • They are not sweet in taste. • Many are insoluble in water. • They are hydrophobic in nature. • They do not form crystals on desiccation. • Can be extracted to form a white powder. • They are high molecular weight carbohydrates. • Inside the cells, they are compact and osmotically inactive. • They consist of hydrogen, carbon, and oxygen. • The hydrogen to oxygen ratio being 2:1.
  • 6. 1.Starch • It occurs in cereal grains, pulses, tubers, fruits etc. • It is the major source of energy in diet of man. • Starch is a polymer of glucose. • Starch is a mixture of two substances, about 25% amylose (straight-chain polymer) and 75% amylopectin (branched chain polymer). Because of the structural differences between amylose and amylopectin, they exhibit different properties. • Amylose contributes to gel-formation while Amylopectin is responsible for thickness properties of foods containing starch. • Amylose & Amylopectin chains in granules – semi- crystalline structure – retards their digestion by pancreatic amylase
  • 7. Starch classification • Starch has been classified as • rapidly digestible starch • slowly digestible starch • resistant starch ( depending upon its digestion profile)
  • 10. Resistant starch • Starch and Starch degradation products escapes digestion in small intestine & available for fermentation by microflora in large intestine. • The body cannot easily digest this form of starch, and it can pass through the digestive system untouched, similar to dietary fiber. • It may support healthy intestinal microflora. RS1 - physically inaccessible starch exists in grains, seeds, and beans & in processed starchy foods ex. Pasta. RS2 - Starch that escapes digestion in Small Intestine because of ungelatinised granules in raw potatoes and unripe bananas highly resistant to hydrolysis by pancreatic amylase. RS3 - retrograded amylose formed during cooling of gelatinized starch (foods that undergo cooking then cooling)such as rice and cornflakes. RS4 – produced by modifying the starch to introduce chemical bonds that leave starch not readily digested - chemically modified starches is bread.
  • 11. 2. Dextrins • Degradation products of starch in which polymers broken down to smaller units by partial hydrolysis • Main source of CHO in proprietary preparation – used as oral supplements for tube feeding. • Liquid glucose – mixture of dextrins, maltose, glucose and water – used in products easily assimilated form to patients who are seriously ill. • They are larger molecules than sucrose/glucose & have less osmotic effect.
  • 12. Nonstarch polysaccharides (NSPs) • occur naturally in many foods. • The physiochemical and biological properties of these compounds correspond to dietary fiber. • Ex. Arabinose, Xylose, Mannose, Galactose, Glucose and Uronic acids
  • 13. Reference • Srilakshmi B.(2022). Nutrition Science. 7th Edition. New Age International (P) Ltd., • http://ecoursesonline.iasri.res.in/mod/page/vi ew.php?id=90238 • https://byjus.com/biology/polysaccharides/ • https://www.vedantu.com/chemistry/polysac charides